Volume 126
Main Index

Issue 01

Design of a Synthetic Foldamer that Modifies the Growth of Calcite Crystals Lara A. Estroff, Christopher D. Incarvito, and Andrew D. Hamilton pp 2–3 DOI: 10.1021/ja037614z Supporting Info

High Affinity, Paralog-Specific Recognition of the Mena EVH1 Domain by a Miniature Protein Dasantila Golemi-Kotra, Rachel Mahaffy, Matthew J. Footer, Jennifer H. Holtzman, Thomas D. Pollard, Julie A. Theriot, and Alanna Schepartz pp 4–5 DOI: 10.1021/ja037954k Supporting Info

Probing Glycosyltransferase Activities with the Staudinger Ligation Howard C. Hang, Chong Yu, Matthew R. Pratt, and Carolyn R. Bertozzi pp 6–7 DOI: 10.1021/ja037692m Supporting Info

A Systematic Study of CO Oxidation on Metals and Metal Oxides:  Density Functional Theory Calculations Xue-Qing Gong, Zhi-Pan Liu, Rasmita Raval, and P. Hu pp 8–9 DOI: 10.1021/ja030392k

Polymer-Initiated Photogeneration of Silver Nanoparticles in SPEEK/PVA Films:  Direct Metal Photopatterning A. S. Korchev, M. J. Bozack, B. L. Slaten, and G. Mills pp 10–11 DOI: 10.1021/ja037933q Supporting Info

Emission Energy Correlates with Inverse of Gold−Gold Distance for Various [Au(SCN)2]- Salts Nathan L. Coker, Jeanette A. Krause Bauer, and R. C. Elder pp 12–13 DOI: 10.1021/ja037012f Supporting Info

Catalytic Asymmetric Acyl Halide−Aldehyde Cyclocondensation Reactions of Substituted Ketenes Scott G. Nelson, Cheng Zhu, and Xiaoqiang Shen pp 14–15 DOI: 10.1021/ja0391208 Supporting Info

Halogen Bonding:  A New Interaction for Liquid Crystal Formation H. Loc Nguyen, Peter N. Horton, Michael B. Hursthouse, Anthony C. Legon, and Duncan W. Bruce pp 16–17 DOI: 10.1021/ja036994l Supporting Info

Catalytic Sulfoxidation and Epoxidation with a Mn(III) Triazacorrole:  Evidence for A “Third Oxidant” in High-Valent Porphyrinoid Oxidations Sheena Hailin Wang, Beaven S. Mandimutsira, Ryan Todd, Bobby Ramdhanie, Joseph P. Fox, and David P. Goldberg pp 18–19 DOI: 10.1021/ja038951a Supporting Info

In Vitro Evolution of Functional DNA Using Capillary Electrophoresis Shaun D. Mendonsa and Michael T. Bowser pp 20–21 DOI: 10.1021/ja037832s Supporting Info

In Vivo Synthesized Proteins with Monoexponential Fluorescence Decay Kinetics Jaap Broos, Francesco Maddalena, and Ben H. Hesp pp 22–23 DOI: 10.1021/ja0385585 Supporting Info

Substituent Effects and Nearly Degenerate Transition States:  Rational Design of Substrates for the Tandem Wolff−Cope Reaction Julius T. Su, Richmond Sarpong, Brian M. Stoltz, and William A. Goddard III pp 24–25 DOI: 10.1021/ja037716p Supporting Info

Nanoparticles from Cationic Copolymer and DNA That Are Soluble and Stable in Common Organic Solvents Munia Ganguli, Kizhakkedathu N. Jayachandran, and Souvik Maiti pp 26–27 DOI: 10.1021/ja037534v Supporting Info

A New Patterning Method Using Photocatalytic Lithography and Selective Atomic Layer Deposition Jae P. Lee and Myung M. Sung pp 28–29 DOI: 10.1021/ja038769+ Supporting Info

Reversible Modulation of Quantum Dot Photoluminescence Using a Protein- Bound Photochromic Fluorescence Resonance Energy Transfer Acceptor Igor L. Medintz, Scott A. Trammell, Hedi Mattoussi, and J. Matthew Mauro pp 30–31 DOI: 10.1021/ja037970h

Microporous Manganese Formate:  A Simple Metal−Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties Danil N. Dybtsev, Hyungphil Chun, Sun Hong Yoon, Dongwoo Kim, and Kimoon Kim pp 32–33 DOI: 10.1021/ja038678c Supporting Info

A Highly Potent Non-Nucleoside Adenosine Deaminase Inhibitor:  Efficient Drug Discovery by Intentional Lead Hybridization Tadashi Terasaka, Takayoshi Kinoshita, Masako Kuno, and Isao Nakanishi pp 34–35 DOI: 10.1021/ja038606l Supporting Info

Fluorous Mixture Synthesis of Stereoisomer Libraries:  Total Syntheses of (+)-Murisolin and Fifteen Diastereoisomers Qisheng Zhang, Hejun Lu, Cyrille Richard, and Dennis P. Curran pp 36–37 DOI: 10.1021/ja038542e Supporting Info

The Nature of the Surface Species Formed on Au/TiO2 during the Reaction of H2 and O2:  An Inelastic Neutron Scattering Study Chinta Sivadinarayana, Tushar V. Choudhary, Luke L. Daemen, Juergen Eckert, and David W. Goodman pp 38–39 DOI: 10.1021/ja0381398

2‘,5‘-Linked DNA Is a Template for Polymerase-Directed DNA Synthesis Surajit Sinha, Paul H. Kim, and Christopher Switzer pp 40–41 DOI: 10.1021/ja034986z Supporting Info

Divalent ansa-Zirconocenes:  Stereoselective Synthesis and High Activity for Propylene Polymerization Eugene Y.-X. Chen, Richard E. Campbell, Jr., David D. Devore, D. Patrick Green, Bernie Link, Jorge Soto, David R. Wilson, and Khalil A. Abboud pp 42–43 DOI: 10.1021/ja0381611 Supporting Info

The Role of Proton Donors in SmI2-Mediated Ketone Reduction:  New Mechanistic Insights Pramod R. Chopade, Edamana Prasad, and Robert A. Flowers, II pp 44–45 DOI: 10.1021/ja038363x Supporting Info

Elucidating the Mechanism of cis Double Bond Formation in Epothilone Biosynthesis Li Tang, Shannon Ward, Loleta Chung, John R. Carney, Yong Li, Ralph Reid, and Leonard Katz pp 46–47 DOI: 10.1021/ja030503f Supporting Info

A Formal Synthesis of (−)-Mycalamide A Barry M. Trost, Hanbiao Yang, and Gary D. Probst pp 48–49 DOI: 10.1021/ja038787r Supporting Info

Gated Electron Transfer as a Probe of the Configurational Dynamics of Peptide−Protein Complexes Liu Liu, Jing Hong, and Michael Y. Ogawa pp 50–51 DOI: 10.1021/ja036579t Supporting Info

A Switchable Self-Doped Polyaniline:  Interconversion between Self-Doped and Non-Self-Doped Forms Bhavana A. Deore, Insun Yu, and Michael S. Freund pp 52–53 DOI: 10.1021/ja038499v Supporting Info

Biomolecule-Assisted Synthesis of Highly Ordered Snowflakelike Structures of Bismuth Sulfide Nanorods Qingyi Lu, Feng Gao, and Sridhar Komarneni pp 54–55 DOI: 10.1021/ja0386389 Supporting Info

A Dramatic Elongation of the Lifetime of Charge-Separated State by Complexation with Yttrium Triflate in Ferrocene−Anthraquinone Linked Dyad Ken Okamoto, Yasuyuki Araki, Osamu Ito, and Shunichi Fukuzumi pp 56–57 DOI: 10.1021/ja037025t Supporting Info

A Stable Radical-Substituted Radical Cation with Strongly Ferromagnetic Interaction:  Nitronyl Nitroxide-Substituted 5,10-Diphenyl-5,10-dihydrophenazine Radical Cation Shinsuke Hiraoka, Toshihiro Okamoto, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, and Keiji Okada pp 58–59 DOI: 10.1021/ja0367748 Supporting Info

Synthesis and Structure of 1-Zirconacyclopent-3-yne Complexes without Substituents Adjacent to the Triple Bond Noriyuki Suzuki, Naoto Aihara, Hidemichi Takahara, Takaaki Watanabe, Masakazu Iwasaki, Masahiko Saburi, Daisuke Hashizume, and Teiji Chihara pp 60–61 DOI: 10.1021/ja0385742 Supporting Info

Reversible Super-hydrophobicity to Super-hydrophilicity Transition of Aligned ZnO Nanorod Films Xinjian Feng, Lin Feng, Meihua Jin, Jin Zhai, Lei Jiang, and Daoben Zhu pp 62–63 DOI: 10.1021/ja038636o

Recognition of G-1:C73 Atomic Groups by Escherichia coli Histidyl-tRNA Synthetase Abbey E. Rosen and Karin Musier-Forsyth pp 64–65 DOI: 10.1021/ja0381609 Supporting Info

Measurement of Five Dipolar Couplings from a Single 3D NMR Multiplet Applied to the Study of RNA Dynamics Erin O'Neil-Cabello, David L. Bryce, Edward P. Nikonowicz, and Ad Bax pp 66–67 DOI: 10.1021/ja038314k Supporting Info

Fragmentation of the Conjugate Base of 2-(1-Hydroxybenzyl)thiamin:  Does Benzoylformate Decarboxylase Prevent Orbital Overlap To Avoid It? Qingyan Hu and Ronald Kluger pp 68–69 DOI: 10.1021/ja0390505

Formation and Stability of a Janus-Wedge Type of DNA Triplex Dongli Chen, Meena, Sunil K. Sharma, and Larry W. McLaughlin pp 70–71 DOI: 10.1021/ja038081x Supporting Info

An Efficient Direct α-Alkylation of Ketones with Primary Alcohols Catalyzed by [Ir(cod)Cl]2/PPh3/KOH System without Solvent Kazuhiko Taguchi, Hideto Nakagawa, Tomotaka Hirabayashi, Satoshi Sakaguchi, and Yasutaka Ishii pp 72–73 DOI: 10.1021/ja037552c Supporting Info

Poly(fluoroalkyl acrylate)-Bound Ruthenium Carbene Complex:  A Fluorous and Recyclable Catalyst for Ring-Closing Olefin Metathesis Qingwei Yao and Yiliang Zhang pp 74–75 DOI: 10.1021/ja037394p Supporting Info

Lateral Quantized Charge Transfer Across Nanoparticle Monolayers at the Air/Water Interface Yiyun Yang, Solulit Pradhan, and Shaowei Chen pp 76–77 DOI: 10.1021/ja037675x Supporting Info

A New Reaction Sequence Involving Palladium-Catalyzed Unsymmetrical Aryl Coupling Fiorenza Faccini, Elena Motti, and Marta Catellani pp 78–79 DOI: 10.1021/ja039043g Supporting Info

Establishing the Parabolic Relationship between Reactivity and Activity for Derivatives and Analogues of the Duocarmycin and CC-1065 Alkylation Subunits Jay P. Parrish, Terry V. Hughes, Inkyu Hwang, and Dale L. Boger pp 80–81 DOI: 10.1021/ja038162t Supporting Info

Cross-Couplings of Alkyl Electrophiles under “Ligandless” Conditions:  Negishi Reactions of Organozirconium Reagents Sheryl L. Wiskur, Alexander Korte, and Gregory C. Fu pp 82–83 DOI: 10.1021/ja0393729 Supporting Info

Copper(I)-Catalyzed Disilylation of Alkylidene Malonates Employing a Lewis Base Activation Strategy Christopher T. Clark, Jason F. Lake, and Karl A. Scheidt pp 84–85 DOI: 10.1021/ja038530t Supporting Info

Low 13C-Background for NMR-Based Studies of Ligand Binding Using 13C-Depleted Glucose as Carbon Source for Microbial Growth:  13C-Labeled Glucose and 13C-Forskolin Binding to the Galactose-H+ Symport Protein GalP in Escherichia coli Simon G. Patching, Richard B. Herbert, John O'Reilly, Adrian R. Brough, and Peter J. F. Henderson pp 86–87 DOI: 10.1021/ja038275c Supporting Info

Chemically Distinct Ni Sites in the A-Cluster in Subunit β of the Acetyl-CoA Decarbonylase/Synthase Complex from Methanosarcina thermophila:  Ni L-Edge Absorption and X-ray Magnetic Circular Dichroism Analyses Tobias Funk, Weiwei Gu, Stephan Friedrich, Hongxin Wang, Simonida Gencic, David A. Grahame, and Stephen P. Cramer pp 88–95 DOI: 10.1021/ja0366033 Supporting Info

Enantioselective Total Synthesis of Erogorgiaene:  Applications of Asymmetric Cu-Catalyzed Conjugate Additions of Alkylzincs to Acyclic Enones Richard R. Cesati, III, Judith de Armas, and Amir H. Hoveyda pp 96–101 DOI: 10.1021/ja0305407 Supporting Info

Dynamics of Protein and Peptide Hydration Kristofer Modig, Edvards Liepinsh, Gottfried Otting, and Bertil Halle pp 102–114 DOI: 10.1021/ja038325d Supporting Info

Hydroxylation by the Hydroperoxy-Iron Species in Cytochrome P450 Enzymes R. Esala P. Chandrasena, Kostas P. Vatsis, Minor J. Coon, Paul F. Hollenberg, and Martin Newcomb pp 115–126 DOI: 10.1021/ja038237t Supporting Info

Model Studies on p-Hydroxybenzoate Hydroxylase. The Catalytic Role of Arg-214 and Tyr-201 in the Hydroxylation Step Robert D. Bach and Olga Dmitrenko pp 127–142 DOI: 10.1021/ja036310+ Supporting Info

DNA Sequence Dependent Monomer−Dimer Binding Modulation of Asymmetric Benzimidazole Derivatives Farial A. Tanious, Donald Hamelberg, Christian Bailly, Agnieska Czarny, David W. Boykin, and W. David Wilson pp 143–153 DOI: 10.1021/ja030403+ Supporting Info

Unique Tautomeric Properties of Isoguanine José Ramón Blas, F. Javier Luque, and Modesto Orozco pp 154–164 DOI: 10.1021/ja036806r Supporting Info

Duplex Dissociation of Telomere DNAs Induced by Molecular Crowding Daisuke Miyoshi, Shizuka Matsumura, Shu-ichi Nakano, and Naoki Sugimoto pp 165–169 DOI: 10.1021/ja036721q Supporting Info

Polymer Brushes on Single-Walled Carbon Nanotubes by Atom Transfer Radical Polymerization of n-Butyl Methacrylate Shuhui Qin, Dongqi Qin, Warren T. Ford, Daniel E. Resasco, and Jose E. Herrera pp 170–176 DOI: 10.1021/ja037937v

Hexakis(4-iodophenyl)-peri-hexabenzocoronene- A Versatile Building Block for Highly Ordered Discotic Liquid Crystalline Materials Jishan Wu, Mark D. Watson, Li Zhang, Zhaohui Wang, and Klaus Müllen pp 177–186 DOI: 10.1021/ja037519q Supporting Info

Schulzeines A−C, New α-Glucosidase Inhibitors from the Marine Sponge Penares schulzei1 Kentaro Takada, Taisuke Uehara, Yoichi Nakao, Shigeki Matsunaga, Rob W. M. van Soest, and Nobuhiro Fusetani pp 187–193 DOI: 10.1021/ja037368r Supporting Info

Direct Observation of Odd−Even Effect for Chiral Alkyl Alcohols in Solution Using Vibrational Circular Dichroism Spectroscopy Hiroshi Izumi, Souko Yamagami, Shigeru Futamura, Laurence A. Nafie, and Rina K. Dukor pp 194–198 DOI: 10.1021/ja037752o Supporting Info

Origins of Enantioselectivity in Reductions of Ketones on Cinchona Alkaloid Modified Platinum Grigoriy Vayner, K. N. Houk, and Y.-K. Sun pp 199–203 DOI: 10.1021/ja035147f

Lanthanide−Transition-Metal Carbonyl Complexes:  New [Co4(CO)11]2- Clusters and Lanthanide(II) Isocarbonyl Polymeric Arrays Christine E. Plenik, Shengming Liu, Xuenian Chen, Edward A. Meyers, and Sheldon G. Shore pp 204–213 DOI: 10.1021/ja0304852 Supporting Info

Shape-Persistent Macrocycles with Intraannular Polar Groups:  Synthesis, Liquid Crystallinity, and 2D Organization Matthias Fischer, Günter Lieser, Almut Rapp, Ingo Schnell, Wael Mamdouh, Steven De Feyter, Frans C. De Schryver, and Sigurd Höger pp 214–222 DOI: 10.1021/ja038484x Supporting Info

Ruffling-Induced Chirality:  Synthesis, Metalation, and Optical Resolution of Highly Nonplanar, Cyclic, Benzimidazole-Based Ligands Tomasz Fekner, Judith Gallucci, and Michael K. Chan pp 223–236 DOI: 10.1021/ja030196d Supporting Info

The Rearrangements of Naphthylnitrenes:  UV/Vis and IR Spectra of Azirines, Cyclic Ketenimines, and Cyclic Nitrile Ylides Alexander Maltsev, Thomas Bally, Meng-Lin Tsao, Matthew S. Platz, Arvid Kuhn, Michael Vosswinkel, and Curt Wentrup pp 237–249 DOI: 10.1021/ja038458z Supporting Info

Ruthenium-Catalyzed Heck-Type Olefination and Suzuki Coupling Reactions:  Studies on the Nature of Catalytic Species Youngim Na, Soyoung Park, Soo Bong Han, Hoon Han, Sangwon Ko, and Sukbok Chang pp 250–258 DOI: 10.1021/ja038742q Supporting Info

[Ni0]-Catalyzed Co-oligomerization of 1,3-Butadiene and Ethylene:  A Theoretical Mechanistic Investigation of Competing Routes for Generation of Linear and Cyclic C10-Olefins Sven Tobisch pp 259–272 DOI: 10.1021/ja0388865 Supporting Info

Monodisperse MFe2O4 (M = Fe, Co, Mn) Nanoparticles Shouheng Sun, Hao Zeng, David B. Robinson, Simone Raoux, Philip M. Rice, Shan X. Wang, and Guanxiong Li pp 273–279 DOI: 10.1021/ja0380852 Supporting Info

Spectroscopic Properties and Quantum Chemistry-Based Normal Coordinate Analysis (QCB-NCA) of a Dinuclear Tantalum Complex Exhibiting the Novel Side-On End-On Bridging Geometry of N2:  Correlations to Electronic Structure and Reactivity Felix Studt, Bruce A. MacKay, Michael D. Fryzuk, and Felix Tuczek pp 280–290 DOI: 10.1021/ja036997y Supporting Info

Proton Transfer and a Dielectric Phase Transition in the Molecular Conductor (HDABCO+)2(TCNQ)3 Tomoyuki Akutagawa, Sadamu Takeda, Tatsuo Hasegawa, and Takayoshi Nakamura pp 291–294 DOI: 10.1021/ja0377697 Supporting Info

Attenuating Negative Differential Resistance in an Electroactive Self-Assembled Monolayer-Based Junction Ronald A. Wassel, Grace M. Credo, Ryan R. Fuierer, Daniel L. Feldheim, and Christopher B. Gorman pp 295–300 DOI: 10.1021/ja037651q Supporting Info

Fluorescence Resonance Energy Transfer Between Quantum Dot Donors and Dye-Labeled Protein Acceptors Aaron R. Clapp, Igor L. Medintz, J. Matthew Mauro, Brent R. Fisher, Moungi G. Bawendi, and Hedi Mattoussi pp 301–310 DOI: 10.1021/ja037088b Supporting Info

A Comparative Study of Claisen and Cope Rearrangements Catalyzed by Chorismate Mutase. An Insight into Enzymatic Efficiency:  Transition State Stabilization or Substrate Preorganization? Sergio Martí, Juan Andrés, Vicente Moliner, Estanislao Silla, Iñaki Tuñón, and Juan Bertrán pp 311–319 DOI: 10.1021/ja0369156

Rhodium-Catalyzed Methylenation of Aldehydes Hélène Lebel and Valérie Paquet pp 320–328 DOI: 10.1021/ja038112o Supporting Info

Highly Active Trialkoxymolybdenum(VI) Alkylidyne Catalysts Synthesized by a Reductive Recycle Strategy Wei Zhang, Stefan Kraft, and Jeffrey S. Moore pp 329–335 DOI: 10.1021/ja0379868 Supporting Info

Energy Migration in Novel pH-Triggered Self-Assembled β-Sheet Ribbons Veysel Kayser, David A. Turton, Amalia Aggeli, Andrew Beevers, Gavin D. Reid, and Godfrey S. Beddard pp 336–343 DOI: 10.1021/ja035340+

Ab Initio Molecular Dynamics Study of Formate Ion Hydration Kevin Leung and Susan B. Rempe pp 344–351 DOI: 10.1021/ja036267q

Mechanism of Homogeneous Ir(III) Catalyzed Regioselective Arylation of Olefins Jonas Oxgaard, Richard P. Muller, William A. Goddard, III, and Roy A. Periana pp 352–363 DOI: 10.1021/ja034126i Supporting Info

Quantum Chemical Study on the Configurations of Encapsulated Metal Ions and the Molecular Vibration Modes in Endohedral Dimetallofullerene La2@C80 Hidekazu Shimotani, Takayoshi Ito, Yoshihiro Iwasa, Atsushi Taninaka, Hisanori Shinohara, Eiji Nishibori, Masaki Takata, and Makoto Sakata pp 364–369 DOI: 10.1021/ja038208i

Direct Covalent Grafting of Conjugated Molecules onto Si, GaAs, and Pd Surfaces from Aryldiazonium Salts Michael P. Stewart, Francisco Maya, Dmitry V. Kosynkin, Shawn M. Dirk, Joshua J. Stapleton, Christine L. McGuiness, David L. Allara, and James M. Tour pp 370–378 DOI: 10.1021/ja0383120 Supporting Info

15N Chemical Shielding in Glycyl Tripeptides:  Measurement by Solid-State NMR and Correlation with X-ray Structure Eduard Y. Chekmenev, Qianwen Zhang, Kevin W. Waddell, Mark S. Mashuta, and Richard J. Wittebort pp 379–384 DOI: 10.1021/ja0370342 Supporting Info

The Role of Intermolecular and Molecule−Substrate Interactions in the Stability of Alkanethiol Nonsaturated Phases on Au(111) Esther Barrena, Elisa Palacios-Lidón, Carmen Munuera, Xavier Torrelles, Salvador Ferrer, Ulrich Jonas, Miquel Salmeron, and Carmen Ocal pp 385–395 DOI: 10.1021/ja036143d

An Approach to Developing a Force Field for Molecular Simulation of Martensitic Phase Transitions between Phases with Subtle Differences in Energy and Structure Sigrid C. Tuble, Jamshed Anwar, and Julian D. Gale pp 396–405 DOI: 10.1021/ja0356131

Supramolecular Structures of Polyoxomolybdate-Based Giant Molecules in Aqueous Solution [J. Am. Chem. Soc. 2002, 124, 10942−10943]. Tianbo Liu p 406 DOI: 10.1021/ja039353z

Novel “Potentially Antiaromatic”, Acidichromic Quinonediimines with Tunable Delocalization of Their 6π-Electron Subunits [J. Am. Chem. Soc. 2003, 125, 13793−13803]. Olivier Siri, Pierre Braunstein, Marie-Madeleine Rohmer, Marc Bénard, and Richard Welter p 406 DOI: 10.1021/ja039572k Supporting Info

BioAdviser 1.0 − High Performance Molecular Rendering and Analysis Software FQS Poland Sp. z o. o. Palac Pugetow, ul. Starowislna 13-15, 31-038 Krakow, Poland. http://www.fqspl.com.pl/bioadviser/intro.html. See Web site for pricing information. Marvin L. Hackert p 407 DOI: 10.1021/ja025325p

Organometallic Conjugation:  Structures, Reactions and Functions of d−d and d−π Conjugated Systems Edited by Akira Nakamura, Norikazu Ueyama, and Kizashi Yamaguchi (Osaka University). From the Series:  Chemical Physics, Volume 73. Kodansha, Ltd:  Tokyo. Springer-Verlag:  Berlin, Heidelberg, New York. 2002. xvi + 352 pp. $129.00. Kodansha ISBN 4-06-209654-4. Springer-Verlag ISBN 3-540-00088-7. Kirk S. Schanze p 408 DOI: 10.1021/ja033547x

Issue 02

Dedifferentiation of Lineage-Committed Cells by a Small Molecule Shuibing Chen, Qisheng Zhang, Xu Wu, Peter G. Schultz, and Sheng Ding pp 410–411 DOI: 10.1021/ja037390k Supporting Info

Controlled Functionalization of Multiwalled Carbon Nanotubes by in Situ Atom Transfer Radical Polymerization Hao Kong, Chao Gao, and Deyue Yan pp 412–413 DOI: 10.1021/ja0380493 Supporting Info

Rearrangement of a 2-Methylenecyclobutanone Derivative Triggered by Photoinduced Electron Transfer:  An Unprecedented Oxa Analogue of the Tetramethyleneethane Radical Cation Hiroshi Ikeda, Futoshi Tanaka, Kimio Akiyama, Shozo Tero-Kubota, and Tsutomu Miyashi pp 414–415 DOI: 10.1021/ja038068c Supporting Info

A Nucleobase that Releases Reporter Tags upon DNA Oxidation Akimitsu Okamoto, Kazuo Tanaka, and Isao Saito pp 416–417 DOI: 10.1021/ja038169a Supporting Info

DNA-Templated Self-Assembly of Protein and Nanoparticle Linear Arrays Hanying Li, Sung Ha Park, John H. Reif, Thomas H. LaBean, and Hao Yan pp 418–419 DOI: 10.1021/ja0383367 Supporting Info

A Tetranuclear 3d−4f Single Molecule Magnet:  [CuIILTbIII(hfac)2]2 Shutaro Osa, Takafumi Kido, Naohide Matsumoto, Nazzareno Re, Andrzej Pochaba, and Jerzy Mrozinski pp 420–421 DOI: 10.1021/ja037365e

Dynamics of Density Fluctuation of Supercritical Fluid Mapped on Phase Diagram Ken-ichi Saitow, Daisuke Kajiya, and Keiko Nishikawa pp 422–423 DOI: 10.1021/ja038176z

A New Solvent System for Recycling Catalysts for Chelation-Assisted Hydroacylation of Olefins with Primary Alcohols Duck-Ho Chang, Dae-Yon Lee, Boo-Sun Hong, Jun-Hack Choi, and Chul-Ho Jun pp 424–425 DOI: 10.1021/ja038071w Supporting Info

Infrared Electronic Absorption in a Single-Component Molecular Metal Akiko Kobayashi, Masaaki Sasa, Wakako Suzuki, Emiko Fujiwara, Hisashi Tanaka, Madoka Tokumoto, Yoshinori Okano, Hideki Fujiwara, and Hayao Kobayashi pp 426–427 DOI: 10.1021/ja0379767

Enantioselective Crystal Growth of Leucine on a Self-Assembled Monolayer with Covalently Attached Leucine Molecules Naoki Banno, Takuya Nakanishi, Mariko Matsunaga, Toru Asahi, and Tetsuya Osaka pp 428–429 DOI: 10.1021/ja037942z

Antiaromaticity in Bare Deltahedral Silicon Clusters Satisfying Wade's and Hirsch's Rules:  An Apparent Correlation of Antiaromaticity with High Symmetry R. Bruce King, Thomas Heine, Clémence Corminboeuf, and Paul v. R. Schleyer pp 430–431 DOI: 10.1021/ja036259+ Supporting Info

Stacking of Molecules Possessing a Fullerene Apex and a Cup-Shaped Cavity Connected by a Silicon Connection Yutaka Matsuo, Ayako Muramatsu, Ryo Hamasaki, Norihiro Mizoshita, Takashi Kato, and Eiichi Nakamura pp 432–433 DOI: 10.1021/ja038816y Supporting Info

Ab Initio Interaction Energies of Hydrogen-Bonded Amino Acid Side Chain−Nucleic Acid Base Interactions Alan C. Cheng and Alan D. Frankel pp 434–435 DOI: 10.1021/ja037264g

Hybridization of Modified-Heme Reconstitution and Distal Histidine Mutation to Functionalize Sperm Whale Myoglobin Hideaki Sato, Takashi Hayashi, Tsutomu Ando, Yoshio Hisaeda, Takafumi Ueno, and Yoshihito Watanabe pp 436–437 DOI: 10.1021/ja038798k Supporting Info

Visual Detection of Cysteine and Homocysteine Oleksandr Rusin, Nadia N. St. Luce, Rezik A. Agbaria, Jorge O. Escobedo, Shan Jiang, Isiah M. Warner, Fareed B. Dawan, Kun Lian, and Robert M. Strongin pp 438–439 DOI: 10.1021/ja036297t Supporting Info

Nondissociative Chemisorption of Methanethiol on Ag(110):  A Critical Result for Self-Assembled Monolayers Jae-Gook Lee, Junseok Lee, and John T. Yates, Jr. pp 440–441 DOI: 10.1021/ja030357d

Mechanism of Ru(II)-Catalyzed Olefin Insertion and C−H Activation from Quantum Chemical Studies Jonas Oxgaard and William A. Goddard, III pp 442–443 DOI: 10.1021/ja038399p Supporting Info

Multicomponent Reactions Are Accelerated in Water Michael C. Pirrung and Koushik Das Sarma pp 444–445 DOI: 10.1021/ja038583a Supporting Info

High-Resolution NMR Spectra in Inhomogeneous Fields via IDEAL (Intermolecular Dipolar-Interaction Enhanced All Lines) Method Zhong Chen, Zhiwei Chen, and Jianhui Zhong pp 446–447 DOI: 10.1021/ja036491f Supporting Info

Enzymatic Synthesis of Phosphoroselenoate DNA Using Thymidine 5‘-(α-P- seleno)triphosphate and DNA Polymerase for X-ray Crystallography via MAD Nicolas Carrasco and Zhen Huang pp 448–449 DOI: 10.1021/ja0383221 Supporting Info

Catalytic Asymmetric Intramolecular α-Alkylation of Aldehydes Nicola Vignola and Benjamin List pp 450–451 DOI: 10.1021/ja0392566 Supporting Info

Hyperconjugative and Inductive Perturbations in Poly(p-phenylene vinylenes) Youngmi Kim, Zhengguo Zhu, and Timothy M. Swager pp 452–453 DOI: 10.1021/ja038472b Supporting Info

Reduction of Dinitrogen to Planar Bimetallic M2(μ-η2:η2-N2) Complexes of Y, Ho, Tm, and Lu Using the K/Ln[N(SiMe3)2]3 Reduction System William J. Evans, David S. Lee, and Joseph W. Ziller pp 454–455 DOI: 10.1021/ja036923m Supporting Info

Chiral Copper Complexes of Phosphino Sulfenyl Ferrocenes as Efficient Catalysts for Enantioselective Formal Aza Diels−Alder Reactions of N-Sulfonyl Imines Olga García Mancheño, Ramón Gómez Arrayás, and Juan C. Carretero pp 456–457 DOI: 10.1021/ja038494y Supporting Info

The Sulfur Chemistry of Shiitake Mushroom Eileen Yu Sneeden, Hugh H. Harris, Ingrid J. Pickering, Roger C. Prince, Sherida Johnson, Xiaojie Li, Eric Block, and Graham N. George pp 458–459 DOI: 10.1021/ja039239g

Expression, Reconstitution, and Mutation of Recombinant Streptomyces coelicolor NiSOD Peter A. Bryngelson, Sumonu E. Arobo, Jennifer L. Pinkham, Diane E. Cabelli, and Michael J. Maroney pp 460–461 DOI: 10.1021/ja0387507 Supporting Info

Synthesis of Silica Nanoparticles Having a Well-Ordered Mesostructure Using a Double Surfactant System Keisei Suzuki, Kenichi Ikari, and Hiroaki Imai pp 462–463 DOI: 10.1021/ja038250d

13C−13C NOESY:  An Attractive Alternative for Studying Large Macromolecules Ivano Bertini, Isabella C. Felli, Rainer Kümmerle, Detlef Moskau, and Roberta Pierattelli pp 464–465 DOI: 10.1021/ja0357036 Supporting Info

One-Pot Synthesis of Nitrogen Heterocycles Initiated by Regio- and Diastereoselective Carbon−Carbon Bond Formation of Bifunctional Carbonyl Compounds Ikuya Shibata, Hirofumi Kato, Nobuaki Kanazawa, Makoto Yasuda, and Akio Baba pp 466–467 DOI: 10.1021/ja038712n Supporting Info

Palladium-Catalyzed Multicomponent Coupling of Alkynes, Imines, and Acid Chlorides:  A Direct and Modular Approach to Pyrrole Synthesis Rajiv Dhawan and Bruce A. Arndtsen pp 468–469 DOI: 10.1021/ja039152v Supporting Info

New Fischer Carbene Complexes of Rhodium(I):  Preparation and 2-Cyclopentenone Ring Synthesis by Annelation to Alkynes José Barluenga, Rubén Vicente, Luis A. López, Eduardo Rubio, Miguel Tomás, and Carmen Álvarez-Rúa pp 470–471 DOI: 10.1021/ja038817q Supporting Info

Nonheme FeIVO Complexes That Can Oxidize the C−H Bonds of Cyclohexane at Room Temperature József Kaizer, Eric J. Klinker, Na Young Oh, Jan-Uwe Rohde, Woon Ju Song, Audria Stubna, Jinheung Kim, Eckard Münck, Wonwoo Nam, and Lawrence Que, Jr. pp 472–473 DOI: 10.1021/ja037288n Supporting Info

Palladium Pincer Complex-Catalyzed Trimethyltin Substitution of Functionalized Propargylic Substrates. An Efficient Route to Propargyl- and Allenyl-Stannanes Johan Kjellgren, Henrik Sundén, and Kálmán J. Szabó pp 474–475 DOI: 10.1021/ja0391715 Supporting Info

Synthesis of Heparin Oligosaccharides Jinq-Chyi Lee, Xin-An Lu, Suvarn S. Kulkarni, Yuh-Sheng Wen, and Shang-Cheng Hung pp 476–477 DOI: 10.1021/ja038244h Supporting Info

Highly Electrophilic (Salen)ruthenium(VI) Nitrido Complexes Wai-Lun Man, Tsz-Man Tang, Tsz-Wing Wong, Tai-Chu Lau, Shie-Ming Peng, and Wing-Tak Wong pp 478–479 DOI: 10.1021/ja037899f Supporting Info

Imidazolium Ion-Terminated Self-Assembled Monolayers on Au:  Effects of Counteranions on Surface Wettability Bang Sook Lee, Young Shik Chi, Jae Kyun Lee, Insung S. Choi, Choong Eui Song, Sung Keon Namgoong, and Sang-gi Lee pp 480–481 DOI: 10.1021/ja038405h Supporting Info

In Situ FTIR-ATR Analysis and Titration of Carboxylic Acid-Terminated SAMs Olga Gershevitz and Chaim N. Sukenik pp 482–483 DOI: 10.1021/ja037610u Supporting Info

Characterization of a Kinetically Stable, Highly Ordered, Octameric Form of Lithium tert-Butoxide and Its Implications Regarding Aggregate Formation John F. Allan, Roger Nassar, Elizabeth Specht, Alicia Beatty, Nathalie Calin, and Kenneth W. Henderson pp 484–485 DOI: 10.1021/ja038420m Supporting Info

Quantum-Chemical Calculations for Paramagnetic 13C NMR Chemical Shifts of Iron-Bound Cyanide Ions of Iron Porphyrins in Ground and Low-Lying Excited States Containing Ferric (dxy)2(dxz,yz)3 and (dxy)1(dxz,yz)4 Configurations Masahiko Hada pp 486–487 DOI: 10.1021/ja038097n

Enantiospecific Electrodeposition of Chiral CuO Films on Single-Crystal Cu(111) Eric W. Bohannan, Hiten M. Kothari, Igor M. Nicic, and Jay A. Switzer pp 488–489 DOI: 10.1021/ja039422+

Coupling a Natural Receptor Protein with an Artificial Receptor to Afford a Semisynthetic Fluorescent Biosensor Eiji Nakata, Tsuyoshi Nagase, Seiji Shinkai, and Itaru Hamachi pp 490–495 DOI: 10.1021/ja035631i Supporting Info

Protein-Template-Driven Formation of Polynuclear Iron Species Simon A. Malone, Allison Lewin, Mehmet A. Kilic, Dimitri A. Svistunenko, Chris E. Cooper, Michael T. Wilson, Nick E. Le Brun, Stephen Spiro, and Geoffrey R. Moore pp 496–504 DOI: 10.1021/ja036483z

Comparison between the Geometric and Electronic Structures and Reactivities of {FeNO}7 and {FeO2}8 Complexes: A Density Functional Theory Study Gerhard Schenk, Monita Y. M. Pau, and Edward I. Solomon pp 505–515 DOI: 10.1021/ja036715u Supporting Info

Selective Formation of Stable Triplexes Including a TA or a CG Interrupting Site with New Bicyclic Nucleoside Analogues (WNA) Shigeki Sasaki, Yosuke Taniguchi, Ryo Takahashi, Yusuke Senko, Keiichi Kodama, Fumi Nagatsugi, and Minoru Maeda pp 516–528 DOI: 10.1021/ja037211z Supporting Info

Insights into the Phosphoryl-Transfer Mechanism of cAMP-Dependent Protein Kinase from Quantum Chemical Calculations and Molecular Dynamics Simulations Natalia Díaz and Martin J. Field pp 529–542 DOI: 10.1021/ja037277u Supporting Info

Experimental and Structural Evidence that Herpes 1 Kinase and Cellular DNA Polymerase(s) Discriminate on the Basis of Sugar Pucker Victor E. Marquez, Tsipi Ben-Kasus, Joseph J. Barchi, Jr., Karen M. Green, Marc C. Nicklaus, and Riad Agbaria pp 543–549 DOI: 10.1021/ja037929e

Fluorogenic Peptide Sequences − Transformation of Short Peptides into Fluorophores under Ambient Photooxidative Conditions Gary L. Juskowiak, Shawn J. Stachel, Parcharee Tivitmahaisoon, and David L. Van Vranken pp 550–556 DOI: 10.1021/ja0379971 Supporting Info

The SPR Sensor Detecting Cytosine−Cytosine Mismatches Akio Kobori, Souta Horie, Hitoshi Suda, Isao Saito, and Kazuhiko Nakatani pp 557–562 DOI: 10.1021/ja037947w

One-Step Multifunctionalization of Random Copolymers via Self-Assembly Joel M. Pollino, Ludger P. Stubbs, and Marcus Weck pp 563–567 DOI: 10.1021/ja0372715 Supporting Info

Polyvalent Scaffolds. Counting the Number of Seats Available for Eosin Guest Molecules in Viologen-Based Host Dendrimers Filippo Marchioni, Margherita Venturi, Alberto Credi, Vincenzo Balzani, Martin Belohradsky, Arkadij M. Elizarov, Hsian-Rong Tseng, and J. Fraser Stoddart pp 568–573 DOI: 10.1021/ja037318m Supporting Info

Effects of Spiroconjugation on the Calculated Singlet−Triplet Energy Gap in 2,2-Dialkoxycyclopentane-1,3-diyls and on the Experimental Electronic Absorption Spectra of Singlet 1,3-Diphenyl Derivatives. Assignment of the Lowest-Energy Electronic Transition of Singlet Cyclopentane-1,3-diyls Manabu Abe, Waldemar Adam, Weston Thatcher Borden, Masanori Hattori, David A. Hrovat, Masatomo Nojima, Koichi Nozaki, and Jakob Wirz pp 574–582 DOI: 10.1021/ja038305b Supporting Info

Insight into G−T Mismatch Recognition Using Molecular Dynamics with Time-Averaged Restraints Derived from NMR Spectroscopy Richard J. Isaacs and H. Peter Spielmann pp 583–590 DOI: 10.1021/ja037333r Supporting Info

Mechanism of Two-Electron Oxidation of Deoxyguanosine 5‘-Monophosphate by a Platinum(IV) Complex Sunhee Choi, Richard B. Cooley, Amanda S. Hakemian, Yuna C. Larrabee, Richard C. Bunt, Stéphane D. Maupas, James G. Muller, and Cynthia J. Burrows pp 591–598 DOI: 10.1021/ja038334m

The Initial Stages of Solid Acid-Catalyzed Reactions of Adsorbed Propane. A Mechanistic Study by in Situ MAS NMR Mohamed Haouas, Stéphane Walspurger, Francis Taulelle, and Jean Sommer pp 599–606 DOI: 10.1021/ja0377549

Total Synthesis of Hybocarpone and Analogues Thereof. A Facile Dimerization of Naphthazarins to Pentacyclic Systems K. C. Nicolaou and David L. F. Gray pp 607–612 DOI: 10.1021/ja030497n Supporting Info

Total Synthesis of Hamigerans and Analogues Thereof. Photochemical Generation and Diels−Alder Trapping of Hydroxy-o-quinodimethanes K. C. Nicolaou, David L. F. Gray, and Jinsung Tae pp 613–627 DOI: 10.1021/ja030498f Supporting Info

A Benchtop Method for the Fabrication and Patterning of Nanoscale Structures on Polymers James M. Helt, Charles M. Drain, and James D. Batteas pp 628–634 DOI: 10.1021/ja035142i Supporting Info

Controlled Synthesis of 2-D and 3-D Dendritic Platinum Nanostructures Yujiang Song, Yi Yang, Craig J. Medforth, Eulalia Pereira, Anup K. Singh, Huifang Xu, Yingbing Jiang, C. Jeffrey Brinker, Frank van Swol, and John A. Shelnutt pp 635–645 DOI: 10.1021/ja037474t Supporting Info

Facile Ring Opening of Iron(III) and Iron(II) Complexes of meso-Amino-octaethylporphyrin by Dioxygen Sankar Prasad Rath, Heather Kalish, Lechosław Latos-Grażyński, Marilyn M. Olmstead, and Alan L. Balch pp 646–654 DOI: 10.1021/ja0384431 Supporting Info

Prediction of Solid Solution Formation in a Family of Diastereomeric Salts. A Molecular Modeling Study Claire Gervais, Reinier F. P. Grimbergen, Imre Markovits, Gerry J. A. Ariaans, Bernard Kaptein, Alle Bruggink, and Quirinus B. Broxterman pp 655–662 DOI: 10.1021/ja0366437 Supporting Info

Theoretical Calculation of the NMR Spin−Spin Coupling Constants and the NMR Shifts Allow Distinguishability between the Specific Direct and the Water-Mediated Binding of a Divalent Metal Cation to Guanine Vladimír Sychrovský, Jiří Šponer, and Pavel Hobza pp 663–672 DOI: 10.1021/ja036942w Supporting Info

Aligned Inclusion of Hemicyanine Dyes into Silica Zeolite Films for Second Harmonic Generation Hyun Sung Kim, Seung Mook Lee, Kwang Ha, Changsoo Jung, Yun-Jo Lee, Yu Sung Chun, Doseok Kim, Bum Ku Rhee, and Kyung Byung Yoon pp 673–682 DOI: 10.1021/ja037772q Supporting Info

Photophysical Properties of Ruthenium(II) Polyazaaromatic Compounds:  A Theoretical Insight Geoffrey Pourtois, David Beljonne, Cécile Moucheron, Stephan Schumm, Andrée Kirsch-De Mesmaeker, Roberto Lazzaroni, and Jean-Luc Brédas pp 683–692 DOI: 10.1021/ja034444h

Kinetic Evaluation of Phenolase Activity of Tyrosinase Using Simplified Catalytic Reaction System [J. Am. Chem. Soc. 2003, 125, 13034−13035]. Shin-ichi Yamazaki and Shinobu Itoh p 693 DOI: 10.1021/ja0334661

Annual Review of NMR Spectroscopy. Volume 46 Edited by G. A. Webb (Royal Society of Chemistry, London). Academic Press:  San Diego, London. 2002. x + 218 pp. $134.00. ISBN 0-12-505446-7. David W. Hoffman p 694 DOI: 10.1021/ja025320s

Issue 03

Conjugate of Palladium(II) Complex and β-Cyclodextrin Acts as a Biomimetic Peptidase Nebojša M. Milović, Jovica D. Badjić, and Nenad M. Kostić pp 696–697 DOI: 10.1021/ja038404p Supporting Info

Improved Treatment of the Protein Backbone in Empirical Force Fields Alexander D. MacKerell, Jr., Michael Feig, and Charles L. Brooks, III pp 698–699 DOI: 10.1021/ja036959e Supporting Info

The Reaction of N-Methyl-1,2,4-triazoline-3,5-dione with Tetracyclopropylethylene. Formation of an Unusual Meso-ionic Product and Its Rearrangement to the Diazetidine Duk Kyung Kim and Kevin E. O'Shea pp 700–701 DOI: 10.1021/ja038359l Supporting Info

Conclusive Evidence for a Retention−Retention Pathway for the Molybdenum-Catalyzed Asymmetric Alkylation Guy C. Lloyd-Jones, Shane W. Krska, David L. Hughes, Laure Gouriou, Veronique D. Bonnet, Kevin Jack, Yongkui Sun, and Robert A. Reamer pp 702–703 DOI: 10.1021/ja0376339 Supporting Info

Thermal Stability of the Secondary Structure of Poly(α,l-glutamate) in Self-Assembled Complexes as Studied by Molecular Dynamics in Chloroform Solution David Zanuy, Jordi Casanovas, and Carlos Alemán pp 704–705 DOI: 10.1021/ja036803e Supporting Info

Catalytic Asymmetric Total Syntheses of Quinine and Quinidine Izzat T. Raheem, Steven N. Goodman, and Eric N. Jacobsen pp 706–707 DOI: 10.1021/ja039550y Supporting Info

Single-Crystal CdSe Nanosaws Christopher Ma, Yong Ding, Daniel Moore, Xudong Wang, and Zhong Lin Wang pp 708–709 DOI: 10.1021/ja0395644 Supporting Info

Isolation of a Stable Covalent Selenium Azide RSeN3 Thomas M. Klapötke, Burkhard Krumm, and Kurt Polborn pp 710–711 DOI: 10.1021/ja038975h Supporting Info

Emission Ratiometric Imaging of Intracellular Zinc:  Design of a Benzoxazole Fluorescent Sensor and Its Application in Two-Photon Microscopy Masayasu Taki, Janet L. Wolford, and Thomas V. O'Halloran pp 712–713 DOI: 10.1021/ja039073j Supporting Info

An Amphiphilic Approach to Nanocrystal Quantum Dot−Titania Nanocomposites Melissa A. Petruska, Andrew P. Bartko, and Victor I. Klimov pp 714–715 DOI: 10.1021/ja037539s Supporting Info

Chiroptical Transcription of Helical Information through Supramolecular Harmonization with Dynamic Helices Yan-Ming Guo, Hideaki Oike, and Takuzo Aida pp 716–717 DOI: 10.1021/ja039369p Supporting Info

Exo Selective Enantioselective Nitrone Cycloadditions Mukund P. Sibi, Zhihua Ma, and Craig P. Jasperse pp 718–719 DOI: 10.1021/ja039087p Supporting Info

Lysine Peroxycarbamates:  Free Radical-Promoted Peptide Cleavage Douglas S. Masterson, Huiyong Yin, Almary Chacon, David L. Hachey, Jeremy L. Norris, and Ned A. Porter pp 720–721 DOI: 10.1021/ja038615u Supporting Info

Sequence-Specific Detection of MicroRNAs by Signal-Amplifying Ribozymes Jörg S. Hartig, Imke Grüne, S. Hani Najafi-Shoushtari, and Michael Famulok pp 722–723 DOI: 10.1021/ja038822u Supporting Info

The Site of Cr+ Attachment to Gas-Phase Aniline from Infrared Spectroscopy Jos Oomens, David T. Moore, Gert von Helden, Gerard Meijer, and Robert C. Dunbar pp 724–725 DOI: 10.1021/ja038867v

A Recoverable Enzymatic Microgel Based on Biomolecular Recognition Rong Cao, Zhenyu Gu, Gary D. Patterson, and Bruce A. Armitage pp 726–727 DOI: 10.1021/ja039502d Supporting Info

A General Strategy to Convert the MerR Family Proteins into Highly Sensitive and Selective Fluorescent Biosensors for Metal Ions Peng Chen and Chuan He pp 728–729 DOI: 10.1021/ja0383975 Supporting Info

A Robust Nanocontainer Based on a Pure Organic Free Radical Daniel Maspoch, Neus Domingo, Daniel Ruiz-Molina, Klaus Wurst, Javier Tejada, Concepció Rovira, and Jaume Veciana pp 730–731 DOI: 10.1021/ja038988v Supporting Info

An Unprecedented Memory of Macromolecular Helicity Induced in an Achiral Polyisocyanide in Water Masayoshi Ishikawa, Katsuhiro Maeda, Yuuki Mitsutsuji, and Eiji Yashima pp 732–733 DOI: 10.1021/ja039279k Supporting Info

Helical Supramolecules and Fibers Utilizing Leucine Zipper-Displaying Dendrimers Min Zhou, David Bentley, and Indraneel Ghosh pp 734–735 DOI: 10.1021/ja036634y Supporting Info

Chemical Synthesis of Normal and Transformed PSA Glycopeptides Vadim Y. Dudkin, Justin S. Miller, and Samuel J. Danishefsky pp 736–738 DOI: 10.1021/ja037988s Supporting Info

Control of Protein Structure and Function through Surface Recognition by Tailored Nanoparticle Scaffolds Rui Hong, Nicholas O. Fischer, Ayush Verma, Catherine M. Goodman, Todd Emrick, and Vincent M. Rotello pp 739–743 DOI: 10.1021/ja037470o Supporting Info

Nature of the Chemical Bond Formed with the Structural Metal Ion at the A9/G10.1 Motif Derived from Hammerhead Ribozymes Yoshiyuki Tanaka, Yasuhiro Kasai, Shunsuke Mochizuki, Akihiro Wakisaka, Eugene H. Morita, Chojiro Kojima, Atsushi Toyozawa, Yoshinori Kondo, Masumi Taki, Yasuomi Takagi, Atsushi Inoue, Kazuhiko Yamasaki, and Kazunari Taira pp 744–752 DOI: 10.1021/ja036826t

Characterization of μs−ms Dynamics of Proteins Using a Combined Analysis of 15N NMR Relaxation and Chemical Shift:  Conformational Exchange in Plastocyanin Induced by Histidine Protonations Mathias A. S. Hass, Marianne H. Thuesen, Hans E. M. Christensen, and Jens J. Led pp 753–765 DOI: 10.1021/ja030366m Supporting Info

Peralkylated Coronenes via Regiospecific Hydrogenation of Hexa-peri-hexabenzocoronenes Mark D. Watson, Michael G. Debije, John M. Warman, and Klaus Müllen pp 766–771 DOI: 10.1021/ja037522+ Supporting Info

Photochemistry and Mobility of Stilbenoid Dendrimers in Their Neat Phases Matthias Lehmann, Ingrid Fischbach, Hans Wolfgang Spiess, and Herbert Meier pp 772–784 DOI: 10.1021/ja0366179 Supporting Info

Solid-State Induced Control of Kinetically Unstable Stereoisomers Joseph M. Keane, Fei Ding, Michal Sabat, and W. Dean Harman pp 785–789 DOI: 10.1021/ja0305860 Supporting Info

Unexpectedly Fast Cis/Trans Isomerization of Xaa-Pro Peptide Bonds in Disulfide-Constrained Cyclic Peptides Tiesheng Shi, Stephen M. Spain, and Dallas L. Rabenstein pp 790–796 DOI: 10.1021/ja030311k

Formation of Zn1-xMnxS Nanowires within Mesoporous Silica of Different Pore Sizes Felix J. Brieler, Petra Grundmann, Michael Fröba, Limei Chen, Peter J. Klar, Wolfram Heimbrodt, Hans-Albrecht Krug von Nidda, Thomas Kurz, and Alois Loidl pp 797–807 DOI: 10.1021/ja038960j

Kinetics of End-to-End Collision in Short Single-Stranded Nucleic Acids Xiaojuan Wang and Werner M. Nau pp 808–813 DOI: 10.1021/ja038263r Supporting Info

First-Principle Predictions of Absolute pKa's of Organic Acids in Dimethyl Sulfoxide Solution Yao Fu, Lei Liu, Rui-Qiong Li, Rui Liu, and Qing-Xiang Guo pp 814–822 DOI: 10.1021/ja0378097 Supporting Info

New 1H-Pyrazole-Containing Polyamine Receptors Able To Complex l-Glutamate in Water at Physiological pH Values Carlos Miranda, Francisco Escartí, Laurent Lamarque, María J. R. Yunta, Pilar Navarro, Enrique García-España, and M. Luisa Jimeno pp 823–833 DOI: 10.1021/ja035671m Supporting Info

Enthalpies of Formation of Gas-Phase N3, N3-, N5+, and N5- from Ab Initio Molecular Orbital Theory, Stability Predictions for N5+N3- and N5+N5-, and Experimental Evidence for the Instability of N5+N3- David A. Dixon, David Feller, Karl O. Christe, William W. Wilson, Ashwani Vij, Vandana Vij, H. Donald Brooke Jenkins, Ryan M. Olson, and Mark S. Gordon pp 834–843 DOI: 10.1021/ja0303182

Microwave Spectroscopy Measurements of Rotational Spectra and DFT Calculations for Two Distinct Structural Isomers of 1,1‘-Dimethylferrocene Chakree Tanjaroon, Kristen S. Keck, and Stephen G. Kukolich pp 844–850 DOI: 10.1021/ja030362h Supporting Info

A General Chemical Route to Polyaniline Nanofibers Jiaxing Huang and Richard B. Kaner pp 851–855 DOI: 10.1021/ja0371754

Crystal Growth and Structure Determination of Barium Rhodates:  Stepping Stones toward 2H−BaRhO3 Katharine E. Stitzer, Ahmed El Abed, Jacques Darriet, and Hans-Conrad zur Loye pp 856–864 DOI: 10.1021/ja0374271 Supporting Info

Facile Synthesis and Characterization of Novel Mesoporous and Mesorelief Oxides with Gyroidal Structures Bozhi Tian, Xiaoying Liu, Leonid A. Solovyov, Zheng Liu, Haifeng Yang, Zhendong Zhang, Songhai Xie, Fuqiang Zhang, Bo Tu, Chengzhong Yu, Osamu Terasaki, and Dongyuan Zhao pp 865–875 DOI: 10.1021/ja037877t Supporting Info

Solvent-Mediated Folding of a Doubly Charged Anion Xin Yang, You-Jun Fu, Xue-Bin Wang, Petr Slavíek, Martin Mucha, Pavel Jungwirth, and Lai-Sheng Wang pp 876–883 DOI: 10.1021/ja038108c Supporting Info

New Heterogeneous Polyoxometalate Based Mesoporous Catalysts for Hydrogen Peroxide Mediated Oxidation Reactions Maxym V. Vasylyev and Ronny Neumann pp 884–890 DOI: 10.1021/ja036702g

Hyponitrite Radical, a Stable Adduct of Nitric Oxide and Nitroxyl Gregory A. Poskrebyshev, Vladimir Shafirovich, and Sergei V. Lymar pp 891–899 DOI: 10.1021/ja038042l Supporting Info

On the Mechanisms of Oxidation of Organic Sulfides by H2O2 in Aqueous Solutions Jhih-Wei Chu and Bernhardt L. Trout pp 900–908 DOI: 10.1021/ja036762m Supporting Info

Extreme Projection of a Proton into the π-Cloud of an Aromatic Ring:  Record Shielding of an Aromatic Proton in trans-10b-Methyl-10c-(1-naphthyl)-10b,10c-dihydropyrene Yuhua Ting and Yee-Hing Lai pp 909–914 DOI: 10.1021/ja038380m

Reversible Voltage-Induced Assembly of Au Nanoparticles at Liquid|Liquid Interfaces Bin Su, Jean-Pierre Abid, David J. Fermín, Hubert H. Girault, Hana Hoffmannová, Petr Krtil, and Zdeněk Samec pp 915–919 DOI: 10.1021/ja0386187

Theoretical Study of the Trapping of the OOH Radical by Coenzyme Q Joaquín Espinosa-García pp 920–927 DOI: 10.1021/ja037858j

Quantitative Analysis of Conformational Exchange Contributions to 1H−15N Multiple-Quantum Relaxation Using Field-Dependent Measurements. Time Scale and Structural Characterization of Exchange in a Calmodulin C-Terminal Domain Mutant Patrik Lundström and Mikael Akke pp 928–935 DOI: 10.1021/ja037529r

Computational Elucidation of the Transition State Shape Selectivity Phenomenon Louis A. Clark, Marek Sierka, and Joachim Sauer pp 936–947 DOI: 10.1021/ja0381712 Supporting Info

Band-Selective Carbonyl to Aliphatic Side Chain 13C−13C Distance Measurements in U-13C,15N-Labeled Solid Peptides by Magic Angle Spinning NMR Vladimir Ladizhansky and Robert G. Griffin pp 948–958 DOI: 10.1021/ja037138c Supporting Info

Modeling the Structure of Amorphous MoS3:  A Neutron Diffraction and Reverse Monte Carlo Study Simon J. Hibble and Glenn B. Wood pp 959–965 DOI: 10.1021/ja037666o Supporting Info

Experimental and Theoretical Investigation of the 13C and 15N Chemical Shift Tensors in MelanostatinExploring the Chemical Shift Tensor as a Structural Probe Mark Strohmeier and David M. Grant pp 966–977 DOI: 10.1021/ja037330e

Microwaves in Organic Synthesis Edited by André Loupy (Université Paris-Sud, France). Wiley-VCH:  Weinheim. 2002. xxiv + 499 pp. $195.00. ISBN 3-527-30514-9. James E. Hutchison p 978 DOI: 10.1021/ja0335061

Advances in Chemical Physics, Volume 125 Edited by I. Prigogine (University of Texas at Austin and Université Libre de Bruxelles) and Stuart A. Rice (University of Chicago). John Wiley & Sons, Inc.:  Hoboken. 2003. x + 596 pp. $175.00. ISBN 0-471-21452-3. Todd J. Martínez pp 978–979 DOI: 10.1021/ja0335364

The Chemical Physics of Solid Surfaces. Volume 10. Surface Alloys and Alloy Surfaces Edited by D. P. Woodruff (University of Warwick). Elsevier:  Amsterdam and NewYork. 2002. xvi + 536 pp. $275. ISBN 0-444-51152-0. Glen R. Kowach p 979 DOI: 10.1021/ja0253540

Encyclopedia of Electrochemistry. Volume 4. Corrosion and Oxide Films Edited by Martin Stratmann (Max-Planck Institut für Eisenforschung, Dusseldorf) and Gerald S. Frankel (The Ohio State University). Series Edited by Allen J. Bard and Martin Stratmann. Wiley-VCH:  Weinheim. 2003. x + 746 pp. $430.00. ISBN 3-527-30396-0. Dennis E. Tallman pp 979–980 DOI: 10.1021/ja033594p

Advances in Polymer Science, 159. Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations By Kelly A. Davis (University of Colorado-Boulder) and Krzysztof Matyjaszewski (Carnegie Mellon University). Springer-Verlag:  Berlin, Heidelberg, New York. 2002. xii + 192 pp. $139.00. ISBN 3-540-43244-2. C. Grant Willson p 980 DOI: 10.1021/ja025347b

Colloid Chemistry I. Topics in Current Chemistry, 226 Edited by Markus Antonietti (Max Planck Institute of Colloids and Interfaces, Potsdam, Germany). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. x + 258 pp. $189.00. ISBN 3-540-00415-7. Gudrun Schmidt pp 980–981 DOI: 10.1021/ja033579k

Polymers for Photonics Applications II:  Nonlinear Optical, Photorefractive and Two-Photon Absorption Polymers Edited by Kwang-Sup Lee (Hannam University, Korea). From the series:  Advances in Polymer Science, 161. Springer-Verlag:  Berlin, Heidelberg, New York. 2003. $149.00. ISBN 3-540-43157-8. James K. Whitesell p 981 DOI: 10.1021/ja033565e

Molecular Imprinting:  From Fundamentals to Applications By Makoto Komiyama (University of Tokyo), Toshifumi Takeuchi (Kobe University), Takashi Mukawa (Kobe University), and Hiroyuki Asanuma (University of Tokyo). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. xii + 147 pp. $155.00. ISBN 3-527-30569-6. Bruce P. Branchaud pp 981–982 DOI: 10.1021/ja033532z

Paramagnetic Resonance of Metallobiomolecules Edited by Joshua Telser (Roosevelt University). American Chemical Society (Distributed by Oxford University Press):  Washington, DC. 2003. xiv + 432 pp. $122.50. ISBN 0-8412-3832-4. p 982 DOI: 10.1021/ja0336168

Handbook of Bond Dissociation Energies in Organic Compounds By Yu-Ran Luo (University of South Florida, St. Petersburg). CRC Press LLC:  Boca Raton. 2003. xii + 380 pp. $159.95. ISBN 0-8493-1589-1. p 982 DOI: 10.1021/ja0336224

Issue 04

High Mobility of Dithiophene-Tetrathiafulvalene Single-Crystal Organic Field Effect Transistors Marta Mas-Torrent, Murat Durkut, Peter Hadley, Xavi Ribas, and Concepció Rovira pp 984–985 DOI: 10.1021/ja0393933 Supporting Info

A New Class of “Tethered” Ruthenium(II) Catalyst for Asymmetric Transfer Hydrogenation Reactions Jérôme Hannedouche, Guy J. Clarkson, and Martin Wills pp 986–987 DOI: 10.1021/ja0392768 Supporting Info

A Condensable Amphiphile with a Cleavable Tail as a “Lizard” Template for the Sol−Gel Synthesis of Functionalized Mesoporous Silica Qingmin Zhang, Katsuhiko Ariga, Akihiro Okabe, and Takuzo Aida pp 988–989 DOI: 10.1021/ja039515r Supporting Info

Labeling Vibrations by Light:  Ultrafast Transient 2D-IR Spectroscopy Tracks Vibrational Modes during Photoinduced Charge Transfer Jens Bredenbeck, Jan Helbing, and Peter Hamm pp 990–991 DOI: 10.1021/ja0380190

Desulfurization of Diesel Fuels by Adsorption via π-Complexation with Vapor-Phase Exchanged Cu(I)−Y Zeolites Arturo J. Hernández-Maldonado and Ralph T. Yang pp 992–993 DOI: 10.1021/ja039304m

One-Dimensional Ion Transport in Self-Organized Columnar Ionic Liquids Masafumi Yoshio, Tomohiro Mukai, Hiroyuki Ohno, and Takashi Kato pp 994–995 DOI: 10.1021/ja0382516 Supporting Info

From Evolution to Green Chemistry:  Rationalization of Biomimetic Oxygen-Transfer Cascades Dirk V. Deubel pp 996–997 DOI: 10.1021/ja039234j Supporting Info

Synthesis of Amphidinolide T1 via Catalytic, Stereoselective Macrocyclization Elizabeth A. Colby, Karen C. O'Brien, and Timothy F. Jamison pp 998–999 DOI: 10.1021/ja039716v Supporting Info

Generalized Reconstruction of n-D NMR Spectra from Multiple Projections:  Application to the 5-D HACACONH Spectrum of Protein G B1 Domain Brian E. Coggins, Ronald A. Venters, and Pei Zhou pp 1000–1001 DOI: 10.1021/ja039430q

Glycosidic Bond Cleavage of Thymidine by Low-Energy Electrons Yi Zheng, Pierre Cloutier, Darel J. Hunting, J. Richard Wagner, and Léon Sanche pp 1002–1003 DOI: 10.1021/ja0388562 Supporting Info

Preparation of Micro- and Nanopatterns of Polymer Chains Grafted onto Flexible Polymer Substrates Hans-Peter Brack, Celestino Padeste, Michal Slaski, Selmiye Alkan, and Harun H. Solak pp 1004–1005 DOI: 10.1021/ja0379870 Supporting Info

Thermal Hysteresis in the Photoresponsivity of a Langmuir Film of Amphiphilic Spiropyran Mutsuyoshi Matsumoto, Takahiro Nakazawa, V. Ajay Mallia, Nobuyuki Tamaoki, Reiko Azumi, Hideki Sakai, and Masahiko Abe pp 1006–1007 DOI: 10.1021/ja038844g Supporting Info

Mutation of Two Active-Site Residues Converts a Phosphatidylinositol-Specific Phospholipase C to a Glucose Phosphatase Jianwen Feng, Kimberly Stieglitz, and Mary F. Roberts pp 1008–1009 DOI: 10.1021/ja038529u

Controlling the Selectivity of Competitive Nitroaldol Condensation by Using a Bifunctionalized Mesoporous Silica Nanosphere-Based Catalytic System Seong Huh, Hung-Ting Chen, Jerzy W. Wiench, Marek Pruski, and Victor S.-Y. Lin pp 1010–1011 DOI: 10.1021/ja0398161 Supporting Info

Comparison of Activation Parameters for Ionization Reactions within Zeolites and in Aqueous Solution Norman P. Schepp, Wendy Monk, and Frances L. Cozens pp 1012–1013 DOI: 10.1021/ja038337z Supporting Info

Selective Interactions of Porphyrins with Semiconducting Single-Walled Carbon Nanotubes Huaping Li, Bing Zhou, Yi Lin, Lingrong Gu, Wei Wang, K. A. Shiral Fernando, Satish Kumar, Lawrence F. Allard, and Ya-Ping Sun pp 1014–1015 DOI: 10.1021/ja037142o Supporting Info

Mono- and Diaminocarbenes from Chloroiminium and -amidinium Salts:  Synthesis of Metal-Free Bis(dimethylamino)carbene Michael Otto, Salvador Conejero, Yves Canac, Vadim D. Romanenko, Valentyn Rudzevitch, and Guy Bertrand pp 1016–1017 DOI: 10.1021/ja0393325

C−H Bond Activation of Hydrocarbons by an Imidozirconocene Complex Helen M. Hoyt, Forrest E. Michael, and Robert G. Bergman pp 1018–1019 DOI: 10.1021/ja0385944 Supporting Info

A Quantum Mechanics-Based Scoring Function:  Study of Zinc Ion-Mediated Ligand Binding Kaushik Raha and Kenneth M. Merz, Jr. pp 1020–1021 DOI: 10.1021/ja038496i Supporting Info

Direct Detection of Oxygen Intermediates in the Non-Heme Fe Enzyme Taurine/α-Ketoglutarate Dioxygenase Denis A. Proshlyakov, Timothy F. Henshaw, Greta R. Monterosso, Matthew J. Ryle, and Robert P. Hausinger pp 1022–1023 DOI: 10.1021/ja039113j

Direct Synthesis of Sulfonamides and Activated Sulfonate Esters from Sulfonic Acids Stephen Caddick, Jonathan D. Wilden, and Duncan B. Judd pp 1024–1025 DOI: 10.1021/ja0397658 Supporting Info

Stereocontrolled Polymerization of Racemic Lactide with Chiral Initiator:  Combining Stereoelection and Chiral Ligand-Exchange Mechanism Katarzyna Majerska and Andrzej Duda pp 1026–1027 DOI: 10.1021/ja0388966 Supporting Info

Detection of Free Nickel Monocarbonyl, NiCO: Rotational Spectrum and Structure Emi Yamazaki, Toshiaki Okabayashi, and Mitsutoshi Tanimoto pp 1028–1029 DOI: 10.1021/ja0391309 Supporting Info

Total Synthesis of Spiruchostatin A, a Potent Histone Deacetylase Inhibitor Alexander Yurek-George, Fay Habens, Matthew Brimmell, Graham Packham, and A. Ganesan pp 1030–1031 DOI: 10.1021/ja039258q Supporting Info

Non-Covalent Assembly of a Photoswitchable Surface Christopher G. F. Cooper, John C. MacDonald, Ernesto Soto, and W. Grant McGimpsey pp 1032–1033 DOI: 10.1021/ja039230e Supporting Info

Switching of Chiral Induction in Helical Aromatic Oligoamides Using Solid State−Solution State Equilibrium Hua Jiang, Christel Dolain, Jean-Michel Léger, Heinz Gornitzka, and Ivan Huc pp 1034–1035 DOI: 10.1021/ja039511m Supporting Info

Extending the Chemistry of the Uranyl Ion:  Lewis Acid Coordination to a UO Oxygen Mark J. Sarsfield and Madeleine Helliwell pp 1036–1037 DOI: 10.1021/ja039101y Supporting Info

Discovery of Potent Cell Migration Inhibitors through Total Synthesis:  Lessons from Structure−Activity Studies of (+)-Migrastatin Jón T. Njardarson, Christoph Gaul, Dandan Shan, Xin-Yun Huang, and Samuel J. Danishefsky pp 1038–1040 DOI: 10.1021/ja039714a Supporting Info

Total Synthesis and Examination of Three Key Analogues of Ramoplanin: A Lipoglycodepsipeptide with Potent Antibiotic Activity Yosup Rew, Dongwoo Shin, Inkyu Hwang, and Dale L. Boger pp 1041–1043 DOI: 10.1021/ja039671y Supporting Info

Modular DNA-Programmed Assembly of Linear and Branched Conjugated Nanostructures Kurt V. Gothelf, Anne Thomsen, Morten Nielsen, Emiliano Cló, and Raymond S. Brown pp 1044–1046 DOI: 10.1021/ja038333u Supporting Info

Dissecting the Cholera Toxin−Ganglioside GM1 Interaction by Isothermal Titration Calorimetry W. Bruce Turnbull, Bernie L. Precious, and Steve W. Homans pp 1047–1054 DOI: 10.1021/ja0378207 Supporting Info

Versatile Protein Biotinylation Strategies for Potential High-Throughput Proteomics Rina Y. P. Lue, Grace Y. J. Chen, Yi Hu, Qing Zhu, and Shao Q. Yao pp 1055–1062 DOI: 10.1021/ja037914g Supporting Info

Regioselective Cis−Trans Isomerization of Arachidonic Double Bonds by Thiyl Radicals:  The Influence of Phospholipid Supramolecular Organization Carla Ferreri, Abdelouahid Samadi, Fabio Sassatelli, Laura Landi, and Chryssostomos Chatgilialoglu pp 1063–1072 DOI: 10.1021/ja038072o

Magneto-Mechanical Detection of Nucleic Acids and Telomerase Activity in Cancer Cells Yossi Weizmann, Fernando Patolsky, Oleg Lioubashevski, and Itamar Willner pp 1073–1080 DOI: 10.1021/ja038257v

Quenched Auto-Ligating DNAs:  Multicolor Identification of Nucleic Acids at Single Nucleotide Resolution Shinsuke Sando, Hiroshi Abe, and Eric T. Kool pp 1081–1087 DOI: 10.1021/ja038665z

Influences of Ribonucleotide on a Duplex Conformation and Its Thermal Stability:  Study with the Chimeric RNA−DNA Strands Shu-ichi Nakano, Takayuki Kanzaki, and Naoki Sugimoto pp 1088–1095 DOI: 10.1021/ja037314h Supporting Info

Efficient Trapping of HNO by Deoxymyoglobin Filip Sulc, Chad E. Immoos, Dmitry Pervitsky, and Patrick J. Farmer pp 1096–1101 DOI: 10.1021/ja0376184 Supporting Info

Toward a New Genetic System with Expanded Dimensions:  Size-Expanded Analogues of Deoxyadenosine and Thymidine Haibo Liu, Jianmin Gao, Lystranne Maynard, Y. David Saito, and Eric T. Kool pp 1102–1109 DOI: 10.1021/ja038384r Supporting Info

The Photochemistry of Polydonor-Substituted Phthalimides:  Curtin-Hammett-Type Control of Competing Reactions of Potentially Interconverting Zwitterionic Biradical Intermediates Ung Chan Yoon, Hyuk Chul Kwon, Tae Gyung Hyung, Kyung Hwa Choi, Sun Wha Oh, Shaorong Yang, Zhiming Zhao, and Patrick S. Mariano pp 1110–1124 DOI: 10.1021/ja0305712 Supporting Info

Charge Separation in DNA via Consecutive Adenine Hopping Tadao Takada, Kiyohiko Kawai, Xichen Cai, Akira Sugimoto, Mamoru Fujitsuka, and Tetsuro Majima pp 1125–1129 DOI: 10.1021/ja035730w

Preparation of Oligodiazo Compounds by Using the Suzuki Coupling Reaction and Characterization of Their Photoproducts Tetsuji Itoh, Katsuyuki Hirai, and Hideo Tomioka pp 1130–1140 DOI: 10.1021/ja038450p Supporting Info

Chemical Synthesis of Selenium-Modified Oligoribonucleotides and Their Enzymatic Ligation Leading to an U6 SnRNA Stem−Loop Segment Claudia Höbartner and Ronald Micura pp 1141–1149 DOI: 10.1021/ja038481k Supporting Info

(2,7-Disubstituted-1,8-biphenylenedioxy)bis(dimethylaluminum) as Bidentate Organoaluminum Lewis Acids:  Elucidation and Synthetic Utility of the Double Electrophilic Activation Phenomenon Takashi Ooi, Makoto Takahashi, Masao Yamada, Eiji Tayama, Kiyoyuki Omoto, and Keiji Maruoka pp 1150–1160 DOI: 10.1021/ja030552s Supporting Info

Directed Metalation Route to Ferroelectric Liquid Crystals with a Chiral Fluorenol Core:  The Effect of Restricted Rotation on Polar Order J. Adam McCubbin, Xia Tong, Ruiyao Wang, Yue Zhao, Victor Snieckus, and Robert P. Lemieux pp 1161–1167 DOI: 10.1021/ja038920f Supporting Info

Selective Growth and Distribution of Crystalline Enantiomers in Hydrogels Rositza I. Petrova and Jennifer A. Swift pp 1168–1173 DOI: 10.1021/ja0392263 Supporting Info

Demonstrating the Feasibility of Monitoring the Molecular-Level Structures of Moving Polymer/Silane Interfaces during Silane Diffusion Using SFG Chunyan Chen, Jie Wang, Cheryl L. Loch, Dongchan Ahn, and Zhan ChenZhan Chen pp 1174–1179 DOI: 10.1021/ja0390911

In Situ TA-MS Study of the Six-Membered-Ring-Based Growth of Carbon Nanotubes with Benzene Precursor Yajun Tian, Zheng Hu, Yong Yang, Xizhang Wang, Xin Chen, Hua Xu, Qiang Wu, Weijie Ji, and Yi Chen pp 1180–1183 DOI: 10.1021/ja037561l Supporting Info

Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction James P. Stambuli, Christopher D. Incarvito, Michael Bühl, and John F. Hartwig pp 1184–1194 DOI: 10.1021/ja037928m Supporting Info

Solution-Phase Synthesis of Single-Crystalline Iron Phosphide Nanorods/Nanowires Cheng Qian, Franklin Kim, Lei Ma, Frank Tsui, Peidong Yang, and Jie Liu pp 1195–1198 DOI: 10.1021/ja038401c

Oxidation of CO on Gold Supported Catalysts Prepared by Laser Vaporization: Direct Evidence of Support Contribution S. Arrii, F. Morfin, A. J. Renouprez, and J. L. Rousset pp 1199–1205 DOI: 10.1021/ja036352y

Water Molecule Adsorption on Protonated Dipeptides Motoya Kohtani, Gary A. Breaux, and Martin F. Jarrold pp 1206–1213 DOI: 10.1021/ja0359557 Supporting Info

Heterotopic Assemblage of Two Different Disk-Shaped Ligands through Trinuclear Silver(I) Complexation:  Ligand Exchange-Driven Molecular Motion Shuichi Hiraoka, Motoo Shiro, and Mitsuhiko Shionoya pp 1214–1218 DOI: 10.1021/ja036388q Supporting Info

Electron Density Distribution of an Oxamato Bridged Mn(II)−Cu(II) Bimetallic Chain and Correlation to Magnetic Properties Sébastien Pillet, Mohamed Souhassou, Corine Mathonière, and Claude Lecomte pp 1219–1228 DOI: 10.1021/ja030279u Supporting Info

Scanning Tunneling Microscopy of Self-Assembled Phenylene Ethynylene Oligomers on Au(111) Substrates Karsten Walzer, Eike Marx, Neil C. Greenham, Robert J. Less, Paul R. Raithby, and Kurt Stokbro pp 1229–1234 DOI: 10.1021/ja036771v Supporting Info

Microwave Spectra and Structures of KrAuF, KrAgF, and KrAgBr; 83Kr Nuclear Quadrupole Coupling and the Nature of Noble Gas−Noble Metal Halide Bonding Jason M. Thomas, Nicholas R. Walker, Stephen A. Cooke, and Michael C. L. Gerry pp 1235–1246 DOI: 10.1021/ja0304300 Supporting Info

Mapping the Electronic Structure of the Blue Copper Site in Plastocyanin by NMR Relaxation D. Flemming Hansen and Jens J. Led pp 1247–1252 DOI: 10.1021/ja0379464

Role of the Spacer in the Singlet−Singlet Energy Transfer Mechanism (Förster vs Dexter) in Cofacial Bisporphyrins Sébastien Faure, Christine Stern, Roger Guilard, and Pierre D. Harvey pp 1253–1261 DOI: 10.1021/ja0379823 Supporting Info

Real-Time 2D NMR Identification of Analytes Undergoing Continuous Chromatographic Separation Boaz Shapira, Amir Karton, Dina Aronzon, and Lucio Frydman pp 1262–1265 DOI: 10.1021/ja0389422

Quasi-Relativistic Density Functional Study of Aurophilic Interactions Shu-Guang Wang and W. H. Eugen Schwarz pp 1266–1276 DOI: 10.1021/ja035097e

Photoinduced Intramolecular Charge Transfer in 4-(Dimethyl)aminobenzonitrile − A Theoretical Perspective Dmitrij Rappoport and Filipp Furche pp 1277–1284 DOI: 10.1021/ja037806u

Hydration Structure and Free Energy of Biomolecularly Specific Aqueous Dications, Including Zn2+ and First Transition Row Metals D. Asthagiri, Lawrence R. Pratt, Michael E. Paulaitis, and Susan B. Rempe pp 1285–1289 DOI: 10.1021/ja0382967 Supporting Info

Primary Intermediates of Oxygen Photoevolution Reaction on TiO2 (Rutile) Particles, Revealed by in Situ FTIR Absorption and Photoluminescence Measurements Ryuhei Nakamura and Yoshihiro Nakato pp 1290–1298 DOI: 10.1021/ja0388764

Biochemical Targets of Plant Bioactive Compounds:  A Pharmacological Reference Guide to Sites of Action and Biological Effects By Gideon Polya (La Trobe University, Melbourne, Australia). Taylor & Francis:  London, New York. 2003. xii + 848 pp. $200.00. ISBN 0-415-30829-1. p 1299 DOI: 10.1021/ja033608r

Supercritical Carbon Dioxide:  Separations and Processes Edited by Aravamudan S. Gopalan (New Mexico State University), Chien M. Wai (University of Idaho), and Hollie K. Jacobs (New Mexico State University). American Chemical Society (distributed by Oxford University Press):  Washington, DC. 2003. xiv + 480 pp. $165.00. ISBN 0-8412-3836-7. p 1299 DOI: 10.1021/ja033615f

Name Reactions:  A Collection of Detailed Reaction Mechanisms, Second Edition By Jie Jack Li (Pfizer Global Research and Development, Ann Arbor, MI). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xviii + 466 pp. $79.95. ISBN 3-540-40203-9. p 1299 DOI: 10.1021/ja033624o

Metal Complexes and Metals in Macromolecules:  Synthesis, Structures and Properties By Dieter Wöhrle (University of Bremen) and Anatoli D. Pomogailo (Russian Academy of Sciences, Chernogolovka). Wiley-VCH:  Weinheim. 2003. xviii + 667 pp. $215.00. ISBN 3-527-30499-1. Randolph P. Thummel pp 1299–1300 DOI: 10.1021/ja033593x

Issue 05

Excess Electron-Transfer-Based Repair of a Cis-Syn Thymine Dimer in DNA Is Not Sequence Dependent Sascha Breeger, Ulrich Hennecke, and Thomas Carell pp 1302–1303 DOI: 10.1021/ja038358t

Mechanistic Studies of the Ethylene Trimerization Reaction with Chromium−Diphosphine Catalysts:  Experimental Evidence for a Mechanism Involving Metallacyclic Intermediates Theodor Agapie, Susan J. Schofer, Jay A. Labinger, and John E. Bercaw pp 1304–1305 DOI: 10.1021/ja038968t Supporting Info

Effect of Molecular Oxygen on the Variable-Temperature 29Si MAS NMR Spectra of Zeolite−Sorbate Complexes Colin A. Fyfe and Darren H. Brouwer pp 1306–1307 DOI: 10.1021/ja0367905

Microporous Metal Organic Materials:  Promising Candidates as Sorbents for Hydrogen Storage Long Pan, Michelle B. Sander, Xiaoying Huang, Jing Li, Milton Smith, Edward Bittner, Bradley Bockrath, and J. Karl Johnson pp 1308–1309 DOI: 10.1021/ja0392871 Supporting Info

Synthesis of the Epoxyquinol Dimer RKB-3564 D:  Utilization of an Alkoxysilanol To Promote [4 + 4] Dimerization Chaomin Li and John A. Porco, Jr. pp 1310–1311 DOI: 10.1021/ja039543+ Supporting Info

Tetranuclear Rare Earth Metal Polyhydrido Complexes Composed of “(C5Me4SiMe3)LnH2” Units. Unique Reactivities toward Unsaturated C−C, C−N, and C−O Bonds Dongmei Cui, Olivier Tardif, and Zhaomin Hou pp 1312–1313 DOI: 10.1021/ja039324o Supporting Info

Evidence for Slow Motion in Proteins by Multiple Refocusing of Heteronuclear Nitrogen/Proton Multiple Quantum Coherences in NMR Jens Dittmer and Geoffrey Bodenhausen pp 1314–1315 DOI: 10.1021/ja0386243 Supporting Info

Direct Chemical Evidence for Charge Transfer between Photoexcited 2-Aminopurine and Guanine in Duplex DNA Melanie A. O'Neill, Chikara Dohno, and Jacqueline K. Barton pp 1316–1317 DOI: 10.1021/ja037802p Supporting Info

Influence of Architecture on the Kinetic Stability of Molecular Assemblies Amesh B. Patel, Stephanie Allen, Martyn C. Davies, Clive J. Roberts, Saul J. B. Tendler, and Philip M. Williams pp 1318–1319 DOI: 10.1021/ja0366991

A Zeolitic Organo−Metallophosphate Hybrid Material with Bimodal Porosity Yueh-Chun Liao, Fen-Ling Liao, Wei-Kuo Chang, and Sue-Lein Wang pp 1320–1321 DOI: 10.1021/ja0390146 Supporting Info

Self-Assembled Spiral Nanoarchitecture and Supramolecular Chirality in Langmuir−Blodgett Films of an Achiral Amphiphilic Barbituric Acid Xin Huang, Chao Li, Siguang Jiang, Xuesong Wang, Baowen Zhang, and Minghua Liu pp 1322–1323 DOI: 10.1021/ja036878i Supporting Info

Near-Complete Suppression of Quantum Dot Blinking in Ambient Conditions Sungchul Hohng and Taekjip Ha pp 1324–1325 DOI: 10.1021/ja039686w Supporting Info

Isolation and Ring-Opening of New 1-Sila-3-metallacyclobutanes (η5-C5H4Fe)(CO)2CH2SiR2 Leading to A New Class of Organometallic Polymer Hemant K. Sharma, Francisco Cervantes-Lee, and Keith H. Pannell pp 1326–1327 DOI: 10.1021/ja030559+ Supporting Info

In Rhodobacter sphaeroides Respiratory Nitrate Reductase, the Kinetics of Substrate Binding Favors Intramolecular Electron Transfer Bettina Frangioni, Pascal Arnoux, Monique Sabaty, David Pignol, Patrick Bertrand, Bruno Guigliarelli, and Christophe Léger pp 1328–1329 DOI: 10.1021/ja0384072 Supporting Info

An Unprecedented Hybrid Scorpionate/Cyclopentadienyl Ligand Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda, Agustín Lara-Sánchez, Luis Sánchez-Barba, Ana M. Rodríguez, and Miguel A. Maestro pp 1330–1331 DOI: 10.1021/ja0391558 Supporting Info

Fabrication of Metal Structures with Nanometer-Scale Lateral Dimensions by Sectioning Using a Microtome Qiaobing Xu, Byron D. Gates, and George M. Whitesides pp 1332–1333 DOI: 10.1021/ja0395893 Supporting Info

Catalytic Dehydrocoupling of Amine-Borane and Phosphine-Borane Adducts:  The Mechanism Is Heterogeneous in One Case and Homogeneous in the Other Cory A. Jaska and Ian Manners pp 1334–1335 DOI: 10.1021/ja039162w Supporting Info

Stereoselective Palladium-Catalyzed O-Glycosylation Using Glycals Hahn Kim, Hongbin Men, and Chulbom Lee pp 1336–1337 DOI: 10.1021/ja039746y Supporting Info

Tellurium-Mediated Cycloaromatization of Acyclic Enediynes under Mild Conditions Chad A. Landis, Marcia M. Payne, David L. Eaton, and John E. Anthony pp 1338–1339 DOI: 10.1021/ja0389467 Supporting Info

Suzuki Cross-Couplings of Unactivated Secondary Alkyl Bromides and Iodides Jianrong (Steve) Zhou and Gregory C. Fu pp 1340–1341 DOI: 10.1021/ja039889k Supporting Info

Amino-Aryl-Carbenes: Alternative Ligands for Transition Metals? Xavier Cattoën, Heinz Gornitzka, Didier Bourissou, and Guy Bertrand pp 1342–1343 DOI: 10.1021/ja0396854 Supporting Info

Radical-Type Reactivity of the 1,3-Dibora-2,4-Diphosphoniocyclobutane-1,3-diyl Hideki Amii, Lidija Vranicar, Heinz Gornitzka, Didier Bourissou, and Guy Bertrand pp 1344–1345 DOI: 10.1021/ja039920i Supporting Info

A Sulfoxide-Promoted, Catalytic Method for the Regioselective Synthesis of Allylic Acetates from Monosubstituted Olefins via C−H Oxidation Mark S. Chen and M. Christina White pp 1346–1347 DOI: 10.1021/ja039107n Supporting Info

Controlled Photoinitiated Release of Nitric Oxide from Polymer Films Containing S-Nitroso-N-acetyl-dl-penicillamine Derivatized Fumed Silica Filler Megan C. Frost and Mark E. Meyerhoff pp 1348–1349 DOI: 10.1021/ja039466i Supporting Info

Nucleophilic Attack by Oxyanions on a Phosphate Monoester Dianion:  The Positive Effect of a Cationic General Acid Anthony J. Kirby, Marcelo F. Lima, Davi da Silva, and Faruk Nome pp 1350–1351 DOI: 10.1021/ja038428w Supporting Info

Rapid Assembly of Polycyclic Substances by a Multicomponent Cascade (4 + 2)−(2 + 2) Cycloadditions:  Total Synthesis of the Proposed Structure of Paesslerin A Kazato Inanaga, Kiyosei Takasu, and Masataka Ihara pp 1352–1353 DOI: 10.1021/ja039808k Supporting Info

Triplet π-Diradical Dication of Directly meso−β-Linked Porphyrin Dimer Hiroshi Segawa, Yutaka Senshu, Jotaro Nakazaki, and Kimihiro Susumu pp 1354–1355 DOI: 10.1021/ja0385989 Supporting Info

Molecular Dynamics Simulations of Gas Diffusion in Metal−Organic Frameworks:  Argon in CuBTC Anastasios I. Skoulidas pp 1356–1357 DOI: 10.1021/ja039215+ Supporting Info

Stereocontrolled Total Synthesis of (−)-Vincamajinine and (−)-11-Methoxy-17-epivincamajine Jianming Yu, Xiangyu Z. Wearing, and James M. Cook pp 1358–1359 DOI: 10.1021/ja039798n

Mechanistic Investigation Leads to a Synthetic Improvement in the Hydrolytic Kinetic Resolution of Terminal Epoxides Lars P. C. Nielsen, Christian P. Stevenson, Donna G. Blackmond, and Eric N. Jacobsen pp 1360–1362 DOI: 10.1021/ja038590z Supporting Info

Mapping Enzyme Active Sites in Complex Proteomes Gregory C. Adam, Jonathan Burbaum, John W. Kozarich, Matthew P. Patricelli, and Benjamin F. Cravatt pp 1363–1368 DOI: 10.1021/ja038441g Supporting Info

Dynamics of an Enzymatic Substitution Reaction in Haloalkane Dehalogenase Kwangho Nam, Xavier Prat-Resina, Mireia Garcia-Viloca, Lakshmi S. Devi-Kesavan, and Jiali Gao pp 1369–1376 DOI: 10.1021/ja039093l

Total Chemical Synthesis of Crambin Duhee Bang, Neeraj Chopra, and Stephen B. H. Kent pp 1377–1383 DOI: 10.1021/ja0385078

Optical Sensors Based on Hybrid Aptamer/Conjugated Polymer Complexes Hoang-Anh Ho and Mario Leclerc pp 1384–1387 DOI: 10.1021/ja037289f

Donor−Acceptor (Electronic) Coupling in the Precursor Complex to Organic Electron Transfer:  Intermolecular and Intramolecular Self-Exchange between Phenothiazine Redox Centers Duoli Sun, Sergiy V. Rosokha, and Jay K. Kochi pp 1388–1401 DOI: 10.1021/ja038746v Supporting Info

A Hexa-peri-hexabenzocoronene Cyclophane:  An Addition to the Toolbox for Molecular Electronics Mark D. Watson, Frank Jäckel, Nikolai Severin, Jürgen P. Rabe, and Klaus Müllen pp 1402–1407 DOI: 10.1021/ja037520p Supporting Info

CD Spectra of Polynuclear Complexes of Diimine Ligands:  Theoretical and Experimental Evidence for the Importance of Internuclear Exciton Coupling Shane G. Telfer, Nobuo Tajima, and Reiko Kuroda pp 1408–1418 DOI: 10.1021/ja037596l Supporting Info

From Achiral Ligands to Chiral Coordination Polymers:  Spontaneous Resolution, Weak Ferromagnetism, and Topological Ferrimagnetism En-Qing Gao, Yan-Feng Yue, Shi-Qiang Bai, Zheng He, and Chun-Hua Yan pp 1419–1429 DOI: 10.1021/ja039104a Supporting Info

Selective Activation of Two Sites in RNA by Acridine-Bearing Oligonucleotides for Clipping of Designated RNA Fragments Akinori Kuzuya, Ryo Mizoguchi, Takuro Sasayama, Jing-Min Zhou, and Makoto Komiyama pp 1430–1436 DOI: 10.1021/ja0389568 Supporting Info

Scope of Palladium-Catalyzed Alkylative Ring Opening Mark Lautens and Sheldon Hiebert pp 1437–1447 DOI: 10.1021/ja037550s Supporting Info

NOE and PGSE NMR Spectroscopic Studies of Solution Structure and Aggregation in Metallocenium Ion-Pairs Cristiano Zuccaccia, Nicholas G. Stahl, Alceo Macchioni, Ming-Chou Chen, John A. Roberts, and Tobin J. Marks pp 1448–1464 DOI: 10.1021/ja0387296 Supporting Info

Choice of Coordination Number in d10 Complexes of Group 11 Metals M. Angels Carvajal, Juan J. Novoa, and Santiago Alvarez pp 1465–1477 DOI: 10.1021/ja038416a Supporting Info

Synthesis, Structure and Physical Properties of the First One-Dimensional Phenalenyl-Based Neutral Radical Molecular Conductor S. K. Pal, M. E. Itkis, R. W. Reed, R. T. Oakley, A. W. Cordes, F. S. Tham, T. Siegrist, and R. C. Haddon pp 1478–1484 DOI: 10.1021/ja037864f Supporting Info

Electron Transfer at Self-Assembled Monolayers Measured by Scanning Electrochemical Microscopy Biao Liu, Allen J. Bard, Michael V. Mirkin, and Stephen E. Creager pp 1485–1492 DOI: 10.1021/ja038611p

Nanogel Nanosecond Photonic Crystal Optical Switching Chad E. Reese, Alexander V. Mikhonin, Marta Kamenjicki, Alexander Tikhonov, and Sanford A. Asher pp 1493–1496 DOI: 10.1021/ja037118a Supporting Info

New Approach to Oligonucleotide Microarrays Using Zirconium Phosphonate-Modified Surfaces Guillaume Nonglaton, Isa O. Benitez, Isabelle Guisle, Muriel Pipelier, Jean Léger, Didier Dubreuil, Charles Tellier, Daniel R. Talham, and Bruno Bujoli pp 1497–1502 DOI: 10.1021/ja039072r

Silver−Phosphine Complexes of the Highly Methylated Carborane Monoanion [closo-1-H-CB11Me11]- Adam J. Clarke, Michael J. Ingleson, Gabriele Kociok-Köhn, Mary F. Mahon, Nathan J. Patmore, Jonathan P. Rourke, Giuseppe D. Ruggiero, and Andrew S. Weller pp 1503–1517 DOI: 10.1021/ja038173m Supporting Info

A Calix[4]arene Carceplex with Four Rh24+ Fasteners F. Albert Cotton, Peng Lei, Chun Lin, Carlos A. Murillo, Xiaoping Wang, Shu-Yan Yu, and Zhong-Xing Zhang pp 1518–1525 DOI: 10.1021/ja0396899 Supporting Info

Encapsulation of Transition Metal Catalysts by Ligand-Template Directed Assembly Vincent F. Slagt, Paul C. J. Kamer, Piet W. N. M. van Leeuwen, and Joost N. H. Reek pp 1526–1536 DOI: 10.1021/ja0386795

The Role of Weakly Bound On-Top Oxygen in the Catalytic CO Oxidation Reaction over RuO2(110) Stefan Wendt, Marcus Knapp, and Herbert Over pp 1537–1541 DOI: 10.1021/ja0364423

New Model for a Theoretical Density Functional Theory Investigation of the Mechanism of the Carbonic Anhydrase:  How Does the Internal Bicarbonate Rearrangement Occur? Andrea Bottoni, Camilla Zaira Lanza, Gian Pietro Miscione, and Domenico Spinelli pp 1542–1550 DOI: 10.1021/ja030336j Supporting Info

Structure Dependence of NO Adsorption and Dissociation on Platinum Surfaces Q. Ge and M. Neurock pp 1551–1559 DOI: 10.1021/ja036575o

Affinity Transformation from Hydrophilicity to Hydrophobicity of Water Molecules on the Basis of Adsorption of Water in Graphitic Nanopores Tomonori Ohba, Hirofumi Kanoh, and Katsumi Kaneko pp 1560–1562 DOI: 10.1021/ja038842w

An Investigation of the Mechanisms of Electronic Sensing of Protein Adsorption on Carbon Nanotube Devices Robert J. Chen, Hee Cheul Choi, Sarunya Bangsaruntip, Erhan Yenilmez, Xiaowu Tang, Qian Wang, Ying-Lan Chang, and Hongjie Dai pp 1563–1568 DOI: 10.1021/ja038702m

Kinetic Inhibitor of Hydrate Crystallization Mark T. Storr, Paul C. Taylor, Jean-Pierre Monfort, and P. Mark Rodger pp 1569–1576 DOI: 10.1021/ja035243g Supporting Info

β-Cyclodextrin Host−Guest Complexes Probed under Thermodynamic Equilibrium:  Thermodynamics and AFM Force Spectroscopy Tommaso Auletta, Menno R. de Jong, Alart Mulder, Frank C. J. M. van Veggel, Jurriaan Huskens, David N. Reinhoudt, Shan Zou, Szczepan Zapotoczny, Holger Schönherr, G. Julius Vancso, and Laurens Kuipers pp 1577–1584 DOI: 10.1021/ja0383569 Supporting Info

X-ray and Inner-Shell Processes. 19th International Conference on X-ray and Inner-Shell Processes Edited by Antonio Bianconi (Università di Roma “La Sapienza”), Augusto Marcelli (INFN-LNF, Rome), and Naurang L. Saini (Università di Roma “La Sapienza”). American Institute of Physics:  New York. 2003. xiv + 534 pp. $190.00. ISBN 0-7354-0111-X. p 1585 DOI: 10.1021/ja033625g

Additives in Water-Borne Coatings Edited by Gerry Davison and Bruce Lane (Consultants). Royal Society of Chemistry:  Cambridge. 2003. viii + 88 pp. $219.00. ISBN 0-85404-613-5. p 1585 DOI: 10.1021/ja033631c

Sample Preparation Techniques in Analytical Chemistry Edited by Somenath Mitra (New Jersey Institute of Technology). From the series Chemical Analysis, Volume 162. Edited by J. D. Winefordner. John Wiley & Sons, Inc.:  Hoboken, NJ. 2003. xx + 458 pp. $89.95. ISBN 0-471-32845-6. p 1585 DOI: 10.1021/ja0336325

Plasma Source Mass Spectrometry:  Applications and Emerging Technologies Edited by J. G. Holland (University of Durham, UK) and S. D. Tanner (PerkinElmer SCIEX, Canada). Royal Society of Chemistry:  Cambridge. 2003. x + 412 pp. $269.00. ISBN 0-85404-603-8. p 1585 DOI: 10.1021/ja033633x

Colloid Chemistry II. Topics in Current Chemistry, 227 Edited by Markus Antonietti (Max Planck Institute of Colloids and Interfaces, Potsdam). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. x + 230 pp. $189.00. ISBN 3-540-00418-1. Jan C. T. Kwak pp 1585–1586 DOI: 10.1021/ja033591c

CRC Handbook of Chemistry and Physics, 84th Edition Edited by David R. Lide (National Institute of Standards and Technology). CRC Press LLC:  Boca Raton. 2003. 2616 pp. $139.95. ISBN 0-8493-0484-9. p 1586 DOI: 10.1021/ja0336372

Encyclopedia of Electrochemistry, Volume 2:  Interfacial Kinetics and Mass Transport Edited by Ernesto Julio Calvo (Universidad de Buenos Aires, Argentina). Series Edited by Allen J. Bard and Martin Stratmann. Wiley-VCH:  Weinheim. 2003. x + 553 pp. $320.00. ISBN 3-527-30394-4. Keith J. Stevenson pp 1586–1587 DOI: 10.1021/ja033595h

Modern Mass Spectrometry. Topics in Current Chemistry, Volume 225 Edited by Christoph A. Schalley (University of Bonn). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xii + 318 pp. $269.00. ISBN 3-540-00098-4. Jennifer S. Brodbelt pp 1587–1588 DOI: 10.1021/ja033605e

Riegel's Handbook of Industrial Chemistry, Tenth Edition Edited by James A. Kent (Morgantown, WV). Kluwer Academic Publishers:  New York, Dordrecht. 2003. 1374 pp. $495.00 until April 1, 2004, $595.00 thereafter. ISBN 0-306-47411-5. p 1588 DOI: 10.1021/ja033645i

Studies in Natural Products Chemistry, Volume 28:  Bioactive Natural Products (Part I) Edited by Atta-ur-Rahman (University of Karachi). Elsevier:  Amsterdam. 2003. xiv + 798 pp. $406.00. ISBN 0-444-51415-5. p 1588 DOI: 10.1021/ja033649n

Issue 06

Small Molecules that Induce Cardiomyogenesis in Embryonic Stem Cells Xu Wu, Sheng Ding, Qiang Ding, Nathanael S. Gray, and Peter G. Schultz pp 1590–1591 DOI: 10.1021/ja038950i Supporting Info

A Case for Enantioselective Allylic Alkylation Catalyzed by Palladium Nanoparticles Susanna Jansat, Montserrat Gómez, Karine Philippot, Guillermo Muller, Ester Guiu, Carmen Claver, Sergio Castillón, and Bruno Chaudret pp 1592–1593 DOI: 10.1021/ja036132k Supporting Info

A New Class of Platinum(II) Vapochromic Salts Levi J. Grove, Jeffrey M. Rennekamp, Hershel Jude, and William B. Connick pp 1594–1595 DOI: 10.1021/ja037783j Supporting Info

Organic Thin Film Transistors from a Soluble Oligothiophene Derivative Containing Thermally Removable Solubilizing Groups Amanda R. Murphy, Jean M. J. Fréchet, Paul Chang, Josephine Lee, and Vivek Subramanian pp 1596–1597 DOI: 10.1021/ja039529x Supporting Info

Photolysis and Recombination of Adenosylcobalamin Bound to Glutamate Mutase Roseanne J. Sension, Allwyn G. Cole, Ahmasi D. Harris, Christel C. Fox, Neal W. Woodbury, Su Lin, and E. Neil G. Marsh pp 1598–1599 DOI: 10.1021/ja0396910

Electron-Transfer State of 9-Mesityl-10-methylacridinium Ion with a Much Longer Lifetime and Higher Energy Than That of the Natural Photosynthetic Reaction Center Shunichi Fukuzumi, Hiroaki Kotani, Kei Ohkubo, Seiji Ogo, Nikolai V. Tkachenko, and Helge Lemmetyinen pp 1600–1601 DOI: 10.1021/ja038656q Supporting Info

Zeotype Ionic Crystal of Cs5[Cr3O(OOCH)6(H2O)3][α-CoW12O40]·7.5H2O with Shape-Selective Adsorption of Water Sayaka Uchida and Noritaka Mizuno pp 1602–1603 DOI: 10.1021/ja038063f Supporting Info

Supramolecular Catalysts by Encapsulating Palladium Complexes within Dendrimers Masahiko Ooe, Makoto Murata, Tomoo Mizugaki, Kohki Ebitani, and Kiyotomi Kaneda pp 1604–1605 DOI: 10.1021/ja038455m Supporting Info

Evidence for Molecularly Chemisorbed Oxygen on TiO2 Supported Gold Nanoclusters and Au(111) James D. Stiehl, Tae S. Kim, Sean M. McClure, and C. Buddie Mullins pp 1606–1607 DOI: 10.1021/ja039214h

A Polymer Scaffold for Protein Oligomerization Byron R. Griffith, Benjamin L. Allen, Alan C. Rapraeger, and Laura L. Kiessling pp 1608–1609 DOI: 10.1021/ja037646m Supporting Info

Isolation of a Stable 1-Iridabicyclo[3.2.0]hepta-1,3,6-triene and Its Reversible Transformation into an Iridacycloheptatriene Margarita Paneque, Manuel L. Poveda, Nuria Rendón, and Kurt Mereiter pp 1610–1611 DOI: 10.1021/ja0393527 Supporting Info

The Brønsted Acid-Catalyzed Direct Aza-Darzens Synthesis of N-Alkyl cis-Aziridines Amie L. Williams and Jeffrey N. Johnston pp 1612–1613 DOI: 10.1021/ja0385282 Supporting Info

The NQR Observation of Spin-Peierls Transition in an Antiferromagnetic MX-Chain Complex [NiBr(chxn)2]Br2 Shinya Takaishi, Yasuhiro Tobu, Hiroshi Kitagawa, Atsushi Goto, Tadashi Shimizu, Takashi Okubo, Tadaoki Mitani, and Ryuichi Ikeda pp 1614–1615 DOI: 10.1021/ja039857x Supporting Info

Heterogeneous Catalysis Using a Nanostructured Solid Acid Resin Based on Lyotropic Liquid Crystals Yanjie Xu, Weiqiang Gu, and Douglas L. Gin pp 1616–1617 DOI: 10.1021/ja038501i Supporting Info

Th-C60F24 Nadezhda I. Denisenko, Sergey I. Troyanov, Alexey A. Popov, Igor V. Kuvychko, Boris Žemva, Erhard Kemnitz, Steven H. Strauss, and Olga V. Boltalina pp 1618–1619 DOI: 10.1021/ja039361f Supporting Info

Stereoselective Synthesis of Tetrahydrofurans via the Palladium-Catalyzed Reaction of Aryl Bromides with γ-Hydroxy Alkenes:  Evidence for an Unusual Intramolecular Olefin Insertion into a Pd(Ar)(OR) Intermediate John P. Wolfe and Michael A. Rossi pp 1620–1621 DOI: 10.1021/ja0394838 Supporting Info

Palladium-Catalyzed Intramolecular Asymmetric Hydroamination of Alkynes Léopold M. Lutete, Isao Kadota, and Yoshinori Yamamoto pp 1622–1623 DOI: 10.1021/ja039774g Supporting Info

Remarkably Facile Hexatriene Electrocyclizations as a Route to Functionalized Cyclohexenones via Ring Expansion of Cyclobutenones Nabi A. Magomedov, Piero L. Ruggiero, and Yuchen Tang pp 1624–1625 DOI: 10.1021/ja0399066 Supporting Info

Highly Enantioselective Asymmetric Hydrogenation of α-Phthalimide Ketone:  An Efficient Entry to Enantiomerically Pure Amino Alcohols Aiwen Lei, Shulin Wu, Minsheng He, and Xumu Zhang pp 1626–1627 DOI: 10.1021/ja039153n Supporting Info

Readily Available [2.2.2]-Bicyclooctadienes as New Chiral Ligands for Ir(I):  Catalytic, Kinetic Resolution of Allyl Carbonates Christian Fischer, Christian Defieber, Takeyuki Suzuki, and Erick M. Carreira pp 1628–1629 DOI: 10.1021/ja0390707 Supporting Info

Fine Control of the Release and Encapsulation of Fe Ions in Dendrimers through Ferritin-like Redox Switching Reina Nakajima, Masanori Tsuruta, Masayoshi Higuchi, and Kimihisa Yamamoto pp 1630–1631 DOI: 10.1021/ja037480p Supporting Info

The Tetra(vinyl)phosphonium Cation [(CH2CH)4P]+ Uwe V. Monkowius, Stefan D. Nogai, and Hubert Schmidbaur pp 1632–1633 DOI: 10.1021/ja0399019 Supporting Info

Chemically Induced Anion Radical Cycloadditions:  Intramolecular Cyclobutanation of Bis(enones) via Homogeneous Electron Transfer Jingkui Yang, Greg A. N. Felton, Nathan L. Bauld, and Michael J. Krische pp 1634–1635 DOI: 10.1021/ja030543j Supporting Info

NMR Probing of Protein−Protein Interactions Using Reporter Ligands and Affinity Tags Martin L. Ludwiczek, Bettina Baminger, and Robert Konrat pp 1636–1637 DOI: 10.1021/ja039149b

Synthesis of Readily Modifiable Cyclodextrin Analogues via Cyclodimerization of an Alkynyl−Azido Trisaccharide Kyle D. Bodine, David Y. Gin, and Mary S. Gin pp 1638–1639 DOI: 10.1021/ja039374t Supporting Info

Gatekeeping Layer Effect:  A Poly(lactic acid)-coated Mesoporous Silica Nanosphere-Based Fluorescence Probe for Detection of Amino-Containing Neurotransmitters Daniela R. Radu, Cheng-Yu Lai, Jerzy W. Wiench, Marek Pruski, and Victor S.-Y. Lin pp 1640–1641 DOI: 10.1021/ja038222v Supporting Info

Toward a General Route to the Eunicellin Diterpenes:  The Asymmetric Total Synthesis of Deacetoxyalcyonin Acetate Gary A. Molander, David J. St. Jean, Jr., and Julia Haas pp 1642–1643 DOI: 10.1021/ja0398464 Supporting Info

ENDOR of Spin-Correlated Radical Pairs in Photosynthesis at High Magnetic Field:  A Tool for Mapping Electron Transfer Pathways Oleg G. Poluektov, Lisa M. Utschig, Alexander A. Dubinskij, and Marion C. Thurnauer pp 1644–1645 DOI: 10.1021/ja039309j

Cyclic Voltammetry and Bulk Electronic Properties of Soluble Carbon Nanotubes Manuel Melle-Franco, Massimo Marcaccio, Demis Paolucci, Francesco Paolucci, Vasilios Georgakilas, Dirk M. Guldi, Maurizio Prato, and Francesco Zerbetto pp 1646–1647 DOI: 10.1021/ja039918r Supporting Info

Folding-Promoted Methylation of a Helical DMAP Analogue Jennifer M. Heemstra and Jeffrey S. Moore pp 1648–1649 DOI: 10.1021/ja031842b Supporting Info

Multiple Hydrogen Bonds Tuning Guest/Host Excited-State Proton Transfer Reaction:  Its Application in Molecular Recognition He-Chun Chou, Chin-Hao Hsu, Yi-Ming Cheng, Chung-Chih Cheng, Hsiao-Wei Liu, Shih-Chieh Pu, and Pi-Tai Chou pp 1650–1651 DOI: 10.1021/ja039240f Supporting Info

Large Parity Violation Effects in the Vibrational Spectrum of Organometallic Compounds Peter Schwerdtfeger and Radovan Bast pp 1652–1653 DOI: 10.1021/ja038383z

The Structure and Stability of Biological Metaphosphate, Phosphate, and Phosphorane Compounds in the Gas Phase and in Solution Kevin Range, Matthew J. McGrath, Xabier Lopez, and Darrin M. York pp 1654–1665 DOI: 10.1021/ja0356277 Supporting Info

Paranemic Crossover DNA:  A Generalized Holliday Structure with Applications in Nanotechnology Zhiyong Shen, Hao Yan, Tong Wang, and Nadrian C. Seeman pp 1666–1674 DOI: 10.1021/ja038381e Supporting Info

Thermodynamics of Binding of 2-Methoxy-3-isopropylpyrazine and 2-Methoxy-3-isobutylpyrazine to the Major Urinary Protein Richard J. Bingham, John B. C. Findlay, Shih-Yang Hsieh, Arnout P. Kalverda, Alexandra Kjellberg, Chiara Perazzolo, Simon E. V. Phillips, Kothandaraman Seshadri, Chi H. Trinh, W. Bruce Turnbull, Geoffrey Bodenhausen, and Steve W. Homans pp 1675–1681 DOI: 10.1021/ja038461i

Repair of Guanyl Radicals in Plasmid DNA by Electron Transfer Is Coupled to Proton Transfer Jamie R. Milligan, Joseph A. Aguilera, Oanh Hoang, Ann Ly, Nancy Q. Tran, and John F. Ward pp 1682–1687 DOI: 10.1021/ja030319u

Elucidation of the Electron Transfer Reduction Mechanism of Anthracene Endoperoxides Robert L. Donkers and Mark S. Workentin pp 1688–1698 DOI: 10.1021/ja035828a Supporting Info

Stereochemistry of Cyclopropane Formation Involving Group IV Organometallic Complexes Charles P. Casey and Neil A. Strotman pp 1699–1704 DOI: 10.1021/ja030436p

Intramolecular Charge Transfer with the Planarized 4-Aminobenzonitrile 1-tert-Butyl-6-cyano-1,2,3,4-tetrahydroquinoline (NTC6) Klaas A. Zachariasse, Sergey I. Druzhinin, Wilfried Bosch, and Reinhard Machinek pp 1705–1715 DOI: 10.1021/ja037544w Supporting Info

Spectroscopic Identification of Oxonium and Carbenium Ions of Protonated Phenol in the Gas Phase:  IR Spectra of Weakly Bound C6H7O+−L Dimers (L = Ne, Ar, N2) Nicola Solcà and Otto Dopfer pp 1716–1725 DOI: 10.1021/ja0305858

Bioactivation of Self-Immolative Dendritic Prodrugs by Catalytic Antibody 38C2 Marina Shamis, Holger N. Lode, and Doron Shabat pp 1726–1731 DOI: 10.1021/ja039052p Supporting Info

Comparison of the Kinetics and Thermodynamics for Methyl Radical Addition to CC, CO, and CS Double Bonds David J. Henry, Michelle L. Coote, Rodolfo Gómez-Balderas, and Leo Radom pp 1732–1740 DOI: 10.1021/ja039139a Supporting Info

Star-Shaped Azo-Based Dipolar Chromophores:  Design, Synthesis, Matrix Compatibility, and Electro-optic Activity Padma Gopalan, Howard E. Katz, David J. McGee, Chris Erben, Thomas Zielinski, Danielle Bousquet, David Muller, John Grazul, and Ylva Olsson pp 1741–1747 DOI: 10.1021/ja039768k

Expanding the Substrate Repertoire of a DNA Polymerase by Directed Evolution Ming Fa, Annalisa Radeghieri, Allison A. Henry, and Floyd E. Romesberg pp 1748–1754 DOI: 10.1021/ja038525p

Minimal Distortion Pathways in Polyhedral Rearrangements David Casanova, Jordi Cirera, Miquel Llunell, Pere Alemany, David Avnir, and Santiago Alvarez pp 1755–1763 DOI: 10.1021/ja036479n

Organic Layered Crystals with Adjustable Interlayer Distances of 1-Naphthylmethylammonium n-Alkanoates and Isomerism of Hydrogen-Bond Networks by Steric Dimension Kazuki Sada, Katsunari Inoue, Tomoyuki Tanaka, Akira Tanaka, Attila Epergyes, Sadamu Nagahama, Akikazu Matsumoto, and Mikiji Miyata pp 1764–1771 DOI: 10.1021/ja038379n Supporting Info

Synthesis, Chiroptical Properties, and Solid-State Structure Determination of Two New Chiral Dipyrrin Difluoroboryl Chelates Albert Gossauer, Freddy Nydegger, Tibor Kiss, Robert Sleziak, and Helen Stoeckli-Evans pp 1772–1780 DOI: 10.1021/ja030542r Supporting Info

SN versus S+N-:  An Experimental and Theoretical Charge Density Study D. Leusser, J. Henn, N. Kocher, B. Engels, and D. Stalke pp 1781–1793 DOI: 10.1021/ja038941+ Supporting Info

Titanium Hydrazido and Imido Complexes:  Synthesis, Structure, Reactivity, and Relevance to Alkyne Hydroamination Yahong Li, Yanhui Shi, and Aaron L. Odom pp 1794–1803 DOI: 10.1021/ja038320g Supporting Info

Iridium Bis(phosphinite) p-XPCP Pincer Complexes:  Highly Active Catalysts for the Transfer Dehydrogenation of Alkanes Inigo Göttker-Schnetmann, Peter White, and Maurice Brookhart pp 1804–1811 DOI: 10.1021/ja0385235 Supporting Info

Electronic Spectroscopy of UO2 Isolated in a Solid Ar Matrix Christopher J. Lue, Jin Jin, Mariana J. Ortiz, Jonathan C. Rienstra-Kiracofe, and Michael C. Heaven pp 1812–1815 DOI: 10.1021/ja038940h

Theoretical Study of the Spin Trapping of Hydroxyl Radical by Cyclic Nitrones:  A Density Functional Theory Approach Frederick A. Villamena, Christopher M. Hadad, and Jay L. Zweier pp 1816–1829 DOI: 10.1021/ja038838k Supporting Info

Laser Flash Photolysis of tert-Butyl Aroylperbenzoates:  Kinetics of the Singlet and Triplet States and the Aroylphenyl Radicals1 Bipin K. Shah and Douglas C. Neckers pp 1830–1835 DOI: 10.1021/ja030231g Supporting Info

Vibrational Signature of Charge Solvation vs Salt Bridge Isomers of Sodiated Amino Acids in the Gas Phase Catherine Kapota, Joël Lemaire, Philippe Maître, and Gilles Ohanessian pp 1836–1842 DOI: 10.1021/ja036932v

The Properties of Methylene- and Amine-Substituted Zeolites from First Principles Roope Astala and Scott M. Auerbach pp 1843–1848 DOI: 10.1021/ja037890d

Polypeptide Folding Using Monte Carlo Sampling, Concerted Rotation, and Continuum Solvation Jakob P. Ulmschneider and William L. Jorgensen pp 1849–1857 DOI: 10.1021/ja0378862

Electrostatic Study of the Proton Pumping Mechanism in Bovine Heart Cytochrome c Oxidase Dragan M. Popović and Alexei A. Stuchebrukhov pp 1858–1871 DOI: 10.1021/ja038267w

Efficiency of Various Lattices from Hard Ball to Soft Ball:  Theoretical Study of Thermodynamic Properties of Dendrimer Liquid Crystal from Atomistic Simulation Youyong Li, Shiang-Tai Lin, and William A. Goddard III pp 1872–1885 DOI: 10.1021/ja038617e

Double- and Zero-Quantum NMR Relaxation Dispersion Experiments Sampling Millisecond Time Scale Dynamics in Proteins Vladislav Yu. Orekhov, Dmitry M. Korzhnev, and Lewis E. Kay pp 1886–1891 DOI: 10.1021/ja038620y

The Influence of Metal Cluster Size on Adsorption Energies:  CO Adsorbed on Au Clusters Supported on TiO2 Douglas C. Meier and D. Wayne Goodman pp 1892–1899 DOI: 10.1021/ja030359y

Diastereoselective [2 + 2] Photocycloaddition of Stilbene to Chiral Fumarate. Direct versus Charge-Transfer Excitation Hideaki Saito, Tadashi Mori, Takehiko Wada, and Yoshihisa Inoue pp 1900–1906 DOI: 10.1021/ja0370140 Supporting Info

Radical Clock Substrates, Their C−H Hydroxylation Mechanism by Cytochrome P450, and Other Reactivity Patterns:  What Does Theory Reveal about the Clocks' Behavior? Devesh Kumar, Samuël P. de Visser, Pankaz K. Sharma, Shimrit Cohen, and Sason Shaik pp 1907–1920 DOI: 10.1021/ja039439s Supporting Info

Divergent Function in the Crotonase Superfamily:  An Anhydride Intermediate in the Reactions Catalyzed by 3-Hydroisobutyryl-CoA Hydrolase [J. Am. Chem. Soc. 2003, 125, 12076−12077]. Brian L. Wong and John A. Gerlt p 1921 DOI: 10.1021/ja033467t

Long-Distance Radical Cation Migration in Duplex DNA:  The Effect of Contiguous A·A and T·T Mismatches on Efficiency and Mechanism [J. Am. Chem. Soc. 2003, 125, 15732−15733]. Nathan W. Schlientz and Gary B. Schuster p 1921 DOI: 10.1021/ja033468l

Catalysis in Application Edited by S. D. Jackson, J. S. J. Hargreaves, and D. Lennon (University of Glasgow). Royal Society of Chemistry:  Cambridge. 2003. x + 318 pp. $229.00. ISBN 0-85404-608-9. p 1922 DOI: 10.1021/ja033601+

Comprehensive Coordination Chemistry II:  From Biology to Nanotechnology. Volumes 1−10 Edited by Jon A. McCleverty (University of Bristol) and Thomas J. Meyer (Los Alamos National Laboratory). Elsevier:  Amsterdam. 2003. ca. 7000 pp. $5975.00. ISBN 0-08-043748-6. p 1922 DOI: 10.1021/ja033635h

The Porphyrin Handbook, Volumes 11−20 Edited by Karl M. Kadish (University of Houston), Kevin M. Smith (Louisiana State University), and Roger Guilard (Université de Bourgogne). Academic Press (an Imprint of Elsevier):  Amsterdam. 2003. ca. 3500 pp. $3500.00. ISBN 0-12-393220-3. p 1922 DOI: 10.1021/ja033636+

Issue 07

Terminal and Four-Coordinate Vanadium(IV) Phosphinidene Complexes. A Pseudo Jahn−Teller Effect of Second Order Stabilizing the V−P Multiple Bond Falguni Basuli, Brad C. Bailey, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola pp 1924–1925 DOI: 10.1021/ja0392216 Supporting Info

Hybrid Approach to the Synthesis of Highly Luminescent CdTe/ZnS and CdHgTe/ZnS Nanocrystals James M. Tsay, Malte Pflughoefft, Laurent A. Bentolila, and Shimon Weiss pp 1926–1927 DOI: 10.1021/ja039227v Supporting Info

A Combined Density Functional Theory and Molecular Mechanics Study of the Relationship between the Structure of Coenzyme B12 and Its Binding to Methylmalonyl-CoA Mutase Marek Freindorf and Pawel M. Kozlowski pp 1928–1929 DOI: 10.1021/ja028473o

NO-Bound Myoglobin:  Structural Diversity and Dynamics of the NO Ligand Tomasz Zemojtel, Matteo Rini, Karsten Heyne, Thomas Dandekar, Erik T. J. Nibbering, and Pawel M. Kozlowski pp 1930–1931 DOI: 10.1021/ja039086x Supporting Info

Designed Self-Assembly of Molecular Necklaces Using Host-Stabilized Charge-Transfer Interactions Young Ho Ko, Kyungpil Kim, Jin-Koo Kang, Hyungphil Chun, Jae Wook Lee, Shigeru Sakamoto, Kentaro Yamaguchi, James C. Fettinger, and Kimoon Kim pp 1932–1933 DOI: 10.1021/ja031567t Supporting Info

Marked Increase in the Binding Strength between the Substrate and the Covalently Attached Monolayers of Zeolite Microcrystals by Lateral Molecular Cross-Linking between the Neighboring Microcrystals Jin Seon Park, Yun-Jo Lee, and Kyung Byung Yoon pp 1934–1935 DOI: 10.1021/ja038605t Supporting Info

Micellar Affinity Gradient Focusing:  A New Method for Electrokinetic Focusing Karin M. Balss, Wyatt N. Vreeland, Peter B. Howell, Alyssa C. Henry, and David Ross pp 1936–1937 DOI: 10.1021/ja0385641 Supporting Info

Periodicity in Residual Dipolar Couplings and Nucleic Acid Structures Joseph D. Walsh, Javier Cabello-Villegas, and Yun-Xing Wang pp 1938–1939 DOI: 10.1021/ja039446g Supporting Info

Electrostatic Control of the Regioselectivity in the Photoisomerization of trans,trans-1-Fluoro-2,4-hexadiene:  Evidence for Competing Conical Intersections Michael Squillacote, Jingsong Wang, and Jiwei Chen pp 1940–1941 DOI: 10.1021/ja037393x

Interpolyelectrolyte Complexes of Conjugated Copolymers and DNA:  Platforms for Multicolor Biosensors Bin Liu and Guillermo C. Bazan pp 1942–1943 DOI: 10.1021/ja038667j Supporting Info

5H-Oxazol-4-ones as Building Blocks for Asymmetric Synthesis of α-Hydroxycarboxylic Acid Derivatives Barry M. Trost, Kalindi Dogra, and Maurizio Franzini pp 1944–1945 DOI: 10.1021/ja031539a Supporting Info

Preparation and Characterization of an Isometallabenzene with the Structure of a 1,2,4-Cyclohexatriene Pilar Barrio, Miguel A. Esteruelas, and Enrique Oñate pp 1946–1947 DOI: 10.1021/ja039633e Supporting Info

Catalytic Homologation of Vinyltributylstannane to Allyltributylstannane by Mo(IV) Complexes in the Presence of Ethylene Richard R. Schrock, M. Duval-Lungulescu, W. C. Peter Tsang, and Amir H. Hoveyda pp 1948–1949 DOI: 10.1021/ja039173p Supporting Info

Shape Evolution of Single-Crystalline Iron Oxide Nanocrystals Jinwoo Cheon, Nam-Jung Kang, Sang-Min Lee, Jae-Hyun Lee, Ji-Hyun Yoon, and Sang Jun Oh pp 1950–1951 DOI: 10.1021/ja038722o Supporting Info

The Assignment of Downfield Proton Resonances in an Enzyme Inhibitor Complex Using Time-Dependent Saturation Transferred NOEs Hua Deng, Sean Cahill, Linda Kurz, and Robert Callender pp 1952–1953 DOI: 10.1021/ja0378714

Construction of Arene-Fused-Piperidine Motifs by Asymmetric Addition of 2-Trityloxymethylaryllithiums to Nitroalkenes:  The Asymmetric Synthesis of a Dopamine D1 Full Agonist, A-86929 Mitsuaki Yamashita, Ken-ichi Yamada, and Kiyoshi Tomioka pp 1954–1955 DOI: 10.1021/ja031760n Supporting Info

An Approach To Enhance Specificity against RNA Targets Using Heteroconjugates of Aminoglycosides and Chloramphenicol (or Linezolid) Jongkook Lee, Miyun Kwon, Kyung Hyun Lee, Sunjoo Jeong, Soonsil Hyun, Kye Jung Shin, and Jaehoon Yu pp 1956–1957 DOI: 10.1021/ja038937y Supporting Info

Impact of Protein Denaturants and Stabilizers on Water Structure Joseph D. Batchelor, Alina Olteanu, Ashutosh Tripathy, and Gary J. Pielak pp 1958–1961 DOI: 10.1021/ja039335h Supporting Info

Determination of the Glycosidic Bond Angle χ in RNA from Cross-Correlated Relaxation of CH Dipolar Coupling and N Chemical Shift Anisotropy Elke Duchardt, Christian Richter, Oliver Ohlenschläger, Matthias Görlach, Jens Wöhnert, and Harald Schwalbe pp 1962–1970 DOI: 10.1021/ja0367041 Supporting Info

Cyclic Amidine Sugars as Transition-State Analogue Inhibitors of Glycosidases: Potent Competitive Inhibitors of Mannosidases Marie-Pierre Heck, Stéphane P. Vincent, Brion W. Murray, François Bellamy, Chi-Huey Wong, and Charles Mioskowski pp 1971–1979 DOI: 10.1021/ja037822r Supporting Info

Electronically Driven Structural Distortions in Lithium Intercalates of the n = 2 Ruddlesden−Popper-Type Host Y2Ti2O5S2:  Synthesis, Structure, and Properties of LixY2Ti2O5S2 (0 < x < 2) Geoffrey Hyett, Oliver J. Rutt, Zoltán A. Gál, Sophie G. Denis, Michael A. Hayward, and Simon J. Clarke pp 1980–1991 DOI: 10.1021/ja037763h

Solution NMR Studies of the Aβ(1−40) and Aβ(1−42) Peptides Establish that the Met35 Oxidation State Affects the Mechanism of Amyloid Formation Liming Hou, Haiyan Shao, Yongbo Zhang, Hua Li, Nanda K. Menon, Elizabeth B. Neuhaus, John M. Brewer, In-Ja L. Byeon, Dale G. Ray, Michael P. Vitek, Takashi Iwashita, Ronald A. Makula, Alan B. Przybyla, and Michael G. Zagorski pp 1992–2005 DOI: 10.1021/ja036813f

Interaction between Non-Heme Iron of Lipoxygenases and Cumene Hydroperoxide:  Basis for Enzyme Activation, Inactivation, and Inhibition Ardeshir Vahedi-Faridi, Pierre-Alexandre Brault, Priya Shah, Yong-Wah Kim, William R. Dunham, and Max O. Funk, Jr. pp 2006–2015 DOI: 10.1021/ja0390855

Heat-Set Gel-like Networks of Lipophilic Co(II) Triazole Complexes in Organic Media and Their Thermochromic Structural Transitions Keita Kuroiwa, Tomoko Shibata, Akihiko Takada, Norio Nemoto, and Nobuo Kimizuka pp 2016–2021 DOI: 10.1021/ja037847q Supporting Info

Saccharide-Dependent Induction of Chiral Helicity in Achiral Synthetic Hydrogen-Bonding Oligomers Masahiko Inouye, Minoru Waki, and Hajime Abe pp 2022–2027 DOI: 10.1021/ja039371g Supporting Info

Comparison of C−H···π and Hydrophobic Interactions in a β-Hairpin Peptide:  Impact on Stability and Specificity Chad D. Tatko and Marcey L. Waters pp 2028–2034 DOI: 10.1021/ja038258n Supporting Info

Crystal Structures and Topochemical Polymerizations of 7,7,8,8-Tetrakis(alkoxycarbonyl)quinodimethanes Shinji Nomura, Takahito Itoh, Hirofumi Nakasho, Takahiro Uno, Masataka Kubo, Kazuki Sada, Katsunari Inoue, and Mikiji Miyata pp 2035–2041 DOI: 10.1021/ja0386086 Supporting Info

Noncovalent Interactions:  Defining Cooperativity. Ligand Binding Aided by Reduced Dynamic Behavior of Receptors. Binding of Bacterial Cell Wall Analogues to Ristocetin A Dudley H. Williams, Nichola L. Davies, Rosa Zerella, and Ben Bardsley pp 2042–2049 DOI: 10.1021/ja039409p Supporting Info

Four-Arm Oligonucleotide Ni(II)−Cyclam-Centered Complexes as Precursors for the Generation of Supramolecular Periodic Assemblies Kristen M. Stewart and Larry W. McLaughlin pp 2050–2057 DOI: 10.1021/ja037424o Supporting Info

Modular Domain Structure:  A Biomimetic Strategy for Advanced Polymeric Materials Zhibin Guan, Jason T. Roland, Jane Z. Bai, Sharon X. Ma, Theresa M. McIntire, and Maianh Nguyen pp 2058–2065 DOI: 10.1021/ja039127p

Catalyst−Nanostructure Interfacial Lattice Mismatch in Determining the Shape of VLS Grown Nanowires and Nanobelts:  A Case of Sn/ZnO Yong Ding, Pu Xian Gao, and Zhong Lin Wang pp 2066–2072 DOI: 10.1021/ja039354r

Selective Metallic Tube Reactivity in the Solution-Phase Osmylation of Single-Walled Carbon Nanotubes Sarbajit Banerjee and Stanislaus S. Wong pp 2073–2081 DOI: 10.1021/ja038111w

A Concept for Controlling Singlet Oxygen (1Δg) Yields Using Nitroxide Radicals:  Phthalocyaninatosilicon Covalently Linked to Nitroxide Radicals Kazuyuki Ishii, Shoji Takeuchi, Shinsuke Shimizu, and Nagao Kobayashi pp 2082–2088 DOI: 10.1021/ja035352v Supporting Info

(Butadiene)metallocene/B(C6F5)3 Pathway to Catalyst Systems for Stereoselective Methyl Methacrylate Polymerization:  Evidence for an Anion Dependent Metallocene Catalyzed Polymerization Process Joachim W. Strauch, Jean-Luc Fauré, Stéphane Bredeau, Cun Wang, Gerald Kehr, Roland Fröhlich, Heinrich Luftmann, and Gerhard Erker pp 2089–2104 DOI: 10.1021/ja035739y Supporting Info

Aromatic vs Aliphatic C−H Cleavage of Alkyl-Substituted Pyridines by (PNPiPr)Re Compounds Oleg V. Ozerov, Maren Pink, Lori A. Watson, and Kenneth G. Caulton pp 2105–2113 DOI: 10.1021/ja036999i Supporting Info

Acrylonitrile Polymerization by Cy3PCuMe and (Bipy)2FeEt2 Frank Schaper, Stephen R. Foley, and Richard F. Jordan pp 2114–2124 DOI: 10.1021/ja039018a Supporting Info

Protons in Supercritical Water:  A Multistate Empirical Valence Bond Study Daniel Laria, Jordi Martí, and Elvira Guàrdia pp 2125–2134 DOI: 10.1021/ja0373418

Binding of an Acetic Acid Ligand to Adenosine:  A Low-Temperature NMR Study Eline M. Basílio Janke, Hans-Heinrich Limbach, and Klaus Weisz pp 2135–2141 DOI: 10.1021/ja038630z

Diffusion NMR Spectroscopy for the Characterization of the Size and Interactions of Colloidal Matter:  The Case of Vesicles and Nanoparticles Massimiliano Valentini, Andrea Vaccaro, Annemie Rehor, Alessandro Napoli, Jeffrey A. Hubbell, and Nicola Tirelli pp 2142–2147 DOI: 10.1021/ja037247r Supporting Info

Definitive Spectroscopic Determination of Zero-Field Splitting in High-Spin Cobalt(II) J. Krzystek, S. A. Zvyagin, Andrew Ozarowski, Adam T. Fiedler, Thomas C. Brunold, and Joshua Telser pp 2148–2155 DOI: 10.1021/ja039257y Supporting Info

Single-Molecule Magnets:  A Large Mn30 Molecular Nanomagnet Exhibiting Quantum Tunneling of Magnetization Monica Soler, Wolfgang Wernsdorfer, Kirsten Folting, Maren Pink, and George Christou pp 2156–2165 DOI: 10.1021/ja0297638 Supporting Info

Long Range 1,4 and 1,6-Interstrand Cross-Links Formed by a Trinuclear Platinum Complex. Minor Groove Preassociation Affects Kinetics and Mechanism of Cross-Link Formation as Well as Adduct Structure Alexander Hegmans, Susan J. Berners-Price, Murray S. Davies, Donald S. Thomas, Anthony S. Humphreys, and Nicholas Farrell pp 2166–2180 DOI: 10.1021/ja036105u Supporting Info

Photoswitchable Flexible and Shape-Persistent Dendrimers:  Comparison of the Interplay between a Photochromic Azobenzene Core and Dendrimer Structure Li-Xin Liao, Francesco Stellacci, and Dominic V. McGrath pp 2181–2185 DOI: 10.1021/ja036418p

Nature of One-Dimensional Short Hydrogen Bonding:  Bond Distances, Bond Energies, and Solvent Effects Seung Bum Suh, Jong Chan Kim, Young Cheol Choi, Sunggoo Yun, and Kwang S. Kim pp 2186–2193 DOI: 10.1021/ja037607a

A Concise Synthesis of the Octalactins Paul T. O'Sullivan, Wilm Buhr, Mary Ann M. Fuhry, Justin R. Harrison, John E. Davies, Neil Feeder, David R. Marshall, Jonathan W. Burton, and Andrew B. Holmes pp 2194–2207 DOI: 10.1021/ja038353w Supporting Info

Molecular Simulations Suggest Protein Salt Bridges Are Uniquely Suited to Life at High Temperatures Andrew S. Thomas and Adrian H. Elcock pp 2208–2214 DOI: 10.1021/ja039159c Supporting Info

Dynamic Nature of the Intramolecular Electronic Coupling Mediated by a Solvent Molecule:  A Computational Study Alessandro Troisi, Mark A. Ratner, and Matthew B. Zimmt pp 2215–2224 DOI: 10.1021/ja038905a

Dynamics of Proton Transfer in Bacteriorhodopsin Yong-Sok LeeMorris Krauss pp 2225–2230 DOI: 10.1021/ja036115v

Separation of Anisotropic and Steric Substituent Effects−Nuclear Chemical Shielding Analysis of H-4 and C-4 in Phenanthrene and 11-Ethynylphenanthrene Erich Kleinpeter and Sabrina Klod pp 2231–2236 DOI: 10.1021/ja038395k Supporting Info

Electronic Structure of the Cysteine Thiyl Radical:  A DFT and Correlated ab Initio Study Maurice van Gastel, Wolfgang Lubitz, Günter Lassmann, and Frank Neese pp 2237–2246 DOI: 10.1021/ja038813l Supporting Info

NMR R1ρ Rotating-Frame Relaxation with Weak Radio Frequency Fields Francesca Massi, Eric Johnson, Chunyu Wang, Mark Rance, and Arthur G. Palmer, III pp 2247–2256 DOI: 10.1021/ja038721w

A Novel Selective Solid State Photoxidant [J. Am. Chem. Soc. 2003, 125, 14917−14925]. Tracy L. Morkin, Nicholas J. Turro, Mark H. Kleinman, Cheyenne S. Brindle, Kirsten Griffiths, Wolfgang H. Kramer, and Ian R. Gould p 2257 DOI: 10.1021/ja0408000

Statistics for the Quality Control Chemistry Lab-oratory By Eamonn Mullins (Trinity College, Dublin, Ireland). Royal Society of Chemistry:  Cambridge. 2003. xviii + 456 pp. $89.95. ISBN 0-85404-671-2. p 2258 DOI: 10.1021/ja033641d

Environmental Radiochemical Analysis II Edited by Peter Warwick (Loughborough University, Leicestershire, UK). Royal Society of Chemistry:  Cambridge. 2003. xii + 420 pp. $275.00. ISBN 0-85404-618-6. p 2258 DOI: 10.1021/ja033643y

Targets in Heterocyclic Systems:  Chemistry and Properties, Volume 6 (2002). Reviews and Accounts on Heterocyclic Chemistry Edited by Orazio A. Attanasi (University of Urbino) and Domenico Spinelli (University of Bologna). Italian Society of Chemistry:  Rome. 2003. viii + 418 pp. $139.00. ISBN 88-86208-23-5. p 2258 DOI: 10.1021/ja033644q

Seminars in Organic Synthesis:  XXVIII Summer School “A. Corbella”, June 16−20, 2003, Palazzo Feltrinelli, Università degli Studi di Milano, Gargnano (BS) Italian Society of Chemistry:  Rome. 2003. 408 pp. (plus a 30 page supplement). $129.00. ISBN 88-86208-27-8. p 2258 DOI: 10.1021/ja033653z

Issue 08

Fluorescence Detection of Surface-Bound Intermediates Produced from UV Photoreactivity of Alkylsiloxane SAMs Eric A. McArthur, Tao Ye, Jason P. Cross, Stéphane Petoud, and Eric Borguet pp 2260–2261 DOI: 10.1021/ja038062n Supporting Info

Direct Observation of Electronic Relaxation Dynamics in Adenine via Time-Resolved Photoelectron Spectroscopy Susanne Ullrich, Thomas Schultz, Marek Z. Zgierski, and Albert Stolow pp 2262–2263 DOI: 10.1021/ja030532q

Direct Monitoring of Enzymatic Glucan Hydrolysis on a 27-MHz Quartz-Crystal Microbalance Hidekazu Nishino, Takanori Nihira, Toshiaki Mori, and Yoshio Okahata pp 2264–2265 DOI: 10.1021/ja0361805 Supporting Info

Direct Determination of Hydrogen-Bonded Structures in Resonant and Tautomeric Reactions Using Ultrafast Electron Diffraction Ramesh Srinivasan, Jonathan S. Feenstra, Sang Tae Park, Shoujun Xu, and Ahmed H. Zewail pp 2266–2267 DOI: 10.1021/ja031927c

Conjugated Polymers Featuring Heavier Main Group Element Multiple Bonds:  A Diphosphene-PPV Rhett C. Smith and John D. Protasiewicz pp 2268–2269 DOI: 10.1021/ja0394683 Supporting Info

Fabrication of Polyelectrolyte Multilayer Films Comprising Nanoblended Layers Jinhan Cho, John F. Quinn, and Frank Caruso pp 2270–2271 DOI: 10.1021/ja039830d Supporting Info

A Highly Selective and Sensitive Fluorescent Chemosensor for Hg2+ in Neutral Buffer Aqueous Solution Xiangfeng Guo, Xuhong Qian, and Lihua Jia pp 2272–2273 DOI: 10.1021/ja037604y Supporting Info

5-Cyanoamino-4-imidazolecarboxamide and Nitrosative Guanine Deamination:  Experimental Evidence for Pyrimidine Ring-Opening during Deamination Ming Qian and Rainer Glaser pp 2274–2275 DOI: 10.1021/ja0389523 Supporting Info

Shear-Induced Alignment and Nanowire Silica Synthesis in a Rigid Crystalline Surfactant Mesophase Limin Liu, Mohit Singh, Vijay T. John, Gary L. McPherson, Jibao He, Vivek Agarwal, and Arijit Bose pp 2276–2277 DOI: 10.1021/ja0375636 Supporting Info

Oligomer-Assisted Synthesis of Chiral Polyaniline Nanofibers Wenguang Li and Hsing-Lin Wang pp 2278–2279 DOI: 10.1021/ja039672q

Lanthanide Coordination Polymers and Their Ag+-Modulated Fluorescence Weisheng Liu, Tianquan Jiao, Yizhi Li, Quanzhong Liu, Minyu Tan, Hong Wang, and Liufang Wang pp 2280–2281 DOI: 10.1021/ja036635q Supporting Info

New Tools for Molecular Imaging of Redox Metabolism:  Development of a Fluorogenic Probe for 3α-Hydroxysteroid Dehydrogenases Dominic J. Yee, Vojtech Balsanek, and Dalibor Sames pp 2282–2283 DOI: 10.1021/ja039799f Supporting Info

A Cα−H···O Hydrogen Bond in a Membrane Protein Is Not Stabilizing Sarah Yohannan, Salem Faham, Duan Yang, David Grosfeld, Aaron K. Chamberlain, and James U. Bowie pp 2284–2285 DOI: 10.1021/ja0317574 Supporting Info

Donor-Stabilized Cations and Imine Transfer from N-Silylphosphoranimines Eric Rivard, Keith Huynh, Alan J. Lough, and Ian Manners pp 2286–2287 DOI: 10.1021/ja039549z Supporting Info

Can Multivalency Be Expressed Kinetically? The Answer Is Yes Jovica D. Badjić, Stuart J. Cantrill, and J. Fraser Stoddart pp 2288–2289 DOI: 10.1021/ja0395285 Supporting Info

Thermoresponsive Nanostructures by Self-Assembly of a Poly(N-isopropylacrylamide)−Lipid Conjugate Daniel N. T. Hay, Paul G. Rickert, Sönke Seifert, and Millicent A. Firestone pp 2290–2291 DOI: 10.1021/ja039023e Supporting Info

Synthesis of Surface Organopalladium Intermediates in Coupling Reactions:  The Mechanistic Insight Boyapati M. Choudary, Sateesh Madhi, Mannepalli L. Kantam, Bojja Sreedhar, and Yasuhiro Iwasawa pp 2292–2293 DOI: 10.1021/ja038270f Supporting Info

Lewis Acid-Promoted Carbon−Carbon Bond Cleavage of Aziridines:  Divergent Cycloaddition Pathways of the Derived Ylides Patrick D. Pohlhaus, Roy K. Bowman, and Jeffrey S. Johnson pp 2294–2295 DOI: 10.1021/ja0397963 Supporting Info

Single-Molecule Conformations Probe Free Volume in Polymers Renaud A. L. Vallée, Mircea Cotlet, Mark Van Der Auweraer, Johan Hofkens, K. Müllen, and Frans C. De Schryver pp 2296–2297 DOI: 10.1021/ja031599g

A Gene Cluster Encoding Resistomycin Biosynthesis in Streptomyces resistomycificus; Exploring Polyketide Cyclization beyond Linear and Angucyclic Patterns Kathrin Jakobi and Christian Hertweck pp 2298–2299 DOI: 10.1021/ja0390698 Supporting Info

A Highly Selective Catalytic Method for the Oxidative Functionalization of C−H Bonds Allison R. Dick, Kami L. Hull, and Melanie S. Sanford pp 2300–2301 DOI: 10.1021/ja031543m Supporting Info

Synthesis of Aryl Ketones by the Pd-Catalyzed C−H Activation of Arenes and Intermolecular Carbopalladation of Nitriles Chengxiang Zhou and Richard C. Larock pp 2302–2303 DOI: 10.1021/ja038687l Supporting Info

Nanometric Sponges Made of Water-Soluble Hydrophobic Dendrimers Julien Leclaire, Yannick Coppel, Anne-Marie Caminade, and Jean-Pierre Majoral pp 2304–2305 DOI: 10.1021/ja039684b Supporting Info

Formaldehyde Encapsulated in Zeolite:  A Long-Lived, Highly Activated One-Carbon Electrophile to Carbonyl-Ene Reactions Takahiro Okachi and Makoto Onaka pp 2306–2307 DOI: 10.1021/ja039737p Supporting Info

Reductive Activation of Carbon−Fluorine Bonds in Perfluoroalkyl Ligands:  An Unexpected Route to the Only Known Tetrafluorobutatriene Transition Metal Complex:  Ir(η5-C5Me5)(PMe3)(2,3-η2-CF2CCCF2) Russell P. Hughes, Roman B. Laritchev, Lev N. Zakharov, and Arnold L. Rheingold pp 2308–2309 DOI: 10.1021/ja031598o Supporting Info

Highly Stable Mesoporous Metal Oxides Using Nano-Propping Hybrid Gemini Surfactants Yi-Yeol Lyu, Seung Hwan Yi, Jeong Kuk Shon, Seok Chang, Lyong Sun Pu, Sang-Yun Lee, Jae Eui Yie, Kookheon Char, Galen D. Stucky, and Ji Man Kim pp 2310–2311 DOI: 10.1021/ja0390348 Supporting Info

Multifunctional Behavior by a Bis-(phosphinimino)methanide Ligand:  η2- vs η3-coordination vs Bronsted Basicity Christine Bibal, Maren Pink, Yegor D. Smurnyy, John Tomaszewski, and Kenneth G. Caulton pp 2312–2313 DOI: 10.1021/ja039711y Supporting Info

The Thiazolium-Catalyzed Sila-Stetter Reaction:  Conjugate Addition of Acylsilanes to Unsaturated Esters and Ketones Anita E. Mattson, Ashwin R. Bharadwaj, and Karl A. Scheidt pp 2314–2315 DOI: 10.1021/ja0318380 Supporting Info

Tuning the Architecture of Mesostructures by Electrodeposition Zhi-Li Xiao, Catherine Y. Han, Wai-Kwong Kwok, Hsien-Hau Wang, Ulrich Welp, Jian Wang, and George W. Crabtree pp 2316–2317 DOI: 10.1021/ja0315154 Supporting Info

Solid-State NMR Spectroscopy of Aligned Lipid Bilayers at Low Temperatures Dong-Kuk Lee, Katherine Henzler Wildman, and Ayyalusamy Ramamoorthy pp 2318–2319 DOI: 10.1021/ja039077o Supporting Info

The Effect of the “Inert” Counteranions in the Deprotonation of the Dihydrogen Complex trans-[FeH(η2-H2)(dppe)2]+:  Kinetic and Theoretical Studies Manuel G. Basallote, Maria Besora, Joaquín Durán, M. Jesús Fernández-Trujillo, Agustí Lledós, M. Angeles Máñez, and Feliu Maseras pp 2320–2321 DOI: 10.1021/ja039844j Supporting Info

Solvent-Resistant Photocurable “Liquid Teflon” for Microfluidic Device Fabrication Jason P. Rolland, R. Michael Van Dam, Derek A. Schorzman, Stephen R. Quake, and Joseph M. DeSimone pp 2322–2323 DOI: 10.1021/ja031657y Supporting Info

Tensegrity:  Construction of Rigid DNA Triangles with Flexible Four-Arm DNA Junctions Dage Liu, Mingsheng Wang, Zhaoxiang Deng, Richard Walulu, and Chengde Mao pp 2324–2325 DOI: 10.1021/ja031754r Supporting Info

Modulation of Radical Ion Pair Lifetimes by the Presence of a Third Spin in Rodlike Donor−Acceptor Triads Emily A. Weiss, Erin T. Chernick, and Michael R. Wasielewski pp 2326–2327 DOI: 10.1021/ja039395n Supporting Info

An EPR, ESEEM, Structural NMR, and DFT Study of a Synthetic Model for the Covalently Ring-Linked Tyrosine-Histidine Structure in the Heme-Copper Oxidases Sun Hee Kim, Constantino Aznar, Marcin Brynda, Louis A. “Pete” Silks, Ryszard Michalczyk, Clifford J. Unkefer, William H. Woodruff, and R. David Britt pp 2328–2338 DOI: 10.1021/ja0303743

Empirical Relationships between Isotope-Edited IR Spectra and Helix Geometry in Model Peptides Wendy Barber-Armstrong, Teraya Donaldson, Himali Wijesooriya, R. A. Gangani D. Silva, and Sean M. Decatur pp 2339–2345 DOI: 10.1021/ja037863n

Nature of Vibrational Coupling in Helical Peptides:  An Isotopic Labeling Study Rong Huang, Jan Kubelka, Wendy Barber-Armstrong, R. A. G. D. Silva, Sean M. Decatur, and Timothy A. Keiderling pp 2346–2354 DOI: 10.1021/ja037998t

Block Catiomer Polyplexes with Regulated Densities of Charge and Disulfide Cross-Linking Directed To Enhance Gene Expression Kanjiro Miyata, Yoshinori Kakizawa, Nobuhiro Nishiyama, Atsushi Harada, Yuichi Yamasaki, Hiroyuki Koyama, and Kazunori Kataoka pp 2355–2361 DOI: 10.1021/ja0379666 Supporting Info

Pyridinedicarboxamide Strands Form Double Helices via an Activated Slippage Mechanism Angela Acocella, Alessandro Venturini, and Francesco Zerbetto pp 2362–2367 DOI: 10.1021/ja038103f

Guanosine Distribution and Oxidation Resistance in Eight Eukaryotic Genomes Keith A. Friedman and Adam Heller pp 2368–2371 DOI: 10.1021/ja038217r Supporting Info

Characteristics of Migration Patterns of DNA Oligomers in Gels and the Relationship to the Question of Intrinsic DNA Bending Tali E. Haran, Ilana Cohen, Alexander Spasic, Kevin Yang, and Udayan Mohanty pp 2372–2377 DOI: 10.1021/ja030572u

Conservation of Mechanism in Three Chorismate-Utilizing Enzymes Ze He, Kimberly D. Stigers Lavoie, Paul A. Bartlett, and Michael D. Toney pp 2378–2385 DOI: 10.1021/ja0389927

Direct Detection of Formate Ligation in Cytochrome c Oxidase by ATR-FTIR Spectroscopy Masayo Iwaki and Peter R. Rich pp 2386–2389 DOI: 10.1021/ja039320j

SOS-NMR:  A Saturation Transfer NMR-Based Method for Determining the Structures of Protein−Ligand Complexes Philip J. Hajduk, Jamey C. Mack, Edward T. Olejniczak, Chang Park, Peter J. Dandliker, and Bruce A. Beutel pp 2390–2398 DOI: 10.1021/ja039480v Supporting Info

Raman Spectroscopic Characterization of Secondary Structure in Natively Unfolded Proteins:  α-Synuclein Nakul C. Maiti, Mihaela M. Apetri, Michael G. Zagorski, Paul R. Carey, and Vernon E. Anderson pp 2399–2408 DOI: 10.1021/ja0356176

Selenium Redox Cycling in the Protective Effects of Organoselenides against Oxidant-Induced DNA Damage Veronica De Silva, Michelle M. Woznichak, Kristi L. Burns, Kathryn B. Grant, and Sheldon W. May pp 2409–2413 DOI: 10.1021/ja037294j

Measurements of Side-Chain 13C−13C Residual Dipolar Couplings in Uniformly Deuterated Proteins Beat Vögeli, Helena Kovacs, and Konstantin Pervushin pp 2414–2420 DOI: 10.1021/ja0381813 Supporting Info

Metal Coordination and Imine−Amine Hydrogen Bonding as the Source of Strongly Shifted Adenine pKa Values Michael Roitzsch and Bernhard Lippert pp 2421–2424 DOI: 10.1021/ja038834f Supporting Info

Total Synthesis of (−)-Apicularen A Qibin Su and James S. Panek pp 2425–2430 DOI: 10.1021/ja037957x Supporting Info

Mechanism of Glucose Oxidation by Quinoprotein Soluble Glucose Dehydrogenase:  Insights from Molecular Dynamics Studies Swarnalatha Y. Reddy and Thomas C. Bruice pp 2431–2438 DOI: 10.1021/ja039722r Supporting Info

Functional Characterization and NMR Spectroscopy on Full-Length Vpu from HIV-1 Prepared by Total Chemical Synthesis Gerd G. Kochendoerfer, David H. Jones, Sangwon Lee, Myrta Oblatt-Montal, Stanley J. Opella, and Mauricio Montal pp 2439–2446 DOI: 10.1021/ja038985i

Nucleophilic Participation in the Transition State for Human Thymidine Phosphorylase Matthew R. Birck and Vern L. Schramm pp 2447–2453 DOI: 10.1021/ja039260h Supporting Info

Molecular Recognition and Fluorescence Sensing of Monophosphorylated Peptides in Aqueous Solution by Bis(zinc(II)−dipicolylamine)-Based Artificial Receptors Akio Ojida, Yasuko Mito-oka, Kazuki Sada, and Itaru Hamachi pp 2454–2463 DOI: 10.1021/ja038277x Supporting Info

Design, Synthesis, and Crystallographic Studies of Neutral Platinum-Based Macrocycles Formed via Self-Assembly Partha Sarathi Mukherjee, Neeladri Das, Yury K. Kryschenko, Atta M. Arif, and Peter J. Stang pp 2464–2473 DOI: 10.1021/ja039235b Supporting Info

High-Efficiency Poly(p-phenylenevinylene)-Based Copolymers Containing an Oxadiazole Pendant Group for Light-Emitting Diodes Sung-Ho Jin, Mock-Yeon Kim, Jin Young Kim, Kwanghee Lee, and Yeong-Soon Gal pp 2474–2480 DOI: 10.1021/ja036955+ Supporting Info

The Active-Site Structure of Umecyanin, the Stellacyanin from Horseradish Roots Christopher Dennison and Mark D. Harrison pp 2481–2489 DOI: 10.1021/ja0375378 Supporting Info

Radical-Promoted Stone−Wales Rearrangements Roger W. Alder and Jeremy N. Harvey pp 2490–2494 DOI: 10.1021/ja039389r Supporting Info

Total Synthesis of the Polyene-Polyol Macrolide RK-397, Featuring Cross-Couplings of Alkynylepoxide Modules Svetlana A. Burova and Frank E. McDonald pp 2495–2500 DOI: 10.1021/ja039618+ Supporting Info

Probing the Ruthenium−Cumulene Bonding Interaction:  Synthesis and Spectroscopic Studies of Vinylidene− and Allenylidene−Ruthenium Complexes Supported by Tetradentate Macrocyclic Tertiary Amine and Comparisons with Diphosphine Analogues of Ruthenium and Osmium Chun-Yuen Wong, Chi-Ming Che, Michael C. W. Chan, King-Hung Leung, David Lee Phillips, and Nianyong Zhu pp 2501–2514 DOI: 10.1021/ja0380648 Supporting Info

An Example of O2 Binding in a Cobalt(II) Corrole System and High-Valent Cobalt−Cyano and Cobalt−Alkynyl Complexes Bobby Ramdhanie, Joshua Telser, Andrea Caneschi, Lev N. Zakharov, Arnold L. Rheingold, and David P. Goldberg pp 2515–2525 DOI: 10.1021/ja036983s Supporting Info

Reactivity of Atomic Gold Anions toward Oxygen and the Oxidation of CO:  Experiment and Theory Michele L. Kimble, A. Welford Castleman, Jr., Roland Mitrić, Christian Bürgel, and Vlasta Bonaić-Koutecký pp 2526–2535 DOI: 10.1021/ja030544b

Reactions of a Platinum(III) Dimeric Complex with Alkynes in Water:  Novel Approach to α-Aminoketone, α-Iminoketone, and α,β-Diimine via Ketonyl−Pt(III) Dinuclear Complexes Masahiko Ochiai, Yong-Shou Lin, Jun Yamada, Hanae Misawa, Saiko Arai, and Kazuko Matsumoto pp 2536–2545 DOI: 10.1021/ja0302634 Supporting Info

Reactivity of Radicals Generated on Irradiation of trans-[Ru(NH3)4(NO2)P(OEt)3](PF6) Rose Maria Carlos, Daniel Rodrigues Cardoso, Eduardo Ernesto Castellano, Renata Zachi Osti, Ademir João Camargo, Luis Guilherme Macedo, and Douglas Wagner Franco pp 2546–2555 DOI: 10.1021/ja0373263 Supporting Info

Utilization of Hydrogen Bonds To Stabilize M−O(H) Units:  Synthesis and Properties of Monomeric Iron and Manganese Complexes with Terminal Oxo and Hydroxo Ligands Cora E. MacBeth, Rajeev Gupta, Katie R. Mitchell-Koch, Victor G. Young, Jr., Gerald H. Lushington, Ward H. Thompson, Michael P. Hendrich, and A. S. Borovik pp 2556–2567 DOI: 10.1021/ja0305151

Electrons Are Transported through Phenylene−Ethynylene Oligomer Monolayers via Localized Molecular Orbitals Fu-Ren F. Fan, Rebecca Y. Lai, Jérôme Cornil, Yasser Karzazi, Jean-Luc Brédas, Lintao Cai, Long Cheng, Yuxing Yao, David W. Price, Jr., Shawn M. Dirk, James M. Tour, and Allen J. Bard pp 2568–2573 DOI: 10.1021/ja038189c Supporting Info

Role of Solvent in Determining Conformational Preferences of Alanine Dipeptide in Water Alexander N. Drozdov, Alan Grossfield, and Rohit V. Pappu pp 2574–2581 DOI: 10.1021/ja039051x

Structure and Dynamics of Au+ Ion in Aqueous Solution: Ab Initio QM/MM MD Simulations Ria Armunanto, Christian F. Schwenk, Hung T. Tran, and Bernd M. Rode pp 2582–2587 DOI: 10.1021/ja037340f

Density Functional Theory Calculations and Exploration of a Possible Mechanism of N2 Reduction by Nitrogenase Uwe Huniar, Reinhart Ahlrichs, and Dimitri Coucouvanis pp 2588–2601 DOI: 10.1021/ja030541z Supporting Info

Factors Governing the Protonation State of Zn-Bound Histidine in Proteins:  A DFT/CDM Study Yen-lin Lin and Carmay Lim pp 2602–2612 DOI: 10.1021/ja038827r Supporting Info

Calculating the Electron Paramagnetic Resonance Parameters of Exchange Coupled Transition Metal Complexes Using Broken Symmetry Density Functional Theory:  Application to a MnIII/MnIV Model Compound Sebastian Sinnecker, Frank Neese, Louis Noodleman, and Wolfgang Lubitz pp 2613–2622 DOI: 10.1021/ja0390202 Supporting Info

Equilibrium Thermodynamic Studies in Water:  Reactions of Dihydrogen with Rhodium(III) Porphyrins Relevant to Rh−Rh, Rh−H, and Rh−OH Bond Energetics Xuefeng Fu and Bradford B. Wayland pp 2623–2631 DOI: 10.1021/ja039218m

Growth of InP Nanostructures via Reaction of Indium Droplets with Phosphide Ions:  Synthesis of InP Quantum Rods and InP−TiO2 Composites Jovan M. Nedeljković, Olga I. Mićić, S. Phillip Ahrenkiel, Alex Miedaner, and Arthur J. Nozik pp 2632–2639 DOI: 10.1021/ja039311a

Dynamics of Competitive Reactions:  Endothermic Proton Transfer and Exothermic Substitution Jianhua Ren and John I. Brauman pp 2640–2646 DOI: 10.1021/ja030006z

Thermodynamics of Forming Water Clusters at Various Temperatures and Pressures by Gaussian-2, Gaussian-3, Complete Basis Set-QB3, and Complete Basis Set-APNO Model Chemistries; Implications for Atmospheric Chemistry Meghan E. Dunn, Emma K. Pokon, and George C. Shields pp 2647–2653 DOI: 10.1021/ja038928p Supporting Info

Concepts in Electron Correlation Edited by Alex C. Hewson (Imperial College, London) and Veljko Zlatic (Institute of Physics, Zagreb). Kluwer Academic Publishers:  Dordrecht. 2003. iv + 386 pp. $164.00. ISBN 1-4020-1418-X. p 2654 DOI: 10.1021/ja033650m

Analyses of Hazardous Substances in Air, Volume 8 Edited by Antonius Kettrup (Institut für Ökologische Chemie, Neuherberg, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. xii + 252 pp. $165.00. ISBN 3-527-27793-5. p 2654 DOI: 10.1021/ja033654r

Industrial Organic Chemistry:  Fourth, Completely Revised Edition By Klaus Weissermel (deceased) and Hans-Jürgen Arpe (Feilbingert, Germany). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim. 2003. xx + 492 pp. $165.00. ISBN 3-527-3578-5. p 2654 DOI: 10.1021/ja033656b

Issue 09

Thermosensitive Gold Nanoparticles Ming-Qiang Zhu, Li-Qiong Wang, Gregory J. Exarhos, and Alexander D. Q. Li pp 2656–2657 DOI: 10.1021/ja038544z Supporting Info

Selective Hydrogenation by Pd Nanoparticles Embedded in Polyelectrolyte Multilayers Srividhya Kidambi, Jinhua Dai, Jin Li, and Merlin L. Bruening pp 2658–2659 DOI: 10.1021/ja038804c Supporting Info

Direct Catalytic Asymmetric Aldol Additions of Methyl Ynones. Spontaneous Reversal in the Sense of Enantioinduction Barry M. Trost, Alec Fettes, and Brock T. Shireman pp 2660–2661 DOI: 10.1021/ja038666r Supporting Info

Transition Metal-Catalyzed One-Pot Synthesis of Water-Soluble Dendritic Molecular Nanocarriers Guanghui Chen and Zhibin Guan pp 2662–2663 DOI: 10.1021/ja039829e Supporting Info

Structural Control of the Excited-State Dynamics of Bis(dipyrrinato)zinc Complexes:  Self-Assembling Chromophores for Light-Harvesting Architectures Igor V. Sazanovich, Christine Kirmaier, Eve Hindin, Lianhe Yu, David F. Bocian, Jonathan S. Lindsey, and Dewey Holten pp 2664–2665 DOI: 10.1021/ja038763k

Synthesis and Characterization of Carboxylate-Rich Complexes Having the {Fe2(μ-OH)2(μ-O2CR)}3+ and {Fe2(μ-O)(μ-O2CR)}3+ Cores of O2-Dependent Diiron Enzymes Sungho Yoon and Stephen J. Lippard pp 2666–2667 DOI: 10.1021/ja031603o Supporting Info

A Bowl-Shaped Fullerene Encapsulates a Water into the Cage Sho-ichi Iwamatsu, Takashi Uozaki, Kaoru Kobayashi, Suyong Re, Shigeru Nagase, and Shizuaki Murata pp 2668–2669 DOI: 10.1021/ja038537a Supporting Info

Sortase-Mediated Protein Ligation:  A New Method for Protein Engineering Hongyuan Mao, Scott A. Hart, Amy Schink, and Brian A. Pollok pp 2670–2671 DOI: 10.1021/ja039915e Supporting Info

Catalysis by Supported Gold:  Correlation between Catalytic Activity for CO Oxidation and Oxidation States of Gold Javier Guzman and Bruce C. Gates pp 2672–2673 DOI: 10.1021/ja039426e Supporting Info

Controlled Vesicle Self-Assembly in Microfluidic Channels with Hydrodynamic Focusing Andreas Jahn, Wyatt N. Vreeland, Michael Gaitan, and Laurie E. Locascio pp 2674–2675 DOI: 10.1021/ja0318030 Supporting Info

Cation−Cation Interactions between Uranyl Cations in a Polar Open-Framework Uranyl Periodate Tyler A. Sullens, Rebecca A. Jensen, Tatiana Y. Shvareva, and Thomas E. Albrecht-Schmitt pp 2676–2677 DOI: 10.1021/ja031695h Supporting Info

Mechanism and Stereochemistry of the Germacradienol/Germacrene D Synthase of Streptomyces coelicolor A3(2) Xiaofei He and David E. Cane pp 2678–2679 DOI: 10.1021/ja039929k Supporting Info

Total Synthesis of (+)-SCH 351448 Eun Joo Kang, Eun Jin Cho, Young Eun Lee, Mi Kyung Ji, Dong Mok Shin, Young Keun Chung, and Eun Lee pp 2680–2681 DOI: 10.1021/ja0315309 Supporting Info

The Absence of Proximal Strain in the Truncated Hemoglobins from Mycobacterium tuberculosis Uri Samuni, Yannick Ouellet, Michel Guertin, Joel M. Friedman, and Syun-Ru Yeh pp 2682–2683 DOI: 10.1021/ja038093i

Interrogating Conformationally Dependent Electron-Transfer Dynamics via Ultrafast Visible Pump/IR Probe Spectroscopy Igor V. Rubtsov, Naomi P. Redmore, Robin M. Hochstrasser, and Michael J. Therien pp 2684–2685 DOI: 10.1021/ja0305499 Supporting Info

Quantification of Hydroxycarbonyls from OH−Isoprene Reactions Jun Zhao, Renyi Zhang, Edward C. Fortner, and Simon W. North pp 2686–2687 DOI: 10.1021/ja0386391 Supporting Info

Remarkable Stereocontrol in the Polymerization of Racemic Lactide Using Aluminum Initiators Supported by Tetradentate Aminophenoxide Ligands Pimpa Hormnirun, Edward L. Marshall, Vernon C. Gibson, Andrew J. P. White, and David J. Williams pp 2688–2689 DOI: 10.1021/ja038757o Supporting Info

Unusually Large Primary 2H/1H Kinetic Isotope Effects Accompanying a syn-β-H Elimination Reaction in a σ-Alkyl−Palladium Complex Guy C. Lloyd-Jones and Paul A. Slatford pp 2690–2691 DOI: 10.1021/ja039349n Supporting Info

Lewis Acid Induced Tandem Diels−Alder Reaction/Ring Expansion as an Equivalent of a [4 + 3] Cycloaddition Huw M. L. Davies and Xing Dai pp 2692–2693 DOI: 10.1021/ja039908q Supporting Info

Imine Insertion into a Late Metal−Carbon Bond To Form a Stable Amido Complex Christopher Krug and John F. Hartwig pp 2694–2695 DOI: 10.1021/ja038819a Supporting Info

Stannaacetylene (RSnCR‘) Showing Carbene-like Reaction Mode Wataru Setaka, Katsuyuki Hirai, Hideo Tomioka, Kenkichi Sakamoto, and Mitsuo Kira pp 2696–2697 DOI: 10.1021/ja0389974 Supporting Info

Ambient Temperature, Tandem Catalytic Dehydrocoupling−Hydrogenation Reactions Using Rh Colloids and Me2NH·BH3 as a Stoichiometric H2 Source Cory A. Jaska and Ian Manners pp 2698–2699 DOI: 10.1021/ja039696x

Enhancement of Molecular Properties in Thin Films by Controlled Orientation of Molecular Building Blocks Roie Yerushalmi, Avigdor Scherz, and Milko E. van der Boom pp 2700–2701 DOI: 10.1021/ja038918o

Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes Masaru Utsunomiya and John F. Hartwig pp 2702–2703 DOI: 10.1021/ja031542u Supporting Info

Three-Dimensionally Packed Nanohelical Phase in Chiral Block Copolymers Rong-Ming Ho, Yeo-Wan Chiang, Chi-Chun Tsai, Chu-Chieh Lin, Bao-Tsan Ko, and Bor-Han Huang pp 2704–2705 DOI: 10.1021/ja039627i Supporting Info

Ruthenium-Catalyzed Functionalization of Aryl Carbon−Oxygen Bonds in Aromatic Ethers with Organoboron Compounds Fumitoshi Kakiuchi, Mayumi Usui, Satoshi Ueno, Naoto Chatani, and Shinji Murai pp 2706–2707 DOI: 10.1021/ja0393170 Supporting Info

Efficient Stereoselective Alkenylation through a Homolytic Domino Reaction Involving a 1,5 Sulfur-to-Carbon Translocation Edward E. Korshin, Yaroslav V. Bilokin, Hailin Zheng, and Mario D. Bachi pp 2708–2709 DOI: 10.1021/ja031766c Supporting Info

Crossover from Positive to Negative Magnetoresistance in a Spinel Dinah R. Parker, Mark A. Green, Steven T. Bramwell, Andrew. S. Wills, Jason S. Gardner, and Dan A. Neumann pp 2710–2711 DOI: 10.1021/ja036965a Supporting Info

Biomimetic Studies on Anti-Thyroid Drugs and Thyroid Hormone Synthesis Gouriprasanna Roy, Munirathinam Nethaji, and G. Mugesh pp 2712–2713 DOI: 10.1021/ja039860g Supporting Info

Rhodium-Catalyzed Carbonylative [3+2+1] Cycloaddition Reaction:  Catalytic Formation of Bicyclic Cyclohexenones from Trienes and Carbon Monoxide Sang Ick Lee, Ji Hoon Park, Young Keun Chung, and Sueg-Geun Lee pp 2714–2715 DOI: 10.1021/ja039301+ Supporting Info

The Complete Characterization of a Rhodium Lewis Acid−Dipolarophile Complex as an Intermediate for the Enantioselective Catalytic 1,3-Dipolar Cycloaddition of C,N-Diphenylnitrone to Methacrolein Daniel Carmona, M. Pilar Lamata, Fernando Viguri, Ricardo Rodríguez, Luis A. Oro, Ana I. Balana, Fernando J. Lahoz, Tomás Tejero, Pedro Merino, Santiago Franco, and Isabel Montesa pp 2716–2717 DOI: 10.1021/ja031995z Supporting Info

Chemometrical Identification of Mutations in HIV-1 Reverse Transcriptase Conferring Resistance or Enhanced Sensitivity to Arylsulfonylbenzonitriles Fátima Rodríguez-Barrios and Federico Gago pp 2718–2719 DOI: 10.1021/ja038893t Supporting Info

Manganese(II) Zero-Field Interaction in Cambialistic and Manganese Superoxide Dismutases and Its Relationship to the Structure of the Metal Binding Site Sun Un, Leandro C. Tabares, Néstor Cortez, B. Yukihiro Hiraoka, and Fumiyuki Yamakura pp 2720–2726 DOI: 10.1021/ja036503x

Electronic Couplings in Organic Mixed-Valence Compounds:  The Contribution of Photoelectron Spectroscopy Veaceslav Coropceanu, Nadine E. Gruhn, Stephen Barlow, Christoph Lambert, Jason C. Durivage, Tonja G. Bill, Gilbert Nöll, Seth R. Marder, and Jean-Luc Brédas pp 2727–2731 DOI: 10.1021/ja039263u

Low-Temperature Cluster Catalysis Ken Judai, Stéphane Abbet, Anke S. Wörz, Ulrich Heiz, and Claude R. Henry pp 2732–2737 DOI: 10.1021/ja039037k

Hydricities of BzNADH, C5H5Mo(PMe3)(CO)2H, and C5Me5Mo(PMe3)(CO)2H in Acetonitrile William W. Ellis, James W. Raebiger, Calvin J. Curtis, Joseph W. Bruno, and Daniel L. DuBois pp 2738–2743 DOI: 10.1021/ja038567d Supporting Info

Gas-Phase Kinetics and Mechanism of the Reactions of Protonated Hydrazine with Carbonyl Compounds. Gas-Phase Hydrazone Formation:  Kinetics and Mechanism Thomas G. Custer, Shuji Kato, Veronica M. Bierbaum, Carleton J. Howard, and Glenn C. Morrison pp 2744–2754 DOI: 10.1021/ja0350886 Supporting Info

Sonoluminescence Quenching of Organic Compounds in Aqueous Solution:  Frequency Effects and Implications for Sonochemistry Gareth J. Price, Muthupandian Ashokkumar, and Franz Grieser pp 2755–2762 DOI: 10.1021/ja0389624 Supporting Info

Efficient Yellow Electroluminescence from a Single Layer of a Cyclometalated Iridium Complex Jason D. Slinker, Alon A. Gorodetsky, Michael S. Lowry, Jingjing Wang, Sara Parker, Richard Rohl, Stefan Bernhard, and George G. Malliaras pp 2763–2767 DOI: 10.1021/ja0345221

The Conformation of Tetraalanine in Water Determined by Polarized Raman, FT-IR, and VCD Spectroscopy Reinhard Schweitzer-Stenner, Fatma Eker, Kai Griebenow, Xiaolin Cao, and Laurence A. Nafie pp 2768–2776 DOI: 10.1021/ja039452c

π-Helix Preference in Unsolvated Peptides Rajagopalan Sudha, Motoya Kohtani, Gary A. Breaux, and Martin F. Jarrold pp 2777–2784 DOI: 10.1021/ja0381353

Dynamic Docking and Electron-Transfer between Cytochrome b5 and a Suite of Myoglobin Surface-Charge Mutants. Introduction of a Functional-Docking Algorithm for Protein−Protein Complexes Zhao-Xun Liang, Igor V. Kurnikov, Judith M. Nocek, A. Grant Mauk, David N. Beratan, and Brian M. Hoffman pp 2785–2798 DOI: 10.1021/ja038163l Supporting Info

Optical Sensor for the Detection of Caspase-9 Activity in a Single Cell Paul M. Kasili, Joon Myong Song, and Tuan Vo-Dinh pp 2799–2806 DOI: 10.1021/ja037388t

Optically Detected ESR and Low Magnetic Field Signals from Spin Triads:  2-Imidazoline-1-Oxyl Derivatives in X-irradiated Alkane Liquids as a Method to Study Three-Spin Systems Fyodor B. Sviridenko, Dmitri V. Stass, Tatyana V. Kobzeva, Evgeny V. Tretyakov, Svetlana V. Klyatskaya, Elena V. Mshvidobadze, Sergey F. Vasilevsky, and Yuri N. Molin pp 2807–2819 DOI: 10.1021/ja037157m

Simulations of the Large Kinetic Isotope Effect and the Temperature Dependence of the Hydrogen Atom Transfer in Lipoxygenase Mats H. M. Olsson, Per E. M. Siegbahn, and Arieh Warshel pp 2820–2828 DOI: 10.1021/ja037233l Supporting Info

Multielectron Chemistry of Zinc Porphyrinogen:  A Ligand-Based Platform for Two-Electron Mixed Valency Julien Bachmann and Daniel G. Nocera pp 2829–2837 DOI: 10.1021/ja039617h Supporting Info

Mechanism of Stereo- and Regioselectivity in the Paternò−Büchi Reaction of Furan Derivatives with Aromatic Carbonyl Compounds:  Importance of the Conformational Distribution in the Intermediary Triplet 1,4-Diradicals Manabu Abe, Takanori Kawakami, Shinji Ohata, Koichi Nozaki, and Masatomo Nojima pp 2838–2846 DOI: 10.1021/ja039491o Supporting Info

Promotion of Iridium-Catalyzed Methanol Carbonylation:  Mechanistic Studies of the Cativa Process Anthony Haynes, Peter M. Maitlis, George E. Morris, Glenn J. Sunley, Harry Adams, Peter W. Badger, Craig M. Bowers, David B. Cook, Paul I. P. Elliott, Talit Ghaffar, Helena Green, Tim R. Griffin, Marc Payne, Jean M. Pearson, Michael J. Taylor, Paul W. Vickers, and Rob J. Watt pp 2847–2861 DOI: 10.1021/ja039464y Supporting Info

Measurement of Nucleobase pKa Values in Model Mononucleotides Shows RNA−RNA Duplexes To Be More Stable than DNA−DNA Duplexes P. Acharya, P. Cheruku, S. Chatterjee, S. Acharya, and J. Chattopadhyaya pp 2862–2869 DOI: 10.1021/ja0386546 Supporting Info

Kinetically Stable Complexes in Water:  The Role of Hydration and Hydrophobicity Shannon M. Biros, Elke C. Ullrich, Fraser Hof, Laurent Trembleau, and Julius Rebek, Jr. pp 2870–2876 DOI: 10.1021/ja038823m Supporting Info

Mechanism for Radical Cation Transport in Duplex DNA Oligonucleotides Chu-Sheng Liu, Rigoberto Hernandez, and Gary B. Schuster pp 2877–2884 DOI: 10.1021/ja0378254 Supporting Info

Amido-Bridged Cu2N2 Diamond Cores that Minimize Structural Reorganization and Facilitate Reversible Redox Behavior between a Cu1Cu1 and a Class III Delocalized Cu1.5Cu1.5 Species Seth B. Harkins and Jonas C. Peters pp 2885–2893 DOI: 10.1021/ja037364m Supporting Info

Serendipity and Design in the Generation of New Coordination Polymers:  An Extensive Series of Highly Symmetrical Guanidinium-Templated, Carbonate-Based Networks with the Sodalite Topology Brendan F. Abrahams, Adrian Hawley, Marissa G. Haywood, Timothy A. Hudson, Richard Robson, and Damian A. Slizys pp 2894–2904 DOI: 10.1021/ja038904i Supporting Info

A Q- and X-Band Pulsed Electron Nuclear Double Resonance Study of the Structure and Location of the Vanadyl Ions in the Cs Salt of Heteropolyacid PVMo11O40 Marlen Gutjahr, Joachim Hoentsch, Rolf Böttcher, Oksana Storcheva, Klaus Köhler, and Andreas Pöppl pp 2905–2911 DOI: 10.1021/ja030576z

Theoretical Study of Benzotriazole UV Photostability:  Ultrafast Deactivation through Coupled Proton and Electron Transfer Triggered by a Charge-Transfer State Martin J. Paterson, Michael A. Robb, Lluís Blancafort, and Anthony D. DeBellis pp 2912–2922 DOI: 10.1021/ja0386593 Supporting Info

How Much Backbone Motion in Ubiquitin Is Required To Account for Dipolar Coupling Data Measured in Multiple Alignment Media as Assessed by Independent Cross-Validation? G. Marius Clore and Charles D. Schwieters pp 2923–2938 DOI: 10.1021/ja0386804 Supporting Info

Kinetics and Thermodynamics of Hexameric Capsule Formation Masamichi Yamanaka, Alexander Shivanyuk, and Julius Rebek, Jr. pp 2939–2943 DOI: 10.1021/ja037035u Supporting Info

BPA-PC on a Ni(111) Surface:  The Interplay between Adsorption Energy and Conformational Entropy for Different Chain-End Modifications Luigi Delle Site, Salvador Leon, and Kurt Kremer pp 2944–2955 DOI: 10.1021/ja0387406

Evidence of Defect-Promoted Reactivity for Epoxidation of Propylene in Titanosilicate (TS-1) Catalysts:  A DFT Study David H. Wells, Jr., W. Nicholas Delgass, and Kendall T. Thomson pp 2956–2962 DOI: 10.1021/ja037741v

Fast Structure-Based Assignment of 15N HSQC Spectra of Selectively 15N-Labeled Paramagnetic Proteins Guido Pintacuda, Max A. Keniry, Thomas Huber, Ah Young Park, Nicholas E. Dixon, and Gottfried Otting pp 2963–2970 DOI: 10.1021/ja039339m Supporting Info

A General Photonic Crystal Sensing Motif:  Creatinine in Bodily Fluids Anjal C. Sharma, Tushar Jana, Rasu Kesavamoorthy, Lianjun Shi, Mohamed A. Virji, David N. Finegold, and Sanford A. Asher pp 2971–2977 DOI: 10.1021/ja038187s Supporting Info

Dioxygen Activation in Methane Monooxygenase:  A Theoretical Study Benjamin F. Gherman, Mu-Hyun Baik, Stephen J. Lippard, and Richard A. Friesner pp 2978–2990 DOI: 10.1021/ja036506+ Supporting Info

Theoretical Study of the Methylbenzene Side-Chain Hydrocarbon Pool Mechanism in Methanol to Olefin Catalysis Bjørnar Arstad, John B. Nicholas, and James F. Haw pp 2991–3001 DOI: 10.1021/ja035923j

The A-Cluster in Subunit β of the Acetyl-CoA Decarbonylase/Synthase Complex from Methanosarcina thermophila:  Ni and Fe K-Edge XANES and EXAFS Analyses [J. Am. Chem. Soc. 2003, 125, 15343−15351]. Weiwei Gu, Simonida Gencic, Stephen P. Cramer, and David A. Grahame p 3002 DOI: 10.1021/ja040801s

Reviews in Computational Chemistry, Volume 19 Edited by Kenny B. Lipkowitz (North Dakota State University), Raima Larter (National Science Foundation, Arlington, VA), Thomas R. Cundari (University of North Texas), and Donald B. Boyd, Editor Emeritus (Indiana University-Purdue University at Indianapolis). John Wiley & Sons, Inc.:  Hoboken. 2003. xxiv + 394 pp. $150.00. ISBN 0-471-23585-7. Joseph S. Francisco p 3003 DOI: 10.1021/ja033619k

Molecular Nanostructures:  XVII International Winterschool/Euroconference on Electronic Properties of Novel Materials Edited by Hans Kuzmany (Universität Wien), Jörg Fink (Institut für Festkörper- und Werkstoff-Forschung, Dresden), Michael Mehring (Universität Stuttgart), and Siegmar Roth (Max-Planck-Institut für Festkörperforschung, Stuttgart). American Institute of Physics:  Melville, New York. 2003. xviii + 640 pp. $215.00. ISBN 0-7354-0154-3. p 3003 DOI: 10.1021/ja033655j

Biomolecular Films:  Design, Function, and Applications. Surfactant Science Series Volume 111 Edited by James F. Rusling (University of Connecticut). Marcel Dekker, Inc.:  New York, Basel. 2003. xii + 638 pp. $195.00. ISBN 0-8247-0899-7. Cindy L. Berrie pp 3003–3004 DOI: 10.1021/ja033609j

Issue 10

A Catalysis-Based Selection for Peroxidase Antibodies with Increased Activity Jun Yin, Jeremy H. Mills, and Peter G. Schultz pp 3006–3007 DOI: 10.1021/ja039198o Supporting Info

Core Structure of Amyloid Fibril Proposed from IR-Microscope Linear Dichroism Hirotsugu Hiramatsu, Yuji Goto, Hironobu Naiki, and Teizo Kitagawa pp 3008–3009 DOI: 10.1021/ja0383017

Ultrasensitive Electrical Biosensing of Proteins and DNA:  Carbon-Nanotube Derived Amplification of the Recognition and Transduction Events Joseph Wang, Guodong Liu, and M. Rasul Jan pp 3010–3011 DOI: 10.1021/ja031723w Supporting Info

Design and Synthesis of 3d−4f Metal-Based Zeolite-type Materials with a 3D Nanotubular Structure Encapsulated “Water” Pipe Bin Zhao, Peng Cheng, Xiaoyan Chen, Cai Cheng, Wei Shi, Daizheng Liao, Shiping Yan, and Zonghui Jiang pp 3012–3013 DOI: 10.1021/ja038784e Supporting Info

Mineralomimetic Sodalite- and Muscovite-Type Coordination Frameworks. Dynamic Crystal-to-Crystal Interconversion Processes Sensitive to Ion Pair Recognition Elisa Barea, Jorge A. R. Navarro, Juan M. Salas, Norberto Masciocchi, Simona Galli, and Angelo Sironi pp 3014–3015 DOI: 10.1021/ja039472e Supporting Info

Surface Amplification of Invasive Cleavage Products Yan Chen, Michael R. Shortreed, Dora Peelen, Manchun Lu, and Lloyd M. Smith pp 3016–3017 DOI: 10.1021/ja039355j Supporting Info

S K-Edge X-ray Absorption Spectroscopic Investigation of the Ni-Containing Superoxide Dismutase Active Site:  New Structural Insight into the Mechanism Robert K. Szilagyi, Peter A. Bryngelson, Michael J. Maroney, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 3018–3019 DOI: 10.1021/ja039106v Supporting Info

pH-Dependent Chemoselective Synthesis of α-Amino Acids. Reductive Amination of α-Keto Acids with Ammonia Catalyzed by Acid-Stable Iridium Hydride Complexes in Water Seiji Ogo, Keiji Uehara, Tsutomu Abura, and Shunichi Fukuzumi pp 3020–3021 DOI: 10.1021/ja031633r

Rational Design of a Supra C-1027:  Kinetically Stabilized Analogue of the Antitumor Enediyne Chromoprotein Toyonobu Usuki, Masayuki Inoue, Masahiro Hirama, and Toshiyuki Tanaka pp 3022–3023 DOI: 10.1021/ja039635z Supporting Info

The Origin of Sticking between a Hydroperoxy Radical and a Water Surface Stephen D. Belair, Heriberto Hernandez, and Joseph S. Francisco pp 3024–3025 DOI: 10.1021/ja030604d

Synthesis of Gold Nanoparticles Modified with Ionic Liquid Based on the Imidazolium Cation Hideaki Itoh, Kensuke Naka, and Yoshiki Chujo pp 3026–3027 DOI: 10.1021/ja039895g Supporting Info

Pseudospecificity of the Acidic Patch of Plastocyanin for the Interaction with Cytochrome f Katsuko Sato, Takamitsu Kohzuma, and Christopher Dennison pp 3028–3029 DOI: 10.1021/ja038188k

Reductively Activated Nitrous Oxide Reductase Reacts Directly with Substrate Jeannine M. Chan, John A. Bollinger, Cassidy L. Grewell, and David M. Dooley pp 3030–3031 DOI: 10.1021/ja0398868 Supporting Info

Fluorescent Polymeric AND Logic Gate with Temperature and pH as Inputs Seiichi Uchiyama, Narumi Kawai, A. Prasanna de Silva, and Kaoru Iwai pp 3032–3033 DOI: 10.1021/ja039697p Supporting Info

Dissociation Behavior of Doubly-Charged Tryptic Peptides:  Correlation of Gas-Phase Cleavage Abundance with Ramachandran Plots Yingying Huang, Joseph M. Triscari, Ljiljana Pasa-Tolic, Gordon A. Anderson, Mary S. Lipton, Richard D. Smith, and Vicki H. Wysocki pp 3034–3035 DOI: 10.1021/ja038041t Supporting Info

Deuterium-Labeling Studies Establishing Stereochemistry at the Oxypalladation Step in Wacker-Type Oxidative Cyclization of an o-Allylphenol Tamio Hayashi, Kaori Yamasaki, Michihiro Mimura, and Yasuhiro Uozumi pp 3036–3037 DOI: 10.1021/ja031946m Supporting Info

Surface-to-Surface Bridges Formed by Reversibly Assembled Polymers Farrell R. Kersey, Gwangrog Lee, Piotr Marszalek, and Stephen L. Craig pp 3038–3039 DOI: 10.1021/ja0499501 Supporting Info

Selective Pairing of Polyfluorinated DNA Bases Jacob S. Lai and Eric T. Kool pp 3040–3041 DOI: 10.1021/ja039571s Supporting Info

Platinum Participation in the Hydrogenation of Phenylacetylene by Ru5(CO)15(C)[Pt(PBut3)] Richard D. Adams, Burjor Captain, and Lei Zhu pp 3042–3043 DOI: 10.1021/ja049955y Supporting Info

[Ni2O(l-Asp)(H2O)2]·4H2O:  A Homochiral 1D Helical Chain Hybrid Compound with Extended Ni−O−Ni Bonding Ekaterina V. Anokhina and Allan J. Jacobson pp 3044–3045 DOI: 10.1021/ja031836f Supporting Info

Thermal Splitting of Bis-Cu(II) Octaphyrin(1.1.1.1.1.1.1.1) into Two Cu(II) Porphyrins Yasuo Tanaka, Wataru Hoshino, Soji Shimizu, Katsuyuki Youfu, Naoki Aratani, Norihiko Maruyama, Shizuo Fujita, and Atsuhiro Osuka pp 3046–3047 DOI: 10.1021/ja031935t Supporting Info

Highly Diastereoselective Heterogeneously Catalyzed Hydrogenation of Enamines for the Synthesis of Chiral β-Amino Acid Derivatives Norihiro Ikemoto, David M. Tellers, Spencer D. Dreher, Jinchu Liu, Angie Huang, Nelo R. Rivera, Eugenia Njolito, Yi Hsiao, J. Christopher McWilliams, J. Michael Williams, Joseph D. Armstrong, III, Yongkui Sun, David J. Mathre, Edward J. J. Grabowski, and Richard D. Tillyer pp 3048–3049 DOI: 10.1021/ja038812t Supporting Info

Branched Phospha[7]triangulanes J. Chris Slootweg, Marius Schakel, Frans J. J. de Kanter, Andreas W. Ehlers, Sergei I. Kozhushkov, Armin de Meijere, Martin Lutz, Anthony L. Spek, and Koop Lammertsma pp 3050–3051 DOI: 10.1021/ja031648p Supporting Info

Toward Single-Site, Immobilized Molecular Catalysts:  Site-Isolated Ti Ethylene Polymerization Catalysts Supported on Porous Silica Michael W. McKittrick and Christopher W. Jones pp 3052–3053 DOI: 10.1021/ja031725g Supporting Info

Investigation of the Origin of Tensile Stress-Induced Rate Enhancements in the Photochemical Degradation of Polymers Rui Chen, Myungok Yoon, Arwyn Smalley, David C. Johnson, and David R. Tyler pp 3054–3055 DOI: 10.1021/ja038945e Supporting Info

Energy Transfer between Singlet (1Δg) and Triplet (3Σg-) Molecular Oxygen in Aqueous Solution Glaucia R. Martinez, Jean-Luc Ravanat, Jean Cadet, Sayuri Miyamoto, Marisa H. G. Medeiros, and Paolo Di Mascio pp 3056–3057 DOI: 10.1021/ja039111z Supporting Info

Room-Temperature Ni(0)-Catalyzed Cross-Coupling Reactions of Aryl Arenesulfonates with Arylboronic Acids Zhen-Yu Tang and Qiao-Sheng Hu pp 3058–3059 DOI: 10.1021/ja038752r Supporting Info

Fabrication of Ru and Ru-Based Functionalized Nanotubes Jun Chen, Zhan-Liang Tao, and Suo-Long Li pp 3060–3061 DOI: 10.1021/ja039031v Supporting Info

Enantioselective Molecular Recognition between β-Sheets De Michael Chung and James S. Nowick pp 3062–3063 DOI: 10.1021/ja031632z Supporting Info

Polyelectrolyte Multilayer as Matrix for Electrochemical Deposition of Gold Clusters:  Toward Super-Hydrophobic Surface Xi Zhang, Feng Shi, Xi Yu, Huan Liu, Yu Fu, Zhiqiang Wang, Lei Jiang, and Xiaoyuan Li pp 3064–3065 DOI: 10.1021/ja0398722 Supporting Info

Carotenoid and Pheophytin on Semiconductor Surface:  Self-Assembly and Photoinduced Electron Transfer Jingxi Pan, Yunhua Xu, Licheng Sun, Villy Sundström, and Tomáš Polívka pp 3066–3067 DOI: 10.1021/ja031775l

The Fluoro Analogue of Wilkinson's Catalyst and Unexpected Ph−Cl Activation Vladimir V. Grushin and William J. Marshall pp 3068–3069 DOI: 10.1021/ja049844z Supporting Info

Metallophosphites as Umpolung Catalysts:  The Enantioselective Cross Silyl Benzoin Reaction Xin Linghu, Justin R. Potnick, and Jeffrey S. Johnson pp 3070–3071 DOI: 10.1021/ja0496468 Supporting Info

Substrate Affinities for Membrane Transport Proteins Determined by 13C Cross-Polarization Magic-Angle Spinning Nuclear Magnetic Resonance Spectroscopy Simon G. Patching, Adrian R. Brough, Richard B. Herbert, J. Anton Rajakarier, Peter J. F. Henderson, and David A. Middleton pp 3072–3080 DOI: 10.1021/ja037163i

C-Terminal Domain of the Membrane Copper Transporter Ctr1 from Saccharomyces cerevisiae Binds Four Cu(I) Ions as a Cuprous-Thiolate Polynuclear Cluster:  Sub-femtomolar Cu(I) Affinity of Three Proteins Involved in Copper Trafficking Zhiguang Xiao, Fionna Loughlin, Graham N. George, Geoffrey J. Howlett, and Anthony G. Wedd pp 3081–3090 DOI: 10.1021/ja0390350 Supporting Info

The Biosynthesis of the Thiazole Phosphate Moiety of Thiamin (Vitamin B1):  The Early Steps Catalyzed by Thiazole Synthase Pieter C. Dorrestein, Huili Zhai, Sean V. Taylor, Fred W. McLafferty, and Tadhg P. Begley pp 3091–3096 DOI: 10.1021/ja039616p

Physicochemical Properties of Mixed Micellar Aggregates Containing CCK Peptides and Gd Complexes Designed as Tumor Specific Contrast Agents in MRI Antonella Accardo, Diego Tesauro, Paola Roscigno, Eliana Gianolio, Luigi Paduano, Gerardino D'Errico, Carlo Pedone, and Giancarlo Morelli pp 3097–3107 DOI: 10.1021/ja039195b

Elaboration of Diaryl Ketones into Naphthalenes Fused on Two or Four Sides:  A Naphthoannulation Procedure Patrick M. Donovan and Lawrence T. Scott pp 3108–3112 DOI: 10.1021/ja038254i Supporting Info

Reaction of Ketones with Lithium Hexamethyldisilazide:  Competitive Enolizations and 1,2-Additions Pinjing Zhao, Anthony Condo, Ivan Keresztes, and David B. Collum pp 3113–3118 DOI: 10.1021/ja030582v Supporting Info

Water-Catalyzed Dehalogenation Reactions of Isobromoform and Its Reaction Products Wai Ming Kwok, Cunyuan Zhao, Yun-Liang Li, Xiangguo Guan, Dongqi Wang, and David Lee Phillips pp 3119–3131 DOI: 10.1021/ja0390552 Supporting Info

Aromaticity of Four-Membered-Ring 6π-Electron Systems:  N2S2 and Li2C4H4 Yousung Jung, Thomas Heine, Paul v. R. Schleyer, and Martin Head-Gordon pp 3132–3138 DOI: 10.1021/ja0351490 Supporting Info

Nanosized Molecular Propellers by Cyclodehydrogenation of Polyphenylene Dendrimers Christopher D. Simpson, Gunter Mattersteig, Kai Martin, Lileta Gherghel, Roland E. Bauer, Hans Joachim Räder, and Klaus Müllen pp 3139–3147 DOI: 10.1021/ja036732j Supporting Info

Backbone-Rigidified Oligo(m-phenylene ethynylenes) Xiaowu Yang, Lihua Yuan, Kazuhiro Yamato, Amy L. Brown, Wen Feng, Mako Furukawa, Xiao Cheng Zeng, and Bing Gong pp 3148–3162 DOI: 10.1021/ja039416d

Crystal Structures and Spectroscopic Characterization of Radical Cations and Dications of Oligothiophenes Stabilized by Annelation with Bicyclo[2.2.2]octene Units:  Sterically Segregated Cationic Oligothiophenes Tohru Nishinaga, Atsushi Wakamiya, Daisuke Yamazaki, and Koichi Komatsu pp 3163–3174 DOI: 10.1021/ja039434v Supporting Info

Polymorphism in NaSbO3:  Structure and Bonding in Metal Oxides Hiroshi Mizoguchi, Patrick M. Woodward, Song-Ho Byeon, and John B. Parise pp 3175–3184 DOI: 10.1021/ja038365h

Synthetic Creatinine Receptor:  Imprinting of a Lewis Acidic Zinc(II)cyclen Binding Site to Shape Its Molecular Recognition Selectivity Michael Subat, Andrew S. Borovik, and Burkhard König pp 3185–3190 DOI: 10.1021/ja038980l Supporting Info

Diamond and Diamond-Like Carbon from a Preceramic Polymer Patricia A. Bianconi, Scott J. Joray, Brian L. Aldrich, Jitapa Sumranjit, Daniel J. Duffy, David P. Long, Jason L. Lazorcik, Louis Raboin, James K. Kearns, Stephenie L. Smulligan, and Jonathan M. Babyak pp 3191–3202 DOI: 10.1021/ja039254l Supporting Info

Synthesis and Characterization of Hypoelectronic Rhenaboranes. Analysis of the Geometric and Electronic Structures of Species Following Neither Borane nor Metal Cluster Electron-Counting Paradigms Boris Le Guennic, Haijun Jiao, Samia Kahlal, Jean-Yves Saillard, Jean-François Halet, Sundargopal Ghosh, Maoyu Shang, Alicia M. Beatty, Arnold L. Rheingold, and Thomas P. Fehlner pp 3203–3217 DOI: 10.1021/ja039770b Supporting Info

Engineering of Layer-by-Layer Coated Capsules with the Prospect of Materials for Efficient and Directed Electron Transfer Concetta Tedeschi, Lidong Li, Helmuth Möhwald, Christian Spitz, David von Seggern, Ralf Menzel, and Stefan Kirstein pp 3218–3227 DOI: 10.1021/ja037128b

Understanding the High Activity of a Nanostructured Catalyst Obtained by a Deposit of Pd on Ni: First Principle Calculations J.-S. Filhol, D. Simon, and P. Sautet pp 3228–3233 DOI: 10.1021/ja038154c

On the Mechanism of the cis−trans Isomerization in the Lowest Electronic States of Azobenzene:  S0, S1, and T1 Alessandro Cembran, Fernando Bernardi, Marco Garavelli, Laura Gagliardi, and Giorgio Orlandi pp 3234–3243 DOI: 10.1021/ja038327y Supporting Info

Weak C−H···O and C−H···F−C Hydrogen Bonds in the Oxirane−Trifluoromethane Dimer José L. Alonso, Sonia Antolínez, Susana Blanco, Alberto Lesarri, Juan C. López, and Walther Caminati pp 3244–3249 DOI: 10.1021/ja038696u Supporting Info

Deuterium NMR Used To Indicate a Common Mechanism for the Biosynthesis of Ricinoleic Acid by Ricinus communis and Claviceps purpurea Isabelle Billault, Peter G. Mantle, and Richard J. Robins pp 3250–3256 DOI: 10.1021/ja038814d

Selective Deposition of Native Cell Membranes on Biocompatible Micropatterns Motomu Tanaka, Amy P. Wong, Florian Rehfeldt, Murat Tutus, and Stefan Kaufmann pp 3257–3260 DOI: 10.1021/ja038981d

Investigation of Noncovalent Interactions in Deprotonated Peptides:  Structural and Energetic Competition between Aggregation and Hydration Dengfeng Liu, Thomas Wyttenbach, Catherine J. Carpenter, and Michael T. Bowers pp 3261–3270 DOI: 10.1021/ja0393628 Supporting Info

Charge Transport Properties in Discotic Liquid Crystals:  A Quantum-Chemical Insight into Structure−Property Relationships Vincent Lemaur, Demetrio A. da Silva Filho, Veaceslav Coropceanu, Matthias Lehmann, Yves Geerts, Jorge Piris, Michael G. Debije, Anick M. van de Craats, Kittusamy Senthilkumar, Laurens D. A Siebbeles, John M. Warman, Jean-Luc Brédas, and Jérôme Cornil pp 3271–3279 DOI: 10.1021/ja0390956

Hydrogen Bond Geometries from Electron Paramagnetic Resonance and Electron−Nuclear Double Resonance Parameters:  Density Functional Study of Quinone Radical Anion−Solvent Interactions Sebastian Sinnecker, Eduard Reijerse, Frank Neese, and Wolfgang Lubitz pp 3280–3290 DOI: 10.1021/ja0392014 Supporting Info

Determination of an Ensemble of Structures Representing the Denatured State of the Bovine Acyl-Coenzyme A Binding Protein Kresten Lindorff-Larsen, Sigridur Kristjansdottir, Kaare Teilum, Wolfgang Fieber, Christopher M. Dobson, Flemming M. Poulsen, and Michele Vendruscolo pp 3291–3299 DOI: 10.1021/ja039250g Supporting Info

Reaction Intermediates in Acid Catalysis by Zeolites:  Prediction of the Relative Tendency To Form Alkoxides or Carbocations as a Function of Hydrocarbon Nature and Active Site Structure M. Boronat, P. M. Viruela, and A. Corma pp 3300–3309 DOI: 10.1021/ja039432a

Peroxovanadate Imidazole Complexes as Catalysts for Olefin Epoxidation:  Density Functional Study of Dynamics, 51V NMR Chemical Shifts, and Mechanism Michael Bühl, Rachel Schurhammer, and Petra Imhof pp 3310–3320 DOI: 10.1021/ja039436f Supporting Info

Mechanism of Ferromagnetic Coupling in Copper(II)-Gadolinium(III) Complexes Jozef Paulovi, Fanica Cimpoesu, Marilena Ferbinteanu, and Kimihiko Hirao pp 3321–3331 DOI: 10.1021/ja030628k Supporting Info

Theoretical Study of the Cp2Zr-Catalyzed Hydrosilylation of Ethylene. Reaction Mechanism Including New σ-Bond Activation Shigeyoshi Sakaki, Tatsunori Takayama, Michinori Sumimoto, and Manabu Sugimoto pp 3332–3348 DOI: 10.1021/ja0304345 Supporting Info

Optical and Electrical Properties of Three-Dimensional Interlinked Gold Nanoparticle Assemblies Jurina M. Wessels, Heinz-Georg Nothofer, William E. Ford, Florian von Wrochem, Frank Scholz, Tobias Vossmeyer, Andrea Schroedter, Horst Weller, and Akio Yasuda pp 3349–3356 DOI: 10.1021/ja0377605 Supporting Info

Highly Sensitive Fluorescence Probes for Nitric Oxide Based on Boron Dipyrromethene ChromophoreRational Design of Potentially Useful Bioimaging Fluorescence Probe Yu Gabe, Yasuteru Urano, Kazuya Kikuchi, Hirotatsu Kojima, and Tetsuo Nagano pp 3357–3367 DOI: 10.1021/ja037944j

How Does Product Isotope Effect Prove the Operation of a Two-State “Rebound” Mechanism in C−H Hydroxylation by Cytochrome P450? [J. Am. Chem. Soc. 2003, 125, 13024−13025]. Devesh Kumar, Samuël P. de Visser, and Sason Shaik p 3368 DOI: 10.1021/ja040802k

Issue 11

An Operational Supramolecular Nanovalve Raquel Hernandez, Hsian-Rong Tseng, Jason W. Wong, J. Fraser Stoddart, and Jeffrey I. Zink pp 3370–3371 DOI: 10.1021/ja039424u

Self-Assembling Peptide Nanotubes from Enantiomeric Pairs of Cyclic Peptides with Alternating d and l Amino Acid Residues Katri Rosenthal-Aizman, Gunnar Svensson, and Anders Undén pp 3372–3373 DOI: 10.1021/ja0372659 Supporting Info

Nanoassembly of Biodegradable Microcapsules for DNA Encasing Dmitry G. Shchukin, Amish A. Patel, Gleb B. Sukhorukov, and Yuri M. Lvov pp 3374–3375 DOI: 10.1021/ja036952x

Photon Antibunching from Oriented Semiconducting Polymer Nanostructures Pradeep Kumar, Tae-Hee Lee, Adosh Mehta, Bobby G. Sumpter, Robert M. Dickson, and Michael D. Barnes pp 3376–3377 DOI: 10.1021/ja031921n

High-Performance Semiconducting Polythiophenes for Organic Thin-Film Transistors Beng S. Ong, Yiliang Wu, Ping Liu, and Sandra Gardner pp 3378–3379 DOI: 10.1021/ja039772w Supporting Info

Sandwich-Like Complexes Based on “All-Metal” (Al42-) Aromatic Compounds Jose M. Mercero and Jesus M. Ugalde pp 3380–3381 DOI: 10.1021/ja039074b Supporting Info

Polymorph Selectivity under Nanoscopic Confinement Jeong-Myeong Ha, Johanna H. Wolf, Marc A. Hillmyer, and Michael D. Ward pp 3382–3383 DOI: 10.1021/ja049724r

A High-Resolution Probe of Protein Folding Laura B. Sagle, Jörg Zimmermann, Philip E. Dawson, and Floyd E. Romesberg pp 3384–3385 DOI: 10.1021/ja049890z Supporting Info

Shotgun Annotation of Histone Modifications:  A New Approach for Streamlined Characterization of Proteins by Top Down Mass Spectrometry James J. Pesavento, Yong-Bin Kim, Gregory K. Taylor, and Neil L. Kelleher pp 3386–3387 DOI: 10.1021/ja039748i Supporting Info

Convergent Synthesis and Photophysics of [60]Fullerene/Porphyrin-Based Rotaxanes Ke Li, David I. Schuster, Dirk M. Guldi, M. Ángeles Herranz, and Luis Echegoyen pp 3388–3389 DOI: 10.1021/ja039698h Supporting Info

Conformational Changes in a Photosensory LOV Domain Monitored by Time-Resolved NMR Spectroscopy Shannon M. Harper, Lori C. Neil, Iain J. Day, P. J. Hore, and Kevin H. Gardner pp 3390–3391 DOI: 10.1021/ja038224f Supporting Info

Nitrilotriacetic Acid-Modified Magnetic Nanoparticles as a General Agent to Bind Histidine-Tagged Proteins Chenjie Xu, Keming Xu, Hongwei Gu, Xiaofen Zhong, Zhihong Guo, Rongkun Zheng, Xixiang Zhang, and Bing Xu pp 3392–3393 DOI: 10.1021/ja031776d Supporting Info

A Highly Potent and Selective PKCα Inhibitor Generated via Combinatorial Modification of a Peptide Scaffold Jung Hwan Lee, Sandip K. Nandy, and David S. Lawrence pp 3394–3395 DOI: 10.1021/ja037300b Supporting Info

Bifunctional Nanocrystalline MgO for Chiral Epoxy Ketones via Claisen−Schmidt Condensation−Asymmetric Epoxidation Reactions Boyapati M. Choudary, Mannepalli L. Kantam, Kalluri V. S. Ranganath, Koosam Mahendar, and Bojja Sreedhar pp 3396–3397 DOI: 10.1021/ja038954n Supporting Info

A Limiting Speed for Protein Folding at Low Solvent Viscosity Linlin Qiu and Stephen J. Hagen pp 3398–3399 DOI: 10.1021/ja049966r

Direct Detection of Homocysteine Weihua Wang, Jorge O. Escobedo, Candace M. Lawrence, and Robert M. Strongin pp 3400–3401 DOI: 10.1021/ja0318838 Supporting Info

Presteady-State Kinetic Evidence for a Ring-Opening Activity in Fructose-1,6-(bis)phosphate Aldolase Kyung H. Choi and Dean R. Tolan pp 3402–3403 DOI: 10.1021/ja038540u Supporting Info

Vinyl Sulfones:  Inhibitors of SrtA, a Transpeptidase Required for Cell Wall Protein Anchoring and Virulence in Staphylococcus aureus Brenda A. Frankel, Matthew Bentley, Ryan G. Kruger, and Dewey G. McCafferty pp 3404–3405 DOI: 10.1021/ja0390294 Supporting Info

C−H to N Substitution Dramatically Alters the Sequence-Specific DNA Alkylation, Cytotoxicity, and Expression of Human Cancer Cell Lines Toshikazu Bando, Akihiko Narita, Aki Iwai, Kazunori Kihara, and Hiroshi Sugiyama pp 3406–3407 DOI: 10.1021/ja0387103 Supporting Info

PtCl2-Catalyzed Cycloisomerizations of Allenynes Nicolas Cadran, Kevin Cariou, Gwénaëlle Hervé, Corinne Aubert, Louis Fensterbank, Max Malacria, and José Marco-Contelles pp 3408–3409 DOI: 10.1021/ja031892g Supporting Info

Structures and Energetics of Models for the Active Site of Acetyl-Coenzyme A Synthase:  Role of Distal and Proximal Metals in Catalysis Charles Edwin Webster, Marcetta Y. Darensbourg, Paul A. Lindahl, and Michael B. Hall pp 3410–3411 DOI: 10.1021/ja038083h Supporting Info

Oxidation of Sulfide, Phosphine, and Benzyl Substrates Tethered to N-Donor Pyridine Ligands in Carboxylate-Bridged Diiron(II) Complexes Emily C. Carson and Stephen J. Lippard pp 3412–3413 DOI: 10.1021/ja031806c Supporting Info

Resonance Raman Spectra of Electrons Solvated in Liquid Alcohols Michael J. Tauber, Christina M. Stuart, and Richard A. Mathies pp 3414–3415 DOI: 10.1021/ja031816d

Intramolecular Arylation Reactions of Alkenes:  A Flexible Approach to Chromans and Tetrahydroquinoline Derivatives José Barluenga, Mónica Trincado, Eduardo Rubio, and José M. González pp 3416–3417 DOI: 10.1021/ja0397299 Supporting Info

Chiral Proton Catalysis:  A Catalytic Enantioselective Direct Aza-Henry Reaction Benjamin M. Nugent, Ryan A. Yoder, and Jeffrey N. Johnston pp 3418–3419 DOI: 10.1021/ja031906i Supporting Info

Valence Electron Orbitals of an Oligo(p-phenylene-ethynylene)thiol on Gold Christopher D. Zangmeister, Steven W. Robey, and Roger D. van ZeeYuxing Yao and James M. Tour pp 3420–3421 DOI: 10.1021/ja0389826

A Simple and General Method for the Synthesis of Multicomponent Na2V6O16·3H2O Single-Crystal Nanobelts Jiaguo Yu, Jimmy C. Yu, Wingkei Ho, Ling Wu, and Xinchen Wang pp 3422–3423 DOI: 10.1021/ja031795n Supporting Info

On the Electronic Structure of Molecular UO2 in the Presence of Ar Atoms:  Evidence for Direct U−Ar Bonding Jun Li, Bruce E. Bursten, Lester Andrews, and Colin J. Marsden pp 3424–3425 DOI: 10.1021/ja039933w

Enzymatic Cyclization of 22,23-Dihydro-2,3-oxidosqualene into Euph-7-en-3β-ol and Bacchar-12-en-3β-ol by Recombinant β-Amyrin Synthase Ikuro Abe, Yuichi Sakano, Hideya Tanaka, Weiwei Lou, Hiroshi Noguchi, Masaaki Shibuya, and Yutaka Ebizuka pp 3426–3427 DOI: 10.1021/ja031955v Supporting Info

De Novo Synthesis of Oligosaccharides Using a Palladium-Catalyzed Glycosylation Reaction Ravula Satheesh Babu, Maoquan Zhou, and George A. O'Doherty pp 3428–3429 DOI: 10.1021/ja039400n Supporting Info

Porphyrins with Four Monodisperse Oligofluorene Arms as Efficient Red Light-Emitting Materials Binsong Li, Jing Li, Yaqin Fu, and Zhishan Bo pp 3430–3431 DOI: 10.1021/ja039832y Supporting Info

Elimination of R−H from Iridium Acyl Hydrides without Loss of CO:  Evidence for the Intervention of Metal Cation/Carbanion Pairs Joseph G. Cordaro and Robert G. Bergman pp 3432–3433 DOI: 10.1021/ja031784u Supporting Info

Carbolithiation for the Generation of Cyclooctadienyl Anions and Tandem Electrocyclization/Alkylation to Functionalized cis-Bicyclo[3.3.0]octenes David R. Williams and Jonathan T. Reeves pp 3434–3435 DOI: 10.1021/ja049353e Supporting Info

Formation of Hypervalent Complexes of PhCCSiF3 with Pyridine through Intermolecular Silicon···Nitrogen Interaction Moshe Nakash and Michael Goldvaser pp 3436–3437 DOI: 10.1021/ja031801f Supporting Info

Asymmetric Benzoin Condensation Catalyzed by Chiral Rotaxanes Tethering a Thiazolium Salt Moiety via the Cooperation of the Component:  Can Rotaxane Be an Effective Reaction Field? Yuya Tachibana, Nobuhiro Kihara, and Toshikazu Takata pp 3438–3439 DOI: 10.1021/ja039461l Supporting Info

Photocatalytic Hydrogen Production from Hantzsch 1,4-Dihydropyridines by Platinum(II) Terpyridyl Complexes in Homogeneous Solution Dong Zhang, Li-Zhu Wu, Li Zhou, Xue Han, Qing-Zheng Yang, Li-Ping Zhang, and Chen-Ho Tung pp 3440–3441 DOI: 10.1021/ja037631o Supporting Info

Cooperative Effects in the Activation of Molecular Oxygen by Anionic Silver Clusters Jan Hagen, Liana D. Socaciu, Jérôme Le Roux, Denisia Popolan, Thorsten M. Bernhardt, Ludger Wöste, Roland Mitrić, Holger Noack, and Vlasta Bonaić-Koutecký pp 3442–3443 DOI: 10.1021/ja038948r

An Unusual Reverse Turn Structure Adopted by a Furanoid Sugar Amino Acid Incorporated in Gramicidin S Gijsbert M. Grotenbreg, Mattie S. M. Timmer, Antonio L. Llamas-Saiz, Martijn Verdoes, Gijsbert A. van der Marel, Mark J. van Raaij, Herman S. Overkleeft, and Mark Overhand pp 3444–3446 DOI: 10.1021/ja0397254 Supporting Info

Fluorescence-Based Approach for Detecting and Characterizing Antibiotic-Induced Conformational Changes in Ribosomal RNA:  Comparing Aminoglycoside Binding to Prokaryotic and Eukaryotic Ribosomal RNA Sequences Malvika Kaul, Christopher M. Barbieri, and Daniel S. Pilch pp 3447–3453 DOI: 10.1021/ja030568i

Ligating DNA with DNA Alavattam Sreedhara, Yingfu Li, and Ronald R. Breaker pp 3454–3460 DOI: 10.1021/ja039713i

A Wrench-Shaped Synthetic Molecule that Modulates a Transcription Factor−Coactivator Interaction Hiroki Shimogawa, Youngjoo Kwon, Qian Mao, Yoshinori Kawazoe, Yongmun Choi, Shinichi Asada, Hideo Kigoshi, and Motonari Uesugi pp 3461–3471 DOI: 10.1021/ja038855+ Supporting Info

Solid-Phase ATRP Synthesis of Peptide−Polymer Hybrids Ying Mei, Kathryn L. Beers, H. C. Michelle Byrd, David L. VanderHart, and Newell R. Washburn pp 3472–3476 DOI: 10.1021/ja039583d Supporting Info

Directed Self-Assembly of Monodisperse Phospholipid Bilayer Nanodiscs with Controlled Size I. G. Denisov, Y. V. Grinkova, A. A. Lazarides, and S. G. Sligar pp 3477–3487 DOI: 10.1021/ja0393574 Supporting Info

Rate of Enolate Formation Is Not Very Sensitive to the Hydrogen Bonding Ability of Donors to Carboxyl Oxygen Lone Pair Acceptors; A Ramification of the Principle of Non-Perfect Synchronization for General-Base-Catalyzed Enolate Formation Zhenlin Zhong, Timothy S. Snowden, Michael D. Best, and Eric V. Anslyn pp 3488–3495 DOI: 10.1021/ja0306011

Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts:  The Role of Ligands and Substrates from a Theoretical Perspective Christian Adlhart and Peter Chen pp 3496–3510 DOI: 10.1021/ja0305757 Supporting Info

1,4-Hydroxybiradical Behavior Revealed through Crystal Structure−Solid-State Reactivity Correlations Dario Braga, Shuang Chen, Heather Filson, Lucia Maini, Matthew R. Netherton, Brian O. Patrick, John R. Scheffer, Carl Scott, and Wujiong Xia pp 3511–3520 DOI: 10.1021/ja039076w Supporting Info

Dynamics of Positive Charge Carriers on Si Chains of Polysilanes Shu Seki, Yoshiko Koizumi, Tomoyo Kawaguchi, Hidefumi Habara, and Seiichi Tagawa pp 3521–3528 DOI: 10.1021/ja039840e

Synthesis of Medium Ring Nitrogen Heterocycles via a Tandem Copper-Catalyzed C−N Bond Formation−Ring-Expansion Process Artis Klapars, Sean Parris, Kevin W. Anderson, and Stephen L. Buchwald pp 3529–3533 DOI: 10.1021/ja038565t Supporting Info

Enantioselective Synthesis of (−)-Gilbertine via a Cationic Cascade Cyclization Jan Jiricek and Siegfried Blechert pp 3534–3538 DOI: 10.1021/ja0399021 Supporting Info

X-ray Diffraction Analysis of Nonequilibrium States in Crystals:  Observation of an Unstable Conformer in Flash-Cooled Crystals Jun Harada and Keiichiro Ogawa pp 3539–3544 DOI: 10.1021/ja038203l Supporting Info

Ion-Driven ATP Pump by Self-Organized Hybrid Membrane Materials Mihail Barboiu, Sophie Cerneaux, Arie van der Lee, and Gavin Vaughan pp 3545–3550 DOI: 10.1021/ja039146z Supporting Info

Self-Assembly of Rod−Coil Molecules into Molecular Length-Dependent Organization Ja-Hyoung Ryu, Nam-Keun Oh, Wang-Cheol Zin, and Myongsoo Lee pp 3551–3558 DOI: 10.1021/ja039793q Supporting Info

Fluorescent and Circular Dichroic Detection of Monosaccharides by Molecular Sensors:  Bis[(Pyrrolyl)ethynyl]naphthyridine and Bis[(Indolyl)ethynyl]naphthyridine Jim-Min Fang, Srinivasan Selvi, Jen-Hai Liao, Zdenek Slanina, Chao-Tsen Chen, and Pi-Tai Chou pp 3559–3566 DOI: 10.1021/ja039237w Supporting Info

Self-Assembly of Electron Donor−Acceptor Dyads into Ordered Architectures in Two and Three Dimensions:  Surface Patterning and Columnar “Double Cables” Paolo Samorì, Xiaomin Yin, Natalia Tchebotareva, Zhaohui Wang, Tadeusz Pakula, Frank Jäckel, Mark D. Watson, Alessandro Venturini, Klaus Müllen, and Jürgen P. Rabe pp 3567–3575 DOI: 10.1021/ja038648+ Supporting Info

Exceptionally Stable, Hollow Tubular Metal−Organic Architectures:  Synthesis, Characterization, and Solid-State Transformation Study Cheng-Yong Su, Andrea M. Goforth, Mark D. Smith, P. J. Pellechia, and Hans-Conrad zur Loye pp 3576–3586 DOI: 10.1021/ja039022m Supporting Info

Crystal Structure and Microstructure of Some La2/3-xLi3xTiO3 Oxides:  An Example of the Complementary Use of Electron Diffraction and Microscopy and Synchrotron X-ray Diffraction To Study Complex Materials Susana García-Martín, Miguel A. Alario-Franco, Helmut Ehrenberg, Juan Rodríguez-Carvajal, and Ulises Amador pp 3587–3596 DOI: 10.1021/ja038410l Supporting Info

Electronic Structure of Tubular Aromatic Molecules Derived from the Metallic (5,5) Armchair Single Wall Carbon Nanotube Zhiyong Zhou, Michael Steigerwald, Mark Hybertsen, Louis Brus, and Richard A. Friesner pp 3597–3607 DOI: 10.1021/ja039294p Supporting Info

Os(II)−Nitrosyl and Os(II)−Dinitrogen Complexes from Reactions between Os(VI)−Nitrido and Hydroxylamines and Methoxylamines My Hang V. Huynh, Thomas J. Meyer, Michael A. Hiskey, and Donald L. Jameson pp 3608–3615 DOI: 10.1021/ja030574e

Alumina-Supported Vanadium Nanoparticles:  Structural Characterization and CO Adsorption Properties Norbert Magg, Javier B. Giorgi, Martin M. Frank, Boonchuan Immaraporn, Thomas Schroeder, Marcus Bäumer, and Hans-Joachim Freund pp 3616–3626 DOI: 10.1021/ja039278s

Kinetics, Thermodynamics, and Effect of BPh3 on Competitive C−C and C−H Bond Activation Reactions in the Interconversion of Allyl Cyanide by [Ni(dippe)] Nicole M. Brunkan, Donna M. Brestensky, and William D. Jones pp 3627–3641 DOI: 10.1021/ja037002e Supporting Info

Why Are Olefins Oxidized by RuO4 under Cleavage of the Carbon−Carbon Bond whereas Oxidation by OsO4 Yields cis-Diols? Jan Frunzke, Christoph Loschen, and Gernot Frenking pp 3642–3652 DOI: 10.1021/ja039921a

13C Nuclear Overhauser Polarization−Magic-Angle Spinning Nuclear Magnetic Resonance Spectroscopy in Uniformly 13C-Labeled Solid Proteins Etsuko Katoh, K. Takegoshi, and Takehiko Terao pp 3653–3657 DOI: 10.1021/ja0352193

The Bond-Forming Reactions of Atomic Dications with Neutral Molecules:  Formation of ArNH+ and ArN+ from Collisions of Ar2+ with NH3 Natalie Lambert, Dominic Kearney, Nikolas Kaltsoyannis, and Stephen D. Price pp 3658–3663 DOI: 10.1021/ja038779a

TiO2 Films Loaded with Silver Nanoparticles:  Control of Multicolor Photochromic Behavior Kenji Naoi, Yoshihisa Ohko, and Tetsu Tatsuma pp 3664–3668 DOI: 10.1021/ja039474z

Molecular Spectroscopy of Oxide Catalyst Surfaces By Anatoli Davydov (University of Alberta and Syntroleum Corporation, Tulsa, OK). John Wiley & Sons, Inc.:  Hoboken, NJ. 2003. xxii + 668 pp. $265.00. ISBN 0-417-98731-X. Israel E. Wachs p 3669 DOI: 10.1021/ja033599m

Macromolecules Containing Metal and Metal-Like Elements, Volume 1:  A Half-Century of Metal- and Metalloid-Containing Polymers By Alaa S. Abd-El-Aziz (University of Winnipeg), Charles E. Carraher, Jr. (Florida Atlantic University), Charles U. Pittman, Jr. (Mississippi State University), John E. Sheats (Rider University), and Martel Zeldin (Hobart and William Smith Colleges). John Wiley & Sons, Inc.:  Hoboken. 2003. x + 268 pp. $125.00. ISBN 0-471-45832-5. Frieder Jäkle pp 3669–3670 DOI: 10.1021/ja033623w

Annual Review of Physical Chemistry, Vol. 54 Edited by Stephen R. Leone, Paul Alivisatos (University of California, Berkeley), and Ann E. McDermott (Columbia University). Annual Reviews:  Palo Alto, CA. 2003. xiv + 608 pp. $75 Print Version for Individuals, $165 Print Version for Institutions. ISBN 0-8243-1054-3. Victor S. Batista p 3670 DOI: 10.1021/ja0336170

Issue 12

How Heme Metabolism Occurs in Heme Oxygenase:  Computational Study of Oxygen-Donation Ability of the Oxo and Hydroperoxo Species Takashi Kamachi, Alexander F. Shestakov, and Kazunari Yoshizawa pp 3672–3673 DOI: 10.1021/ja030393c Supporting Info

Enantioselective Guest Binding and Dynamic Resolution of Cationic Ruthenium Complexes by a Chiral Metal−Ligand Assembly Dorothea Fiedler, Dennis H. Leung, Robert G. Bergman, and Kenneth N. Raymond pp 3674–3675 DOI: 10.1021/ja039225a Supporting Info

Facile Quantification of Enantiomeric Excess and Concentration with Indicator-Displacement Assays:  An Example in the Analyses of α-Hydroxyacids Lei Zhu and Eric V. Anslyn pp 3676–3677 DOI: 10.1021/ja031839s Supporting Info

Permanent Bubble Arrays from a Cross-Linked Poly(para-phenyleneethynylene):  Picoliter Holes without Microfabrication Belma Erdogan, Lulu Song, James N. Wilson, Jung O. Park, Mohan Srinivasarao, and Uwe H. F. Bunz pp 3678–3679 DOI: 10.1021/ja0320020 Supporting Info

Thermochemistry of Aqueous Hydroxyl Radical from Advances in Photoacoustic Calorimetry and ab Initio Continuum Solvation Theory Tom Autrey, Aaron K. Brown, Donald M. Camaioni, Michel Dupuis, Nancy S. Foster, and April Getty pp 3680–3681 DOI: 10.1021/ja039827u Supporting Info

Sensitivity-Enhanced Quantitative 13C NMR Spectroscopy via Cancellation of 1JCH Dependence in DEPT Polarization Transfers Terry J. Henderson pp 3682–3683 DOI: 10.1021/ja039261+ Supporting Info

Formation of Pseudorotaxane Induced by Electrochemical Oxidation of Ferrocene-Containing Axis Molecule in the Presence of Crown Ether Masaki Horie, Yuji Suzaki, and Kohtaro Osakada pp 3684–3685 DOI: 10.1021/ja039899l Supporting Info

Iron-Catalyzed Cross-Coupling of Primary and Secondary Alkyl Halides with Aryl Grignard Reagents Masaharu Nakamura, Keiko Matsuo, Shingo Ito, and Eiichi Nakamura pp 3686–3687 DOI: 10.1021/ja049744t Supporting Info

Catalytic Enantioselective Hydrostannation of Cyclopropenes Marina Rubina, Michael Rubin, and Vladimir Gevorgyan pp 3688–3689 DOI: 10.1021/ja0496928 Supporting Info

P-Chirogenic Diaminophosphine Oxide:  A New Class of Chiral Phosphorus Ligands for Asymmetric Catalysis Tetsuhiro Nemoto, Takayoshi Matsumoto, Takamasa Masuda, Tsukasa Hitomi, Keiichiro Hatano, and Yasumasa Hamada pp 3690–3691 DOI: 10.1021/ja031792a Supporting Info

Design and Use of Fluorogenic Aldehydes for Monitoring the Progress of Aldehyde Transformations Fujie Tanaka, Nobuyuki Mase, and Carlos F. Barbas, III pp 3692–3693 DOI: 10.1021/ja049641a Supporting Info

Biosynthetic Origin of the Rare Nitroaryl Moiety of the Polyketide Antibiotic Aureothin:  Involvement of an Unprecedented N-Oxygenase Jing He and Christian Hertweck pp 3694–3695 DOI: 10.1021/ja039328t Supporting Info

Fully Extended Polyelectrolyte−Amphiphile Complexes Adsorbed on Graphite Nikolai Severin, Jürgen P. Rabe, and Dirk G. Kurth pp 3696–3697 DOI: 10.1021/ja039708e Supporting Info

Ligand-Dependent Scope and Divergent Mechanistic Behavior in Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes Gireesh M. Mahandru, Gang Liu, and John Montgomery pp 3698–3699 DOI: 10.1021/ja049644n Supporting Info

Platinum-Catalyzed Intramolecular Alkylation of Indoles with Unactivated Olefins Cong Liu, Xiaoqing Han, Xiang Wang, and Ross A. Widenhoefer pp 3700–3701 DOI: 10.1021/ja031814t Supporting Info

A One-Pot Multicomponent Coupling Reaction for the Stereocontrolled Synthesis of (Z)-Trisubstituted Allylic Alcohols Young K. Chen and Patrick J. Walsh pp 3702–3703 DOI: 10.1021/ja0396145 Supporting Info

Total Synthesis and Structural Revision of (+)-Amphidinolide W Arun K. Ghosh and Gangli Gong pp 3704–3705 DOI: 10.1021/ja049754u Supporting Info

Hydration of Nitrosylruthenium Bis(alkynyl) Complexes with Hydrotris(pyrazolyl)borate:  Insertion/Hydration and Double Hydration Products Yasuhiro Arikawa, Yoshimasa Nishimura, Kenta Ikeda, and Masayoshi Onishi pp 3706–3707 DOI: 10.1021/ja039365k Supporting Info

Molecular Optical Gating Devices Based on Polymer Nanosheets Assemblies Jun Matsui, Masaya Mitsuishi, Atsushi Aoki, and Tokuji Miyashita pp 3708–3709 DOI: 10.1021/ja039871+ Supporting Info

Sequence-Specific Assignments of Methyl Groups in High-Molecular Weight Proteins Daiwen Yang, Yu Zheng, Dingjiang Liu, and Daniel F. Wyss pp 3710–3711 DOI: 10.1021/ja039102q Supporting Info

Ru(II)-Catalyzed Chemo- and Regioselective Cyclotrimerization of Three Unsymmetrical Alkynes through Boron Temporary Tether. One-Pot Four-Component Coupling via Cyclotrimerization/Suzuki−Miyaura Coupling Yoshihiko Yamamoto, Jun-ichi Ishii, Hisao Nishiyama, and Kenji Itoh pp 3712–3713 DOI: 10.1021/ja049673y Supporting Info

Molecular Details of Urease Inhibition by Boric Acid:  Insights into the Catalytic Mechanism Stefano Benini, Wojciech R. Rypniewski, Keith S. Wilson, Stefano Mangani, and Stefano Ciurli pp 3714–3715 DOI: 10.1021/ja049618p Supporting Info

Magnetically Ordered (Tc = 200 K) Bis(tetracyanopyrazine)vanadium, V[TCNP]2·yCH2Cl2 Elaine B. Vickers, Trent D. Selby, and Joel S. Miller pp 3716–3717 DOI: 10.1021/ja0397308

Interior Surface Modification of Bacteriophage MS2 Jacob M. Hooker, Ernest W. Kovacs, and Matthew B. Francis pp 3718–3719 DOI: 10.1021/ja031790q Supporting Info

A New Method for Rapid Characterization of the Folding Pathways of Multidisulfide-Containing Proteins Ervin Welker, Laura Hathaway, and Harold A. Scheraga pp 3720–3721 DOI: 10.1021/ja031658q

Stable Helical Polyguanidines:  Poly{N-(1-anthryl)-N‘-[(R)- and/or (S)-3,7-dimethyloctyl]guanidines} Hong-Zhi Tang, Yujie Lu, Gonglu Tian, Michael D. Capracotta, and Bruce M. Novak pp 3722–3723 DOI: 10.1021/ja049937g Supporting Info

Synthesis and Electronic Properties of Donor−Acceptor π-Conjugated Siloles A. J. Boydston, Youshi Yin, and Brian L. Pagenkopf pp 3724–3725 DOI: 10.1021/ja049758z Supporting Info

Short Total Synthesis of (±)-Sceptrin Phil S. Baran, Alexandros L. Zografos, and Daniel P. O'Malley pp 3726–3727 DOI: 10.1021/ja049648s Supporting Info

trans-Bis(alkynyl) Diruthenium(III) Tetra(amidinate):  An Effective Facilitator of Electronic Delocalization Guo-Lin Xu, Maria C. DeRosa, Robert J. Crutchley, and Tong Ren pp 3728–3729 DOI: 10.1021/ja049915u Supporting Info

Two-Dimensional Diversity:  Screening Human cDNA Phage Display Libraries with a Random Diversity Probe for the Display Cloning of Phosphotyrosine Binding Domains Elizabeth J. Videlock, Victor K. Chung, Michael A. Mohan, Timothy M. Strok, and David J. Austin pp 3730–3731 DOI: 10.1021/ja039006p Supporting Info

Asymmetric Catalysis with CO2:  Direct Synthesis of Optically Active Propylene Carbonate from Racemic Epoxides Xiao-Bing Lu, Bin Liang, Yin-Ju Zhang, Yu-Zeng Tian, Yi-Ming Wang, Chen-Xi Bai, Hui Wang, and Rong Zhang pp 3732–3733 DOI: 10.1021/ja049734s Supporting Info

Ag-Catalyzed Asymmetric Mannich Reactions of Enol Ethers with Aryl, Alkyl, Alkenyl, and Alkynyl Imines Nathan S. Josephsohn, Marc L. Snapper, and Amir H. Hoveyda pp 3734–3735 DOI: 10.1021/ja049388e Supporting Info

Solid-Phase Synthesis of Positively Charged Deoxynucleic Guanidine (DNG) Tethering a Hoechst 33258 Analogue:  Triplex and Duplex Stabilization by Simultaneous Minor Groove Binding Putta Mallikarjuna Reddy and Thomas C. Bruice pp 3736–3747 DOI: 10.1021/ja031557s Supporting Info

Chemical Genetic Control of Protein Levels:  Selective in Vivo Targeted Degradation John S. Schneekloth, Jr., Fabiana N. Fonseca, Michael Koldobskiy, Amit Mandal, Raymond Deshaies, Kathleen Sakamoto, and Craig M. Crews pp 3748–3754 DOI: 10.1021/ja039025z Supporting Info

Control of Bacteria Adhesion by Cell-Wall Engineering Reiko Sadamoto, Kenichi Niikura, Taichi Ueda, Kenji Monde, Norio Fukuhara, and Shin-Ichiro Nishimura pp 3755–3761 DOI: 10.1021/ja039391i

The Diastereomeric Assembly of Polylysine Is the Low-Volume Pathway for Preferential Formation of β-Sheet Aggregates Wojciech Dzwolak, Revanur Ravindra, Chiara Nicolini, Ralf Jansen, and Roland Winter pp 3762–3768 DOI: 10.1021/ja039138i

Probing the Transition States of Four Glucoside Hydrolyses with 13C Kinetic Isotope Effects Measured at Natural Abundance by NMR Spectroscopy Jason K. Lee, Alex D. Bain, and Paul J. Berti pp 3769–3776 DOI: 10.1021/ja0394028 Supporting Info

Electronic and Spectroscopic Studies of the Non-Heme Reduced Binuclear Iron Sites of Two Ribonucleotide Reductase Variants:  Comparison to Reduced Methane Monooxygenase and Contributions to O2 Reactivity Pin-pin Wei, Andrew J. Skulan, Natasa Mitić, Yi-Shan Yang, Lana Saleh, J. Martin Bollinger, Jr., and Edward I. Solomon pp 3777–3788 DOI: 10.1021/ja0374731 Supporting Info

The Role of Large Conformational Changes in Efficient Ultrafast Internal Conversion:  Deviations from the Energy Gap Law Henk Fidder, Matteo Rini, and Erik T. J. Nibbering pp 3789–3794 DOI: 10.1021/ja038741y

Mechanisms of HNO and NO Production from Angeli's Salt:  Density Functional and CBS-QB3 Theory Predictions Andrew S. Dutton, Jon M. Fukuto, and K. N. Houk pp 3795–3800 DOI: 10.1021/ja0391614 Supporting Info

Conformational Control in the Cyclization of Hydrogen-Bonded Supramolecular Polymers A. Tessa ten Cate, Huub Kooijman, Anthony L. Spek, Rint P. Sijbesma, and E. W. Meijer pp 3801–3808 DOI: 10.1021/ja039408x Supporting Info

Characterization of a Chiral Stationary Phase by HR/MAS NMR Spectroscopy and Investigation of Enantioselective Interaction with Chiral Ligates by Transferred NOE Christine Hellriegel, Urban Skogsberg, Klaus Albert, Michael Lämmerhofer, Norbert M. Maier, and Wolfgang Lindner pp 3809–3816 DOI: 10.1021/ja0306359

A Contrivance for a Dynamic Porous Framework:  Cooperative Guest Adsorption Based on Square Grids Connected by Amide−Amide Hydrogen Bonds Kazuhiro Uemura, Susumu Kitagawa, Kôichi Fukui, and Kazuya Saito pp 3817–3828 DOI: 10.1021/ja039914m Supporting Info

Resonance Raman Studies of HOO−Co(III)Bleomycin and Co(III)Bleomycin:  Identification of Two Important Vibrational Modes, ν(Co−OOH) and ν(O−OH) Cynthia Rajani, James R. Kincaid, and David H. Petering pp 3829–3836 DOI: 10.1021/ja030622v

Further Studies on the Biosynthesis of the Manumycin-Type Antibiotic, Asukamycin, and the Chemical Synthesis of Protoasukamycin Yiding Hu and Heinz G. Floss pp 3837–3844 DOI: 10.1021/ja039336+ Supporting Info

Covalent versus Electrostatic Nature of the Strong Hydrogen Bond:  Discrimination among Single, Double, and Asymmetric Single-Well Hydrogen Bonds by Variable-Temperature X-ray Crystallographic Methods in β-Diketone Enol RAHB Systems Paola Gilli, Valerio Bertolasi, Loretta Pretto, Valeria Ferretti, and Gastone Gilli pp 3845–3855 DOI: 10.1021/ja030213z Supporting Info

Liquid-Crystalline Octopus Dendrimers:  Block Molecules with Unusual Mesophase Morphologies Lionel Gehringer, Cyril Bourgogne, Daniel Guillon, and Bertrand Donnio pp 3856–3867 DOI: 10.1021/ja031506v Supporting Info

Photocatalytic Synthesis of Silver Nanoparticles Stabilized by TiO2 Nanorods:  A Semiconductor/Metal Nanocomposite in Homogeneous Nonpolar Solution P. Davide Cozzoli, Roberto Comparelli, Elisabetta Fanizza, M. Lucia Curri, Angela Agostiano, and Danièle Laub pp 3868–3879 DOI: 10.1021/ja0395846

Syntheses and Spectroscopic and Quadratic Nonlinear Optical Properties of Extended Dipolar Complexes with Ruthenium(II) Ammine Electron Donor and N-Methylpyridinium Acceptor Groups Benjamin J. Coe, Lathe A. Jones, James A. Harris, Bruce S. Brunschwig, Inge Asselberghs, Koen Clays, André Persoons, Javier Garín, and Jesús Orduna pp 3880–3891 DOI: 10.1021/ja0315412

Mechanistic Study on the Replacement Reaction between Silver Nanostructures and Chloroauric Acid in Aqueous Medium Yugang Sun and Younan Xia pp 3892–3901 DOI: 10.1021/ja039734c

Molecule-Specific Imaging with Mass Spectrometry and a Buckminsterfullerene Probe:  Application to Characterizing Solid-Phase Synthesized Combinatorial Libraries Jiyun Xu, Christopher W. Szakal, Scott E. Martin, Blake R. Peterson, Andreas Wucher, and Nicholas Winograd pp 3902–3909 DOI: 10.1021/ja036549q

Competitive Paths for Methanol Decomposition on Pt(111) Jeff Greeley and Manos Mavrikakis pp 3910–3919 DOI: 10.1021/ja037700z

Chemical Activity of the Nitrogenase FeMo Cofactor with a Central Nitrogen Ligand:  Density Functional Study Berit Hinnemann and Jens K. Nørskov pp 3920–3927 DOI: 10.1021/ja037792s Supporting Info

Electronic Structure and Solvation of Copper and Silver Ions:  A Theoretical Picture of a Model Aqueous Redox Reaction Jochen Blumberger, Leonardo Bernasconi, Ivano Tavernelli, Rodolphe Vuilleumier, and Michiel Sprik pp 3928–3938 DOI: 10.1021/ja0390754

Molecular View of the Anomalous Acidities of Sn2+, Pb2+, and Hg2+ Hazel Cox and Anthony J. Stace pp 3939–3947 DOI: 10.1021/ja039248p

Protein-Induced Bonding Perturbation of the Rhodopsin Chromophore Detected by Double-Quantum Solid-State NMR Marina Carravetta, Xin Zhao, Ole G. Johannessen, Wai Cheu Lai, Michiel A. Verhoeven, Petra H. M. Bovee-Geurts, Peter J. E. Verdegem, Suzanne Kiihne, Henrik Luthman, Huub J. M. de Groot, Willem J. deGrip, Johan Lugtenburg, and Malcolm H. Levitt pp 3948–3953 DOI: 10.1021/ja039390q

The Dynamics of Noble Metal Atom Penetration through Methoxy-Terminated Alkanethiolate Monolayers Amy V. Walker, Timothy B. Tighe, Orlando M. Cabarcos, Michael D. Reinard, Brendan C. Haynie, Sundararajan Uppili, Nicholas Winograd, and David L. Allara pp 3954–3963 DOI: 10.1021/ja0395792

Probing Slow Dynamics in High Molecular Weight Proteins by Methyl-TROSY NMR Spectroscopy:  Application to a 723-Residue Enzyme Dmitry M. Korzhnev, Karin Kloiber, Voula Kanelis, Vitali Tugarinov, and Lewis E. Kay pp 3964–3973 DOI: 10.1021/ja039587i Supporting Info

Charge Transfer in the Electron Donor−Acceptor Complex BH3NH3 Yirong Mo, Lingchun Song, Wei Wu, and Qianer Zhang pp 3974–3982 DOI: 10.1021/ja039778l

Perturbation of Conjugation in Allylic Lithium Compounds Due to Stereochemical Control of Internal Lithium Coordination:  Crystallography, NMR, and Calculational Studies Gideon Fraenkel, Albert Chow, Roland Fleischer, and Hua Liu pp 3983–3995 DOI: 10.1021/ja030370y Supporting Info

A Theoretical Study of the Mechanism for the Biogenesis of Cofactor Topaquinone in Copper Amine Oxidases Rajeev Prabhakar and Per E. M. Siegbahn pp 3996–4006 DOI: 10.1021/ja034721k

Failure of Time-Dependent Density Functional Theory for Long-Range Charge-Transfer Excited States:  The Zincbacteriochlorin−Bacteriochlorin and Bacteriochlorophyll−Spheroidene Complexes Andreas Dreuw and Martin Head-Gordon pp 4007–4016 DOI: 10.1021/ja039556n Supporting Info

Quantum Mechanical/Molecular Mechanical Investigation of the Mechanism of C−H Hydroxylation of Camphor by Cytochrome P450cam:  Theory Supports a Two-State Rebound Mechanism Jan C. Schöneboom, Shimrit Cohen, Hai Lin, Sason Shaik, and Walter Thiel pp 4017–4034 DOI: 10.1021/ja039847w Supporting Info

Structure-Dependent Charge Transport and Storage in Self-Assembled Monolayers of Compounds of Interest in Molecular Electronics:  Effects of Tip Material, Headgroup, and Surface Concentration Fu-Ren F. Fan, Yuxing Yao, Lintao Cai, Long Cheng, James M. Tour, and Allen J. Bard pp 4035–4042 DOI: 10.1021/ja0359815 Supporting Info

Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications Emerilis Casado-Rivera, David J. Volpe, Laif Alden, Cora Lind, Craig Downie, Terannie Vázquez-Alvarez, Antonio C. D. Angelo, Francis J. DiSalvo, and Héctor D. Abruña pp 4043–4049 DOI: 10.1021/ja038497a

Strong Two-Photon Absorption of Self-Assembled Butadiyne-Linked Bisporphyrin [J. Am. Chem. Soc. 2003, 125, 13356−13357]. Kazuya Ogawa, Atsushi Ohashi, Yoshiaki Kobuke, Kenji Kamada, and Koji Ohta p 4050 DOI: 10.1021/ja0492135

Issue 13

Thermally Activated Conduction in Molecular Junctions Yoram Selzer, Marco A. Cabassi, Theresa S. Mayer, and David L. Allara pp 4052–4053 DOI: 10.1021/ja039015y

Molecularly Imprinted Sol−Gel Nanotubes Membrane for Biochemical Separations Huang-Hao Yang, Shu-Qiong Zhang, Wei Yang, Xiao-Lan Chen, Zhi-Xia Zhuang, Jin-Gou Xu, and Xiao-Ru Wang pp 4054–4055 DOI: 10.1021/ja0389570 Supporting Info

Supraphos:  A Supramolecular Strategy To Prepare Bidentate Ligands Vincent F. Slagt, Marc Röder, Paul C. J. Kamer, Piet W. N. M. van Leeuwen, and Joost N. H. Reek pp 4056–4057 DOI: 10.1021/ja038955f Supporting Info

Wolff Rearrangement of 2-Diazo-1(2H)-Naphthalenone Induced by Nonresonant Two-Photon Absorption of NIR Radiation Nurtay K. Urdabayev and Vladimir V. Popik pp 4058–4059 DOI: 10.1021/ja0497328 Supporting Info

Li+-Induced σ-Bond Metathesis:  Aryl for Methyl Exchange on Boron in a Methylated Monocarbadodecaborate Anion Zbyněk Janoušek, Uwe Lehmann, Jakub Častulík, Ivana Císařová, and Josef Michl pp 4060–4061 DOI: 10.1021/ja0387857 Supporting Info

Synthesis of Polymer Dielectric Layers for Organic Thin Film Transistors via Surface-Initiated Ring-Opening Metathesis Polymerization Isaac M. Rutenberg, Oren A. Scherman, Robert H. Grubbs, Weirong Jiang, Eric Garfunkel, and Zhenan Bao pp 4062–4063 DOI: 10.1021/ja035773c Supporting Info

Squaraines as Fluoro−Chromogenic Probes for Thiol-Containing Compounds and Their Application to the Detection of Biorelevant Thiols Jose V. Ros-Lis, Beatriz García, Diego Jiménez, Ramón Martínez-Máñez, Félix Sancenón, Juan Soto, Fernando Gonzalvo, and M. Carmen Valldecabres pp 4064–4065 DOI: 10.1021/ja031987i Supporting Info

Fast Lithium Ion Diffusion in the Ternary Layered Nitridometalate LiNiN Zlatka Stoeva, Ruben Gomez, Alexandra G. Gordon, Mark Allan, Duncan H. Gregory, Gary B. Hix, and Jeremy J. Titman pp 4066–4067 DOI: 10.1021/ja039603b Supporting Info

Nickel Oxidation States of F430 Cofactor in Methyl-Coenzyme M Reductase Jennifer L. Craft, Yih-Chern Horng, Stephen W. Ragsdale, and Thomas C. Brunold pp 4068–4069 DOI: 10.1021/ja038082p Supporting Info

Nanohybrids from Liquid Crystalline Extended Amphiphilic Dendrimers Byoung-Ki Cho, Anurag Jain, Surbhi Mahajan, Hooisweng Ow, Sol M. Gruner, and Ulrich Wiesner pp 4070–4071 DOI: 10.1021/ja0318986 Supporting Info

Bis-allenylidene Metal Complex and Unique Related Radical with Delocalization of One Electron over Both Trans Carbon-Rich Chains Stéphane Rigaut, Karine Costuas, Daniel Touchard, Jean-Yves Saillard, Stéphane Golhen, and Pierre H. Dixneuf pp 4072–4073 DOI: 10.1021/ja049631+ Supporting Info

Rational Design of a Novel Fluorescent Biosensor for β-Lactam Antibiotics from a Class A β-Lactamase Pak-Ho Chan, Hong-Bing Liu, Yu Wai Chen, Kwok-Chu Chan, Chun-Wai Tsang, Yun-Chung Leung, and Kwok-Yin Wong pp 4074–4075 DOI: 10.1021/ja038409m Supporting Info

Characterization of TectoRNA Assembly with Cationic Conjugated Polymers Bin Liu, Stéphanie Baudrey, Luc Jaeger, and Guillermo C. Bazan pp 4076–4077 DOI: 10.1021/ja031552v Supporting Info

Ambient Pressure Synthesis of Corundum-Type In2O3 Mauro Epifani and Pietro SicilianoAlexander Gurlo, Nicolae Barsan, and Udo Weimar pp 4078–4079 DOI: 10.1021/ja0318075 Supporting Info

Isomerization of a Peptidic Fragment Studied Theoretically in Vacuum and in Explicit Water Solvent at Finite Temperature Yves A. Mantz, Helene Gerard, Radu Iftimie, and Glenn J. Martyna pp 4080–4081 DOI: 10.1021/ja030512o Supporting Info

Helix-Sense Selective Polymerization of Carbodiimides:  Building Permanently Optically Active Polymers from Achiral Monomers Gonglu Tian, Yujie Lu, and Bruce M. Novak pp 4082–4083 DOI: 10.1021/ja049548m Supporting Info

Structural Characterization of a Pentacene Monolayer on an Amorphous SiO2 Substrate with Grazing Incidence X-ray Diffraction Sandra E. Fritz, Stephen M. Martin, C. Daniel Frisbie, Michael D. Ward, and Michael F. Toney pp 4084–4085 DOI: 10.1021/ja049726b

Direct Detection of Genomic DNA by Enzymatically Amplified SPR Imaging Measurements of RNA Microarrays Terry T. Goodrich, Hye Jin Lee, and Robert M. Corn pp 4086–4087 DOI: 10.1021/ja039823p Supporting Info

Photolithographic Synthesis of Peptoids Shuwei Li, Dawn Bowerman, Nishanth Marthandan, Stanley Klyza, Kevin J. Luebke, Harold R. Garner, and Thomas Kodadek pp 4088–4089 DOI: 10.1021/ja039565w Supporting Info

AXAFS as a Probe of Charge Redistribution within Organometallic Complexes Moniek Tromp, Jeroen A. van Bokhoven, Martijn Q. Slagt, Robertus J. M. Klein Gebbink, Gerard van Koten, David E. Ramaker, and Diek C. Koningsberger pp 4090–4091 DOI: 10.1021/ja031885s Supporting Info

Solid-State NMR Spectroscopy of Molecular Hydrogen Trapped Inside an Open-Cage Fullerene Marina Carravetta, Yasujiro Murata, Michihisa Murata, Ivo Heinmaa, Raivo Stern, Ana Tontcheva, Ago Samoson, Yves Rubin, Koichi Komatsu, and Malcolm H. Levitt pp 4092–4093 DOI: 10.1021/ja031536y Supporting Info

Redox-Active Star Molecules Incorporating the 4-Benzoylpyridinium Cation:  Implications for the Charge Transfer Efficiency along Branches vs Across the Perimeter in Dendrimers Nicholas Leventis, Jinhua Yang, Eve F. Fabrizio, Abdel-Monem M. Rawashdeh, Woon Su Oh, and Chariklia Sotiriou-Leventis pp 4094–4095 DOI: 10.1021/ja0390247 Supporting Info

The Rotational Spectrum and Geometrical Structure of Thiozone, S3 Michael C. McCarthy, Sven Thorwirth, Carl A. Gottlieb, and Patrick Thaddeus pp 4096–4097 DOI: 10.1021/ja049645f

A Versatile Chemo-Enzymatic Route to Enantiomerically Pure β-Branched α-Amino Acids Geoffrey J. Roff, Richard C. Lloyd, and Nicholas J. Turner pp 4098–4099 DOI: 10.1021/ja049499d Supporting Info

Amidopalladation of Alkoxyallenes Applied in the Synthesis of an Enantiopure 1-Ethylquinolizidine Frog Alkaloid Sape S. Kinderman, René de Gelder, Jan H. van Maarseveen, Hans E. Schoemaker, Henk Hiemstra, and Floris P. J. T. Rutjes pp 4100–4101 DOI: 10.1021/ja039919j Supporting Info

Thiourea-Catalyzed Enantioselective Hydrophosphonylation of Imines:  Practical Access to Enantiomerically Enriched α-Amino Phosphonic Acids Guy D. Joly and Eric N. Jacobsen pp 4102–4103 DOI: 10.1021/ja0494398 Supporting Info

Reversible Cleavage and Recombination of an Acetylenic Carbon−Carbon Bond on a Tetrairon Cluster Coupled with a Two-Electron Redox Reaction Masaaki Okazaki, Takeo Ohtani, and Hiroshi Ogino pp 4104–4105 DOI: 10.1021/ja049720m Supporting Info

Characterization of Ar‘Sn(μ-Br)Sn(Ar‘)CH2C6H4-4-Pri (Ar‘ = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2):  A Stable Structural Analogue for a Heavier Group 14 Element Monobridged Alkene Isomer HM(μ-H)MH2 (M = Sn or Pb) Corneliu Stanciu, Anne F. Richards, and Philip P. Power pp 4106–4107 DOI: 10.1021/ja0316871 Supporting Info

Direct and Enantioselective Organocatalytic α-Chlorination of Aldehydes Michael P. Brochu, Sean P. Brown, and David W. C. MacMillan pp 4108–4109 DOI: 10.1021/ja049562z Supporting Info

Spontaneous Anti-Resolution in Heterochiral Clusters of Serine Ryan R. Julian, Sunnie Myung, and David E. Clemmer pp 4110–4111 DOI: 10.1021/ja031516w Supporting Info

Transition-Metal-Free:  A Highly Efficient Catalytic Aerobic Alcohol Oxidation Process Renhua Liu, Xinmiao Liang, Chunyan Dong, and Xinquan Hu pp 4112–4113 DOI: 10.1021/ja031765k Supporting Info

The Raman Spectrum and Aromatic Stabilization in a Cyclic Germylene Larissa A. Leites, Sergey S. Bukalov, Alexander V. Zabula, Irina A. Garbuzova, Daniel F. Moser, and Robert West pp 4114–4115 DOI: 10.1021/ja0317877

Charge Injection and Photooxidation of Single Conjugated Polymer Molecules So-Jung Park, Andre J. Gesquiere, Ji Yu, and Paul F. Barbara pp 4116–4117 DOI: 10.1021/ja031929x

Phosphine-Mediated Reductive Condensation of γ-Acyloxy Butynoates:  A Diversity Oriented Strategy for the Construction of Substituted Furans Cheol-Kyu Jung, Jian-Cheng Wang, and Michael J. Krische pp 4118–4119 DOI: 10.1021/ja049377l Supporting Info

Multipotential Electrochemical Detection of Primer Extension Reactions on DNA Self-Assembled Monolayers Daniel A. Di Giusto, Wjatschesslaw A. Wlassoff, Susanne Giesebrecht, J. Justin Gooding, and Garry C. King pp 4120–4121 DOI: 10.1021/ja0319036 Supporting Info

Molecular Sieving in a Nanoporous b-Oriented Pure-Silica-Zeolite MFI Monocrystal Film Shuang Li, Xin Wang, Derek Beving, Zhongwei Chen, and Yushan Yan pp 4122–4123 DOI: 10.1021/ja031985y Supporting Info

DNA Deformability at the Base Pair Level Filip Lankaš, Jiří Šponer, Jörg Langowski, and Thomas E. Cheatham, III pp 4124–4125 DOI: 10.1021/ja0390449 Supporting Info

The Chirality of a Four-Way Helical Junction in RNA Terry A. Goody, David M. J. Lilley, and David G. Norman pp 4126–4127 DOI: 10.1021/ja0319240 Supporting Info

Catalytic, Highly Enantio, and Diastereoselective Nitroso Diels−Alder Reaction Yuhei Yamamoto and Hisashi Yamamoto pp 4128–4129 DOI: 10.1021/ja049849w Supporting Info

Alkene-Directed, Nickel-Catalyzed Alkyne Coupling Reactions Karen M. Miller, Torsak Luanphaisarnnont, Carmela Molinaro, and Timothy F. Jamison pp 4130–4131 DOI: 10.1021/ja0491735 Supporting Info

A Unified Description of the Electrochemical, Charge Distribution, and Spectroscopic Properties of the Special-Pair Radical Cation in Bacterial Photosynthesis Jeffrey R. Reimers and Noel S. Hush pp 4132–4144 DOI: 10.1021/ja036883m

Covalent Schiff Base Catalysis and Turnover by a DNAzyme:  A M2+-Independent AP-Endonuclease Mimic Jonathan P. May, Richard Ting, Leonard Lermer, Jason M. Thomas, Yoann Roupioz, and David M. Perrin pp 4145–4156 DOI: 10.1021/ja037625s Supporting Info

The Nature of the Exchange Coupling between High-Spin Fe(III) Heme o3 and CuB(II) in Escherichia coli Quinol Oxidase, Cytochrome bo3:  MCD and EPR Studies Myles R. Cheesman, Vasily S. Oganesyan, Nicholas J. Watmough, Clive S. Butler, and Andrew J. Thomson pp 4157–4166 DOI: 10.1021/ja038858m Supporting Info

Proton Binding to Proteins:  pKa Calculations with Explicit and Implicit Solvent Models Thomas Simonson, Jens Carlsson, and David A. Case pp 4167–4180 DOI: 10.1021/ja039788m

Substrate Binding Favors Enhanced NO Binding to P450cam Alicja Franke, Grazyna Stochel, Christiane Jung, and Rudi van Eldik pp 4181–4191 DOI: 10.1021/ja038774d

Design of a Functional Protein for Molecular Recognition:  Specificity of Ligand Binding in a Metal-Assembled Protein Cavity Probed by 19F NMR Allison J. Doerr, Martin A. Case, István Pelczer, and George L. McLendon pp 4192–4198 DOI: 10.1021/ja035798b Supporting Info

Structure Distribution in an Elastin-Mimetic Peptide (VPGVG)3 Investigated by Solid-State NMR X. L. Yao and M. Hong pp 4199–4210 DOI: 10.1021/ja036686n

Quantitative Vibrational Dynamics of Iron in Nitrosyl Porphyrins Bogdan M. Leu, Marek Z. Zgierski, Graeme R. A. Wyllie, W. Robert Scheidt, Wolfgang Sturhahn, E. Ercan Alp, Stephen M. Durbin, and J. Timothy Sage pp 4211–4227 DOI: 10.1021/ja038526h Supporting Info

Photoactivation of the Photoactive Yellow Protein:  Why Photon Absorption Triggers a Trans-to-Cis Isomerization of the Chromophore in the Protein Gerrit Groenhof, Mathieu Bouxin-Cademartory, Berk Hess, Sam P. de Visser, Herman J. C. Berendsen, Massimo Olivucci, Alan E. Mark, and Michael A. Robb pp 4228–4233 DOI: 10.1021/ja039557f Supporting Info

Biofunctionalized, Ultrathin Coatings of Cross-Linked Star-Shaped Poly(ethylene oxide) Allow Reversible Folding of Immobilized Proteins Jürgen Groll, Elza V. Amirgoulova, Thomas Ameringer, Colin D. Heyes, Carlheinz Röcker, G. Ulrich Nienhaus, and Martin Möller pp 4234–4239 DOI: 10.1021/ja0318028

Fluorescent Polymeric Transducer for the Rapid, Simple, and Specific Detection of Nucleic Acids at the Zeptomole Level Kim Doré, Sébastien Dubus, Hoang-Anh Ho, Isabelle Lévesque, Maryse Brunette, Geneviève Corbeil, Maurice Boissinot, Guy Boivin, Michel G. Bergeron, Denis Boudreau, and Mario Leclerc pp 4240–4244 DOI: 10.1021/ja038900d

Catalytic, Asymmetric α-Chlorination of Acid Halides Stefan France, Harald Wack, Andrew E. Taggi, Ahmed M. Hafez, Ty R. Wagerle, Meha H. Shah, Crystal L. Dusich, and Thomas Lectka pp 4245–4255 DOI: 10.1021/ja039046t Supporting Info

Extended Barbaralanes:  Sigmatropic Shiftamers or σ-Polyacenes? Dean J. Tantillo, Roald Hoffmann, Kendall N. Houk, Philip M. Warner, Eric C. Brown, and Daven K. Henze pp 4256–4263 DOI: 10.1021/ja0392364 Supporting Info

Toward Synthetic Tubes for NO2/N2O4:  Design, Synthesis, and Host−Guest Chemistry Grigory V. Zyryanov and Dmitry M. Rudkevich pp 4264–4270 DOI: 10.1021/ja0392869

Simple Strategy for the Immobilization of Dirhodium Tetraprolinate Catalysts Using a Pyridine-Linked Solid Support Huw M. L. Davies, Abbas M. Walji, and Tadamichi Nagashima pp 4271–4280 DOI: 10.1021/ja0393067 Supporting Info

Cyclic Disulfide C(8) Iminoporfiromycin:  Nucleophilic Activation of a Porfiromycin Sang Hyup Lee and Harold Kohn pp 4281–4292 DOI: 10.1021/ja030577r Supporting Info

Reactivities of Carboxyalkyl-Substituted 1,4,5,8-Naphthalene Diimides in Aqueous Solution Bindu Abraham, Sun McMasters, Mellisa A. Mullan, and Lisa A. Kelly pp 4293–4300 DOI: 10.1021/ja0389265

Faster Dissociation:  Measured Rates and Computed Effects on Barriers in Aryl Halide Radical Anions Norihiko Takeda, Pavel V. Poliakov, Andrew R. Cook, and John R. Miller pp 4301–4309 DOI: 10.1021/ja0389671 Supporting Info

Total Synthesis of the Ristocetin Aglycon Brendan M. Crowley, Yoshiki Mori, Casey C. McComas, Datong Tang, and Dale L. Boger pp 4310–4317 DOI: 10.1021/ja039795a Supporting Info

Solid-State Packing of Conjugated Oligomers:  From π-Stacks to the Herringbone Structure M. David Curtis, Jie Cao, and Jeff W. Kampf pp 4318–4328 DOI: 10.1021/ja0397916 Supporting Info

Mechanism of Helix Induction on a Stereoregular Poly((4-carboxyphenyl)acetylene) with Chiral Amines and Memory of the Macromolecular Helicity Assisted by Interaction with Achiral Amines Katsuhiro Maeda, Kazuhide Morino, Yoshio Okamoto, Takahiro Sato, and Eiji Yashima pp 4329–4342 DOI: 10.1021/ja0318378 Supporting Info

Combining Magnetic Resonance Spectroscopies, Mass Spectrometry, and Molecular Dynamics:  Investigation of Chiral Recognition by 2,6-di-O-Methyl-β-cyclodextrin Paola Franchi, Marco Lucarini, Elisabetta Mezzina, and Gian Franco Pedulli pp 4343–4354 DOI: 10.1021/ja049713y Supporting Info

Methane-to-Methanol Oxidation by the Hydrated Iron(IV) Oxo Species in Aqueous Solution:  A Combined DFT and Car−Parrinello Molecular Dynamics Study Bernd Ensing Francesco Buda, Michiel C. M. Gribnau, and Evert Jan Baerends pp 4355–4365 DOI: 10.1021/ja038865a

Formation and Stability of N-Heterocyclic Carbenes in Water:  The Carbon Acid pKa of Imidazolium Cations in Aqueous Solution Tina L. Amyes, Steven T. Diver, John P. Richard, Felix M. Rivas, and Krisztina Toth pp 4366–4374 DOI: 10.1021/ja039890j Supporting Info

Synthons for Coordinatively Unsaturated Complexes of Tungsten, and Their Use for the Synthesis of High Oxidation-State Silylene Complexes Benjamin V. Mork and T. Don Tilley pp 4375–4385 DOI: 10.1021/ja030548g Supporting Info

Li17Ag3Sn6:  A Polar Intermetallic π-System with Carbonate-like [AgSn3]11- Anions and Trefoil Aromatic [Ag2Sn3]6- Layers Corina Lupu, Craig Downie, Arnold M. Guloy, Thomas A. Albright, and Jiang-Gao Mao pp 4386–4397 DOI: 10.1021/ja038868n Supporting Info

Mn14Al56+xGe3-x (x = 0−0.6):  A New Intermetallic Phase Containing Unprecedented “Half-Broken” Mackay Icosahedra as Building Units Li-Ming Wu and Dong-Kyun Seo pp 4398–4403 DOI: 10.1021/ja039154f Supporting Info

DNA Nucleosides and Their Radical Anions:  Molecular Structures and Electron Affinities Nancy A. Richardson, Jiande Gu, Suyun Wang, Yaoming Xie, and Henry F. Schaefer III pp 4404–4411 DOI: 10.1021/ja030487m

13C NMR Study of Halogen Bonding of Haloarenes:  Measurements of Solvent Effects and Theoretical Analysis Rainer Glaser, Naijun Chen, Hong Wu, Nathan Knotts, and Martin Kaupp pp 4412–4419 DOI: 10.1021/ja0383672 Supporting Info

Oxidation and Oxygenation of Iron Complexes of 2-Aza-21-carbaporphyrin Krystyna Rachlewicz, Sian-Ling Wang, Jia-Ling Ko, Chen-Hsiung Hung, and Lechosław Latos-Grażyński pp 4420–4431 DOI: 10.1021/ja039792y Supporting Info

Hydrogen Isotope Effects and Mechanism of Aqueous Ozone and Peroxone Decompositions Timothy M. Lesko, A. J. Colussi, and Michael R. Hoffmann pp 4432–4436 DOI: 10.1021/ja038907v Supporting Info

Density Functional Calculation of the 2D Potential Surface and Deuterium Isotope Effect on 13C Chemical Shifts in Picolinic Acid N-Oxide. Comparison with Experiment Jernej Stare, Aneta Jezierska, Gabriela Ambroži, Iztok J. Košir, Jurka Kidri, Aleksander Koll, Janez Mavri, and Dušan Hadži pp 4437–4443 DOI: 10.1021/ja021345f

Strain Energy of Small Ring Hydrocarbons. Influence of C−H Bond Dissociation Energies Robert D. Bach and Olga Dmitrenko pp 4444–4452 DOI: 10.1021/ja036309a Supporting Info

NMR-Based Characterization of Phenothiazines as a RNA Binding Scaffold Moriz Mayer and Thomas L. James pp 4453–4460 DOI: 10.1021/ja0398870

Issue 14

Fabrication and Characterization of Thin Films of Single-Walled Carbon Nanotube Bundles on Flexible Plastic Substrates Neerja Saran, Kunjal Parikh, Dong-Seok Suh, Edgar Muñoz, Harsha Kolla, and Sanjeev K. Manohar pp 4462–4463 DOI: 10.1021/ja037273p

Designed, Functionalized Helix−Loop−Helix Motifs that Bind Human Carbonic Anhydrase II:  A New Class of Synthetic Receptor Molecules Karin Enander, Gunnar T. Dolphin, and Lars Baltzer pp 4464–4465 DOI: 10.1021/ja038799c

Essential Amino Acid Residues Controlling the Unique Regioselectivity of Heme Oxygenase in Pseudomonas aeruginosa Hiroshi Fujii, Xuhong Zhang, and Tadashi Yoshida pp 4466–4467 DOI: 10.1021/ja031791i Supporting Info

A Dodecameric Porphyrin Wheel Xiaobin Peng, Naoki Aratani, Akihiko Takagi, Takuya Matsumoto, Tomoji Kawai, In-Wook Hwang, Tae Kyu Ahn, Dongho Kim, and Atsuhiro Osuka pp 4468–4469 DOI: 10.1021/ja0392972 Supporting Info

Cytochrome P450:  An Investigation of the Mössbauer Spectra of a Reaction Intermediate and an Fe(IV)O Model System Yong Zhang and Eric Oldfield pp 4470–4471 DOI: 10.1021/ja030664j Supporting Info

Unusual Equilibria Involving Group 4 Amides, Silyl Complexes, and Silyl Anions via Ligand Exchange Reactions Xianghua Yu, Hu Cai, Ilia A. Guzei, and Ziling Xue pp 4472–4473 DOI: 10.1021/ja031899y Supporting Info

Yb8Ge3Sb5, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric 1∞[Ge34-] Anions James R. Salvador, Daniel Bilc, S. D. Mahanti, Tim Hogan, Fu Guo, and Mercouri G. Kanatzidis pp 4474–4475 DOI: 10.1021/ja0395487 Supporting Info

Highly Polarized Luminescence from Optical Quality Films of a Semiconducting Polymer Aligned within Oriented Mesoporous Silica William C. Molenkamp, Masatoshi Watanabe, Hirokatsu Miyata, and Sarah H. Tolbert pp 4476–4477 DOI: 10.1021/ja039296+

Absolute Structural Constraints on Amyloid Fibrils from Solid-State NMR Spectroscopy of Partially Oriented Samples Nathan A. Oyler and Robert Tycko pp 4478–4479 DOI: 10.1021/ja031719k Supporting Info

An Asymmetric Synthesis of Hamigeran B via a Pd Asymmetric Allylic Alkylation for Enantiodiscrimination Barry M. Trost, Carole Pissot-Soldermann, Irwin Chen, and Gretchen M. Schroeder pp 4480–4481 DOI: 10.1021/ja0497025 Supporting Info

An Experimentally Derived Model for Stereoselectivity in the Aerobic Oxidative Kinetic Resolution of Secondary Alcohols by (Sparteine)PdCl2 Raissa M. Trend and Brian M. Stoltz pp 4482–4483 DOI: 10.1021/ja039551q Supporting Info

Cys-Gly-Cys Tripeptide Complexes of Nickel:  Binuclear Analogues for the Catalytic Site in Acetyl Coenzyme A Synthase Rangan Krishnan and Charles G. Riordan pp 4484–4485 DOI: 10.1021/ja038086u Supporting Info

CD and MCD Studies of the Non-Heme Ferrous Active Site in (4-Hydroxyphenyl)pyruvate Dioxygenase:  Correlation between Oxygen Activation in the Extradiol and α-KG-Dependent Dioxygenases Michael L. Neidig, Michael Kavana, Graham R. Moran, and Edward I. Solomon pp 4486–4487 DOI: 10.1021/ja0316521 Supporting Info

Molecular Dynamics Simulation of the Spontaneous Formation of a Small DPPC Vesicle in Water in Atomistic Detail Alex H. de Vries, Alan E. Mark, and Siewert J. Marrink pp 4488–4489 DOI: 10.1021/ja0398417 Supporting Info

A Reactivity/Affinity Switch for Parallel Kinetic Resolution:  α-Amino Acid Quasienantiomers and the Resolution of Cyclopropene Carboxylic Acids Lian-an Liao, Fan Zhang, Olga Dmitrenko, Robert D. Bach, and Joseph M. Fox pp 4490–4491 DOI: 10.1021/ja049779t Supporting Info

Metal−Intercalator-Mediated Self-Association and One-Dimensional Aggregation in the Structure of the Excised Major DNA Adduct of a Platinum−Acridine Agent Hemanta Baruah, Cynthia S. Day, Marcus W. Wright, and Ulrich Bierbach pp 4492–4493 DOI: 10.1021/ja038592j Supporting Info

Asymmetric Catalysis Using Self-Assembled Chiral Bidentate P,P-Ligands James M. Takacs, D. Sahadeva Reddy, Shin A. Moteki, Di Wu, and Hector Palencia pp 4494–4495 DOI: 10.1021/ja049873+ Supporting Info

The Dynamic Structure of Jadomycin B and the Amino Acid Incorporation Step of Its Biosynthesis Uwe Rix, Jianting Zheng, Lily L. Remsing Rix, Lisa Greenwell, Keqian Yang, and Jürgen Rohr pp 4496–4497 DOI: 10.1021/ja031724o Supporting Info

Valence Instabilities, Phase Transitions, and Abrupt Lattice Expansion at 5 K in the YbGaGe System Serena Margadonna, Kosmas Prassides, Andrew N. Fitch, James R. Salvador, and Mercouri G. Kanatzidis pp 4498–4499 DOI: 10.1021/ja049728w Supporting Info

Halogen Bonding and π···π Stacking Control Reactivity in the Solid State Tullio Caronna, Rosalba Liantonio, Thomas A. Logothetis, Pierangelo Metrangolo, Tullio Pilati, and Giuseppe Resnati pp 4500–4501 DOI: 10.1021/ja039884n Supporting Info

Synthesis of Polyaniline Nanofibers by “Nanofiber Seeding” Xinyu Zhang, Warren J. Goux, and Sanjeev K. Manohar pp 4502–4503 DOI: 10.1021/ja031867a Supporting Info

Distributed Computing and NMR Constraint-Based High-Resolution Structure Determination:  Applied for Bioactive Peptide Endothelin-1 To Determine C-Terminal Folding Hiroyuki Takashima, Norio Mimura, Tadayasu Ohkubo, Takuya Yoshida, Haruhiko Tamaoki, and Yuji Kobayashi pp 4504–4505 DOI: 10.1021/ja031637w Supporting Info

Local Structure of the Zeolitic Catalytically Active Site during Reaction Jeroen A. van Bokhoven, Ad M. J. van der Eerden, and Roel Prins pp 4506–4507 DOI: 10.1021/ja031755j

Anion−π Interactions in a Carousel Copper(II)−Triazine Complex Serhiy Demeshko, Sebastian Dechert, and Franc Meyer pp 4508–4509 DOI: 10.1021/ja049458h Supporting Info

Rhenium(V)-Catalyzed Synthesis of 2-Deoxy-α-glycosides Benjamin D. Sherry, Rebecca N. Loy, and F. Dean Toste pp 4510–4511 DOI: 10.1021/ja031895t Supporting Info

The LOV2 Domain of Phototropin:  A Reversible Photochromic Switch John T. M. Kennis, Ivo H. M. van Stokkum, Sean Crosson, Magdalena Gauden, Keith Moffat, and Rienk van Grondelle pp 4512–4513 DOI: 10.1021/ja031840r Supporting Info

Charge Development in the Transition State for Decarboxylations in Water:  Spontaneous and Acetone-Catalyzed Decarboxylation of Aminomalonate Brian P. Callahan and Richard Wolfenden pp 4514–4515 DOI: 10.1021/ja031720j

Structural Change of the Heme Pocket Due to Disulfide Bridge Formation Is Significantly Larger for Neuroglobin than for Cytoglobin Evi Vinck, Sabine Van Doorslaer, Sylvia Dewilde, and Luc Moens pp 4516–4517 DOI: 10.1021/ja0383322 Supporting Info

Lewis Acids Catalyze the Addition of Allylboronates to Aldehydes by Electrophilic Activation of the Dioxaborolane in a Closed Transition Structure Vivek Rauniyar and Dennis G. Hall pp 4518–4519 DOI: 10.1021/ja049446w Supporting Info

Enantioselective Total Synthesis of (+)-Tricycloclavulone Hisanaka Ito, Mineki Hasegawa, Yosuke Takenaka, Tatsuya Kobayashi, and Kazuo Iguchi pp 4520–4521 DOI: 10.1021/ja049750p Supporting Info

A Sulfido-Bridged Diiron(II) Compound and Its Reactions with Nitrogenase-Relevant Substrates Javier Vela, Sebastian Stoian, Christine J. Flaschenriem, Eckard Münck, and Patrick L. Holland pp 4522–4523 DOI: 10.1021/ja049417l Supporting Info

Ionic Strength-Controlled Virtual Area of Mesoporous Platinum Electrode Hankil Boo, Sejin Park, Bonkyung Ku, Yunmee Kim, Jin Hyung Park, Hee Chan Kim, and Taek Dong Chung pp 4524–4525 DOI: 10.1021/ja0398316 Supporting Info

Gold(I)-Catalyzed Conia-Ene Reaction of β-Ketoesters with Alkynes Joshua J. Kennedy-Smith, Steven T. Staben, and F. Dean Toste pp 4526–4527 DOI: 10.1021/ja049487s Supporting Info

Copper-Catalyzed Tandem Conjugate Addition−Electrophilic Trapping:  Ketones, Esters, and Nitriles as Terminal Electrophiles Kyriacos Agapiou, David F. Cauble, and Michael J. Krische pp 4528–4529 DOI: 10.1021/ja030603l Supporting Info

Large-Scale Synthesis of Uniform Nanotubes of a Nickel Complex by a Solution Chemical Route Lin Guo, Chenmin Liu, Rongming Wang, Huibin Xu, Ziyu Wu, and Shihe Yang pp 4530–4531 DOI: 10.1021/ja039381h Supporting Info

Core Electron Transitions as a Probe for Molecular Chirality:  Natural Circular Dichroism at the Carbon K-edge of Methyloxirane Stefano Turchini, Nicola Zema, Stefano Zennaro, Lucilla Alagna, Brian Stewart, Robert D. Peacock, and Tommaso Prosperi pp 4532–4533 DOI: 10.1021/ja039348v Supporting Info

Rational Pathway Engineering of Type I Fatty Acid Synthase Allows the Biosynthesis of Triacetic Acid Lactone from d-Glucose in Vivo Wenjuan Zha, Zengyi Shao, John W. Frost, and Huimin Zhao pp 4534–4535 DOI: 10.1021/ja0317271 Supporting Info

End-Group-Confined Chain Walking within a Group 4 Living Polyolefin and Well-Defined Cationic Zirconium Alkyl Complexes for Modeling This Behavior Matthew B. Harney, Richard J. Keaton, and Lawrence R. Sita pp 4536–4537 DOI: 10.1021/ja0496975 Supporting Info

Hydrogenolysis of [PhBP3]FeN-p-tolyl:  Probing the Reactivity of an Iron Imide with H2 Steven D. Brown and Jonas C. Peters pp 4538–4539 DOI: 10.1021/ja0399122 Supporting Info

Dipolar and Nonpolar Altitudinal Molecular Rotors Mounted on an Au(111) Surface Xiaolai Zheng, Mary E. Mulcahy, Dominik Horinek, Francesco Galeotti, Thomas F. Magnera, and Josef Michl pp 4540–4542 DOI: 10.1021/ja039482f Supporting Info

Toward Efficient Zn(II)-Based Artificial Nucleases Elisa Boseggia, Maddalena Gatos, Lorena Lucatello, Fabrizio Mancin, Stefano Moro, Manlio Palumbo, Claudia Sissi, Paolo Tecilla, Umberto Tonellato, and Giuseppe Zagotto pp 4543–4549 DOI: 10.1021/ja039465q Supporting Info

Nucleic Acid Analysis Using an Expanded Genetic Alphabet to Quench Fluorescence Christopher B. Sherrill, David J. Marshall, Michael J. Moser, Christine A. Larsen, Lygia Daudé-Snow, and James R. Prudent pp 4550–4556 DOI: 10.1021/ja0315558

Crystallographic Distinction between “Contact” and “Separated” Ion Pairs:  Structural Effects on Electronic/ESR Spectra of Alkali-Metal Nitrobenzenides Milya G. Davlieva, Jian-Ming Lü, Sergey V. Lindeman, and Jay K. Kochi pp 4557–4565 DOI: 10.1021/ja049856k Supporting Info

Cadmium(II) and Nickel(II) Complexes of Benziporphyrins. A Study of Weak Intramolecular Metal−Arene Interactions Marcin Stpień, Lechosław Latos-Grażyński, Ludmiła Szterenberg, Jarosław Panek, and Zdzisław Latajka pp 4566–4580 DOI: 10.1021/ja039384u Supporting Info

Photochemical Reaction Mechanisms of 2-Nitrobenzyl Compounds:  Methyl Ethers and Caged ATP Yuri V. Il'ichev, Markus A. Schwörer, and Jakob Wirz pp 4581–4595 DOI: 10.1021/ja039071z Supporting Info

Recognition of Chiral Catechols Using Oxo−Titanium Phthalocyanine Atsuya Muranaka, Masako Okuda, Nagao Kobayashi, Ken Somers, and Arnout Ceulemans pp 4596–4604 DOI: 10.1021/ja039843r

Marked Counteranion Effects on Single-Site Olefin Polymerization Processes. Correlations of Ion Pair Structure and Dynamics with Polymerization Activity, Chain Transfer, and Syndioselectivity Ming-Chou Chen, John A. S. Roberts, and Tobin J. Marks pp 4605–4625 DOI: 10.1021/ja036288k Supporting Info

The α-Helical Peptide Nucleic Acid Concept:  Merger of Peptide Secondary Structure and Codified Nucleic Acid Recognition Yumei Huang, Subhakar Dey, Xiao Zhang, Frank Sönnichsen, and Philip Garner pp 4626–4640 DOI: 10.1021/ja038434s Supporting Info

The Optical and Charge Transport Properties of Discotic Materials with Large Aromatic Hydrocarbon Cores Michael G. Debije, Jorge Piris, Matthijs P. de Haas, John M. Warman, Željko Tomović, Christopher D. Simpson, Mark D. Watson, and Klaus Müllen pp 4641–4645 DOI: 10.1021/ja0395994

Photochemistry of A1E, a Retinoid with a Conjugated Pyridinium Moiety:  Competition between Pericyclic Photooxygenation and Pericyclization Steffen Jockusch, Rex X. Ren, Young Pyo Jang, Yasuhiro Itagaki, Heidi R. Vollmer-Snarr, Janet R. Sparrow, Koji Nakanishi, and Nicholas J. Turro pp 4646–4652 DOI: 10.1021/ja039048d Supporting Info

New Caged Coumarin Fluorophores with Extraordinary Uncaging Cross Sections Suitable for Biological Imaging Applications YuRui Zhao, Quan Zheng, Kenneth Dakin, Ke Xu, Manuel L. Martinez, and Wen-Hong Li pp 4653–4663 DOI: 10.1021/ja036958m Supporting Info

Hydrogen-Mediated C−C Bond Formation:  Catalytic Regio- and Stereoselective Reductive Condensation of α-Keto Aldehydes and 1,3-Enynes Hye-Young Jang, Ryan R. Huddleston, and Michael J. Krische pp 4664–4668 DOI: 10.1021/ja0316566 Supporting Info

Deuterium Attachment to Carbon Nanotubes in Deuterated Water Kefu Fu, Huaping Li, Bing Zhou, Alex Kitaygorodskiy, Lawrence F. Allard, and Ya-Ping Sun pp 4669–4675 DOI: 10.1021/ja030312c

New Solid−Gas Metathetical Synthesis of Binary Metal Polysulfides and Sulfides at Intermediate Temperatures:  Utilization of Boron Sulfides Li-Ming Wu and Dong-Kyun Seo pp 4676–4681 DOI: 10.1021/ja0392521 Supporting Info

Inelastic Incoherent Neutron Scattering Measurements of Intact Cells and Tissues and Detection of Interfacial Water Robert C. Ford, Stuart V. Ruffle, Anibal J. Ramirez-Cuesta, Ilias Michalarias, Ilir Beta, Aline Miller, and Jichen Li pp 4682–4688 DOI: 10.1021/ja0393269

Tetraorganylammonium Superoxide Compounds:  Close to Unperturbed Superoxide Ions in the Solid State Pascal D. C. Dietzel, Reinhard K. Kremer, and Martin Jansen pp 4689–4696 DOI: 10.1021/ja039880i Supporting Info

Selective Depositions on Polyelectrolyte Multilayers:  Self-Assembled Monolayers of m-dPEG Acid as Molecular Template Srivatsan Kidambi, Christina Chan, and Ilsoon Lee pp 4697–4703 DOI: 10.1021/ja039359o

Calculation of the Deuteron Quadrupole Relaxation Rate in a Mixture of Water and Dimethyl Sulfoxide Markus G. Müller, Edme H. Hardy, Patrick S. Vogt, Christoph Bratschi, Barbara Kirchner, Hanspeter Huber, and Debra J. Searles pp 4704–4710 DOI: 10.1021/ja0397759 Supporting Info

Density Functional Theory Investigations on the Chemical Basis of the Selectivity Filter in the K+ Channel Protein Fuqiang Ban, Peter Kusalik, and Donald F. Weaver pp 4711–4716 DOI: 10.1021/ja0367290 Supporting Info

Adsorption and Dissociation of O2 on Pt−Co and Pt−Fe Alloys Ye Xu, Andrei V. Ruban, and Manos Mavrikakis pp 4717–4725 DOI: 10.1021/ja031701+

Tryptophan Chemical Shift in Peptides and Proteins:  A Solid State Carbon-13 Nuclear Magnetic Resonance Spectroscopic and Quantum Chemical Investigation Haihong Sun and Eric Oldfield pp 4726–4734 DOI: 10.1021/ja030612u Supporting Info

Zinc Solid-State NMR Spectroscopy of Human Carbonic Anhydrase:  Implications for the Enzymatic Mechanism Andrew S. Lipton, Robert W. Heck, and Paul D. Ellis pp 4735–4739 DOI: 10.1021/ja0305609

Novel Photoisomerization of Azoferrocene with a Low-Energy MLCT Band and Significant Change of the Redox Behavior between the cis- and trans-Isomers [J. Am. Chem. Soc. 2000, 122, 12373−12374]. Masato Kurihara, Takayuki Matsuda, Akira Hirooka, Tomona Yutaka, and Hiroshi Nishihara p 4740 DOI: 10.1021/ja040803c

Anomeric Configuration, Glycosidic Linkage, and the Solution Conformational Entropy of O-Linked Disaccharides [J. Am. Chem. Soc. 2003, 125, 4146−4148]. André M. Striegel p 4740 DOI: 10.1021/ja048929x

Modern Styrenic Polymers:  Polystyrenes and Styrenic Copolymers Edited by John Scheirs (ExcelPlas Australia, Edithvale) and Duane Priddy (Priddy & Associates, LLC, Midland, MI). J. Wiley and Sons, Ltd:  Chichester. 2003. xxxiv + 758 pp. $330.00. ISBN 0-471-49752-5. Daniel M. Knauss p 4741 DOI: 10.1021/ja033590k

Topics in Current Chemistry, 229:  New Aspects in Phosphorus Chemistry III Edited by J.-P. Majoral (Laboratoire de Chimie de Coordination du CNRS, Toulouse). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xii + 214 pp. $189.00. ISBN 3-540-00714-8. David S. Glueck p 4741 DOI: 10.1021/ja033638u

Catalysis and Electrocatalysis at Nanoparticle Surfaces By Andrzej Wieckowski (University of Illinois, Urbana-Champaign), Elena R. Savinova (Boreskov Institute of Catalysis, Russian Academy of Sciences), and Constantinos G. Vayenas (University of Patras). Marcel Dekker, Inc.:  New York, Basel. 2003. xviii + 970 pp. $225.00. ISBN 0-8247-0879-2. Dennis W. Bennett pp 4741–4742 DOI: 10.1021/ja0336123

Comprehensive Asymmetric Catalysis, Supplement 1 Edited by Eric N. Jacobsen (Harvard University), Andreas Pfaltz (University of Basel), and Hisashi Yamamoto (University of Chicago). Springer-Verlag:  Berlin, Heidelberg. 2004. xiv + 238 pp. $199.00. ISBN 3-540-00333-9. p 4742 DOI: 10.1021/ja033659o

Handbook of Reagents for Organic Synthesis:  Chiral Reagents for Asymmetric Synthesis Edited by Leo A. Paquette (The Ohio State University). John Wiley & Sons, Ltd.:  Chichester. 2003. xiv + 594 pp. $150.00. ISBN 0-470-85625-4. p 4742 DOI: 10.1021/ja033660n

Annual Review of Biophysics and Biomolecular Structure, Volume 32 Edited by Robert M. Stroud (University of California, San Francisco), Wilma K. Olson (Rutgers University), and Michael P. Sheetz (Columbia University). Annual Reviews:  Palo Alto, CA. 2003. xvi + 534 pp. $80.00 Print Version for Individuals, $180 Print Version for Institutions. ISBN 0-8243-1832-3. Ulrich Bierbach pp 4742–4743 DOI: 10.1021/ja033618s

Oxazoles:  Synthesis, Reactions and Spectroscopy. Part A. The Chemistry of Heterocyclic Compounds, Volume 20 Edited by David C. Palmer (Johnson & Johnson Pharmaceutical R&D, L.L.C., Raritan, NJ). John Wiley and Sons, Inc.:  Hoboken. 2003. xx + 640 pp. $325.00. ISBN 0-471-39494-7. Kim Albizati p 4743 DOI: 10.1021/ja033588t

Inorganic Electrochemistry:  Theory, Practice and Application By Piero Zanello (University of Siena, Italy). Royal Society of Chemistry:  Cambridge. 2003. xiv + 616 pp. $199.00. ISBN 0-85404-661-5. Andrew A. Gewirth pp 4743–4744 DOI: 10.1021/ja0336022

Affinity Capillary Electrophoresis in Pharmaceutics and Biopharmaceutics. Drugs and the Pharmaceutical Sciences, Volume 128 Edited by Reinhard H. H. Neubert and Hans-Hermann Ruttinger (Martin Luther University, Halle-Wittenberg, Germany). Marcel Dekker, Inc.:  Basel, New York. 2003. xiv + 362 pp. $175. ISBN 0-8247-0951-9 Frank A. Gomez p 4744 DOI: 10.1021/ja033611a

Handbook of Chemoinformatics:  From Data to Knowledge, Volumes 1−4 Edited by Johann Gasteiger (University of Erlangen-Nürnberg). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. xlvii + 1870 pp. $750.00. ISBN 3-527-30680-3. David Flaxbart pp 4744–4745 DOI: 10.1021/ja0336527

Classics in Total Synthesis II:  More Targets, Strat-egies, Methods By K. C. Nicolaou (The Scripps Re-search Institute and University of California, San Diego) and Scott A. Snyder (The Scripps Research Institute). Wiley-VCH Verlag GmbH & Co KGaA:  Weinheim. 2003. xx + 640 pp. $64.95. ISBN 3-527-30684-6. p 4745 DOI: 10.1021/ja033664s

Solvents and Solvent Effects in Organic Chemistry:  Third, Updated and Enlarged Edition By Christian Reichardt (Philipps-Universität Marburg). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim. 2003. 653 pp. $135.00. ISBN 3-527-30618-8. Alexandru T. Balaban pp 4745–4746 DOI: 10.1021/ja040904a

Issue 15

Segment Dynamics in Thin Polystyrene Films Probed by Single-Molecule Optics Nikodem Tomczak, Renaud A. L. Vallée, Erik M. H. P. van Dijk, Laurens Kuipers, Niek F. van Hulst, and G. Julius Vancso pp 4748–4749 DOI: 10.1021/ja039249h Supporting Info

Glycodendriproteins:  A Synthetic Glycoprotein Mimic Enzyme with Branched Sugar-Display Potently Inhibits Bacterial Aggregation Phillip M. Rendle, Andreas Seger, Joao Rodrigues, Neil J. Oldham, Richard R. Bott, J. Bryan Jones, Marjorie M. Cowan, and Benjamin G. Davis pp 4750–4751 DOI: 10.1021/ja031698u Supporting Info

Sensing of Aqueous Phosphates by Polymers with Dual Modes of Signal Transduction Dmitry Aldakov and Pavel Anzenbacher, Jr. pp 4752–4753 DOI: 10.1021/ja039934o Supporting Info

Estrogen Receptor Microarrays:  Subtype-Selective Ligand Binding Sung Hoon Kim, Anobel Tamrazi, Kathryn E. Carlson, Jonathan R. Daniels, In Young Lee, and John A. Katzenellenbogen pp 4754–4755 DOI: 10.1021/ja039586q Supporting Info

Probing Local and Long-Range Structure Simultaneously:  An In Situ Study of the High-Temperature Phase Transition of α-AlF3 Peter J. Chupas, Santanu Chaudhuri, Jonathan C. Hanson, Xiangyun Qiu, Peter L. Lee, Sarvjit D. Shastri, Simon J. L. Billinge, and Clare P. Grey pp 4756–4757 DOI: 10.1021/ja031553n Supporting Info

Cyclobutadiene Dianions Consisting of Heavier Group 14 Elements:  Synthesis and Characterization Vladimir Ya. Lee, Kazunori Takanashi, Tadahiro Matsuno, Masaaki Ichinohe, and Akira Sekiguchi pp 4758–4759 DOI: 10.1021/ja030662z Supporting Info

C−C Bond Cleavage of Acetonitrile by a Dinuclear Copper(II) Cryptate Tongbu Lu, Xiaomei Zhuang, Yanwu Li, and Shi Chen pp 4760–4761 DOI: 10.1021/ja031874z Supporting Info

5‘-Tethered Stilbene Derivatives as Fidelity- and Affinity-Enhancing Modulators of DNA Duplex Stability Zeynep Dogan, Ralph Paulini, Jan A. Rojas Stütz, Sukunath Narayanan, and Clemens Richert pp 4762–4763 DOI: 10.1021/ja0394434 Supporting Info

Low-Power High-Resolution Solid-State NMR of Peptides and Proteins Matthias Ernst, Marcel A. Meier, Tiit Tuherm, Ago Samoson, and Beat H. Meier pp 4764–4765 DOI: 10.1021/ja0494510 Supporting Info

Single-Molecule Magnets:  A Mn25 Complex with a Record S = 51/2 Spin for a Molecular Species Muralee Murugesu, Malgorzata Habrych, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 4766–4767 DOI: 10.1021/ja0316824 Supporting Info

Flux Growth of Hexagonal Bipyramidal Ruby Crystals Shuji Oishi, Katsuya Teshima, and Hitoshi Kondo pp 4768–4769 DOI: 10.1021/ja049678v

Enzymatic Nanolithography of a Self-Assembled Oligonucleotide Monolayer on Gold Jinho Hyun, Jeonghan Kim, Stephen L. Craig, and Ashutosh Chilkoti pp 4770–4771 DOI: 10.1021/ja049956q

Superoxide Reactivity of KatG:  Insights into Isoniazid Resistance Pathways in TB Reza A. Ghiladi, Diane E. Cabelli, and Paul R. Ortiz de Montellano pp 4772–4773 DOI: 10.1021/ja031728t Supporting Info

Inhibition of the Proteolytic Activity of Anthrax Lethal Factor by Aminoglycosides Lac V. Lee, Kristen E. Bower, Fu-Sen Liang, Jin Shi, Douglass Wu, Steven J. Sucheck, Peter K. Vogt, and Chi-Huey Wong pp 4774–4775 DOI: 10.1021/ja0495359 Supporting Info

Molecular Sieving MFI-Type Zeolite Membranes for Pervaporation Separation of Xylene Isomers Wenhui Yuan, Y. S. Lin, and Weishen Yang pp 4776–4777 DOI: 10.1021/ja031653t

Tunneling and Coupled Motion in the Escherichia coli Dihydrofolate Reductase Catalysis R. Steven Sikorski, Lin Wang, Kelli A. Markham, P. T. Ravi Rajagopalan, Stephen J. Benkovic, and Amnon Kohen pp 4778–4779 DOI: 10.1021/ja031683w Supporting Info

Reactions of Nitric Oxide with a Low-Spin Fe(III) Center Ligated to a Tetradentate Dicarboxamide N4 Ligand:  Parallels between Heme and Non-heme Systems Apurba K. Patra, Michael J. Rose, Marilyn M. Olmstead, and Pradip K. Mascharak pp 4780–4781 DOI: 10.1021/ja040015n Supporting Info

Efficient Degradation of Toxic Organic Pollutants with Ni2O3/TiO2-xBx under Visible Irradiation Wei Zhao, Wanhong Ma, Chuncheng Chen, Jincai Zhao, and Zhigang Shuai pp 4782–4783 DOI: 10.1021/ja0396753 Supporting Info

[(iPr3P)6Rh6H12]2+:  A High-Hydride Content Octahedron that Bridges the Gap between Late and Early Transition Metal Clusters Michael J. Ingleson, Mary F. Mahon, Paul R. Raithby, and Andrew S. Weller pp 4784–4785 DOI: 10.1021/ja049402n Supporting Info

Determination of Protein−Ligand Association Thermochemistry Using Variable-Temperature Nanoelectrospray Mass Spectrometry Rambod Daneshfar, Elena N. Kitova, and John S. Klassen pp 4786–4787 DOI: 10.1021/ja0316972 Supporting Info

Characterization of the pH-Dependent Resonance Raman Transitions of Archaeal and Bacterial Rieske [2Fe−2S] Proteins Toshio Iwasaki, Asako Kounosu, Derrick R. J. Kolling, Antony R. Crofts, Sergei A. Dikanov, Akihisa Jin, Takeo Imai, and Akio Urushiyama pp 4788–4789 DOI: 10.1021/ja031976p Supporting Info

Direct Organocatalytic Asymmetric α-Chlorination of Aldehydes Nis Halland, Alan Braunton, Stephan Bachmann, Mauro Marigo, and Karl Anker Jørgensen pp 4790–4791 DOI: 10.1021/ja049231m Supporting Info

Facile Oxidative Addition of N−C and N−H Bonds to Monovalent Rhodium and Iridium Oleg V. Ozerov, Chengyun Guo, Vyacheslav A. Papkov, and Bruce M. Foxman pp 4792–4793 DOI: 10.1021/ja049659l Supporting Info

Symbioimine Exhibiting Inhibitory Effect of Osteoclast Differentiation, from the Symbiotic Marine Dinoflagellate Symbiodinium sp. Masaki Kita, Mikiko Kondo, Tomoyuki Koyama, Kaoru Yamada, Tsuyosi Matsumoto, Kun-Hyung Lee, Je-Tae Woo, and Daisuke Uemura pp 4794–4795 DOI: 10.1021/ja049277f Supporting Info

Fabrication of Superhydrophobic Surface from a Supramolecular Organosilane with Quadruple Hydrogen Bonding Joong Tark Han, Dae Ho Lee, Chang Yeol Ryu, and Kilwon Cho pp 4796–4797 DOI: 10.1021/ja0499400 Supporting Info

[Me2NN]Co(η6-toluene):  OO, NN, and ON Bond Cleavage Provides β-Diketiminato Cobalt μ-Oxo and Imido Complexes Xuliang Dai, Pooja Kapoor, and Timothy H. Warren pp 4798–4799 DOI: 10.1021/ja036308i Supporting Info

Enantioselective and Structure-Selective Diels−Alder Reactions of Unsymmetrical Quinones Catalyzed by a Chiral Oxazaborolidinium Cation. Predictive Selection Rules Do Hyun Ryu, Gang Zhou, and E. J. Corey pp 4800–4802 DOI: 10.1021/ja049323b Supporting Info

Photonic Switching of Photoinduced Electron Transfer in a Dihydropyrene−Porphyrin−Fullerene Molecular Triad Paul A. Liddell, Gerdenis Kodis, Joakim Andréasson, Linda de la Garza, Subhajit Bandyopadhyay, Reginald H. Mitchell, Thomas A. Moore, Ana L. Moore, and Devens Gust pp 4803–4811 DOI: 10.1021/ja039800a

Carbohydrate Chips for Studying High-Throughput Carbohydrate−Protein Interactions Sungjin Park, Myung-ryul Lee, Soon-Jin Pyo, and Injae Shin pp 4812–4819 DOI: 10.1021/ja0391661 Supporting Info

Pyrene-Labeled Base-Discriminating Fluorescent DNA Probes for Homogeneous SNP Typing Akimitsu Okamoto, Keiichiro Kanatani, and Isao Saito pp 4820–4827 DOI: 10.1021/ja039625y

α-Turn Mimetics:  Short Peptide α-Helices Composed of Cyclic Metallopentapeptide Modules Michael J. Kelso, Renée L. Beyer, Huy N. Hoang, Ami S. Lakdawala, James P. Snyder, Warren V. Oliver, Tom A. Robertson, Trevor G. Appleton, and David P. Fairlie pp 4828–4842 DOI: 10.1021/ja037980i Supporting Info

[CpRu((R)-Binop-F)(H2O)][SbF6], a New Fluxional Chiral Lewis Acid Catalyst:  Synthesis, Dynamic NMR, Asymmetric Catalysis, and Theoretical Studies Valérie Alezra, Gérald Bernardinelli, Clémence Corminboeuf, Urban Frey, E. Peter Kündig, André E. Merbach, Christophe M. Saudan, Florian Viton, and Jacques Weber pp 4843–4853 DOI: 10.1021/ja0374123 Supporting Info

Nano-Architectural Silica Thin Films with Two-Dimensionally Connected Cagelike Pores Synthesized from Vapor Phase Shunsuke Tanaka, Norikazu Nishiyama, Yoshiaki Oku, Yasuyuki Egashira, and Korekazu Ueyama pp 4854–4858 DOI: 10.1021/ja039267z Supporting Info

Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes Hans-Joachim Gais, Leleti R. Reddy, Gadamsetti S. Babu, and Gerhard Raabe pp 4859–4864 DOI: 10.1021/ja030501v Supporting Info

Fluoride-Promoted Cross-Coupling Reactions of Alkenylsilanols. Elucidation of the Mechanism through Spectroscopic and Kinetic Analysis Scott E. Denmark, Ramzi F. Sweis, and Daniel Wehrli pp 4865–4875 DOI: 10.1021/ja037234d Supporting Info

Cross-Coupling Reactions of Alkenylsilanolates. Investigation of the Mechanism and Identification of Key Intermediates through Kinetic Analysis Scott E. Denmark and Ramzi F. Sweis pp 4876–4882 DOI: 10.1021/ja0372356 Supporting Info

Characterization of Ce@C82 and Its Anion Takatsugu Wakahara, Jun-ichi Kobayashi, Michio Yamada, Yutaka Maeda, Takahiro Tsuchiya, Mutsuo Okamura, Takeshi Akasaka, Markus Waelchli, Kaoru Kobayashi, Shigeru Nagase, Tatsuhisa Kato, Masahiro Kako, Kazunori Yamamoto, and Karl M. Kadish pp 4883–4887 DOI: 10.1021/ja039865d Supporting Info

Engineering of Highly Luminescent Lanthanide Tags Suitable for Protein Labeling and Time-Resolved Luminescence Imaging Nicolas Weibel, Loïc J. Charbonnière, Massimo Guardigli, Aldo Roda, and Raymond Ziessel pp 4888–4896 DOI: 10.1021/ja031886k

ansa-Zirconocene Ester Enolates:  Synthesis, Structure, Reaction with Organo-Lewis Acids, and Application to Polymerization of Methacrylates Andrew D. Bolig and Eugene Y.-X. Chen pp 4897–4906 DOI: 10.1021/ja031558k Supporting Info

Anisotropic Small Amplitude Peptide Plane Dynamics in Proteins from Residual Dipolar Couplings Pau Bernadó and Martin Blackledge pp 4907–4920 DOI: 10.1021/ja036977w Supporting Info

Line Narrowing in Methyl-TROSY Using Zero-Quantum 1H-13C NMR Spectroscopy Vitali Tugarinov, Remco Sprangers, and Lewis E. Kay pp 4921–4925 DOI: 10.1021/ja039732s Supporting Info

The Complete 51V MAS NMR Spectrum of Surface Vanadia Nanoparticles on Anatase (TiO2):  Vanadia Surface Structure of a DeNOx Catalyst Ulla Gro Nielsen, Nan-Yu Topsøe, Michael Brorson, Jørgen Skibsted, and Hans J. Jakobsen pp 4926–4933 DOI: 10.1021/ja030091a

Electrocatalytic Reductions of Nitrite, Nitric Oxide, and Nitrous Oxide by Thermophilic Cytochrome P450 CYP119 in Film-Modified Electrodes and an Analytical Comparison of Its Catalytic Activities with Myoglobin Chad E. Immoos, Ju Chou, Mekki Bayachou, Emek Blair, John Greaves, and Patrick J. Farmer pp 4934–4942 DOI: 10.1021/ja038925c Supporting Info

Catalysis with TiO2/Gold Nanocomposites. Effect of Metal Particle Size on the Fermi Level Equilibration Vaidyanathan Subramanian, Eduardo E. Wolf, and Prashant V. Kamat pp 4943–4950 DOI: 10.1021/ja0315199 Supporting Info

Carbon Nanotube Synthesis in Supercritical Toluene Doh C. Lee, Frederic V. Mikulec, and Brian A. Korgel pp 4951–4957 DOI: 10.1021/ja031522s Supporting Info

Light-Emitting Tridentate Cyclometalated Platinum(II) Complexes Containing σ-Alkynyl Auxiliaries:  Tuning of Photo- and Electrophosphorescence Wei Lu, Bao-Xiu Mi, Michael C. W. Chan, Zheng Hui, Chi-Ming Che, Nianyong Zhu, and Shuit-Tong Lee pp 4958–4971 DOI: 10.1021/ja0317776 Supporting Info

Dirhodium Tetracarboxylate Scaffolds as Reversible Fluorescence-Based Nitric Oxide Sensors Scott A. Hilderbrand, Mi Hee Lim, and Stephen J. Lippard pp 4972–4978 DOI: 10.1021/ja038471j Supporting Info

Solid-State NMR Yields Structural Constraints on the V3 Loop from HIV-1 Gp120 Bound to the 447-52D Antibody Fv Fragment Simon Sharpe, Naama Kessler, Jacob A. Anglister, Wai-Ming Yau, and Robert Tycko pp 4979–4990 DOI: 10.1021/ja0392162

Oxygen Activation by the Noncoupled Binuclear Copper Site in Peptidylglycine α-Hydroxylating Monooxygenase. Reaction Mechanism and Role of the Noncoupled Nature of the Active Site Peng Chen and Edward I. Solomon pp 4991–5000 DOI: 10.1021/ja031564g Supporting Info

Ellipsometric Approach for the Real-Time Detection of Label-Free Protein Adsorption by Second Harmonic Generation Mark A. Polizzi, Ryan M. Plocinik, and Garth J. Simpson pp 5001–5007 DOI: 10.1021/ja031627v Supporting Info

Complete Relative Stereochemistry of Multiple Stereocenters Using Only Residual Dipolar Couplings Jiangli Yan, Frank Delaglio, Andreas Kaerner, Allen D. Kline, Huaping Mo, Michael J. Shapiro, Tim A. Smitka, Gregory A. Stephenson, and Edward R. Zartler pp 5008–5017 DOI: 10.1021/ja037605q Supporting Info

Jaguar 5.5 Schrödinger, Inc., 1500 SW First Avenue, Suite 1180, Portland, OR 97201. www.schrodinger.com. See Web site for pricing information. Steven M. Bachrach p 5018 DOI: 10.1021/ja033634p

Issue 16

A Combinatorial Selective Labeling Method for the Assignment of Backbone Amide NMR Resonances Martin J. Parker, Marc Aulton-Jones, Andrea M. Hounslow, and C. Jeremy Craven pp 5020–5021 DOI: 10.1021/ja039601r

The Degree of Charge Transfer in Ground and Charge-Separated States Revealed by Ultrafast Visible Pump/Mid-IR Probe Spectroscopy Igor V. Rubtsov, Youn K. Kang, Naomi P. Redmore, Rebecca M. Allen, Jieru Zheng, David N. Beratan, and Michael J. Therien pp 5022–5023 DOI: 10.1021/ja030674k

Manganese(II) Octacyanotungstate(V)-Based Magnet Containing a Noncoordinated Aromatic Molecule Toshinori Kashiwagi, Shin-ichi Ohkoshi, Hidetake Seino, Yasushi Mizobe, and Kazuhito Hashimoto pp 5024–5025 DOI: 10.1021/ja030648m Supporting Info

Designed Synthesis of Atom-Economical Pd/Ni Bimetallic Nanoparticle-Based Catalysts for Sonogashira Coupling Reactions Seung Uk Son, Youngjin Jang, Jongnam Park, Hyon Bin Na, Hyun Min Park, Hyung Joong Yun, Jouhahn Lee, and Taeghwan Hyeon pp 5026–5027 DOI: 10.1021/ja039757r Supporting Info

Structure Elucidation of (+)-Amphidinolide A by Total Synthesis and NMR Chemical Shift Analysis Barry M. Trost and Paul E. Harrington pp 5028–5029 DOI: 10.1021/ja049292k Supporting Info

Metal−Organic Anion Receptors:  Arranging Urea Hydrogen-Bond Donors to Encapsulate Sulfate Ions Chantelle R. Bondy, Philip A. Gale, and Stephen J. Loeb pp 5030–5031 DOI: 10.1021/ja039712q Supporting Info

Active-Site Modifications of Adenylation Domains Lead to Hydrolysis of Upstream Nonribosomal Peptidyl Thioester Intermediates Gabriel C. Uguru, Claire Milne, Matthew Borg, Fiona Flett, Colin P. Smith, and Jason Micklefield pp 5032–5033 DOI: 10.1021/ja048778y Supporting Info

Positive Homotropic Allosteric Binding of Benzenediols in a Hydrindacene-Based Exoditopic Receptor:  Cooperativity in Amide Hydrogen Bonding Hidetoshi Kawai, Ryo Katoono, Kouki Nishimura, Shunsuke Matsuda, Kenshu Fujiwara, Takashi Tsuji, and Takanori Suzuki pp 5034–5035 DOI: 10.1021/ja049336p Supporting Info

Aqueous−Organic Phase Transfer of Gold Nanoparticles and Gold Nanorods Using an Ionic Liquid Guor-Tzo Wei, Zusing Yang, Chia-Ying Lee, Hsiao-Yen Yang, and C. R. Chris Wang pp 5036–5037 DOI: 10.1021/ja039874m Supporting Info

Lipopolysaccharide Identification with Functionalized Polydiacetylene Liposome Sensors Marianne Rangin and Amit Basu pp 5038–5039 DOI: 10.1021/ja039822x Supporting Info

Direct Electrochemistry of Immobilized Human Cytochrome P450 2E1 Andrea Fantuzzi, Michael Fairhead, and Gianfranco Gilardi pp 5040–5041 DOI: 10.1021/ja049855s

Quantum Calculations of Vibrational Energies of H3O2- on an ab Initio Potential Xinchuan Huang, Bastiaan J. Braams, Stuart Carter, and Joel M. Bowman pp 5042–5043 DOI: 10.1021/ja049801i Supporting Info

Reduction of an Aldehyde by a NADH/Zn2+-Dependent Redox Active Ribozyme Shinya Tsukiji, Swetansu B. Pattnaik, and Hiroaki Suga pp 5044–5045 DOI: 10.1021/ja0495213 Supporting Info

Structure and Reactivity of “Unusual” N-Heterocyclic Carbene (NHC) Palladium Complexes Synthesized from Imidazolium Salts Hélène Lebel, Marc K. Janes, André B. Charette, and Steven P. Nolan pp 5046–5047 DOI: 10.1021/ja049759r Supporting Info

NMR Assignments for a Helical 40 kDa Membrane Protein Kirill Oxenoid, Hak Jun Kim, Jaison Jacob, Frank D. Sönnichsen, and Charles R. Sanders pp 5048–5049 DOI: 10.1021/ja049916m Supporting Info

A Conformationally Constrained Nucleotide Analogue Controls the Folding Topology of a DNA G-Quadruplex Pamela K. Dominick and Michael B. Jarstfer pp 5050–5051 DOI: 10.1021/ja039192z Supporting Info

Probing the Geometry and Interconnectivity of Pores in Organic Aerogels Using Hyperpolarized 129Xe NMR Spectroscopy I. L. Moudrakovski, L.-Q. Wang, T. Baumann, J. H. Satcher, Jr., G. J. Exarhos, C. I. Ratcliffe, and J. A. Ripmeester pp 5052–5053 DOI: 10.1021/ja049577x Supporting Info

Double C−H Activation in a Rh−NHC Complex Leading to the Isolation of a 14-Electron Rh(III) Complex Reto Dorta, Edwin D. Stevens, and Steven P. Nolan pp 5054–5055 DOI: 10.1021/ja049545+ Supporting Info

Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone Richard D. Adams and Shaobin Miao pp 5056–5057 DOI: 10.1021/ja049170s Supporting Info

1,3-Disila-2-gallata- and -indataallenic Anions [>SiMSi<]-·Li+ (M = Ga, In):  Compounds Featuring Double Bonds between Elements of Groups 13 and 14 Norio Nakata, Rika Izumi, Vladimir Ya. Lee, Masaaki Ichinohe, and Akira Sekiguchi pp 5058–5059 DOI: 10.1021/ja040001h Supporting Info

Phosphasilaferracyclopropane:  An Activator of Small Molecules Having Polarized Single, Double, and Aromatic Unsaturated Bonds Masaaki Okazaki, Kyeong A Jung, Kazuyuki Satoh, Hiroshi Okada, Junpei Naito, Tadahiro Akagi, Hiromi Tobita, and Hiroshi Ogino pp 5060–5061 DOI: 10.1021/ja039704+ Supporting Info

Reactivity of Ar‘GeGeAr‘ (Ar‘ = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) toward Alkynes:  Isolation of a Stable Digermacyclobutadiene Chunming Cui, Marilyn M. Olmstead, and Philip P. Power pp 5062–5063 DOI: 10.1021/ja0318481 Supporting Info

Synthesis of Monofunctionalized Gold Nanoparticles by Fmoc Solid-Phase Reactions Kie-Moon Sung, David W. Mosley, Beau R. Peelle, Shuguang Zhang, and Joseph M. Jacobson pp 5064–5065 DOI: 10.1021/ja049578p Supporting Info

Formation of Inclusion Organoactinide Complexes with Boron-Containing Macrocycles Eyal Barnea, Tamer Andrea, Moshe Kapon, and Moris S. Eisen pp 5066–5067 DOI: 10.1021/ja0498843 Supporting Info

Total Synthesis of (±)-Perophoramidine James R. Fuchs and Raymond L. Funk pp 5068–5069 DOI: 10.1021/ja049569g Supporting Info

Large-Scale Synthesis of Perpendicularly Aligned Helical Carbon Nanotubes Vardhan Bajpai, Liming Dai, and Toshiyuki Ohashi pp 5070–5071 DOI: 10.1021/ja031738u

Oxygen Economy of Cytochrome P450:  What Is the Origin of the Mixed Functionality as a Dehydrogenase−Oxidase Enzyme Compared with Its Normal Function? Devesh Kumar, Samuël P. de Visser, and Sason Shaik pp 5072–5073 DOI: 10.1021/ja0318737 Supporting Info

Palladium-Catalyzed C−H Homocoupling of Thiophenes:  Facile Construction of Bithiophene Structure Kentaro Masui, Haruka Ikegami, and Atsunori Mori pp 5074–5075 DOI: 10.1021/ja031855p Supporting Info

Vibrational Raman Optical Activity Characterization of Poly(l-proline) II Helix in Alanine Oligopeptides Iain H. McColl, Ewan W. Blanch, Lutz Hecht, Neville R. Kallenbach, and Laurence D. Barron pp 5076–5077 DOI: 10.1021/ja049271q

A New Method for Determining the Local Environment and Orientation of Individual Side Chains of Membrane-Binding Peptides Matthew J. Tucker, Zelleka Getahun, Vikas Nanda, William F. DeGrado, and Feng Gai pp 5078–5079 DOI: 10.1021/ja032015d Supporting Info

Efficient and Selective Nickel-Catalyzed Addition of H−P(O) and H−S Bonds to Alkynes Li-Biao Han, Chen Zhang, Hideaki Yazawa, and Shigeru Shimada pp 5080–5081 DOI: 10.1021/ja0494297 Supporting Info

CO2 Fixation by Copper(II) Complexes of a Terpyridinophane Aza Receptor Enrique García-España, Pablo Gaviña, Julio Latorre, Conxa Soriano, and Begoña Verdejo pp 5082–5083 DOI: 10.1021/ja039577h Supporting Info

2,6-Diphenylbenzo[1,2-b:4,5-b‘]dichalcogenophenes:  A New Class of High-Performance Semiconductors for Organic Field-Effect Transistors Kazuo Takimiya, Yoshihito Kunugi, Yasushi Konda, Naoto Niihara, and Tetsuo Otsubo pp 5084–5085 DOI: 10.1021/ja0496930 Supporting Info

Unusual Selectivity of Unprotected Aziridines in Palladium-Catalyzed Allylic Amination Enables Facile Preparation of Branched Aziridines Iain D. G. Watson, Sarah A. Styler, and Andrei K. Yudin pp 5086–5087 DOI: 10.1021/ja049242f Supporting Info

Enantioselective Total Synthesis of Semperoside A Paolo Piccinini, Giovanni Vidari, and Giuseppe Zanoni pp 5088–5089 DOI: 10.1021/ja0493796 Supporting Info

Translation of DNA into Synthetic N-Acyloxazolidines Xiaoyu Li, Zev J. Gartner, Brian N. Tse, and David R. Liu pp 5090–5092 DOI: 10.1021/ja049666+ Supporting Info

Investigation of the NMR Spin−Spin Coupling Constants across the Hydrogen Bonds in Ubiquitin:  The Nature of the Hydrogen Bond as Reflected by the Coupling Mechanism Tell Tuttle, Elfi Kraka, Anan Wu, and Dieter Cremer pp 5093–5107 DOI: 10.1021/ja030246e

Pluronic Microemulsions as Nanoreservoirs for Extraction of Bupivacaine from Normal Saline Manoj Varshney, Timothy E. Morey, Dinesh O. Shah, Jason A. Flint, Brij M. Moudgil, Christoph N. Seubert, and Donn M. Dennis pp 5108–5112 DOI: 10.1021/ja0394479 Supporting Info

Sequence-Specific Gene Silencing in Mammalian Cells by Alkylating Pyrrole−Imidazole Polyamides Ken-ichi Shinohara, Akihiko Narita, Takanori Oyoshi, Toshikazu Bando, Hirobumi Teraoka, and Hiroshi Sugiyama pp 5113–5118 DOI: 10.1021/ja031673v Supporting Info

Photoelectron Spectroscopy of the Doubly-Charged Anions [MIVO(mnt)2]2- (M = Mo, W; mnt = S2C2(CN)22-):  Access to the Ground and Excited States of the [MVO(mnt)2]- Anion Tom Waters, Xue-Bin Wang, Xin Yang, Lianyi Zhang, Richard A. J. O'Hair, Lai-Sheng Wang, and Anthony G. Wedd pp 5119–5129 DOI: 10.1021/ja039652o Supporting Info

Informational Complexity and Functional Activity of RNA Structures James M. Carothers, Stephanie C. Oestreich, Jonathan H. Davis, and Jack W. Szostak pp 5130–5137 DOI: 10.1021/ja031504a Supporting Info

Structural, Spectroscopic, and Computational Study of an Octahedral, Non-Heme {Fe−NO}6-8 Series:  [Fe(NO)(cyclam-ac)]2+/+/0 Ricardo García Serres, Craig A. Grapperhaus, Eberhard Bothe, Eckhard Bill, Thomas Weyhermüller, Frank Neese, and Karl Wieghardt pp 5138–5153 DOI: 10.1021/ja030645+ Supporting Info

Design, Synthesis, and Characterization of a Series of Cytochrome P450 3A-Activated Prodrugs (HepDirect Prodrugs) Useful for Targeting Phosph(on)ate-Based Drugs to the Liver§ Mark D. Erion, K. Raja Reddy, Serge H. Boyer, Michael C. Matelich, Jorge Gomez-Galeno, Robert H. Lemus, Bheemarao G. Ugarkar, Timothy J. Colby, Jürgen Schanzer, and Paul D. van Poelje pp 5154–5163 DOI: 10.1021/ja031818y Supporting Info

A Comparison of the Electrophilic Reactivities of Zn2+ and Acetic Acid as Catalysts of Enolization:  Imperatives for Enzymatic Catalysis of Proton Transfer at Carbon Juan Crugeiras and John P. Richard pp 5164–5173 DOI: 10.1021/ja049489c

Solvent Nucleophilicity Shinya Minegishi, Shinjiro Kobayashi, and Herbert Mayr pp 5174–5181 DOI: 10.1021/ja031828z Supporting Info

Palladium-Catalyzed Arylation of Trimethylsilyl Enolates of Esters and Imides. High Functional Group Tolerance and Stereoselective Synthesis of α-Aryl Carboxylic Acid Derivatives Xiaoxiang Liu and John F. Hartwig pp 5182–5191 DOI: 10.1021/ja031544e Supporting Info

o-Iodoxybenzoic Acid (IBX) as a Viable Reagent in the Manipulation of Nitrogen- and Sulfur-Containing Substrates:  Scope, Generality, and Mechanism of IBX-Mediated Amine Oxidations and Dithiane Deprotections K. C. Nicolaou, Casey J. N. Mathison, and Tamsyn Montagnon pp 5192–5201 DOI: 10.1021/ja0400382 Supporting Info

NMR Studies of Structure and Reorganization Dynamics of an [6Li]-Allylic Lithium Compound Complexed to [14N,15N]-N,N,N‘,N‘-Tetramethylethylenediamine:  Inversion and Ligand Lithium Exchange Gideon Fraenkel and Hua Liu pp 5202–5206 DOI: 10.1021/ja030285q Supporting Info

DNA-Templated Ag Nanocluster Formation Jeffrey T. Petty, Jie Zheng, Nicholas V. Hud, and Robert M. Dickson pp 5207–5212 DOI: 10.1021/ja031931o

Nitrophenolate as a Building Block for Lanthanide Chains, Layers, and Clusters Markus R. Bürgstein, Michael T. Gamer, and Peter W. Roesky pp 5213–5218 DOI: 10.1021/ja0396044 Supporting Info

Fluoride Complexation of Element 104, Rutherfordium Hiromitsu Haba, Kazuaki Tsukada, Masato Asai, Atsushi Toyoshima, Kazuhiko Akiyama, Ichiro Nishinaka, Masaru Hirata, Tsuyoshi Yaita, Shin-ichi Ichikawa, Yuichiro Nagame, Ken-ichiro Yasuda, Yutaka Miyamoto, Tetsuya Kaneko, Shin-ichi Goto, Sawako Ono, Toshiyuki Hirai, Hisaaki Kudo, Mitsuru Shigekawa, Atsushi Shinohara, Yasuji Oura, Hiromichi Nakahara, Keisuke Sueki, Hidetoshi Kikunaga, Norikazu Kinoshita, Naoya Tsuruga, Akihiko Yokoyama, Minoru Sakama, Shuich Enomoto, Matthias Schädel, Willy Brüchle, and Jens V. Kratz pp 5219–5224 DOI: 10.1021/ja031824u

Molecular Control of Recombination Dynamics in Dye-Sensitized Nanocrystalline TiO2 Films:  Free Energy vs Distance Dependence John N. Clifford, Emilio Palomares, Md. K. Nazeeruddin, M. Grätzel, Jenny Nelson, X. Li, Nicholas J. Long, and James R. Durrant pp 5225–5233 DOI: 10.1021/ja039924n Supporting Info

Molecular Interactions in One-Dimensional Organic Nanostructures Thuc-Quyen Nguyen, Richard Martel, Phaedon Avouris, Mark L. Bushey, Louis Brus, and Colin Nuckolls pp 5234–5242 DOI: 10.1021/ja031600b Supporting Info

Quantitative Evaluation of the Catalytic Activity of Dendrimers with Only One Active Center at the Core:  Application to the Nitroaldol (Henry) Reaction Aizpea Zubia, Fernando P. Cossío, Iñaki Morao, Marina Rieumont, and Xabier Lopez pp 5243–5252 DOI: 10.1021/ja039888s Supporting Info

Bimetallic Cluster Complexes:  The Synthesis, Structures, and Bonding of Ruthenium Carbonyl Cluster Complexes Containing Palladium and Platinum with the Bulky Tri-tert-butyl-phosphine Ligand Richard D. Adams, Burjor Captain, Wei Fu, Michael B. Hall, Josiah Manson, Mark D. Smith, and Charles Edwin Webster pp 5253–5267 DOI: 10.1021/ja039541p Supporting Info

A Comparison of C−F and C−H Bond Activation by Zerovalent Ni and Pt:  A Density Functional Study Meike Reinhold, John E. McGrady, and Robin N. Perutz pp 5268–5276 DOI: 10.1021/ja0396908 Supporting Info

Unusual Electronic and Bonding Properties of the Zintl Phase Ca5Ge3 and Related Compounds. A Theoretical Analysis1 Anja-Verena Mudring and John D. Corbett pp 5277–5281 DOI: 10.1021/ja030216b Supporting Info

Solvent Dependence of Intramolecular Electron Transfer in a Helical Oligoproline Assembly Durwin R. Striplin, Steven Y. Reece, Dewey G. McCafferty, Craig G. Wall, Duane A. Friesen, Bruce W. Erickson, and Thomas J. Meyer pp 5282–5291 DOI: 10.1021/ja0304289

Charge-Driven Flocculation of Poly(l-lysine)Gold Nanoparticle Assemblies Leading to Hollow Microspheres Vinit S. Murthy, Jennifer N. Cha, Galen D. Stucky, and Michael S. Wong pp 5292–5299 DOI: 10.1021/ja038953v Supporting Info

Why Is CO2 So Soluble in Imidazolium-Based Ionic Liquids? Cesar Cadena, Jennifer L. Anthony, Jindal K. Shah, Timothy I. Morrow, Joan F. Brennecke, and Edward J. Maginn pp 5300–5308 DOI: 10.1021/ja039615x Supporting Info

Nature of Nonbonded Se···O Interactions Characterized by 17O NMR Spectroscopy and NBO and AIM Analyses Michio Iwaoka, Hiroto Komatsu, Takayuki Katsuda, and Shuji Tomoda pp 5309–5317 DOI: 10.1021/ja049690n

Scanning Tunneling Microscopy of Prochiral Anthracene Derivatives on Graphite:  Chain Length Effects on Monolayer Morphology Yanhu Wei, Kavita Kannappan, George W. Flynn, and Matthew B. Zimmt pp 5318–5322 DOI: 10.1021/ja038658a Supporting Info

Assignment of the Backbone Resonances for Microcrystalline Ubiquitin Tatyana I. Igumenova, A. Joshua Wand, and Ann E. McDermott pp 5323–5331 DOI: 10.1021/ja030546w

Zwitterionic Ring-Borylated ansa-Chromocene Complexes   [J. Am. Chem. Soc. 2002, 124, 10996−10997]. Piet-Jan Sinnema, Pamela J. Shapiro, David Min Jin Foo, and Brendan Twamley p 5332 DOI: 10.1021/ja0408045

The Practice of Medicinal Chemistry, Second Edition Edited by Camille George Wermuth (Université Louis Pasteur, Illkirch, France). Academic Press (an imprint of Elsevier):  Amsterdam. 2003. xvi + 768 pp. $174.95. ISBN 0-12-744481-5. Christian P. Whitman p 5333 DOI: 10.1021/ja033648v

Handbook of Elemental Speciation:  Techniques and Methodology Edited by Rita Cornelis (Ghent University), Editor-in-Chief, and by Associate Editors Joe Caruso (University of Cincinnati), Helen Crews (Central Science Laboratory, UK), and Klaus Heumann (Johannes Gutenberg-University, Mainz). John Wiley & Sons, Ltd.:  Chichester. 2003. xii + 658 pp. $260.00. ISBN 0-471-49214-0. p 5333 DOI: 10.1021/ja033661f

Modern Phosphonate Chemistry By Philippe Savignac (Ecole Polytechnique, Palaiseau, France) and Bogdan Iorga (Institut de Chimie des Substances Naturelles, Gif sur Yvette, France). CRC Press LLC:  Boca Raton, FL. 2003. xxii + 530 pp. $199.95. ISBN 0-8493-1099-7. David F. Wiemer pp 5333–5334 DOI: 10.1021/ja033620j

Issue 17

Synthesis of a Silene from 1,1-Dilithiosilole and 2-Adamantanone Irina S. Toulokhonova, Ilia A. Guzei, and Robert West pp 5336–5337 DOI: 10.1021/ja0318176 Supporting Info

Antisymmetric Exchange in [2Fe−2S]1+ Clusters:  EPR of the Rieske Protein from Thermus thermophilus at pH 14 Filipe Tiago de Oliveira, Emile L. Bominaar, Judy Hirst, James A. Fee, and Eckard Münck pp 5338–5339 DOI: 10.1021/ja031746a Supporting Info

Exceptionally Small Attenuation Factors in Molecular Wires Francesco Giacalone, José L. Segura, Nazario Martín, and Dirk M. Guldi pp 5340–5341 DOI: 10.1021/ja0318333 Supporting Info

The Structure of a Biosynthetic Intermediate of Pyrroloquinoline Quinone (PQQ) and Elucidation of the Final Step of PQQ Biosynthesis Olafur T. Magnusson, Hirohide Toyama, Megumi Saeki, Robert Schwarzenbacher, and Judith P. Klinman pp 5342–5343 DOI: 10.1021/ja0493852 Supporting Info

Synthesis, Structure, and Reductive Elimination Chemistry of Three-Coordinate Arylpalladium Amido Complexes Makoto Yamashita and John F. Hartwig pp 5344–5345 DOI: 10.1021/ja0315107 Supporting Info

Selectivity Control of Carbonylation of Methanol to Dimethyl Oxalate and Dimethyl Carbonate over Gold Anode by Electrochemical Potential Akiyasu Funakawa, Ichiro Yamanaka, Sakae Takenaka, and Kiyoshi Otsuka pp 5346–5347 DOI: 10.1021/ja0395700

Simplification of Protein NOESY Spectra Using Bioorganic Precursor Synthesis and NMR Spectral Editing Roman Lichtenecker, Martin L. Ludwiczek, Walther Schmid, and Robert Konrat pp 5348–5349 DOI: 10.1021/ja049679n Supporting Info

Phosphine Catalyzed α-Arylation of Enones and Enals Using Hypervalent Bismuth Reagents:  Regiospecific Enolate Arylation via Nucleophilic Catalysis Phillip K. Koech and Michael J. Krische pp 5350–5351 DOI: 10.1021/ja048987i Supporting Info

Cinchona Alkaloid-Lewis Acid Catalyst Systems for Enantioselective Ketene−Aldehyde Cycloadditions Cheng Zhu, Xiaoqiang Shen, and Scott G. Nelson pp 5352–5353 DOI: 10.1021/ja0492900 Supporting Info

Homogeneous Two-Component Polycondensation without Strict Stoichiometric Balance via the Tsuji−Trost Reaction:  Remote Control of Two Reaction Sites by Catalysis Nobuyoshi Nomura, Ko Tsurugi, T. V. RajanBabu, and Tadao Kondo pp 5354–5355 DOI: 10.1021/ja0492743 Supporting Info

Chiral Brønsted Acid-Catalyzed Direct Mannich Reactions via Electrophilic Activation Daisuke Uraguchi and Masahiro Terada pp 5356–5357 DOI: 10.1021/ja0491533 Supporting Info

Chirality Exchange from sp3 Central Chirality to Axial Chirality:  Benzannulation of Optically Active Diaryl-2,2-dichlorocyclopropylmethanols to Axially Chiral α-Arylnaphthalenes Yoshinori Nishii, Kazunori Wakasugi, Keisuke Koga, and Yoo Tanabe pp 5358–5359 DOI: 10.1021/ja0319442 Supporting Info

Enantioselective O- and N-Nitroso Aldol Synthesis of Tin Enolates. Isolation of Three BINAP−Silver Complexes and Their Role in Regio- and Enantioselectivity Norie Momiyama and Hisashi Yamamoto pp 5360–5361 DOI: 10.1021/ja039103i Supporting Info

Experimental Measurement of the Strength of a Cα−H···O Bond in a Lipid Bilayer Eyal Arbely and Isaiah T. Arkin pp 5362–5363 DOI: 10.1021/ja049826h

A Phosphorimidate Rearrangement for the Facile and Selective Preparation of Allylic Amines Bin Chen and Anna K. Mapp pp 5364–5365 DOI: 10.1021/ja0490469 Supporting Info

Chiral Lewis Acid Catalysis in Nitrile Oxide Cycloadditions Mukund P. Sibi, Kennosuke Itoh, and Craig P. Jasperse pp 5366–5367 DOI: 10.1021/ja0318636 Supporting Info

Solvent Polarity Effects and Limited Acid Catalysis in Rearrangements of Model Radicals for the Methylmalonyl-CoA Mutase- and Isobutyryl-CoA Mutase-Catalyzed Isomerization Reactions Pierre Daublain, John H. Horner, Andriy Kuznetsov, and Martin Newcomb pp 5368–5369 DOI: 10.1021/ja049913+ Supporting Info

Conductance Titration of Single-Peptide Molecules Xiaoyin Xiao, Bingqian Xu, and Nongjian Tao pp 5370–5371 DOI: 10.1021/ja049469a Supporting Info

Synthesis and Structure of 2,5,8-Triazido-s-Heptazine:  An Energetic and Luminescent Precursor to Nitrogen-Rich Carbon Nitrides Dale R. Miller, Dale C. Swenson, and Edward G. Gillan pp 5372–5373 DOI: 10.1021/ja048939y Supporting Info

Arginine Deiminase Uses an Active-Site Cysteine in Nucleophilic Catalysis of l-Arginine Hydrolysis Xuefeng Lu, Andrey Galkin, Osnat Herzberg, and Debra Dunaway-Mariano pp 5374–5375 DOI: 10.1021/ja049543p

Electrically Forced Coaxial Nanojets for One-Step Hollow Nanofiber Design Ignacio G. Loscertales, Antonio Barrero, Manuel Márquez, Rubén Spretz, Raffet Velarde-Ortiz, and Gustavo Larsen pp 5376–5377 DOI: 10.1021/ja049443j Supporting Info

Spectroscopic and Quantum Chemical Characterization of the Electronic Structure and Bonding in a Non-Heme FeIVO Complex Andrea Decker, Jan-Uwe Rohde, Lawrence Que, Jr., and Edward I. Solomon pp 5378–5379 DOI: 10.1021/ja0498033 Supporting Info

Singlet Oxygen Generation via Two-Photon Excited FRET William R. Dichtel, Jason M. Serin, Carine Edder, Jean M. J. Fréchet, Michael Matuszewski, Loon-Seng Tan, Tymish Y. Ohulchanskyy, and Paras N. Prasad pp 5380–5381 DOI: 10.1021/ja031647x Supporting Info

Carbon Monoxide Induced Decomposition of the Active Site [Ni−4Fe−5S] Cluster of CO Dehydrogenase Holger Dobbek, Vitali Svetlitchnyi, Jago Liss, and Ortwin Meyer pp 5382–5387 DOI: 10.1021/ja037776v

Preparation of Protein Gradients through the Controlled Deposition of Protein−Nanoparticle Conjugates onto Functionalized Surfaces Stephan Krämer, Huan Xie, John Gaff, John R. Williamson, Alexander G. Tkachenko, Navid Nouri, David A. Feldheim, and Daniel L. Feldheim pp 5388–5395 DOI: 10.1021/ja031674n Supporting Info

Filipin Orientation Revealed by Linear Dichroism. Implication for a Model of Action Sílvia C. D. N. Lopes, Erik Goormaghtigh, Benedito J. Costa Cabral, and Miguel A. R. B. Castanho pp 5396–5402 DOI: 10.1021/ja031782+ Supporting Info

Ni(II)·Arg-Gly-His−DNA Interactions:  Investigation into the Basis for Minor-Groove Binding and Recognition Ya-Yin Fang, Bruce D. Ray, Craig A. Claussen, Kenny B. Lipkowitz, and Eric C. Long pp 5403–5412 DOI: 10.1021/ja049875u Supporting Info

Strategy for the Study of Paramagnetic Proteins with Slow Electronic Relaxation Rates by NMR Spectroscopy:  Application to Oxidized Human [2Fe-2S] Ferredoxin Timothy E. Machonkin, William M. Westler, and John L. Markley pp 5413–5426 DOI: 10.1021/ja037077i Supporting Info

Structural and Rate Studies of the 1,2-Additions of Lithium Phenylacetylide to Lithiated Quinazolinones:  Influence of Mixed Aggregates on the Reaction Mechanism Timothy F. Briggs, Mark D. Winemiller, David B. Collum, Rodney L. Parsons, Jr., Akin H. Davulcu, Gregory D. Harris, Joseph M. Fortunak, and Pat N. Confalone pp 5427–5435 DOI: 10.1021/ja0305813 Supporting Info

Practical Procedures for the Preparation of N-tert-Butyldimethylsilylhydrazones and Their Use in Modified Wolff−Kishner Reductions and in the Synthesis of Vinyl Halides and gem-Dihalides Michael E. Furrow and Andrew G. Myers pp 5436–5445 DOI: 10.1021/ja049694s Supporting Info

Fluorescein Provides a Resonance Gate for FRET from Conjugated Polymers to DNA Intercalated Dyes Shu Wang, Brent S. Gaylord, and Guillermo C. Bazan pp 5446–5451 DOI: 10.1021/ja035550m

Origin, Nature, and Fate of the Fluorescent State of the Green Fluorescent Protein Chromophore at the CASPT2//CASSCF Resolution María Elena Martin, Fabrizia Negri, and Massimo Olivucci pp 5452–5464 DOI: 10.1021/ja037278m Supporting Info

Solvophobic Acceleration of Diels−Alder Reactions in Supercritical Carbon Dioxide Jin Qian, Michael T. Timko, Andrew J. Allen, Christopher J. Russell, Bozena Winnik, Brian Buckley, Jeffrey I. Steinfeld, and Jefferson W. Tester pp 5465–5474 DOI: 10.1021/ja030620a Supporting Info

Asymmetric Total Synthesis of Dendrobatid Alkaloids:  Preparation of Indolizidine 251F and Its 3-Desmethyl Analogue Using an Intramolecular Schmidt Reaction Strategy Aaron Wrobleski, Kiran Sahasrabudhe, and Jeffrey Aubé pp 5475–5481 DOI: 10.1021/ja0320018 Supporting Info

Diffusion of α-Tocopherol in Membrane Models:  Probing the Kinetics of Vitamin E Antioxidant Action by Fluorescence in Real Time Gabriela Gramlich, Jiayun Zhang, and Werner M. Nau pp 5482–5492 DOI: 10.1021/ja039845b Supporting Info

Biomimetically Inspired Total Synthesis and Structure Activity Relationships of 1-O-Methyllateriflorone. 6π Electrocyclizations in Organic Synthesis K. C. Nicolaou, Pradip K. Sasmal, and Hao Xu pp 5493–5501 DOI: 10.1021/ja040037+ Supporting Info

Using Ligand Bite Angles To Control the Hydricity of Palladium Diphosphine Complexes James W. Raebiger, Alex Miedaner, Calvin J. Curtis, Susie M. Miller, Oren P. Anderson, and Daniel L. DuBois pp 5502–5514 DOI: 10.1021/ja0395240 Supporting Info

Hydrolysis of Uranium(VI) at Variable Temperatures (10−85 °C) PierLuigi Zanonato, Plinio Di Bernardo, Arturo Bismondo, Guokui Liu, Xueyuan Chen, and Linfeng Rao pp 5515–5522 DOI: 10.1021/ja0398666 Supporting Info

Chemoselective Hydrogenation Catalysts:  Pt on Mesostructured CeO2 Nanoparticles Embedded within Ultrathin Layers of SiO2 Binder Patricia Concepción, Avelino Corma, Joaquín Silvestre-Albero, Victor Franco, and Jean Y. Chane-Ching pp 5523–5532 DOI: 10.1021/ja031768x

The Syntheses of Carbocations by Use of the Noble-Gas Oxidant, [XeOTeF5][Sb(OTeF5)6]:  The Syntheses and Characterization of the CX3+ (X = Cl, Br, OTeF5) and CBr(OTeF5)2+ Cations and Theoretical Studies of CX3+ and BX3 (X = F, Cl, Br, I, OTeF5) Hélène P. A. Mercier, Matthew D. Moran, Gary J. Schrobilgen, Christoph Steinberg, and Reijo J. Suontamo pp 5533–5548 DOI: 10.1021/ja030649e Supporting Info

Nonclassical vs Classical Metal···H3C−C Interactions:  Accurate Characterization of a 14-Electron Ruthenium(II) System by Neutron Diffraction, Database Analysis, Solution Dynamics, and DFT Studies Walter Baratta, Carlo Mealli, Eberhardt Herdtweck, Andrea Ienco, Sax A. Mason, and Pierluigi Rigo pp 5549–5562 DOI: 10.1021/ja038986a Supporting Info

Si−E (E = N, O, F) Bonding in a Hexacoordinated Silicon Complex:  New Facts from Experimental and Theoretical Charge Density Studies Nikolaus Kocher, Julian Henn, Boris Gostevskii, Daniel Kost, Inna Kalikhman, Bernd Engels, and Dietmar Stalke pp 5563–5568 DOI: 10.1021/ja038459r Supporting Info

Widely-Applicable Gold Substrate for the Study of Ultrathin Overlayers Meni Wanunu, Alexander Vaskevich, and Israel Rubinstein pp 5569–5576 DOI: 10.1021/ja0396448 Supporting Info

Making a Molecular Wire:  Charge and Spin Transport through para-Phenylene Oligomers Emily A. Weiss, Michael J. Ahrens, Louise E. Sinks, Alexey V. Gusev, Mark A. Ratner, and Michael R. Wasielewski pp 5577–5584 DOI: 10.1021/ja0398215 Supporting Info

Reversal of Enantioselectivity in the Hydroformylation of Styrene with [2S,4S-BDPP]Pt(SnCl3)Cl at High Temperature Arises from a Change in the Enantioselective-Determining Step Charles P. Casey, Susie C. Martins, and Maureen A. Fagan pp 5585–5592 DOI: 10.1021/ja0318479 Supporting Info

Structure Determination of the Intramolecular Charge Transfer State in Crystalline 4-(Diisopropylamino)benzonitrile from Picosecond X-ray Diffraction Simone Techert and Klaas A. Zachariasse pp 5593–5600 DOI: 10.1021/ja0379518 Supporting Info

Exploring the Electronic and Mechanical Properties of Protein Using Conducting Atomic Force Microscopy Jianwei Zhao, Jason J. Davis, Mark S. P. Sansom, and Andrew Hung pp 5601–5609 DOI: 10.1021/ja039392a Supporting Info

Multinuclear NMR Investigations of the Oxygen, Water, and Hydroxyl Environments in Sodium Hexaniobate Todd M. Alam, May Nyman, Brian R. Cherry, Judith M. Segall, and Leslie E. Lybarger pp 5610–5620 DOI: 10.1021/ja0398159 Supporting Info

Characterization of Fluxional Hydrogen-Bonded Complexes of Acetic Acid and Acetate by NMR:  Geometries and Isotope and Solvent Effects Peter M. Tolstoy, Parwin Schah-Mohammedi, Sergei N. Smirnov, Nikolai S. Golubev, Gleb S. Denisov, and Hans-Heinrich Limbach pp 5621–5634 DOI: 10.1021/ja039280j

Electron Self-Exchange Kinetics Determined by MARY Spectroscopy:  Theory and Experiment M. Justinek, G. Grampp, S. Landgraf, P. J. Hore, and N. N. Lukzen pp 5635–5646 DOI: 10.1021/ja0394784 Supporting Info

Defluorination of Perfluoropropene Using Cp*2ZrH2 and Cp*2ZrHF:  A Mechanism Investigation from a Joint Experimental−Theoretical Perspective Eric Clot, Claire Mégret, Bradley M. Kraft, Odile Eisenstein, and William D. Jones pp 5647–5653 DOI: 10.1021/ja0499243 Supporting Info

Slow Diffusion of Macromolecular Assemblies Measured by a New Pulsed Field Gradient NMR Method [J. Am. Chem. Soc. 2003, 125, 2541−2545]. Fabien Ferrage, Manuela Zoonens, Dror E. Warschawski, Jean-Luc Popot, and Geoffrey Bodenhausen p 5654 DOI: 10.1021/ja033464g

Issue 18

Pattern-Based Detection of Different Proteins Using an Array of Fluorescent Protein Surface Receptors Laura Baldini, Andrew J. Wilson, Jason Hong, and Andrew D. Hamilton pp 5656–5657 DOI: 10.1021/ja039562j Supporting Info

Mapping of the Binding Site on Pseudoazurin in the Transient 152 kDa Complex with Nitrite Reductase Antonietta Impagliazzo and Marcellus Ubbink pp 5658–5659 DOI: 10.1021/ja049619h Supporting Info

Enhanced Production of Functional Proteins from Defective Genes Biao Xi, Fangxia Guan, and David S. Lawrence pp 5660–5661 DOI: 10.1021/ja0318939 Supporting Info

A Ruthenium-Grafted Hydrotalcite as a Multifunctional Catalyst for Direct α-Alkylation of Nitriles with Primary Alcohols Ken Motokura, Daisuke Nishimura, Kohsuke Mori, Tomoo Mizugaki, Kohki Ebitani, and Kiyotomi Kaneda pp 5662–5663 DOI: 10.1021/ja049181l Supporting Info

Facile One-Pot Synthesis of Bifunctional Heterodimers of Nanoparticles:  A Conjugate of Quantum Dot and Magnetic Nanoparticles Hongwei Gu, Rongkun Zheng, XiXiang Zhang, and Bing Xu pp 5664–5665 DOI: 10.1021/ja0496423 Supporting Info

Hydrogen Sorption in Functionalized Metal−Organic Frameworks Jesse L. C. Rowsell, Andrew R. Millward, Kyo Sung Park, and Omar M. Yaghi pp 5666–5667 DOI: 10.1021/ja049408c Supporting Info

Isolation and Characterization of a Monomeric Cationic Titanium Hydride Kuangbiao Ma, Warren E. Piers, Yuan Gao, and Masood Parvez pp 5668–5669 DOI: 10.1021/ja048952i Supporting Info

Multistep Electron Transfer Processes on Dye Co-sensitized Nanocrystalline TiO2 Films John N. Clifford, Emilio Palomares, Md. K. Nazeeruddin, Ravindranathan Thampi, Michael Grätzel, and James R. Durrant pp 5670–5671 DOI: 10.1021/ja049705h Supporting Info

Organocatalytic Enantioselective Conjugate Addition to Alkynones Marco Bella and Karl Anker Jørgensen pp 5672–5673 DOI: 10.1021/ja0493594 Supporting Info

Layer-by-Layer Nanotube Template Synthesis Shifeng Hou, C. Chad Harrell, Lacramioara Trofin, Punit Kohli, and Charles R. Martin pp 5674–5675 DOI: 10.1021/ja049537t

Convenient Synthesis of Alkylhydrazides by the Cobalt-Catalyzed Hydrohydrazination Reaction of Olefins and Azodicarboxylates Jérôme Waser and Erick M. Carreira pp 5676–5677 DOI: 10.1021/ja048698u Supporting Info

Genome Mining To Identify New Plant Triterpenoids Gia C. Fazio, Ran Xu, and Seiichi P. T. Matsuda pp 5678–5679 DOI: 10.1021/ja0318784 Supporting Info

Copper-Catalyzed Electrophilic Amination of Diorganozinc Reagents Ashley M. Berman and Jeffrey S. Johnson pp 5680–5681 DOI: 10.1021/ja049474e Supporting Info

CO Oxidation on Aun/TiO2 Catalysts Produced by Size-Selected Cluster Deposition Sungsik Lee, Chaoyang Fan, Tianpin Wu, and Scott L. Anderson pp 5682–5683 DOI: 10.1021/ja049436v

Electroconductive Langmuir−Blodgett Films Containing a Carotenoid Amphiphile for Sugar Recognition Takashi Miyahara and Kazue Kurihara pp 5684–5685 DOI: 10.1021/ja0390101 Supporting Info

Enantioselective Allylation of Ketone-Derived Benzoylhydrazones:  Practical Synthesis of Tertiary Carbinamines Richard Berger, Keiko Duff, and James L. Leighton pp 5686–5687 DOI: 10.1021/ja0486418 Supporting Info

N1···N3 Hydrogen Bonds of A:U Base Pairs of RNA Are Stronger than Those of A:T Base Pairs of DNA Ioannis Vakonakis and Andy C. LiWang pp 5688–5689 DOI: 10.1021/ja048981t

Inhibitors of ADP-Ribosylating Bacterial Toxins Based on Oxacarbenium Ion Character at Their Transition States Guo-Chun Zhou, Sapan L. Parikh, Peter C. Tyler, Gary B. Evans, Richard H. Furneaux, Olga V. Zubkova, Paul A. Benjes, and Vern L. Schramm pp 5690–5698 DOI: 10.1021/ja038159+

Oxidative Fragmentation of Hydroxy Octadecadienoates Generates Biologically Active γ-Hydroxyalkenals Mingjiang Sun and Robert G. Salomon pp 5699–5708 DOI: 10.1021/ja038756w Supporting Info

Probing the Glycosidic Linkage:  UV and IR Ion-Dip Spectroscopy of a Lactoside Rebecca A. Jockusch, Romano T. Kroemer, Francis O. Talbot, Lavina C. Snoek, Pierre Çarçabal, John P. Simons, Martina Havenith, Joost M. Bakker, Isabelle Compagnon, Gerard Meijer, and Gert von Helden pp 5709–5714 DOI: 10.1021/ja031679k Supporting Info

Activation of Crystalline Cellulose Surfaces through the Chemoenzymatic Modification of Xyloglucan Harry Brumer III, Qi Zhou, Martin J. Baumann, Kjell Carlsson, and Tuula T. Teeri pp 5715–5721 DOI: 10.1021/ja0316770 Supporting Info

A PELDOR-Based Nanometer Distance Ruler for Oligonucleotides Olav Schiemann, Nelly Piton, Yuguang Mu, Gerhard Stock, Joachim W. Engels, and Thomas F. Prisner pp 5722–5729 DOI: 10.1021/ja0393877 Supporting Info

Template Assembled Cyclopeptides as Multimeric System for Integrin Targeting and Endocytosis Didier Boturyn, Jean-Luc Coll, Elisabeth Garanger, Marie-Christine Favrot, and Pascal Dumy pp 5730–5739 DOI: 10.1021/ja049926n Supporting Info

Encoding Method for OBOC Small Molecule Libraries Using a Biphasic Approach for Ladder-Synthesis of Coding Tags Xiaobing Wang, Jinhua Zhang, Aimin Song, Carlito B. Lebrilla, and Kit S. Lam pp 5740–5749 DOI: 10.1021/ja049322j

Evidence for Specific Solvation of Two Halocarbene Amides Eric M. Tippmann, Matthew S. Platz, Irina B. Svir, and Oleksiy V. Klymenko pp 5750–5762 DOI: 10.1021/ja039693k Supporting Info

Proton-Coupled Electron Transfer in Soybean Lipoxygenase Elizabeth Hatcher, Alexander V. Soudackov, and Sharon Hammes-Schiffer pp 5763–5775 DOI: 10.1021/ja039606o Supporting Info

New Synthesis and Insight into the Structure of Blue Ultramarine Pigments D. Arieli, D. E. W. Vaughan, and D. Goldfarb pp 5776–5788 DOI: 10.1021/ja0320121 Supporting Info

Do Spin State Changes Matter in Organometallic Chemistry? A Computational Study José-Luis Carreón-Macedo and Jeremy N. Harvey pp 5789–5797 DOI: 10.1021/ja049346q Supporting Info

Synthesis of Polyphenylene Dendrimers Related to “Cubic Graphite” Xianfeng Shen, Douglas M. Ho, and Robert A. Pascal, Jr. pp 5798–5805 DOI: 10.1021/ja030675c Supporting Info

Mechanism of Host−Guest Complexation by Cucurbituril César Márquez, Robert R. Hudgins, and Werner M. Nau pp 5806–5816 DOI: 10.1021/ja0319846

Synthesis, Structure Solution, Characterization, and Catalytic Properties of TNU-10:  A High-Silica Zeolite with the STI Topology Suk Bong Hong, Emily G. Lear, Paul A. Wright, Wuzong Zhou, Paul A. Cox, Chae-Ho Shin, Joo-Hyoung Park, and In-Sik Nam pp 5817–5826 DOI: 10.1021/ja031981t Supporting Info

A Mechanistic Investigation of the Polymerization of Ethylene Catalyzed by Neutral Ni(II) Complexes Derived from Bulky Anilinotropone Ligands Jason C. Jenkins and Maurice Brookhart pp 5827–5842 DOI: 10.1021/ja030634g Supporting Info

Vibrational Coupling, Isotopic Editing, and β-Sheet Structure in a Membrane-Bound Polypeptide Cynthia Paul, Jianping Wang, William C. Wimley, Robin M. Hochstrasser, and Paul H. Axelsen pp 5843–5850 DOI: 10.1021/ja038869f

Electronic Band Structure of Titania Semiconductor Nanosheets Revealed by Electrochemical and Photoelectrochemical Studies Nobuyuki Sakai, Yasuo Ebina, Kazunori Takada, and Takayoshi Sasaki pp 5851–5858 DOI: 10.1021/ja0394582 Supporting Info

X-ray Magnetic Circular Dichroism of Pseudomonas aeruginosa Nickel(II) Azurin Tobias Funk, Pierre Kennepohl, Angel J. Di Bilio, William A. Wehbi, Anthony T. Young, Stephan Friedrich, Elke Arenholz, Harry B. Gray, and Stephen P. Cramer pp 5859–5866 DOI: 10.1021/ja036218d Supporting Info

WISE NMR Characterization of Nanoscale Heterogeneity and Mobility in Supercontracted Nephila clavipes Spider Dragline Silk Gregory P. Holland, Randolph V. Lewis, and Jeff L. Yarger pp 5867–5872 DOI: 10.1021/ja031930w

Biomolecular NMR Using a Microcoil NMR Probe − New Technique for the Chemical Shift Assignment of Aromatic Side Chains in Proteins Wolfgang Peti, James Norcross, Gary Eldridge, and Mark O'Neil-Johnson pp 5873–5878 DOI: 10.1021/ja039779d Supporting Info

Ensemble Approach for NMR Structure Refinement against 1H Paramagnetic Relaxation Enhancement Data Arising from a Flexible Paramagnetic Group Attached to a Macromolecule Junji Iwahara, Charles D. Schwieters, and G. Marius Clore pp 5879–5896 DOI: 10.1021/ja031580d Supporting Info

Direct Experimental Evaluation of Charge Scheme Performance by a Molecular Charge-Meter Roie Yerushalmi, Avigdor Scherz, and Kim K. Baldridge pp 5897–5905 DOI: 10.1021/ja039545u

Gas-Phase Hydrogen/Deuterium Exchange and Conformations of Deprotonated Flavonoids and Gas-Phase Acidities of Flavonoids Junmei Zhang and Jennifer S. Brodbelt pp 5906–5919 DOI: 10.1021/ja031655d

Surface Adsorption and Transfer of Organomercaptans to Colloidal Gold and Direct Identification by Matrix Assisted Laser Desorption/Ionization Mass Spectrometry John S. Kirk and Paul W. Bohn pp 5920–5926 DOI: 10.1021/ja030573m

Protein Structure:  Determination, Analysis, and Applications for Drug Discovery Edited by Daniel E. Chasman (Variagenics, Inc., Cambridge, MA). Marcel Dekker, Inc.:  New York and Basel. 2003. xi + 606 pp. $195.00. ISBN 0-8247-4032-7. Norma Mary Allewell p 5927 DOI: 10.1021/ja033610i

Chemical Process Research:  The Art of Practical Organic Synthesis Edited by Ahmed F. Abdel-Magid (Johnson and Johnson Pharmaceutical Research and Development) and John A. Ragan (Pfizer Global Research and Development). American Chemical Society (distributed by Oxford University Press):  Washington, DC. 2004. xii + 212 pp. $125.00. ISBN 0-8412-3824-3. p 5927 DOI: 10.1021/ja033678y

Topics in Stereochemistry, Volume 24:  Materials-Chirality Edited by Mark M. Green (Polytechnic University, Brooklyn), R. J. M. Nolte (University of Nijmegen, the Netherlands), and E. W. Meijer (Eindhoven University of Technology, The Netherlands). Series Edited by Scott E. Denmark and Jay Siegel. John Wiley & Sons, Inc.:  Hoboken. 2003. xvi + 608 pp. $175.00. ISBN 0-471-05497-6. Rawle I. Hollingsworth pp 5927–5928 DOI: 10.1021/ja033630k

Issue 19

Direct Determination of Product Radical Structure Reveals the Radical Rearrangement Pathway in a Coenzyme B12-Dependent Enzyme Kurt Warncke and Jeffrey M. Canfield pp 5930–5931 DOI: 10.1021/ja031569d Supporting Info

Bio-Bar-Code-Based DNA Detection with PCR-like Sensitivity Jwa-Min Nam, Savka I. Stoeva, and Chad A. Mirkin pp 5932–5933 DOI: 10.1021/ja049384+ Supporting Info

Hierarchical Porphyrin Self-Assembly in Aqueous Solution Massimo De Napoli, Sara Nardis, Roberto Paolesse, M. Graça H. Vicente, Rosaria Lauceri, and Roberto Purrello pp 5934–5935 DOI: 10.1021/ja0494757 Supporting Info

Computational Study of the Ground State of Thermophilic Indole Glycerol Phosphate Synthase:  Structural Alterations at the Active Site with Temperature Devleena Mazumder-Shivakumar, Kalju Kahn, and Thomas C. Bruice pp 5936–5937 DOI: 10.1021/ja049512u

Characterization of β-Amino Ester Enolates as Hexamers via 6Li NMR Spectroscopy Anne J. McNeil, Gilman E. S. Toombes, Sithamalli V. Chandramouli, Benoit J. Vanasse, Timothy A. Ayers, Michael K. O'Brien, Emil Lobkovsky, Sol M. Gruner, John A. Marohn, and David B. Collum pp 5938–5939 DOI: 10.1021/ja049245s Supporting Info

Ag Nanowires Coated with Ag/Pd Alloy Sheaths and Their Use as Substrates for Reversible Absorption and Desorption of Hydrogen Yugang Sun, Zhanliang Tao, Jun Chen, Thurston Herricks, and Younan Xia pp 5940–5941 DOI: 10.1021/ja0495765 Supporting Info

Mutasynthesis of Glycopeptide Antibiotics:  Variations of Vancomycin's AB-Ring Amino Acid 3,5-Dihydroxyphenylglycine Stefan Weist, Claudia Kittel, Daniel Bischoff, Bojan Bister, Volker Pfeifer, Graeme J. Nicholson, Wolfgang Wohlleben, and Roderich D. Süssmuth pp 5942–5943 DOI: 10.1021/ja0499389 Supporting Info

A PNA4 Quadruplex Yamuna Krishnan-Ghosh, Elaine Stephens, and Shankar Balasubramanian pp 5944–5945 DOI: 10.1021/ja031508f Supporting Info

Nucleophilic Character of a Charge Neutral, High Oxidation State d0 Zirconium Trimethylenemethane Complex Denis A. Kissounko and Lawrence R. Sita pp 5946–5947 DOI: 10.1021/ja0493897 Supporting Info

Rhodium(I)-Catalyzed [2+2+1] Cycloadditions of 1,3-Dienes, Alkenes, and CO Paul A. Wender, Mitchell P. Croatt, and Nicole M. Deschamps pp 5948–5949 DOI: 10.1021/ja0489487 Supporting Info

Tandem Mass Spectrometry Defines the Stoichiometry and Quaternary Structural Arrangement of Tryptophan Molecules in the Multiprotein Complex TRAP Margaret G. McCammon, Helena Hernández, Frank Sobott, and Carol V. Robinson pp 5950–5951 DOI: 10.1021/ja0317170 Supporting Info

AgBF4-Impregnated Poly(vinyl phenyl ketone):  An Ethylene Sensing Film Omar Green, Nickolaus A. Smith, Arthur B. Ellis, and Judith N. Burstyn pp 5952–5953 DOI: 10.1021/ja039203o Supporting Info

Effect of Zn on Acetyl Coenzyme A Synthase:  Evidence for a Conformational Change in the α Subunit during Catalysis Xiangshi Tan, Matthew R. Bramlett, and Paul A. Lindahl pp 5954–5955 DOI: 10.1021/ja039600z

Highly Enantioselective Catalytic Carbon Dioxide Incorporation Reaction:  Nickel-Catalyzed Asymmetric Carboxylative Cyclization of Bis-1,3-dienes Masanori Takimoto, Yoichi Nakamura, Kaoru Kimura, and Miwako Mori pp 5956–5957 DOI: 10.1021/ja049506y Supporting Info

Synthesis of Allenes via Palladium-Catalyzed Hydrogen-Transfer Reactions:  Propargylic Amines as an Allenyl Anion Equivalent Hiroyuki Nakamura, Takaya Kamakura, Makoto Ishikura, and Jean- François Biellmann pp 5958–5959 DOI: 10.1021/ja039175+ Supporting Info

Polymorphism in Biphenyl-Based Self-Assembled Monolayers of Thiols Piotr Cyganik and Manfred Buck pp 5960–5961 DOI: 10.1021/ja049146e Supporting Info

Enantioselective Tandem O-Nitroso Aldol/Michael Reaction Yuhei Yamamoto, Norie Momiyama, and Hisashi Yamamoto pp 5962–5963 DOI: 10.1021/ja049741g Supporting Info

An Au-Catalyzed Cyclialkylation of Electron-Rich Arenes with Epoxides To Prepare 3-Chromanols Zhangjie Shi and Chuan He pp 5964–5965 DOI: 10.1021/ja031953a Supporting Info

Highly Selective Asymmetric Hydrogenation Using a Three Hindered Quadrant Bisphosphine Rhodium Catalyst Garrett Hoge, He-Ping Wu, William S. Kissel, Derek A. Pflum, Derek J. Greene, and Jian Bao pp 5966–5967 DOI: 10.1021/ja048496y Supporting Info

Synthesis of Tertiary Propargylamines by Sequential Reactions of in Situ Generated Thioiminium Salts with Organolithium and -magnesium Reagents Toshiaki Murai, Yuichiro Mutoh, Yukiyasu Ohta, and Masahiro Murakami pp 5968–5969 DOI: 10.1021/ja048627v Supporting Info

Contingency and Serendipity in the Reactions of Fischer Carbene Complexes with Conjugated Triynes May Xiao-Wu Jiang, Manish Rawat, and William D. Wulff pp 5970–5971 DOI: 10.1021/ja049836i Supporting Info

Large-Scale, Solution-Phase Growth of Single-Crystalline SnO2 Nanorods Bin Cheng, Joette M. Russell, Wensheng Shi, Lei Zhang, and Edward T. Samulski pp 5972–5973 DOI: 10.1021/ja0493244 Supporting Info

Metal-Controlled Selective [3+2] Cyclization Reactions of Alkenyl Fischer Carbene Complexes and Allenes José Barluenga, Rubén Vicente, Pablo Barrio, Luis A. López, and Miguel Tomás pp 5974–5975 DOI: 10.1021/ja049200r Supporting Info

Synthesis of Eu2O3 Nanotube Arrays through a Facile Sol−Gel Template Approach Guosheng Wu, Lide Zhang, Baochang Cheng, Ting Xie, and Xiaoyou Yuan pp 5976–5977 DOI: 10.1021/ja039012l Supporting Info

Colloidal Crystallization and Banding in a Cylindrical Geometry Manouk Abkarian, Janine Nunes, and Howard A. Stone pp 5978–5979 DOI: 10.1021/ja049775o

Geometry Changes of a Cu(I) Phenanthroline Complex on Photoexcitation in a Confining Medium by Time-Resolved X-ray Diffraction Philip Coppens, Ivan I. Vorontsov, Timothy Graber, Andrey Yu. Kovalevsky, Yu-Sheng Chen, Guang Wu, Milan Gembicky, and Irina V. Novozhilova pp 5980–5981 DOI: 10.1021/ja049781k

Genetically Encoded Fluorescent Reporters of Histone Methylation in Living Cells Chi-Wang Lin, Cindy Y. Jao, and Alice Y. Ting pp 5982–5983 DOI: 10.1021/ja038854h Supporting Info

Simple, Catalytic Enantioselective Syntheses of Estrone and Desogestrel Qi-Ying Hu, Pankaj D. Rege, and E. J. Corey pp 5984–5986 DOI: 10.1021/ja048808x Supporting Info

Ultrastructure in Frozen/Etched Saline Solutions:  On the Internal Cleansing of Ice Fredric M. Menger, Ashley L. Galloway, Mary E. Chlebowski, and Robert P. Apkarian pp 5987–5989 DOI: 10.1021/ja040066k

Designing Sequence to Control Protein Function in an EF-Hand Protein Christopher G. Bunick, Melanie R. Nelson, Sheryll Mangahas, Michael J. Hunter, Jonathan H. Sheehan, Laura S. Mizoue, Gerard J. Bunick, and Walter J. Chazin pp 5990–5998 DOI: 10.1021/ja0397456 Supporting Info

Factors Governing the Kinetic Competition of Nitrogen and Sulfur Ligands in Cisplatin Binding to Biological Targets Dirk V. Deubel pp 5999–6004 DOI: 10.1021/ja0499602 Supporting Info

Spectroscopic Description of the Two Nitrosyl−Iron Complexes Responsible for Fur Inhibition by Nitric Oxide Benoît D'Autréaux, Olivier Horner, Jean-Louis Oddou, Claudine Jeandey, Serge Gambarelli, Catherine Berthomieu, Jean-Marc Latour, and Isabelle Michaud-Soret pp 6005–6016 DOI: 10.1021/ja031671a Supporting Info

Proton Inventory Studies of α-Thrombin-Catalyzed Reactions of Substrates with Selected P and P‘ Sites Edith J. Enyedy and Ildiko M. Kovach pp 6017–6024 DOI: 10.1021/ja0320166 Supporting Info

Exchange Mechanisms for Sodium Dodecyl Sulfate Micelles: High Salt Concentration Yahya Rharbi, Liusheng Chen, and Mitchell A. Winnik pp 6025–6034 DOI: 10.1021/ja0304805 Supporting Info

Carbazole Compounds as Host Materials for Triplet Emitters in Organic Light-Emitting Diodes:  Tuning the HOMO Level without Influencing the Triplet Energy in Small Molecules Klemens Brunner, Addy van Dijken, Herbert Börner, Jolanda J. A. M. Bastiaansen, Nicole M. M. Kiggen, and Bea M. W. Langeveld pp 6035–6042 DOI: 10.1021/ja049883a Supporting Info

Density Functional Theory Determination of an Axial Gateway To Explain the Rate and Endo Selectivity Enhancement of Diels−Alder Reactions by Bis(oxazoline)-Cu(II) Jason DeChancie, Orlando Acevedo, and Jeffrey D. Evanseck pp 6043–6047 DOI: 10.1021/ja037702j Supporting Info

A New Class of Foldamers Based on cis-γ-Amino-l-proline1,2 Josep Farrera-Sinfreu, Laura Zaccaro, David Vidal, Xavier Salvatella, Ernest Giralt, Miquel Pons, Fernando Albericio, and Miriam Royo pp 6048–6057 DOI: 10.1021/ja0398621

Connecting π-Chromophores by σ-P−P Bonds:  New Type of Assemblies Exhibiting σ−π-Conjugation Claire Fave, Muriel Hissler, Tamás Kárpáti, Joëlle Rault-Berthelot, Valérie Deborde, Loic Toupet, László Nyulászi, and Régis Réau pp 6058–6063 DOI: 10.1021/ja0317067 Supporting Info

The N-Acyloxyiminium Ion Aza-Prins Route to Octahydroindoles:  Total Synthesis and Structural Confirmation of the Antithrombotic Marine Natural Product Oscillarin Stephen Hanessian, Martin Tremblay, and Jens F. W. Petersen pp 6064–6071 DOI: 10.1021/ja030669g Supporting Info

Threshold Detection Using Indicator-Displacement Assays:  An Application in the Analysis of Malate in Pinot Noir Grapes Anna M. Pitek, Yannick J. Bomble, Sheryl L. Wiskur, and Eric V. Anslyn pp 6072–6077 DOI: 10.1021/ja040006e Supporting Info

Designing Libraries of First Generation AB3 and AB2 Self-Assembling Dendrons via the Primary Structure Generated from Combinations of (AB)y−AB3 and (AB)y−AB2 Building Blocks Virgil Percec, Catherine M. Mitchell, Wook-Dong Cho, Satoshi Uchida, Martin Glodde, Goran Ungar, Xiangbing Zeng, Yongsong Liu, Venkatachalapathy S. K. Balagurusamy, and Paul A. Heiney pp 6078–6094 DOI: 10.1021/ja049846j Supporting Info

Debundling and Dissolution of Single-Walled Carbon Nanotubes in Amide Solvents C. A. Furtado, U. J. Kim, H. R. Gutierrez, Ling Pan, E. C. Dickey, and Peter C. Eklund pp 6095–6105 DOI: 10.1021/ja039588a Supporting Info

Permanent Microporosity and Enantioselective Sorption in a Chiral Open Framework Darren Bradshaw, Timothy J. Prior, Edmund J. Cussen, John B. Claridge, and Matthew J. Rosseinsky pp 6106–6114 DOI: 10.1021/ja0316420 Supporting Info

Bioactivation and Cell Targeting of Semiconductor CdSe/ZnS Nanocrystals with Phytochelatin-Related Peptides Fabien Pinaud, David King, Hsiao-Ping Moore, and Shimon Weiss pp 6115–6123 DOI: 10.1021/ja031691c Supporting Info

Solvent-Induced Self-Assembly of Mixed Poly(methyl methacrylate)/Polystyrene Brushes on Planar Silica Substrates:  Molecular Weight Effect Bin Zhao, Richard T. Haasch, and Scott MacLaren pp 6124–6134 DOI: 10.1021/ja049570f Supporting Info

3,5-PyridyneA Heterocyclic meta-Benzyne Derivative Michael Winkler, Bayram Cakir, and Wolfram Sander pp 6135–6149 DOI: 10.1021/ja039142u Supporting Info

Molybdenum Triamidoamine Complexes that Contain Hexa-tert-butylterphenyl, Hexamethylterphenyl, or p-Bromohexaisopropylterphenyl Substituents. An Examination of Some Catalyst Variations for the Catalytic Reduction of Dinitrogen Vincent Ritleng, Dmitry V. Yandulov, Walter W. Weare, Richard R. Schrock, Adam S. Hock, and William M. Davis pp 6150–6163 DOI: 10.1021/ja0306415 Supporting Info

Shape Control and Associated Magnetic Properties of Spinel Cobalt Ferrite Nanocrystals Qing Song and Z. John Zhang pp 6164–6168 DOI: 10.1021/ja049931r

Conformational Analysis and Assignments of Relative Stereocenter Configurations in Fluoroalkyl−Iridium Complexes Using 19F{1H} HOESY Experiments. Comparison with Solid-State X-ray Structural Results Russell P. Hughes, Donghui Zhang, Antony J. Ward, Lev. N. Zakharov, and Arnold L. Rheingold pp 6169–6178 DOI: 10.1021/ja049225q Supporting Info

The Dipole Moment, Polarizabilities, and First Hyperpolarizabilities of HArF. A Computational and Comparative Study Aggelos Avramopoulos, Heribert Reis, Jiabo Li, and Manthos G. Papadopoulos pp 6179–6184 DOI: 10.1021/ja036319b

Marcus Theory of Outer-Sphere Heterogeneous Electron Transfer Reactions:  Dependence of the Standard Electrochemical Rate Constant on the Hydrodynamic Radius from High Precision Measurements of the Oxidation of Anthracene and Its Derivatives in Nonaqueous Solvents Using the High-Speed Channel Electrode Antony D. Clegg, Neil V. Rees, Oleksiy V. Klymenko, Barry A. Coles, and Richard G. Compton pp 6185–6192 DOI: 10.1021/ja040014v Supporting Info

Electrochemistry and Optical Absorbance and Luminescence of Molecule-like Au38 Nanoparticles Dongil Lee, Robert L. Donkers, Gangli Wang, Amanda S. Harper, and Royce W. Murray pp 6193–6199 DOI: 10.1021/ja049605b Supporting Info

Molecular Rectification and Conductance Switching in Carbon-Based Molecular Junctions by Structural Rearrangement Accompanying Electron Injection  [J. Am. Chem. Soc. 2003, 125, 10748−10758].  Richard McCreery, Jon Dieringer, Ali Osman Solak, Brian Snyder, Aletha M. Nowak, William R. McGovern, and Stacy DuVall p 6200 DOI: 10.1021/ja048667z

Issue 20

Osmotic Pressure Control in Response to a Specific Ion Signal at Physiological Temperature Using a Molecular Recognition Ion Gating Membrane Taichi Ito and Takeo Yamaguchi pp 6202–6203 DOI: 10.1021/ja0306213

Chiral Dimeric Capsules from N,C-Linked Peptidocalix[4]arenes Self-Assembled through an Antiparallel β-Sheetlike Motif Francesco Sansone, Laura Baldini, Alessandro Casnati, Elisa Chierici, Giovanni Faimani, Franco Ugozzoli, and Rocco Ungaro pp 6204–6205 DOI: 10.1021/ja031511z Supporting Info

Zinc Oxide Quantum Rods Ming Yin, Yi Gu, Igor L. Kuskovsky, Tamar Andelman, Yimei Zhu, G. F. Neumark, and Stephen O'Brien pp 6206–6207 DOI: 10.1021/ja031696+ Supporting Info

Zn2+-Dependent Peptide Nucleic Acids Probes Andriy Mokhir, Roland Krämer, and Helena Wolf pp 6208–6209 DOI: 10.1021/ja0397613 Supporting Info

Formation of a Highly Oxidized Iron Biliverdin Complex upon Treatment of a Five-Coordinate Verdoheme with Dioxygen Khoi T. Nguyen, Sankar Prasad Rath, Lechosław Latos-Grażyński, Marilyn M. Olmstead, and Alan L. Balch pp 6210–6211 DOI: 10.1021/ja049222d Supporting Info

Building Addressable Libraries:  The Use of Electrochemistry for Generating Reactive Pd(II) Reagents at Preselected Sites on a Chip Eden Tesfu, Karl Maurer, Steven R. Ragsdale, and Kevin D. Moeller pp 6212–6213 DOI: 10.1021/ja0489036 Supporting Info

Substrate Electric Dipole Moment Exerts a pH-Dependent Effect on Electron Transfer in Escherichia coli Photolyase Sofia M. Kapetanaki, Meghan Ramsey, Yvonne M. Gindt, and Johannes P. M. Schelvis pp 6214–6215 DOI: 10.1021/ja049226i Supporting Info

Steric and Magnetic Asymmetry Distinguished by Encapsulation Toru Amaya and Julius Rebek, Jr. pp 6216–6217 DOI: 10.1021/ja049043w Supporting Info

Nanomechanical Control of Glucopyranose Rotamers Gwangrog Lee, Wiesław Nowak, Justyna Jaroniec, Qingmin Zhang, and Piotr E. Marszalek pp 6218–6219 DOI: 10.1021/ja0491984 Supporting Info

Stair Motifs at Protein−DNA Interfaces:  Nonadditivity of H-Bond, Stacking, and Cation−π Interactions Christophe Biot, René Wintjens, and Marianne Rooman pp 6220–6221 DOI: 10.1021/ja049620g Supporting Info

A Charge-Transfer-Induced Spin Transition in the Discrete Cyanide-Bridged Complex {[Co(tmphen)2]3[Fe(CN)6]2} Curtis P. Berlinguette, Alina Dragulescu-Andrasi, Andreas Sieber, José Ramón Galán-Mascarós, Hans-Ulrich Güdel, Catalina Achim, and Kim R. Dunbar pp 6222–6223 DOI: 10.1021/ja039451k Supporting Info

Development of a Quantum Mechanics-Based Free-Energy Perturbation Method:  Use in the Calculation of Relative Solvation Free Energies M. Rami Reddy, U. C. Singh, and Mark D. Erion pp 6224–6225 DOI: 10.1021/ja049281r Supporting Info

Redox Modulation of Electroosmotic Flow in a Carbon Nanotube Membrane Scott A. Miller and Charles R. Martin pp 6226–6227 DOI: 10.1021/ja0496322

Long-Lived Nuclear Spin States in High-Field Solution NMR Marina Carravetta and Malcolm H. Levitt pp 6228–6229 DOI: 10.1021/ja0490931

A Simple Stereocontrolled Synthesis of Salinosporamide A Leleti Rajender Reddy, P. Saravanan, and E. J. Corey pp 6230–6231 DOI: 10.1021/ja048613p Supporting Info

Protein Backbone 1HN−13Cα and 15N−13Cα Residual Dipolar and J Couplings:  New Constraints for NMR Structure Determination Keyang Ding and Angela M. Gronenborn pp 6232–6233 DOI: 10.1021/ja049049l Supporting Info

A New Method for the Stereoselective Synthesis of α- and β-Glycosylamines Using the Burgess Reagent K. C. Nicolaou, Scott A. Snyder, Annie Z. Nalbandian, and Deborah A. Longbottom pp 6234–6235 DOI: 10.1021/ja049293c Supporting Info

Distribution and Modification of Sorption Sites in Amphiphilic Calixarene-Based Solid Lipid Nanoparticles from Hyperpolarized 129Xe NMR Spectroscopy Alix Dubes, Igor L. Moudrakovski, Patrick Shahgaldian, Anthony W. Coleman, Christopher I. Ratcliffe, and John A. Ripmeester pp 6236–6237 DOI: 10.1021/ja038653d Supporting Info

Zinc-Induced Switching of the Nonlinear Optical Properties of a Functionalized Bis(styryl)benzene Graziano Fabbrini, Enzo Menna, Michele Maggini, Alessandro Canazza, Gabriele Marcolongo, and Moreno Meneghetti pp 6238–6239 DOI: 10.1021/ja049204w Supporting Info

A New Entry of Nucleophiles in Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions:  Addition of Organozinc Reagents for the Synthesis of 2-Aryl-4-piperidones Ryo Shintani, Norihito Tokunaga, Hidenori Doi, and Tamio Hayashi pp 6240–6241 DOI: 10.1021/ja048825m Supporting Info

Polymer Lateral Diffusion at the Solid−Liquid Interface Jiang Zhao and Steve Granick pp 6242–6243 DOI: 10.1021/ja0493749

Comparison of Enzymatic and Non-Enzymatic Nitroethane Anion Formation:  Thermodynamics and Contribution of Tunneling Michael P. Valley and Paul F. Fitzpatrick pp 6244–6245 DOI: 10.1021/ja0484606

Autocatalysis and Self-Inhibition:  Coupled Kinetic Phenomena in the Chlorite−Tetrathionate Reaction Attila K. Horváth, István Nagypál, Gábor Peintler, and Irving R. Epstein pp 6246–6247 DOI: 10.1021/ja048982l

Seedless Growth of Free-Standing Copper Nanowires by Chemical Vapor Deposition Hyungsoo Choi and Sung-Ho Park pp 6248–6249 DOI: 10.1021/ja049217+

Reactivity Control of an Allylsilane Bearing a 2-(Phenylazo)phenyl Group by Photoswitching of the Coordination Number of Silicon Naokazu Kano, Masaki Yamamura, and Takayuki Kawashima pp 6250–6251 DOI: 10.1021/ja037404m Supporting Info

A Tetrahedrally Coordinated L3Fe−Nx Platform that Accommodates Terminal Nitride (FeIVN) and Dinitrogen (FeI−N2−FeI) Ligands Theodore A. Betley and Jonas C. Peters pp 6252–6254 DOI: 10.1021/ja048713v Supporting Info

Diastereomer Assignment of an Olefin-Linked Bis-paracyclophane by Ion Mobility Mass Spectrometry Erin Shammel Baker, Janice W. Hong, Jennifer Gidden, Glenn P. Bartholomew, Guillermo C. Bazan, and Michael T. Bowers pp 6255–6257 DOI: 10.1021/ja039486k Supporting Info

Completely Automated, Highly Error-Tolerant Macromolecular Structure Determination from Multidimensional Nuclear Overhauser Enhancement Spectra and Chemical Shift Assignments John Kuszewski, Charles D. Schwieters, Daniel S. Garrett, R. Andrew Byrd, Nico Tjandra, and G. Marius Clore pp 6258–6273 DOI: 10.1021/ja049786h

Highly Efficient Photochemical 2‘-Deoxyribonolactone Formation at the Diagonal Loop of a 5-Iodouracil-Containing Antiparallel G-Quartet Yan Xu and Hiroshi Sugiyama pp 6274–6279 DOI: 10.1021/ja031942h Supporting Info

Hydrogen Bond Driven Chemical Reactions:  Beckmann Rearrangement of Cyclohexanone Oxime into ε-Caprolactam in Supercritical Water Mauro Boero, Tamio Ikeshoji, Chee Chin Liew, Kiyoyuki Terakura, and Michele Parrinello pp 6280–6286 DOI: 10.1021/ja049363f

Mechanism and Regioselectivity of Reductive Elimination of π-Allylcopper (III) Intermediates Masahiro Yamanaka, Seiichi Kato, and Eiichi Nakamura pp 6287–6293 DOI: 10.1021/ja049211k Supporting Info

Self-Assembling Molecular Trees Containing Octa-p-phenylene:  From Nanocrystals to Nanocapsules Yong-Sik Yoo, Jin-Ho Choi, Ji-Ho Song, Nam-Keun Oh, Wang-Cheol Zin, Soojin Park, Taihyun Chang, and Myongsoo Lee pp 6294–6300 DOI: 10.1021/ja048856h Supporting Info

Subphthalocyanines:  Tuneable Molecular Scaffolds for Intramolecular Electron and Energy Transfer Processes David González-Rodríguez, Tomás Torres, Dirk M. Guldi, José Rivera, Maria Ángeles Herranz, and Luis Echegoyen pp 6301–6313 DOI: 10.1021/ja039883v Supporting Info

Directed Assembly of Transition-Metal-Coordinated Molecular Loops and Squares from Salen-Type Components. Examples of Metalation-Controlled Structural Conversion Shih-Sheng Sun, Charlotte L. Stern, SonBinh T. Nguyen, and Joseph T. Hupp pp 6314–6326 DOI: 10.1021/ja037378s Supporting Info

A Synthetic Reaction Network:  Chemical Amplification Using Nonequilibrium Autocatalytic Reactions Coupled in Time Cory J. Gerdts, David E. Sharoyan, and Rustem F. Ismagilov pp 6327–6331 DOI: 10.1021/ja031689l

Mechanism of Palladium-Catalyzed Diene Cyclization/Hydrosilylation:  Direct Observation of Intramolecular Carbometalation Nicholas S. Perch and Ross A. Widenhoefer pp 6332–6346 DOI: 10.1021/ja049806f Supporting Info

Total Synthesis of TMC-95A and -B via a New Reaction Leading to Z-Enamides. Some Preliminary Findings as to SAR Songnian Lin, Zhi-Qiang Yang, Benjamin H. B. Kwok, Michael Koldobskiy, Craig M. Crews, and Samuel J. Danishefsky pp 6347–6355 DOI: 10.1021/ja049821k Supporting Info

Oxidation of Alkylarenes by Nitrate Catalyzed by Polyoxophosphomolybdates:  Synthetic Applications and Mechanistic Insights Alexander M. Khenkin and Ronny Neumann pp 6356–6362 DOI: 10.1021/ja031710i Supporting Info

Transformation of Acyclic Alkenes to Hydrido Carbynes by (PNPR)Re Complexes Oleg V. Ozerov, Lori A. Watson, Maren Pink, and Kenneth G. Caulton pp 6363–6378 DOI: 10.1021/ja031617u Supporting Info

The Effects of Axial Ligands on Electron Distribution and Spin States in Iron Complexes of Octaethyloxophlorin, Intermediates in Heme Degradation Sankar Prasad Rath, Marilyn M. Olmstead, and Alan L. Balch pp 6379–6386 DOI: 10.1021/ja0316014 Supporting Info

A Comparative Study of π-Arene-Bridged Lanthanum Arylamide and Aryloxide Dimers. Solution Behavior, Exchange Mechanisms, and X-ray Crystal Structures of La2(NH-2,6-iPr2C6H3)6, La(NH-2,6-iPr2C6H3)3(THF)3, and La(NH-2,6-iPr2C6H3)3(py)2 Garth R. Giesbrecht, John C. Gordon, David L. Clark, P. Jeffrey Hay, Brian L. Scott, and C. Drew Tait pp 6387–6401 DOI: 10.1021/ja0398262 Supporting Info

Heterogeneous Growth of Metal Clusters from Solutions of Seed Nanoparticles Jess Patrick Wilcoxon and Paula P. Provencio pp 6402–6408 DOI: 10.1021/ja031622y Supporting Info

Site-Specific Fabrication of Nanoscale Heterostructures:  Local Chemical Modification of GaN Nanowires Using Electrochemical Dip-Pen Nanolithography Benjamin W. Maynor, Jianye Li, Chenguang Lu, and Jie Liu pp 6409–6413 DOI: 10.1021/ja0317832 Supporting Info

A New Thermoelectric Material: CsBi4Te6 Duck-Young Chung, Tim P. Hogan, Melissa Rocci-Lane, Paul Brazis, John R. Ireland, Carl R. Kannewurf, Marina Bastea, Ctirad Uher, and Mercouri G. Kanatzidis pp 6414–6428 DOI: 10.1021/ja039885f Supporting Info

Projection−Reconstruction Technique for Speeding up Multidimensional NMR Spectroscopy Ēriks Kupe and Ray Freeman pp 6429–6440 DOI: 10.1021/ja049432q Supporting Info

Damage to Model DNA Fragments from Very Low-Energy (<1 eV) Electrons Joanna Berdys, Iwona Anusiewicz, Piotr Skurski, and Jack Simons pp 6441–6447 DOI: 10.1021/ja049876m

Initial Structure Modification of Tetrahedral to Planar Nickel(II) in a Nickel−Iron−Sulfur Cluster Related to the C-Cluster of Carbon Monoxide Dehydrogenase Rashmishree Panda, Yugen Zhang, Craig C. McLauchlan, P. Venkateswara Rao, F. A. Tiago de Oliveira, E. Münck, and R. H. Holm pp 6448–6459 DOI: 10.1021/ja030627s Supporting Info

Local and Global Chirality at Surfaces:  Succinic Acid versus Tartaric Acid on Cu(110) Vincent Humblot, Maria Ortega Lorenzo, Christopher J. Baddeley, Sam Haq, and Rasmita Raval pp 6460–6469 DOI: 10.1021/ja0382056 Supporting Info

Atropisomerization, C−H Activation, and Dissociative Substitution at Some Biphenyl Platinum(II) Complexes Maria Rosaria Plutino, Luigi Monsu' Scolaro, Alberto Albinati, and Raffaello Romeo pp 6470–6484 DOI: 10.1021/ja030486u Supporting Info

Gas-Phase H/D Exchange of Sodiated Glycine Oligomers with ND3:  Exchange Kinetics Do Not Reflect Parent Ion Structures Heather A. Cox, Ryan R. Julian, Sang-Won Lee, and J. L. Beauchamp pp 6485–6490 DOI: 10.1021/ja049834y

Differential Conductance Switching of Planar Tunnel Junctions Mediated by Oxidation/Reduction of Functionally Protected Ferrocene Jose A. M. Dinglasan, Michael Bailey, Jong B. Park, and Al-Amin Dhirani pp 6491–6497 DOI: 10.1021/ja0394176 Supporting Info

Catalytic Enantioselective Synthesis of α-Aminooxy and α-Hydroxy Ketone Using Nitrosobenzene [J. Am. Chem. Soc. 2003, 125, 6038].  Norie Momiyama and Hisashi Yamamoto p 6498 DOI: 10.1021/ja040805x

Electron Spin Resonance Spectroscopy of Organic Radicals By Fabian Gerson (University of Basel) and Walter Huber (Hoffmann-La Roche & Cie AG, Basel). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. xvi + 464 pp. $115. ISBN 3-527-30275-1. Stephen F. Nelsen p 6499 DOI: 10.1021/ja0336675

Challenges in Taste Chemistry and Biology Edited by Thomas Hofmann (Universität Münster), Chi-Tang Ho (Rutgers, The State University of New Jersey), and Wilhelm Pickenhagen (Dragoco Gerberding and Company). American Chemical Society (distributed by Oxford University Press):  Washington, DC. 2004. xiv + 290 pp. $135.00. ISBN 0-8412-3852-9. p 6499 DOI: 10.1021/ja033680p

Chiral Separations:  Methods and Protocols. Meth-ods in Molecular Biology, Volume 243 Edited by Gerald Gübitz and Martin G. Schmid (Karl-Franzens University, Graz, Austria). Humana Press:  Totowa. 2004. xiv + 432 pp. $99.50. ISBN 1-58829-150-2. p 6499 DOI: 10.1021/ja033682+

Radioanalytical Methods in Interdisciplinary Research:  Fundamentals in Cutting-Edge Applications Edited by Carola A. Laue (Lawrence Livermore National Lab) and Kenneth L. Nash (Argonne National Laboratory). American Chemical Society (distributed by Oxford University Press):  Washington, DC. 2004. xii + 364 pp. $165.00. ISBN 0-8412-3837-5. pp 6499–6500 DOI: 10.1021/ja033681h

Silicon Chemistry:  From the Atom to Extended Systems Edited by Peter Jutzi (University of Bielefeld) and Ulrich Schubert (Vienna University of Technology). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. xii + 494 pp. $165.00. ISBN 3-527-30647-1. p 6500 DOI: 10.1021/ja0336630

Chemicals in the Atmosphere − Solubility, Sources and Reactivity Edited by P. Fogg (University of North London, Retired) and J. Sangster (Sangster Research Labs, Montreal). John Wiley & Sons, Ltd.:  Chichester. 2003. xiv + 454 pp. $180.00. ISBN 0-471-98651-8. Jonathan Abbatt p 6500 DOI: 10.1021/ja033670o

Energetic Materials, Part 2. Detonation, Combustion Edited by Peter A. Politzer and Jane S. Murray (University of New Orleans). From the Series:  Theoretical and Computational Chemistry, 13. Elsevier:  Amsterdam and New York. 2003. xx + 454 pp. $210.00. ISBN 0-444-51519-4. Thomas B. Brill pp 6500–6501 DOI: 10.1021/ja040902q

Organosilicon Chemistry V:  From Molecules to Materials Edited by Norbert Auner (University of Frankfurt) and Johann Weis (Consortium of Electro-chemical Industry GmbH). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim. 2003. xviii + 838 pp. $160.00. ISBN 3-527-30670-6. p 6501 DOI: 10.1021/ja033665k

Host-Guest-Systems Based on Nanoporous Crys-tals Edited by Franco Laeri (Technical University Darmstadt, Germany), Ferdi Schüth (Max-Planck-Institute of Coal Research, Mülheim an der Ruhr, Germany), Ulrich Simon (RWTH, Aachen, Germany), and Michael Wark (Hannover University, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. xxiv + 662 pp. $220.00. ISBN 3-527-30501-7. Roger G. Harrison p 6501 DOI: 10.1021/ja0336731

Dendrimers V:  Functional and Hyperbranched Building Blocks, Photophysical Properties, Applications in Materials and Life Sciences Edited by Christoph A. Schalley and Fritz Vögtle (University of Bonn). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xii + 274 pp. $239.00. ISBN 3-540-00669-9. Jon R. Parquette pp 6501–6502 DOI: 10.1021/ja033628t

Issue 21

Rewiring Cell Adhesion Mihoko Kato and Milan Mrksich pp 6504–6505 DOI: 10.1021/ja039058e Supporting Info

Self-Assembly of C3h and Cs Symmetric Keto-enamine Forms of Tris(N-salicyl-ideneanilines) into Columnar Phases: A New Family of Discotic Liquid Crystals Channabasaveshwar V. Yelamaggad, Ammathnadu S. Achalkumar, Doddamane S. Shankar Rao, and Subbarao Krishna Prasad pp 6506–6507 DOI: 10.1021/ja0495967 Supporting Info

An Addressable Antibody Nanoarray Produced on a Nanostructured Surface Andreas Bruckbauer, Dejian Zhou, Dae-Joon Kang, Yuri E. Korchev, Chris Abell, and David Klenerman pp 6508–6509 DOI: 10.1021/ja0317426 Supporting Info

Synthesis and Characterization of the Non-Kekulé, Singlet Biradicaloid Ar‘Ge(μ-NSiMe3)2GeAr‘ (Ar‘ = 2,6-Dipp2C6H3, Dipp = 2,6-i-Pr2C6H3) Chunming Cui, Marcin Brynda, Marilyn M. Olmstead, and Philip P. Power pp 6510–6511 DOI: 10.1021/ja0492182 Supporting Info

Creating Fluid and Air-Stable Solid Supported Lipid Bilayers Matthew A. Holden, Seung-Yong Jung, Tinglu Yang, Edward T. Castellana, and Paul S. Cremer pp 6512–6513 DOI: 10.1021/ja048504a Supporting Info

Multistep Energy Transfer in Single Molecular Photonic Wires Mike Heilemann, Philip Tinnefeld, Gabriel Sanchez Mosteiro, Maria Garcia Parajo, Niek F. Van Hulst, and Markus Sauer pp 6514–6515 DOI: 10.1021/ja049351u Supporting Info

Cavitand-Based Nanoscale Coordination Cages Roberta Pinalli, Veronica Cristini, Valerio Sottili, Silvano Geremia, Mara Campagnolo, Andrea Caneschi, and Enrico Dalcanale pp 6516–6517 DOI: 10.1021/ja038694+ Supporting Info

Magic-Numbered Aun Clusters Protected by Glutathione Monolayers (n = 18, 21, 25, 28, 32, 39):  Isolation and Spectroscopic Characterization Yuichi Negishi, Yoshimitsu Takasugi, Seiichi Sato, Hiroshi Yao, Keisaku Kimura, and Tatsuya Tsukuda pp 6518–6519 DOI: 10.1021/ja0483589 Supporting Info

A Quantum Dot Conjugated Sugar Ball and Its Cellular Uptake. On the Size Effects of Endocytosis in the Subviral Region Fumio Osaki, Takuya Kanamori, Shinsuke Sando, Takashi Sera, and Yasuhiro Aoyama pp 6520–6521 DOI: 10.1021/ja048792a Supporting Info

Chalcogens as Terminal Ligands to Iron:  Synthesis and Structure of Complexes with FeIII−S and FeIII−Se Motifs Peter L. Larsen, Rajeev Gupta, Douglas R. Powell, and A. S. Borovik pp 6522–6523 DOI: 10.1021/ja049118w Supporting Info

Dynamic Helicity Inversion by Achiral Anion Stimulus in Synthetic Labile Cobalt(II) Complex Hiroyuki Miyake, Kana Yoshida, Hideki Sugimoto, and Hiroshi Tsukube pp 6524–6525 DOI: 10.1021/ja049130o Supporting Info

Definitive Evidence for the Contribution of Biradical Character in a Closed-Shell Molecule, Derivative of 1,4-Bis-(4,5-diphenylimidazol-2-ylidene)cyclohexa-2,5-diene Azusa Kikuchi, Fumiyasu Iwahori, and Jiro Abe pp 6526–6527 DOI: 10.1021/ja049423h Supporting Info

A Highly Discriminating Quencher-Free Molecular Beacon for Probing DNA Gil Tae Hwang, Young Jun Seo, and Byeang Hyean Kim pp 6528–6529 DOI: 10.1021/ja049795q Supporting Info

Salt-Dependent Heat Capacity Changes for RNA Duplex Formation Jennifer C. Takach, Peter J. Mikulecky, and Andrew L. Feig pp 6530–6531 DOI: 10.1021/ja0316263 Supporting Info

Electrochemical Detection of DNA Triplet Repeat Expansion Miroslav Fojta, Ludek Havran, Marie Vojtiskova, and Emil Palecek pp 6532–6533 DOI: 10.1021/ja048781h Supporting Info

Characterization of the Glycosyltransferase Activity of DesVII:  Analysis of and Implications for the Biosynthesis of Macrolide Antibiotics Svetlana A. Borisova, Lishan Zhao, Charles E. Melançon III, Chai-Lin Kao, and Hung-wen Liu pp 6534–6535 DOI: 10.1021/ja049967j Supporting Info

Identification of Nuclear Proteins that Interact with Platinum-Modified DNA by Photoaffinity Labeling Christiana Xin Zhang, Pamela V. Chang, and Stephen J. Lippard pp 6536–6537 DOI: 10.1021/ja049533o Supporting Info

Catalytic Asymmetric Vinylation of Ketones Hongmei Li and Patrick J. Walsh pp 6538–6539 DOI: 10.1021/ja049206g Supporting Info

Electron Conduction across Electrode-Immobilized Neutravidin Bound with Biotin-Labeled Ruthenium Pentaamine Sulay D. Jhaveri, Scott A. Trammell, Daniel A. Lowy, and Leonard M. Tender pp 6540–6541 DOI: 10.1021/ja037949g Supporting Info

Bimetallic Catalysis for Styrene Homopolymerization and Ethylene−Styrene Copolymerization. Exceptional Comonomer Selectivity and Insertion Regiochemistry Neng Guo, Liting Li, and Tobin J. Marks pp 6542–6543 DOI: 10.1021/ja048761f Supporting Info

Importance of Intermolecular Interactions in Assessing Hopping Mobilities in Organic Field Effect Transistors:  Pentacene versus Dithiophene-tetrathiafulvalene Stefan T. Bromley, Marta Mas-Torrent, Peter Hadley, and Concepció Rovira pp 6544–6545 DOI: 10.1021/ja049762a Supporting Info

Experimental Resolution of Early Steps in Protein Folding:  Testing Molecular Dynamics Simulations Dung M. Vu, Eric S. Peterson, and R. Brian Dyer pp 6546–6547 DOI: 10.1021/ja048416q

Oxidation of 5-Hydroxy-2‘-deoxyuridine into Isodialuric Acid, Dialuric Acid, and Hydantoin Products Johann Rivière, François Bergeron, Sébastien Tremblay, Didier Gasparutto, Jean Cadet, and J. Richard Wagner pp 6548–6549 DOI: 10.1021/ja049438f Supporting Info

Employing End-Functional Polythiophene To Control the Morphology of Nanocrystal−Polymer Composites in Hybrid Solar Cells Jinsong Liu, Toru Tanaka, Kevin Sivula, A. Paul Alivisatos, and Jean M. J. Fréchet pp 6550–6551 DOI: 10.1021/ja0489184 Supporting Info

Facile Formation of an Intrastrand Cross-Link Lesion between Cytosine and Guanine upon Pyrex-Filtered UV Light Irradiation of d(BrCG) and Duplex DNA Containing 5-Bromocytosine Yu Zeng and Yinsheng Wang pp 6552–6553 DOI: 10.1021/ja049760q Supporting Info

Homogeneous Palladium Catalyst Suppressing Pd Black Formation in Air Oxidation of Alcohols Tetsuo Iwasawa, Makoto Tokunaga, Yasushi Obora, and Yasushi Tsuji pp 6554–6555 DOI: 10.1021/ja031936l Supporting Info

Cross-Coupling of sp3 C−H Bonds and Alkenes:  Catalytic Cyclization of Alkene−Amide Substrates Brenton DeBoef, Stefan J. Pastine, and Dalibor Sames pp 6556–6557 DOI: 10.1021/ja049111e Supporting Info

Catalytic Asymmetric Synthesis of α-Amino Phosphonates Using Enantioselective Carbon−Carbon Bond-Forming Reactions Shū Kobayashi, Hiroshi Kiyohara, Yoshitaka Nakamura, and Ryosuke Matsubara pp 6558–6559 DOI: 10.1021/ja048791i Supporting Info

Mixed-Metal Metallocryptands. Short Metal−Metal Separations Strengthened by a Dipolar Interaction Vincent J. Catalano and Mark A. Malwitz pp 6560–6561 DOI: 10.1021/ja048800n Supporting Info

Two-Stage Dispersion Polymerization toward Monodisperse, Controlled Micrometer-Sized Copolymer Particles Jing-She Song, Frédéric Tronc, and Mitchell A. Winnik pp 6562–6563 DOI: 10.1021/ja048862d

Intramolecular Reductive Nitrosylation:  Reaction of Nitric Oxide and a Copper(II) Complex of a Cyclam Derivative with Pendant Luminescent Chromophores Kiyoshi Tsuge, Frank DeRosa, Mark D. Lim, and Peter C. Ford pp 6564–6565 DOI: 10.1021/ja049444b Supporting Info

(P)-Helicene Displays Chiral Selection in Binding to Z-DNA Yan Xu, You Xin Zhang, Hiroshi Sugiyama, Tomoko Umano, Hideji Osuga, and Kazuhiko Tanaka pp 6566–6567 DOI: 10.1021/ja0499748 Supporting Info

Enantiodifferentiating Photoaddition of Alcohols to 1,1-Diphenylpropene in Supercritical Carbon Dioxide:  Sudden Jump of Optical Yield at the Critical Density Yasuhiro Nishiyama, Masayuki Kaneda, Ryota Saito, Tadashi Mori, Takehiko Wada, and Yoshihisa Inoue pp 6568–6569 DOI: 10.1021/ja0494609 Supporting Info

Selective Extraction of Higher Fullerenes Using Cyclic Dimers of Zinc Porphyrins Yoshiaki Shoji, Kentaro Tashiro, and Takuzo Aida pp 6570–6571 DOI: 10.1021/ja0489947 Supporting Info

In Situ Gamma Ray-Initiated Polymerization To Stabilize Surface Micelles Xi Zhang, Mingfeng Wang, Tao Wu, Shichun Jiang, and Zhiqiang Wang pp 6572–6573 DOI: 10.1021/ja049431y Supporting Info

High-Frequency and -Field EPR of a Pseudo-octahedral Complex of High-Spin Fe(II):  Bis(2,2‘-bi-2-thiazoline)bis(isothiocyanato)iron(II) Andrew Ozarowski, S. A. Zvyagin, William M. Reiff, Joshua Telser, Louis-Claude Brunel, and J. Krzystek pp 6574–6575 DOI: 10.1021/ja048336m Supporting Info

Toward Fully Synthetic Glycoproteins by Ultimately Convergent Routes:  A Solution to a Long-Standing Problem J. David Warren, Justin S. Miller, Stacy J. Keding, and Samuel J. Danishefsky pp 6576–6578 DOI: 10.1021/ja0491836 Supporting Info

Ferrous Binding to the Multicopper Oxidases Saccharomyces cerevisiae Fet3p and Human Ceruloplasmin:  Contributions to Ferroxidase Activity Liliana Quintanar, Mark Gebhard, Tzu-Pin Wang, Daniel J. Kosman, and Edward I. Solomon pp 6579–6589 DOI: 10.1021/ja049220t Supporting Info

A Controlled Supramolecular Approach toward Cation-Specific Chemosensors:  Alkaline Earth Metal Ion-Driven Exciton Signaling in Squaraine Tethered Podands Easwaran Arunkumar, Parayali Chithra, and Ayyappanpillai Ajayaghosh pp 6590–6598 DOI: 10.1021/ja0393776 Supporting Info

Determination of the Bioavailability of Biotin Conjugated onto Shell Cross-Linked (SCK) Nanoparticles Kai Qi, Qinggao Ma, Edward E. Remsen, Christopher G. Clark, Jr., and Karen L. Wooley pp 6599–6607 DOI: 10.1021/ja039647k Supporting Info

Organic Spin Clusters:  Macrocyclic-Macrocyclic Polyarylmethyl Polyradicals with Very High Spin S = 5−13 Andrzej Rajca, Jirawat Wongsriratanakul, and Suchada Rajca pp 6608–6626 DOI: 10.1021/ja031549b Supporting Info

Divalent Binding of a Bis(adamantyl)-Functionalized Calix[4]arene to β-cyclodextrin-based Hosts:  An Experimental and Theoretical Study on Multivalent Binding in Solution and at Self-Assembled Monolayers Alart Mulder, Tommaso Auletta, Andrea Sartori, Susanna Del Ciotto, Alessandro Casnati, Rocco Ungaro, Jurriaan Huskens, and David N. Reinhoudt pp 6627–6636 DOI: 10.1021/ja0317168 Supporting Info

Dynamic Devices. Shape Switching and Substrate Binding in Ion-Controlled Nanomechanical Molecular Tweezers Anne Petitjean, Richard G. Khoury, Nathalie Kyritsakas, and Jean-Marie Lehn pp 6637–6647 DOI: 10.1021/ja031915r Supporting Info

Self-Assembly of Irregular Graphs Whose Edges Are DNA Helix Axes Phiset Sa-Ardyen, Natasha Jonoska, and Nadrian C. Seeman pp 6648–6657 DOI: 10.1021/ja049953d Supporting Info

Homologous Series of Dendronized Polymethacrylates with a Methyleneoxycarbonyl Spacer between the Backbone and Dendritic Side Chain:  Synthesis, Characterization, and Some Bulk Properties Afang Zhang, Lidia Okrasa, Tadeusz Pakula, and A. Dieter Schlüter pp 6658–6666 DOI: 10.1021/ja0494205 Supporting Info

Synthesis of Atomically Ordered AuCu and AuCu3 Nanocrystals from Bimetallic Nanoparticle Precursors Amandeep K. Sra and Raymond E. Schaak pp 6667–6672 DOI: 10.1021/ja031547r

Kinetic and Mechanistic Investigations of Hydrothermal Transformations in Zinc Phosphates Alexander J. Norquist and Dermot O'Hare pp 6673–6679 DOI: 10.1021/ja049860w

Activation of the Sulfhydryl Group by Mo Centers:  Kinetics of Reaction of Benzyl Radical with a Binuclear Mo(μ-SH)Mo Complex and with Arene and Alkane Thiols James A. Franz, Jerome C. Birnbaum, Douglas S. Kolwaite, John C. Linehan, Donald M. Camaioni, and Michel Dupuis pp 6680–6691 DOI: 10.1021/ja049321r Supporting Info

Cyclic Perfluorocarbon Radicals and Anions Having High Global Warming Potentials (GWPs):  Structures, Electron Affinities, and Vibrational Frequencies Partha Pratim Bera, Ľuboš Horný, and Henry F. Schaefer III pp 6692–6702 DOI: 10.1021/ja0305297

Formation of Piezoelectric Single-Crystal Nanorings and Nanobows William L. Hughes and Zhong L. Wang pp 6703–6709 DOI: 10.1021/ja049266m

Intersystem Crossing versus Electron Transfer in Porphyrin-Based Donor−Bridge−Acceptor Systems:  Influence of a Paramagnetic Species Karin Pettersson, Kristine Kilså, Jerker Mårtensson, and Bo Albinsson pp 6710–6719 DOI: 10.1021/ja0370488 Supporting Info

Assignments of Carbon NMR Resonances for Microcrystalline Ubiquitin Tatyana I. Igumenova, Ann E. McDermott, Kurt W. Zilm, Rachel W. Martin, Eric K. Paulson, and A. Joshua Wand pp 6720–6727 DOI: 10.1021/ja030547o

Spin−Orbit-Induced Anomalous pH-Dependence in 1H NMR Spectra of CoIII Amine Complexes:  A Diagnostic Tool for Structure Elucidation Kaspar Hegetschweiler, Dirk Kuppert, Jochen Huppert, Michal Straka, and Martin Kaupp pp 6728–6738 DOI: 10.1021/ja0316723 Supporting Info

Competitive Na+ and Rb+ Binding in the Minor Groove of DNA Flaminia Cesare Marincola, Vladimir P. Denisov, and Bertil Halle pp 6739–6750 DOI: 10.1021/ja049930z

Proton-Mediated Dynamics of the Alkaline Conformational Transition of Yeast Iso-1-Cytochrome c Robert E. Martinez and Bruce E. Bowler pp 6751–6758 DOI: 10.1021/ja0494454 Supporting Info

Aza-Amino Acid Scan for Rapid Identification of Secondary Structure Based on the Application of N-Boc-Aza1-Dipeptides in Peptide Synthesis Rosa E. Melendez and William D. Lubell pp 6759–6764 DOI: 10.1021/ja039643f Supporting Info

Reduction of Strained Polycycles:  How Much Strain Can a Pyrene Anion Take? Ivan Aprahamian, Graham J. Bodwell, Jim J. Fleming, Greg P. Manning, Michael R. Mannion, Brad L. Merner, Tuvia Sheradsky, Rudolf J. Vermeij, and Mordecai Rabinovitz pp 6765–6775 DOI: 10.1021/ja040039u

Transformation of Zirconocene−Olefin Complexes into Zirconocene Allyl Hydride and Their Use as Dual Nucleophilic Reagents:  Reactions with Acid Chloride and 1,4-Diketone Kazuya Fujita, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima pp 6776–6783 DOI: 10.1021/ja049184y Supporting Info

A Model for Describing the Thermodynamics of Multivalent Host−Guest Interactions at Interfaces Jurriaan Huskens, Alart Mulder, Tommaso Auletta, Christian A. Nijhuis, Manon J. W. Ludden, and David N. Reinhoudt pp 6784–6797 DOI: 10.1021/ja049085k

Mixed Complexes Formed by Lithioacetonitrile and Chiral Lithium Amides:  Observation of 6Li,15N and 6Li,13C Couplings Due to Both C−Li and N−Li Contacts Richard Sott, Johan Granander, and Göran Hilmersson pp 6798–6805 DOI: 10.1021/ja0388461

Transition Metal-Stabilized Arenium Cations:  Protonation of Arenes Dihapto-Coordinated to π-Basic Metal Fragments Joseph M. Keane, Mahendra D. Chordia, Christopher J. Mocella, Michal Sabat, Carl O. Trindle, and W. Dean Harman pp 6806–6815 DOI: 10.1021/ja039824h Supporting Info

Experimental and Theoretical Evidence for Homogeneous Catalysis in the Gas-Phase Reaction of SiH2 with H2O (and D2O):  A Combined Kinetic and Quantum Chemical Study Rosa Becerra, Nicola Goldberg, J. Pat Cannady, Matthew J. Almond, J. Steven Ogden, and Robin Walsh pp 6816–6824 DOI: 10.1021/ja049373g

Anisotropic In-Plane Gradients of Poly(acrylic acid) Formed by Electropolymerization with Spatiotemporal Control of the Electrochemical Potential Xuejun Wang and Paul W. Bohn pp 6825–6832 DOI: 10.1021/ja0400436

A Highly Potent Non-Nucleoside Adenosine Deaminase Inhibitor:  Efficient Drug Discovery by Intentional Lead Hybridization [J. Am. Chem. Soc. 2004, 126, 34−35]. Tadashi Terasaka, Takayoshi Kinoshita, Masako Kuno, and Isao Nakanishi p 6833 DOI: 10.1021/ja040807h

Synthesis of Surface Organopalladium Intermediates in Coupling Reactions:  The Mechanistic Insight. [J. Am. Chem. Soc. 2004, 126, 2292−2293]. Boyapati M. Choudary, Sateesh Madhi, Mannepalli L. Kantam, Bojja Sreedhar, and Yasuhiro Iwasawa p 6833 DOI: 10.1021/ja040808+

First Estimation of C4−H Bond Dissociation Energies of NADH and Its Radical Cation in Aqueous Solution [J. Am. Chem. Soc. 2003, 125, 15298−15299]. Xiao-Qing Zhu, Yuan Yang, Min Zhang, and Jin-Pei Cheng p 6833 DOI: 10.1021/ja0408092

Origin 7.5 OriginLab Corporation, One Roundhouse Plaza, Northampton, MA 01060. 1-800-969-7720. www.OriginLab.com. Suggested price $699.00 (retail, single user), $489.00 (educational, single user). Contact company for other pricing options. Timothy J. Smith and Keith J. Stevenson p 6834 DOI: 10.1021/ja040926x

Modern Methods of Drug Discovery Edited by Alexander Hillisch (EnTec GmbH) and Rolf Hilgenfeld (Institut für Molekulare Biotechnolgie e.V.). Birkhäuser Verlag:  Basel, Boston, Berlin. 2003. x + 292 pp. $149.00. ISBN 3-7643-6081-X. J. Phillip Bowen p 6835 DOI: 10.1021/ja033528n

Kirk-Othmer Encyclopedia of Chemical Technology, Fifth Edition Edited by Arza Seidel (John Wiley & Sons, Inc., Hoboken). John Wiley & Sons, Inc:  Hoboken. 2004. $5400 for prepaid set or $6075 for standing order. Online pricing based on needs of user. ISBN (set):  0-471-48810-0. p 6835 DOI: 10.1021/ja033679q

Electrokinetic Phenomena. Principles and Applications in Analytical Chemistry and Microchip Technology Edited by Anurag S. Rathore (Amgen, Inc., Thousand Oaks, CA) and Andras Guttman (Diversa Corporation, San Diego, CA). Marcel Dekker:  New York and Basel. 2004. xiv + 476 pp. $175.00. ISBN 0-8247-4306-7. Stuart Allison pp 6835–6836 DOI: 10.1021/ja040906v

Fundamental World of Quantum Chemistry:  A Tribute to the Memory of Per-Olov Löwdin, Volumes 1 and 2 Edited by Erkki J. Brändas (Uppsala University) and Eugene S. Kryachko (Bogoliubov Institute for Theoretical Physics, Kiev, and University of Leuven, Belgium). Kluwer Academic Publishers:  Dordrecht. 2003. xxxii + 678 pp (Volume 1) and xxxii + 696 pp (Volume 2). $450.00 (set). ISBN:  1-4020-1286-1 (set). Russell J. Boyd p 6836 DOI: 10.1021/ja0336269

Issue 22

Uranyl-Based Metallamacrocycles:  Tri- and Tetranuclear Complexes with (2R,3R,4S,5S)-Tetrahydrofurantetracarboxylic Acid Pierre Thuéry, Claude Villiers, Joël Jaud, Michel Ephritikhine, and Bernardo Masci pp 6838–6839 DOI: 10.1021/ja0485964 Supporting Info

High-Energy Intermediate or Stable Transition State Analogue:  Theoretical Perspective of the Active Site and Mechanism of β-Phosphoglucomutase Charles Edwin Webster pp 6840–6841 DOI: 10.1021/ja049232e Supporting Info

Catalytic Carbonylation of β-Lactones to Succinic Anhydrides Yutan D. Y. L. Getzler, Vinod Kundnani, Emil B. Lobkovsky, and Geoffrey W. Coates pp 6842–6843 DOI: 10.1021/ja048946m Supporting Info

Design of New Chiral Phase-Transfer Catalysts with Dual Functions for Highly Enantioselective Epoxidation of α,β-Unsaturated Ketones Takashi Ooi, Daisuke Ohara, Masazumi Tamura, and Keiji Maruoka pp 6844–6845 DOI: 10.1021/ja048600b Supporting Info

AND/OR Bimolecular Recognition Michito Yoshizawa, Masazumi Tamura, and Makoto Fujita pp 6846–6847 DOI: 10.1021/ja048860t Supporting Info

Unexpected Relationships between Structure and Function in α,β-Peptides:  Antimicrobial Foldamers with Heterogeneous Backbones Margaret A. Schmitt, Bernard Weisblum, and Samuel H. Gellman pp 6848–6849 DOI: 10.1021/ja048546z Supporting Info

Nanotube Molecular Transporters:  Internalization of Carbon Nanotube−Protein Conjugates into Mammalian Cells Nadine Wong Shi Kam, Theodore C. Jessop, Paul A. Wender, and Hongjie Dai pp 6850–6851 DOI: 10.1021/ja0486059 Supporting Info

Silver(I) 1,3-Butadiynediide and Two Related Silver(I) Double Salts Containing the C42- Dianion Liang Zhao and Thomas C. W. Mak pp 6852–6853 DOI: 10.1021/ja049772b Supporting Info

Controlling Synthesis of BiIn Dendritic Nanocrystals by Solution Dispersion Yanbao Zhao, Zhijun Zhang, Weimin Liu, Hongxin Dang, and Qunji Xue pp 6854–6855 DOI: 10.1021/ja031735h Supporting Info

Creation of a Shikimate Pathway Variant Ningqing Ran, K. M. Draths, and J. W. Frost pp 6856–6857 DOI: 10.1021/ja049730n Supporting Info

Isolation and Characterization of a Carbene Derivative of La@C82 Yutaka Maeda, Yoichiro Matsunaga, Takatsugu Wakahara, Satomi Takahashi, Takahiro Tsuchiya, Midori O. Ishitsuka, Tadashi Hasegawa, Takeshi Akasaka, Michael T. H. Liu, Kisato Kokura, Ernst Horn, Kenji Yoza, Tatsuhisa Kato, Shingo Okubo, Kaoru Kobayashi, Shigeru Nagase, and Kazunori Yamamoto pp 6858–6859 DOI: 10.1021/ja0316115 Supporting Info

Naked Deltahedral Silicon Clusters in Solution:  Synthesis and Characterization of Si93- and Si52- Jose M. Goicoechea and Slavi C. Sevov pp 6860–6861 DOI: 10.1021/ja0488075 Supporting Info

Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br) Haiping Xia, Guomei He, Hong Zhang, Ting Bin Wen, Herman H. Y. Sung, Ian D. Williams, and Guochen Jia pp 6862–6863 DOI: 10.1021/ja0486871 Supporting Info

Efficient Catalysis of Nazarov Cyclization Using a Cationic Iridium Complex Possessing Adjacent Labile Coordination Sites Mesfin Janka, Wei He, Alison J. Frontier, and Richard Eisenberg pp 6864–6865 DOI: 10.1021/ja049643v Supporting Info

The Structure and Conformational Behavior of Sulfonium Salt Glycosidase Inhibitors in Solution:  A Combined Quantum Mechanical NMR Approach Jorge Gonzalez-Outeiriño, John Glushka, Aloysius Siriwardena, and Robert J. Woods pp 6866–6867 DOI: 10.1021/ja049700k Supporting Info

Rare Example of Nucleophilic Substitution at Vinylic Carbon with Inversion:  Mechanism of Methyleneaziridine Formation by Sodium Amide Induced Ring Closure Revisited Jason J. Shiers, Michael Shipman, Jerome F. Hayes, and Alexandra M. Z. Slawin pp 6868–6869 DOI: 10.1021/ja0482684 Supporting Info

Enamines from Terminal Epoxides and Hindered Lithium Amides David M. Hodgson, Christopher D. Bray, and Nicholas D. Kindon pp 6870–6871 DOI: 10.1021/ja031770o Supporting Info

Antifungal Cyclopentenediones from Piper coruscans Xing-Cong Li, Daneel Ferreira, Melissa R. Jacob, Qifeng Zhang, Shabana I. Khan, Hala N. ElSohly, Dale G. Nagle, Troy J. Smillie, Ikhlas A. Khan, Larry A. Walker, and Alice M. Clark pp 6872–6873 DOI: 10.1021/ja048081c Supporting Info

Low-Temperature Synthesis of Hexagonal (Wurtzite) ZnS Nanocrystals Yuwen Zhao, Yong Zhang, Hao Zhu, George C. Hadjipanayis, and John Q. Xiao pp 6874–6875 DOI: 10.1021/ja048650g Supporting Info

Metallic Mesoporous Nanocomposites for Electrocatalysis Yi Ding, Mingwei Chen, and Jonah Erlebacher pp 6876–6877 DOI: 10.1021/ja0320119

Ultrasensitive ATP Detection Using Firefly Luciferase Entrapped in Sugar-Modified Sol−Gel-Derived Silica Jorge A. Cruz-Aguado, Yang Chen, Zheng Zhang, Nadine H. Elowe, Michael A. Brook, and John D. Brennan pp 6878–6879 DOI: 10.1021/ja0490424 Supporting Info

Mechanism and Stereochemistry of Enzymatic Cyclization of 24,30-Bisnor-2,3-oxidosqualene by Recombinant β-Amyrin Synthase Ikuro Abe, Yuichi Sakano, Megumi Sodeyama, Hideya Tanaka, Hiroshi Noguchi, Masaaki Shibuya, and Yutaka Ebizuka pp 6880–6881 DOI: 10.1021/ja0490368 Supporting Info

Binding Causes the Remote [5‘-3H]Thymidine Kinetic Isotope Effect in Human Thymidine Phosphorylase Matthew R. Birck and Vern L. Schramm pp 6882–6883 DOI: 10.1021/ja0492642

Highly Efficient Addition of Activated Methylene Compounds to Alkenes Catalyzed by Gold and Silver Xiaoquan Yao and Chao-Jun Li pp 6884–6885 DOI: 10.1021/ja0482637 Supporting Info

Electron Spin Dynamics in Photoexcited Diamagnetic and Paramagnetic Corroles Eli Stavitski, Alexander Berg, Tapan Ganguly, Atif Mahammed, Zeev Gross, and Haim Levanon pp 6886–6890 DOI: 10.1021/ja0306819

The Role of Ligand Displacement in Sm(II)−HMPA-Based Reductions Edamana Prasad, Brian W. Knettle, and Robert A. Flowers, II pp 6891–6894 DOI: 10.1021/ja049161j Supporting Info

Ruthenium-Catalyzed Cyclization of Epoxide with a Tethered Alkyne:  Formation of Ketene Intermediates via Oxygen Transfer from Epoxides to Terminal Alkynes Reniguntala J. Madhushaw, Ming-Yuan Lin, Shariar Md. Abu Sohel, and Rai-Shung Liu pp 6895–6899 DOI: 10.1021/ja049943c Supporting Info

Solution Structure of xDNA:  A Paired Genetic Helix with Increased Diameter Haibo Liu, Stephen R. Lynch, and Eric T. Kool pp 6900–6905 DOI: 10.1021/ja0497835 Supporting Info

Structural Mimicry of Retroviral Tat Proteins by Constrained β-Hairpin Peptidomimetics:  Ligands with High Affinity and Selectivity for Viral TAR RNA Regulatory Elements Zafiria Athanassiou, Ricardo L. A. Dias, Kerstin Moehle, Neil Dobson, Gabriele Varani, and John A. Robinson pp 6906–6913 DOI: 10.1021/ja0497680 Supporting Info

Multiple States of the Tyr318Leu Mutant of Dihydroorotate Dehydrogenase Revealed by Single-Molecule Kinetics Jue Shi, Bruce A. Palfey, Joe Dertouzos, Kaj Frank Jensen, Ari Gafni, and Duncan Steel pp 6914–6922 DOI: 10.1021/ja038902y

Efforts To Expand the Genetic Alphabet:  Identification of a Replicable Unnatural DNA Self-Pair Allison A. Henry, Anne Goldbech Olsen, Shigeo Matsuda, Chengzhi Yu, Bernhard H. Geierstanger, and Floyd E. Romesberg pp 6923–6931 DOI: 10.1021/ja049961u

The Hydrolysis of Urea and the Proficiency of Urease Guillermina Estiu and Kenneth M. Merz, Jr. pp 6932–6944 DOI: 10.1021/ja049327g

Mechanistic Studies of the Isomerization of Peroxynitrite to Nitrate Catalyzed by Distal Histidine Metmyoglobin Mutants Susanna Herold, Shivashankar Kalinga, Toshitaka Matsui, and Yoshihito Watanabe pp 6945–6955 DOI: 10.1021/ja0493300 Supporting Info

Effect of Side Chains on Turns and Helices in Peptides of β3-Aminoxy Acids Dan Yang, Yu-Hui Zhang, Bing Li, Dan-Wei Zhang, Jenny Chun-Yu Chan, Nian-Yong Zhu, Shi-Wei Luo, and Yun-Dong Wu pp 6956–6966 DOI: 10.1021/ja049976s Supporting Info

Structure-Selectivity Relationships and Structure for a Peptide-Based Enantioselective Acylation Catalyst Matthew B. Fierman, Daniel J. O'Leary, Wayne E. Steinmetz, and Scott J. Miller pp 6967–6971 DOI: 10.1021/ja049661c Supporting Info

Organic Spin Clusters. A Dendritic-Macrocyclic Poly(arylmethyl) Polyradical with Very High Spin of S = 10 and Its Derivatives:  Synthesis, Magnetic Studies, and Small-Angle Neutron Scattering Suchada Rajca, Andrzej Rajca, Jirawat Wongsriratanakul, Paul Butler, and Sung-min Choi pp 6972–6986 DOI: 10.1021/ja031548j Supporting Info

Ladder-Type Pentaphenylenes and Their Polymers:  Efficient Blue-Light Emitters and Electron-Accepting Materials via a Common Intermediate Josemon Jacob, Stefan Sax, Thomas Piok, Emil J. W. List, Andrew C. Grimsdale, and Klaus Müllen pp 6987–6995 DOI: 10.1021/ja0398823

A Model for Double Asymmetric Induction in the Stereocontrolled Reduction of Glycosyl α-Ketoesters with Oxazaborolidines W. Harb, M. F. Ruiz-López, F. Coutrot, C. Grison, and P. Coutrot pp 6996–7008 DOI: 10.1021/ja031778y Supporting Info

Anion-Directed Self-Assembly of Coordination Polymer into Tunable Secondary Structure Ho-Joong Kim, Wang-Cheol Zin, and Myongsoo Lee pp 7009–7014 DOI: 10.1021/ja049799v Supporting Info

Luminescent Organoboron Quinolate Polymers Yang Qin, Cynthia Pagba, Piotr Piotrowiak, and Frieder Jäkle pp 7015–7018 DOI: 10.1021/ja039133l Supporting Info

Colloidal Lithographic Nanopatterning via Reactive Ion Etching Dae-Geun Choi, Hyung Kyun Yu, Se Gyu Jang, and Seung-Man Yang pp 7019–7025 DOI: 10.1021/ja0319083 Supporting Info

Pincer Complex-Catalyzed Allylation of Aldehyde and Imine Substrates via Nucleophilic η1-Allyl Palladium Intermediates Niclas Solin, Johan Kjellgren, and Kálmán J. Szabó pp 7026–7033 DOI: 10.1021/ja049357j

Evidence for Epitaxial Arrangement and High Conformational Order of an Organic Monolayer on Si(111) by Sum Frequency Generation Spectroscopy Satoshi Nihonyanagi, Dai Miyamoto, Satoru Idojiri, and Kohei Uosaki pp 7034–7040 DOI: 10.1021/ja049911p

Solution-Processible Conjugated Electrophosphorescent Polymers Albertus J. Sandee, Charlotte K. Williams, Nicholas R. Evans, John E. Davies, Clare E. Boothby, Anna Köhler, Richard H. Friend, and Andrew B. Holmes pp 7041–7048 DOI: 10.1021/ja039445o Supporting Info

Monocyclopentadienylhydride Derivatives of Ruthenium:  Stereoselective Proton Transfer and Proton-Hydride Exchange in an Extremely Short Dihydrogen Bond Ester Cayuela, Félix A. Jalón, Blanca R. Manzano, Gustavo Espino, Walter Weissensteiner, and Kurt Mereiter pp 7049–7062 DOI: 10.1021/ja031926k Supporting Info

NMR Analysis of Surfaces and Interfaces in 2-nm CdSe Mia G. Berrettini, Gary Braun, Jerry G. Hu, and Geoffrey F. Strouse pp 7063–7070 DOI: 10.1021/ja037228h Supporting Info

Characterization of Complicated New Polymorphs of Chlorothalonil by X-ray Diffraction and Computer Crystal Structure Prediction Maryjane Tremayne, Leanne Grice, James C. Pyatt, Colin C. Seaton, Benson M. Kariuki, Helen H. Y. Tsui, Sarah L. Price, and Julian C. Cherryman pp 7071–7081 DOI: 10.1021/ja0498235 Supporting Info

Molecular and Electronic Structures by Design:  Tuning Symmetrical and Unsymmetrical Linear Trichromium Chains John F. Berry, F. Albert Cotton, Tongbu Lu, Carlos A. Murillo, Brian K. Roberts, and Xiaoping Wang pp 7082–7096 DOI: 10.1021/ja049055h Supporting Info

Polyaniline Nanowires on Si Surfaces Fabricated with DNA Templates Yufeng Ma, Jianming Zhang, Guojin Zhang, and Huixin He pp 7097–7101 DOI: 10.1021/ja039621t

Molecular Rectification:  Self-Assembled Monolayers in Which Donor−(π-Bridge)−Acceptor Moieties Are Centrally Located and Symmetrically Coupled to Both Gold Electrodes Geoffrey J. Ashwell, Wayne D. Tyrrell, and Anne J. Whittam pp 7102–7110 DOI: 10.1021/ja049633u

Role of Asp102 in the Catalytic Relay System of Serine Proteases:  A Theoretical Study Toyokazu Ishida and Shigeki Kato pp 7111–7118 DOI: 10.1021/ja030405u

Methyl Groups as Probes for Proteins and Complexes in In-Cell NMR Experiments Zach Serber, Wesley Straub, Lorenzo Corsini, Anson M. Nomura, Nobuhisa Shimba, Charles S. Craik, Paul Ortiz de Montellano, and Volker Dötsch pp 7119–7125 DOI: 10.1021/ja049977k

Electron Transport in Two-Dimensional Arrays of Gold Nanocrystals Investigated by Scanning Electrochemical Microscopy Peter Liljeroth, Daniël Vanmaekelbergh, Virginia Ruiz, Kyösti Kontturi, Hua Jiang, Esko Kauppinen, and Bernadette M. Quinn pp 7126–7132 DOI: 10.1021/ja0493188 Supporting Info

Enzyme-Catalyzed Bio-Pumping of Electrons into Au-Nanoparticles:  A Surface Plasmon Resonance and Electrochemical Study Oleg Lioubashevski, Vladimir I. Chegel, Fernando Patolsky, Eugenii Katz, and Itamar Willner pp 7133–7143 DOI: 10.1021/ja049275v

Electronic Control of the Regiochemistry in Palladium−Phosphine Catalyzed Intermolecular Heck Reactions Robert J. Deeth, Andrew Smith, and John M. Brown pp 7144–7151 DOI: 10.1021/ja0315098 Supporting Info

N1···N3 Hydrogen Bonds of A:U Base Pairs of RNA Are Stronger than Those of A:T Base Pairs of DNA [J. Am. Chem. Soc. 2004, 18, 5688−5689].  Ioannis Vakonakis and Andy C. LiWang p 7152 DOI: 10.1021/ja0408101

The Quantum Classical Theory By Gert D. Billing (University of Copenhagen). Oxford University Press:  New York. 2003. xii + 236 pp. $85.00. ISBN 0-19-514619-0. Randall S. Dumont p 7153 DOI: 10.1021/ja033600h

Catalysis from A to Z:  A Concise Encyclopedia. Second, Completely Revised, and Enlarged Edition Edited by Boy Cornils (Hofheim, Germany), Wolfgang A. Herrmann (Technical University of Munich), R. Schlögl (Fritz-Haber-Institute of the Max-Planck Society, Berlin), and Chi-Huey Wong (The Scripps Research Institute, La Jolla, CA). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. xxii + 840 pp. $145.00. ISBN:  3-527-30373-1. p 7153 DOI: 10.1021/ja0336628

Quinoxalines, Supplement II. The Chemistry of Heterocyclic Compounds, Volume 61 Series edited by Edward C. Taylor and Peter Wipf. By D. J. Brown (Australian National University, Canberra). John Wiley & Sons, Inc.:  Hoboken. 2004. xvi + 510 pp. $425.00. ISBN:  0-471-26495-4. pp 7153–7154 DOI: 10.1021/ja0409098

Analytical Method Validation and Instrument Performance Verification Edited by Chung Chow Chan (Eli Lilly Canada, Inc.), Herman Lam (GlaxoSmithKline Canada, Inc.), Y. C. Lee (Pantheon YM, Inc.), and Xue-Ming Zhang (Novex Pharma). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. x + 304 pp. $89.95. 0-471-25953-5. p 7154 DOI: 10.1021/ja040912r

Basic Principles in Applied Catalysis Edited by Manfred Baerns (Institut für Angewandte Chemistry, Berlin). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 558 pp. $189.00. ISBN:  3-540-40261-6. p 7154 DOI: 10.1021/ja040918g

Issue 23

One-Directional Crystal Growth in Charged Colloidal Silica Dispersions Driven by Diffusion of Base Junpei Yamanaka, Masako Murai, Yumie Iwayama, Masakastu Yonese, Kensaku Ito, and Tsutomu Sawada pp 7156–7157 DOI: 10.1021/ja049164w Supporting Info

Single-Cell Detection of Trans-Splicing Ribozyme In Vivo Activity Sumitaka Hasegawa, Jung W. Choi, and Jianghong Rao pp 7158–7159 DOI: 10.1021/ja049144u Supporting Info

Real Time Differentiation of G-Protein Coupled Receptor (GPCR) Agonist and Antagonist by Two Photon Fluorescence Laser Microscopy Minying Cai, Magda Stankova, Stephanie J. K. Pond, Alexander V. Mayorov, Joseph W. Perry, Henry I. Yamamura, Dev Trivedi, and Victor J. Hruby pp 7160–7161 DOI: 10.1021/ja049473m

Spontaneous Formation of Cadmium Hydroxide Nanostrands in Water Izumi Ichinose, Keiji Kurashima, and Toyoki Kunitake pp 7162–7163 DOI: 10.1021/ja049141h Supporting Info

A Solvent-Free, SeCN-/(SeCN)3- Based Ionic Liquid Electrolyte for High-Efficiency Dye-Sensitized Nanocrystalline Solar Cells Peng Wang, Shaik M. Zakeeruddin, Jacques-E. Moser, Robin Humphry-Baker, and Michael Grätzel pp 7164–7165 DOI: 10.1021/ja048472r Supporting Info

Sweeping Capillary Electrophoresis:  A Non-Stopped-Flow Method for Measuring Bimolecular Rate Constant of Complex Formation between Protein and DNA Victor Okhonin, Maxim Berezovski, and Sergey N. Krylov pp 7166–7167 DOI: 10.1021/ja0481124 Supporting Info

Reductive Desorption of Thiolate from Monolayer Protected Gold Clusters Bernadette M. Quinn and Kyösti Kontturi pp 7168–7169 DOI: 10.1021/ja048431v Supporting Info

Simultaneous Triggering of Protein Activity and Fluorescence Jean-Philippe Pellois, Michael E. Hahn, and Tom W. Muir pp 7170–7171 DOI: 10.1021/ja0499142 Supporting Info

Zirconocene-Mediated Intermolecular Coupling of One Molecule of Si-Tethered Diyne with Three Molecules of Organonitriles:  One-Pot Formation of Pyrrolo[3,2-c]pyridine Derivatives via Cleavage of CN Triple Bonds of Organonitriles Xiaohua Sun, Congyang Wang, Zhiping Li, Shiwei Zhang, and Zhenfeng Xi pp 7172–7173 DOI: 10.1021/ja0497173 Supporting Info

Isotope Effects in Photochemistry. 1. o-Nitrobenzyl Alcohol Derivatives Aurélien Blanc and Christian G. Bochet pp 7174–7175 DOI: 10.1021/ja049686b Supporting Info

Stabilization and Size Control of Gold Nanoparticles during Laser Ablation in Aqueous Cyclodextrins Jean-Philippe Sylvestre, Andrei V. Kabashin, Edward Sacher, Michel Meunier, and John H. T. Luong pp 7176–7177 DOI: 10.1021/ja048678s Supporting Info

Tuning Porphyrin/DNA Supramolecular Assemblies by Competitive Binding Luigi Monsù Scolaro, Andrea Romeo, and Robert F. Pasternack pp 7178–7179 DOI: 10.1021/ja049669m Supporting Info

Single- and Double-Linkage Isomerism in a Six-Coordinate Iron Porphyrin Containing Nitrosyl and Nitro Ligands Jonghyuk Lee, Andrey Yu. Kovalevsky, Irina V. Novozhilova, Kimberly A. Bagley, Philip Coppens, and George B. Richter-Addo pp 7180–7181 DOI: 10.1021/ja0488986 Supporting Info

α-Aminoallylation of Aldehydes with Ammonia:  Stereoselective Synthesis of Homoallylic Primary Amines Masaharu Sugiura, Keiichi Hirano, and Shū Kobayashi pp 7182–7183 DOI: 10.1021/ja049689o Supporting Info

Spatial Encoding and the Acquisition of High-Resolution NMR Spectra in Inhomogeneous Magnetic Fields Boaz Shapira and Lucio Frydman pp 7184–7185 DOI: 10.1021/ja048859u

Indium-Catalyzed Direct Chlorination of Alcohols Using Chlorodimethylsilane−Benzil as a Selective and Mild System Makoto Yasuda, Satoshi Yamasaki, Yoshiyuki Onishi, and Akio Baba pp 7186–7187 DOI: 10.1021/ja048688t Supporting Info

Evolution of Function in the Crotonase Superfamily:  The Stereochemical Course of the Reaction Catalyzed by 2-Ketocyclohexanecarboxyl-CoA Hydrolase Ellen D. Eberhard and John A. Gerlt pp 7188–7189 DOI: 10.1021/ja0482381

SmCP-Networked Films Obtained by in Situ Photopolymerization of Neat Reactive Banana-Shaped Liquid Crystals Joaquín Barberá, Nélida Gimeno, Laura Monreal, Rafael Piñol, M. Blanca Ros, and José Luis Serrano pp 7190–7191 DOI: 10.1021/ja048437k Supporting Info

Highly Efficient and Enantioselective Cyclization of Aromatic Imines via Directed C−H Bond Activation Reema K. Thalji, Jonathan A. Ellman, and Robert G. Bergman pp 7192–7193 DOI: 10.1021/ja0394986 Supporting Info

Changing Catalytic Activity during Colloidal Platinum Nanocatalysis Due to Shape Changes:  Electron-Transfer Reaction Radha Narayanan and Mostafa A. El-Sayed pp 7194–7195 DOI: 10.1021/ja0486061 Supporting Info

Diluting Abundant Spins by Isotope Edited Radio Frequency Field Assisted Diffusion Corey R. Morcombe, Vadim Gaponenko, R. Andrew Byrd, and Kurt W. Zilm pp 7196–7197 DOI: 10.1021/ja047919t

Acetylcholinesterase:  Enhanced Fluctuations and Alternative Routes to the Active Site in the Complex with Fasciculin-2 Jennifer M. Bui, Kaihsu Tai, and J. Andrew McCammon pp 7198–7205 DOI: 10.1021/ja0485715 Supporting Info

A Bifunctional Poly(ethylene glycol) Silane Immobilized on Metallic Oxide-Based Nanoparticles for Conjugation with Cell Targeting Agents Nathan Kohler, Glen E. Fryxell, and Miqin Zhang pp 7206–7211 DOI: 10.1021/ja049195r

Aristolochene Synthase:  Mechanistic Analysis of Active Site Residues by Site-Directed Mutagenesis Brunella Felicetti and David E. Cane pp 7212–7221 DOI: 10.1021/ja0499593 Supporting Info

Preparation and Characterization of Individual Peptide-Wrapped Single-Walled Carbon Nanotubes Vasiliki Zorbas, Alfonso Ortiz-Acevedo, Alan B. Dalton, Mario Miki Yoshida, Gregg R. Dieckmann, Rockford K. Draper, Ray H. Baughman, Miguel Jose-Yacaman, and Inga H. Musselman pp 7222–7227 DOI: 10.1021/ja049202b Supporting Info

Investigation of the Calcium-Binding Site of the Oxygen Evolving Complex of Photosystem II Using 87Sr ESEEM Spectroscopy Sun Hee Kim, Wolfgang Gregor, Jeffrey M. Peloquin, Marcin Brynda, and R. David Britt pp 7228–7237 DOI: 10.1021/ja030614e

Enhanced Hairpin Stability through Loop Design:  The Case of the Protein G B1 Domain Hairpin R. Matthew Fesinmeyer, F. Michael Hudson, and Niels H. Andersen pp 7238–7243 DOI: 10.1021/ja0379520 Supporting Info

The Selenocysteine-Substituted Blue Copper Center:  Spectroscopic Investigations of Cys112SeCys Pseudomonas aeruginosa Azurin Martina Ralle, Steven M. Berry, Mark J. Nilges, Matt D. Gieselman, Wilfred A. van der Donk, Yi Lu, and Ninian J. Blackburn pp 7244–7256 DOI: 10.1021/ja031821h

Design, Synthesis, and Photophysical Studies of a Porphyrin-Fullerene Dyad with Parachute Topology; Charge Recombination in the Marcus Inverted Region David I. Schuster, Peng Cheng, Peter D. Jarowski, Dirk M. Guldi, Chuping Luo, Luis Echegoyen, Soomi Pyo, Alfred R. Holzwarth, Silvia E. Braslavsky, René M. Williams, and Gudrun Klihm pp 7257–7270 DOI: 10.1021/ja038676s Supporting Info

Reaction Pathway and Stereoselectivity of Asymmetric Synthesis of Chrysanthemate with the Aratani C1-Symmetric Salicylaldimine−Copper Catalyst Katsuhiro Suenobu, Makoto Itagaki, and Eiichi Nakamura pp 7271–7280 DOI: 10.1021/ja031524c Supporting Info

An Empirical Backbone−Backbone Hydrogen-Bonding Potential in Proteins and Its Applications to NMR Structure Refinement and Validation Alexander Grishaev and Ad Bax pp 7281–7292 DOI: 10.1021/ja0319994 Supporting Info

A Simple Approach to Sensor Discovery and Fabrication on Self-Assembled Monolayers on Glass Lourdes Basabe-Desmonts, Joris Beld, Rebecca S. Zimmerman, Jordi Hernando, Petra Mela, María F. García Parajó, Niek F. van Hulst, Albert van den Berg, David N. Reinhoudt, and Mercedes Crego-Calama pp 7293–7299 DOI: 10.1021/ja049901o Supporting Info

Synthesis, Photophysics, Electrochemistry, Theoretical, and Transient Absorption Studies of Luminescent Copper(I) and Silver(I) Diynyl Complexes. X-ray Crystal Structures of [Cu3(μ-dppm)3(μ3-η1-CCCCPh)2]PF6 and [Cu3(μ-dppm)3(μ3-η1-CCCCH)2]PF6 Wing-Yin Lo, Chi-Ho Lam, Vivian Wing-Wah Yam, Nianyong Zhu, Kung-Kai Cheung, Sofiane Fathallah, Sabri Messaoudi, Boris Le Guennic, Samia Kahlal, and Jean-François Halet pp 7300–7310 DOI: 10.1021/ja049300x Supporting Info

Theoretical Study of the Relative Stability of Rotational Conformers of α and β-d-Glucopyranose in Gas Phase and Aqueous Solution Jose C. Corchado, María L. Sánchez, and Manuel A. Aguilar pp 7311–7319 DOI: 10.1021/ja0398767 Supporting Info

Multiple-Quantum Relaxation Dispersion NMR Spectroscopy Probing Millisecond Time-Scale Dynamics in Proteins:  Theory and Application Dmitry M. Korzhnev, Karin Kloiber, and Lewis E. Kay pp 7320–7329 DOI: 10.1021/ja049968b

Capture and Release of Proteins on the Nanoscale by Stimuli-Responsive Elastin-Like Polypeptide “Switches” Jinho Hyun, Woo-Kyung Lee, Nidhi Nath, Ashutosh Chilkoti, and Stefan Zauscher pp 7330–7335 DOI: 10.1021/ja049721e

Why Is Silver Catalytically Active for NO Reduction? A Unique Pathway via an Inverted (NO)2 Dimer Zhi-Pan Liu, Stephen J. Jenkins, and David A. King pp 7336–7340 DOI: 10.1021/ja049126c

One-Electron Oxidation of DNA:  The Effect of Replacement of Cytosine with 5-Methylcytosine on Long-Distance Radical Cation Transport and Reaction Sriram Kanvah and Gary B. Schuster pp 7341–7344 DOI: 10.1021/ja049468i

Dimer-of-Dimers Model for the Oxygen-Evolving Complex of Photosystem II. Synthesis and Properties of [MnIV4O5(terpy)4(H2O)2](ClO4)6 Hongyu Chen, J. W. Faller, Robert H. Crabtree, and Gary W. Brudvig pp 7345–7349 DOI: 10.1021/ja037389l Supporting Info

Reversible Dimerization of [5,6]-C60O Dmitri Tsyboulski, Dieter Heymann, Sergei M. Bachilo, Lawrence B. Alemany, and R. Bruce Weisman pp 7350–7358 DOI: 10.1021/ja048937d Supporting Info

Efficient Methods for the Preparation of Alkyl−Aryl and Symmetrical or Unsymmetrical Dialkyl Ethers between Alcohols and Phenols or Two Alcohols by Oxidation−Reduction Condensation Taichi Shintou and Teruaki Mukaiyama pp 7359–7367 DOI: 10.1021/ja0487877 Supporting Info

Continuous Chemoselective Methylation of Functionalized Amines and Diols with Supercritical Methanol over Solid Acid and Acid−Base Bifunctional Catalysts Tomoharu Oku, Yoshitaka Arita, Hideaki Tsuneki, and Takao Ikariya pp 7368–7377 DOI: 10.1021/ja048557s Supporting Info

Reactivity of the Indole Ring in Palladium(II) Complexes of 2N1O-Donor Ligands:  Cyclopalladation and π-Cation Radical Formation Takeshi Motoyama, Yuichi Shimazaki, Tatsuo Yajima, Yasuo Nakabayashi, Yoshinori Naruta, and Osamu Yamauchi pp 7378–7385 DOI: 10.1021/ja031587v Supporting Info

A Catalytic Synthesis of Thiosilanes and Silthianes:  Palladium Nanoparticle-Mediated Cross-Coupling of Silanes with Thio Phenyl and Thio Vinyl Ethers through Selective Carbon−Sulfur Bond Activation Mee-Kyung Chung and Marcel Schlaf pp 7386–7392 DOI: 10.1021/ja049386u Supporting Info

Observation of Molecules Adsorbed on III-V Semiconductor Quantum Dots by Surface-Enhanced Raman Scattering Lucia G. Quagliano pp 7393–7398 DOI: 10.1021/ja031640f

On the Nature of the Low-Lying Singlet States of 4-(Dimethyl-amino)benzonitrile Andreas Köhn and Christof Hättig pp 7399–7410 DOI: 10.1021/ja0490572 Supporting Info

Organic Reactions, Volume 63 Editor-in-Chief:  Larry E. Overman (University of California, Irvine). John Wiley & Sons, Inc.:  Hoboken. 2004. vii + 584 pp. $125.00. ISBN:  0-471-44532-0. p 7411 DOI: 10.1021/ja0409208

Differential Scanning Calorimetry, Second Edition By G. W. Höhne (Retired from the Universität Ulm), W. F. Hemminger (Physikalisch-Technische Bundesanstalt), and H.-J. Flammersheim (Universität Jena). Springer Verlag:  Berlin, Heidelberg, New York. 2003. xii + 298 pp. $149.00. ISBN 3-540-00467-X. Bernhard Wunderlich pp 7411–7412 DOI: 10.1021/ja0336271

Advances in Heterocyclic Chemistry, Volume 84 Edited by Alan R. Katritzky (University of Florida, Gainesville). Academic Press (an imprint of Elsevier):  San Diego, CA. 2003. x + 354 pp. $152.00. ISBN:  0-12-020784-2. Madeleine M. Joullié p 7412 DOI: 10.1021/ja033669p

Issue 24

Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis Reactions Soon Hyeok Hong, Michael W. Day, and Robert H. Grubbs pp 7414–7415 DOI: 10.1021/ja0488380 Supporting Info

Oligoacenes:  Theoretical Prediction of Open-Shell Singlet Diradical Ground States Michael Bendikov, Hieu M. Duong, Kyle Starkey, K. N. Houk, Emily A. Carter, and Fred Wudl pp 7416–7417 DOI: 10.1021/ja048919w Supporting Info

Proper and Improper Hydrogen Bonds in Metalloorganic Crystal Architecture:  Experimental Evidence in [CoCp2]+ and [FeCp2]+ Salts Eliano Diana and Pier Luigi Stanghellini pp 7418–7419 DOI: 10.1021/ja049665h Supporting Info

Extreme Stability of an Unsolvated α-Helix Motoya Kohtani, Thaddeus C. Jones, Jean E. Schneider, and Martin F. Jarrold pp 7420–7421 DOI: 10.1021/ja048766c

New Poly(d-glucaramidoamine)s Induce DNA Nanoparticle Formation and Efficient Gene Delivery into Mammalian Cells Yemin Liu, Laura Wenning, Matthew Lynch, and Theresa M. Reineke pp 7422–7423 DOI: 10.1021/ja049831l Supporting Info

A Functionalized, Deep Cavitand Catalyzes the Aminolysis of a Choline Derivative Arnaud Gissot and Julius Rebek, Jr. pp 7424–7425 DOI: 10.1021/ja049074r Supporting Info

Expeditious Assembly of Mesoscopic Metallocycles Hua Jiang and Wenbin Lin pp 7426–7427 DOI: 10.1021/ja049145m Supporting Info

Density Functional Theory Calculation of Indirect Nuclear Magnetic Resonance Spin−Spin Coupling Constants in C70 Juan E. Peralta, Verónica Barone, Gustavo E. Scuseria, and Rubén H. Contreras pp 7428–7429 DOI: 10.1021/ja048141e Supporting Info

Catalytic Beacons for the Detection of DNA and Telomerase Activity Yi Xiao, Valeri Pavlov, Tamara Niazov, Arnon Dishon, Moshe Kotler, and Itamar Willner pp 7430–7431 DOI: 10.1021/ja031875r Supporting Info

Stepwise Photocleavage of Two C−O Bonds of 1,8-Bis[(4-benzoylphenoxy)-methyl]naphthalene with Three-Step Excitation Using Three-Color, Three-Laser Flash Photolysis Xichen Cai, Masanori Sakamoto, Michihiro Hara, Sachiko Tojo, Akihiko Ouchi, Kiyohiko Kawai, Masayuki Endo, Mamoru Fujitsuka, and Tetsuro Majima pp 7432–7433 DOI: 10.1021/ja049007x Supporting Info

Electrochemical Control of CO/NO Ligand Exchange in a Triruthenium Cluster Monolayer Assembled on a Gold Electrode Surface Shen Ye, Wei Zhou, Masaaki Abe, Takuma Nishida, Longfei Cui, Kohei Uosaki, Masatoshi Osawa, and Yoichi Sasaki pp 7434–7435 DOI: 10.1021/ja049478j Supporting Info

Precursor-Directed Biosynthesis of Epothilone in Escherichia coli Christopher N. Boddy, Kinya Hotta, Martha Lovato Tse, R. Edward Watts, and Chaitan Khosla pp 7436–7437 DOI: 10.1021/ja048108s Supporting Info

Inclusion-Water-Cluster in a Three-Dimensional Superlattice of Gold Nanoparticles Suhua Wang, Hiroshi Yao, Seiichi Sato, and Keisaku Kimura pp 7438–7439 DOI: 10.1021/ja031822+ Supporting Info

Unusual Mesoporous SBA-15 with Parallel Channels Running along the Short Axis He Zhang, Junming Sun, Ding Ma, Xinhe Bao, Achim Klein-Hoffmann, Giesela Weinberg, Dangsheng Su, and Robert Schlögl pp 7440–7441 DOI: 10.1021/ja048630e Supporting Info

Silver-Catalyzed [2 + 2] Cycloadditions of Siloxy Alkynes Randy F. Sweis, Michael P. Schramm, and Sergey A. Kozmin pp 7442–7443 DOI: 10.1021/ja048251l Supporting Info

Ketone Deprotonation Mediated by Mono- and Heterobimetallic Alkali and Alkaline Earth Metal Amide Bases:  Structural Characterization of Potassium, Calcium, and Mixed Potassium−Calcium Enolates Xuyang He, Bruce C. Noll, Alicia Beatty, Robert E. Mulvey, and Kenneth W. Henderson pp 7444–7445 DOI: 10.1021/ja048750m Supporting Info

Effect of Chemical Oxidation on the Self-Assembly of Organometallic Block Copolymers Hany B. Eitouni and Nitash P. Balsara pp 7446–7447 DOI: 10.1021/ja048570c Supporting Info

Conversion of Aquifex aeolicus 3-Deoxy-d-manno-octulosonate 8-Phosphate Synthase, a Metalloenzyme, into a Nonmetalloenzyme Jingjing Li, Jing Wu, Angela S. Fleischhacker, and Ronald W. Woodard pp 7448–7449 DOI: 10.1021/ja0480872 Supporting Info

Direct Coupling of Indoles with Carbonyl Compounds:  Short, Enantioselective, Gram-Scale Synthetic Entry into the Hapalindole and Fischerindole Alkaloid Families Phil S. Baran and Jeremy M. Richter pp 7450–7451 DOI: 10.1021/ja047874w Supporting Info

Functional Mimicry of the Active Site of Carboxypeptidase A by a Molecular Imprinting Strategy:  Cooperativity of an Amidinium and a Copper Ion in a Transition-State Imprinted Cavity Giving Rise to High Catalytic Activity Jun-qiu Liu and Günter Wulff pp 7452–7453 DOI: 10.1021/ja048372l Supporting Info

Fiber Recruiting Peptides:  Noncovalent Decoration of an Engineered Protein Scaffold Maxim G. Ryadnov and Derek N. Woolfson pp 7454–7455 DOI: 10.1021/ja048144r Supporting Info

Synthesis of Square Gadolinium-Oxide Nanoplates Y. Charles Cao pp 7456–7457 DOI: 10.1021/ja0481676 Supporting Info

AuBr3-Catalyzed [4 + 2] Benzannulation between an Enynal Unit and Enol Naoki Asao, Haruo Aikawa, and Yoshinori Yamamoto pp 7458–7459 DOI: 10.1021/ja0477367 Supporting Info

Pd-Catalyzed Alkyl to Aryl Migration and Cyclization:  An Efficient Synthesis of Fused Polycycles via Multiple C−H Activation Qinhua Huang, Alessia Fazio, Guangxiu Dai, Marino A. Campo, and Richard C. Larock pp 7460–7461 DOI: 10.1021/ja047980y Supporting Info

Dissecting Ramoplanin:  Mechanistic Analysis of Synthetic Ramoplanin Analogues as a Guide to the Design of Improved Antibiotics Lan Chen, Yanqiu Yuan, Jeremiah S. Helm, Yanan Hu, Yosup Rew, Dongwoo Shin, Dale L. Boger, and Suzanne Walker pp 7462–7463 DOI: 10.1021/ja047879t

Alanine Racemase Free Energy Profiles from Global Analyses of Progress Curves M. Ashley Spies, Joshua J. Woodward, Mitchell R. Watnik, and Michael D. Toney pp 7464–7475 DOI: 10.1021/ja049579h Supporting Info

Homo-N-oligonucleotides (N1/N9−C1‘ Methylene Bridge Oligonucleotides):  Nucleic Acids with Left-Handed Helicity Kouichi Ishiyama, Gerald E. Smyth, Toshihiro Ueda, Yutaka Masutomi, Tadaaki Ohgi, and Junichi Yano pp 7476–7485 DOI: 10.1021/ja049865t

Single Crystal X- and Q-Band EPR Spectroscopy of a Binuclear Mn2(III,IV) Complex Relevant to the Oxygen-Evolving Complex of Photosystem II Junko Yano, Kenneth Sauer, Jean-Jacques Girerd, and Vittal K. Yachandra pp 7486–7495 DOI: 10.1021/ja038218j Supporting Info

Partitioning of Dual-Lipidated Peptides into Membrane Microdomains:  Lipid Sorting vs Peptide Aggregation Sascha Janosch, Chiara Nicolini, Björn Ludolph, Carsten Peters, Martin Völkert, Theodore L. Hazlet, Enrico Gratton, Herbert Waldmann, and Roland Winter pp 7496–7503 DOI: 10.1021/ja049922i

Hybrid QM/MM Study of Thio Effects in Transphosphorylation Reactions:  The Role of Solvation Brent A. Gregersen, Xabier Lopez, and Darrin M. York pp 7504–7513 DOI: 10.1021/ja031815l Supporting Info

Determination of the Absolute Configuration of [32](1,4)Barrelenophanedicarbonitrile Using Concerted Time-Dependent Density Functional Theory Calculations of Optical Rotation and Electronic Circular Dichroism P. J. Stephens, D. M. McCann, F. J. Devlin, J. R. Cheeseman, and M. J. Frisch pp 7514–7521 DOI: 10.1021/ja049185q Supporting Info

Self-Assembling Peptide as a Potential Carrier of Hydrophobic Compounds Christine Keyes-Baig, Jean Duhamel, Shan-Yu Fung, Jeremy Bezaire, and P. Chen pp 7522–7532 DOI: 10.1021/ja0381297

Supramolecular Assemblies of Nucleoside Phosphocholine Amphiphiles Louis Moreau, Philippe Barthélémy, Mohamed El Maataoui, and Mark W. Grinstaff pp 7533–7539 DOI: 10.1021/ja039597j Supporting Info

Synthesis of a Malaria Candidate Glycosylphosphatidylinositol (GPI) Structure:  A Strategy for Fully Inositol Acylated and Phosphorylated GPIs Jun Lu, K. N. Jayaprakash, Urs Schlueter, and Bert Fraser-Reid pp 7540–7547 DOI: 10.1021/ja038807p Supporting Info

Elimination−Addition Mechanism for Nucleophilic Substitution Reaction of Cyclohexenyl Iodonium Salts and Regioselectivity of Nucleophilic Addition to the Cyclohexyne Intermediate Morifumi Fujita, Wan Hyeok Kim, Yuichi Sakanishi, Koji Fujiwara, Sayaka Hirayama, Tadashi Okuyama, Yasuhiro Ohki, Kazuyuki Tatsumi, and Yasunori Yoshioka pp 7548–7558 DOI: 10.1021/ja0496672 Supporting Info

Catalytic Asymmetric 1,4-Addition Reactions Using α,β-Unsaturated N-Acylpyrroles as Highly Reactive Monodentate α,β-Unsaturated Ester Surrogates Shigeki Matsunaga, Tomofumi Kinoshita, Shigemitsu Okada, Shinji Harada, and Masakatsu Shibasaki pp 7559–7570 DOI: 10.1021/ja0485917 Supporting Info

Water Adducts of BX3 and CX3+:  Implications for Structure, Bonding, and Reactivity Ingo Krossing and Ines Raabe pp 7571–7577 DOI: 10.1021/ja030274x Supporting Info

Chemistry of the t-Butoxyl Radical:  Evidence that Most Hydrogen Abstractions from Carbon are Entropy-Controlled Meghan Finn, Robert Friedline, N. Kamrudin Suleman, Christopher J. Wohl, and James M. Tanko pp 7578–7584 DOI: 10.1021/ja0493493 Supporting Info

Scandium Ion-Promoted Photoinduced Electron Transfer from Electron Donors to Acridine and Pyrene. Essential Role of Scandium Ion in Photocatalytic Oxygenation of Hexamethylbenzene Shunichi Fukuzumi, Junpei Yuasa, Naoya Satoh, and Tomoyoshi Suenobu pp 7585–7594 DOI: 10.1021/ja031649h Supporting Info

Reaction of Organosilicon Hydrides with Solid Surfaces:  An Example of Surface-Catalyzed Self-Assembly Roy Helmy, Robert W. Wenslow, and Alexander Y. Fadeev pp 7595–7600 DOI: 10.1021/ja0498336

Rhodium-Catalyzed Cycloisomerization of 1,6-Enynes with an Intramolecular Halogen Shift:  Reaction Scope and Mechanism Xiaofeng Tong, Dao Li, Zhaoguo Zhang, and Xumu Zhang pp 7601–7607 DOI: 10.1021/ja0498639 Supporting Info

Electrodeless Determination of the Trap Density, Decay Kinetics, and Charge Separation Efficiency of Dye-Sensitized Nanocrystalline TiO2 Jessica E. Kroeze, Tom J. Savenije, and John M. Warman pp 7608–7618 DOI: 10.1021/ja039303u

Iridium Luminophore Complexes for Unimolecular Oxygen Sensors Maria C. DeRosa, Derek J. Hodgson, Gary D. Enright, Brian Dawson, Christopher E. B. Evans, and Robert J. Crutchley pp 7619–7626 DOI: 10.1021/ja049872h Supporting Info

Electronic Structure Control of the Nucleophilicity of Transition Metal−Thiolate Complexes:  An Experimental and Theoretical Study Derek C. Fox, Adam T. Fiedler, Heather L. Halfen, Thomas C. Brunold, and Jason A. Halfen pp 7627–7638 DOI: 10.1021/ja039419q Supporting Info

Structural and Spectroscopic Studies on Pt···Pt and π−π Interactions in Luminescent Multinuclear Cyclometalated Platinum(II) Homologues Tethered by Oligophosphine Auxiliaries Wei Lu, Michael C. W. Chan, Nianyong Zhu, Chi-Ming Che, Chuannan Li, and Zheng Hui pp 7639–7651 DOI: 10.1021/ja039727o Supporting Info

Mixed Quantum Mechanical/Molecular Mechanical (QM/MM) Study of the Deacylation Reaction in a Penicillin Binding Protein (PBP) versus in a Class C β-Lactamase Benjamin F. Gherman, Shalom D. Goldberg, Virginia W. Cornish, and Richard A. Friesner pp 7652–7664 DOI: 10.1021/ja036879a Supporting Info

Probe-Induced Native Oxide Decomposition and Localized Oxidation on 6H-SiC (0001) Surface:  An Atomic Force Microscopy Investigation Xian Ning Xie, Hong Jing Chung, Hai Xu, Xin Xu, Chorng Haur Sow, and Andrew Thye Shen Wee pp 7665–7675 DOI: 10.1021/ja049560e

Electrochemical Catalysis of Styrene Epoxidation with Films of MnO2 Nanoparticles and H2O2 Laura Espinal, Steven L. Suib, and James F. Rusling pp 7676–7682 DOI: 10.1021/ja048940x Supporting Info

Standard Free Energy of Releasing a Localized Water Molecule from the Binding Pockets of Proteins:  Double-Decoupling Method Donald Hamelberg and J. Andrew McCammon pp 7683–7689 DOI: 10.1021/ja0377908

Substituent Effects in π−π Interactions:  Sandwich and T-Shaped Configurations Mutasem Omar Sinnokrot and C. David Sherrill pp 7690–7697 DOI: 10.1021/ja049434a Supporting Info

Adsorption and Reactions of C6 Hydrocarbons at High Pressures on Pt(111) Single-Crystal Surfaces Studied by Sum Frequency Generation Vibrational Spectroscopy:  Mechanisms of Isomerization and Dehydrocyclization of n-Hexane Minchul Yang and Gabor A. Somorjai pp 7698–7708 DOI: 10.1021/ja0361446 Supporting Info

Is There Hydrogen Scrambling in the Gas Phase? Energetic and Structural Determinants of Proton Mobility within Protein Ions Joshua K. Hoerner, Hui Xiao, Andras Dobo, and Igor A. Kaltashov pp 7709–7717 DOI: 10.1021/ja049513m

Carbazole Compounds as Host Materials for Triplet Emitters in Organic Light-Emitting Diodes:  Polymer Hosts for High-Efficiency Light-Emitting Diodes Addy van Dijken, Jolanda J. A. M. Bastiaansen, Nicole M. M. Kiggen, Bea M. W. Langeveld, Carsten Rothe, Andy Monkman, Ingrid Bach, Philipp Stössel, and Klemens Brunner pp 7718–7727 DOI: 10.1021/ja049771j Supporting Info

Glow Discharge Optical Emission Spectroscopy:  A Practical Guide By Thomas Nelis (Ste Croix, France) and Richard Payling (The University of Newcastle, Australia). Royal Society of Chemistry:  Cambridge. 2003. xii + 212 pp. $249.00. ISBN:  0-85404-521-X. R. Kenneth Marcus p 7728 DOI: 10.1021/ja0409154

Mesoscale Phenomena in Fluid Systems Edited by Fiona Case (Colgate Palmolive Company) and Paschalis Alexandridis (The State University of New York). American Chemical Society (distributed by Oxford University):  Washington, DC. 2003. xiv + 447 pp. $185.00. ISBN:  0-8412-3867-7. p 7728 DOI: 10.1021/ja040917o

Advances in Chemical Physics Volume 128 Edited by Stuart A. Rice (University of Chicago). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. x + 384 pp. $175.00. ISBN 0-471-44528-2. Robert E. Continetti pp 7728–7729 DOI: 10.1021/ja033675l

International Tables for Crystallography, Volume D:  Physical Properties of Crystals Edited by A. Authier (Université Pierre et Marie Curie). Published for the International Union of Crystallography by Kluwer Academic Publishers:  Dordrecht, The Netherlands. 2003. xii + 522 pp. $220. ISBN:  1-4020-0714-0. p 7729 DOI: 10.1021/ja0336832

An Introduction to Chemoinformatics By Andrew R. Leach (GlaxoSmithKline, Stevenage, U.K.) and Valerie J. Gillet (University of Sheffield, U.K.). Kluwer Academic Publishers:  Dordrecht. 2003. xvi + 260 pp. $74.00. ISBN:  1-4020-1347-7. Robert S. Pearlman pp 7729–7730 DOI: 10.1021/ja033604m

Studies in Natural Products Chemistry, Volume 29, Bioactive Natural Products (Part J) Edited by Atta-ur-Rahman (University of Karachi, Pakistan). Elsevier:  Amsterdam. 2003. xiv + 902 pp. $410. ISBN:  0-444-51510-0. p 7730 DOI: 10.1021/ja040927p

Annual Reports in Organic Synthesis 2003 Edited by Philip M. Weintraub (Aventis Pharmaceuticals, Bridgewater, NJ), Kenneth Turnbull (Wright State University), Jeffrey Sabol (Aventis Pharmaceuticals), and Peter Norris (Youngstown State University). Elsevier Academic Press:  San Diego, CA. 2003. xxiv + 408 pp. $105.00. ISBN:  0-12-040833-3. p 7730 DOI: 10.1021/ja040929+

Issue 25

Potentiometric Differentiation of Mono- and Macromolecular Thiol within Human Plasma at Carbon Fiber Electrodes Laura Yonge, Svetlana Gracheva, Shelley J. Wilkins, Callum Livingstone, and James Davis pp 7732–7733 DOI: 10.1021/ja048093y Supporting Info

The Origin of Protein Sidechain Order Parameter Distributions Robert B. Best, Jane Clarke, and Martin Karplus pp 7734–7735 DOI: 10.1021/ja049078w Supporting Info

A Chondroitin Sulfate Small Molecule that Stimulates Neuronal Growth Sarah E. Tully, Ross Mabon, Cristal I. Gama, Sherry M. Tsai, Xuewei Liu, and Linda C. Hsieh-Wilson pp 7736–7737 DOI: 10.1021/ja0484045 Supporting Info

Isotopomer Encapsulation in a Cylindrical Molecular Capsule:  A Probe for Understanding Noncovalent Isotope Effects on a Molecular Level Dalit Rechavi, Alessandro Scarso, and Julius Rebek, Jr. pp 7738–7739 DOI: 10.1021/ja048366p

Polyvalent Carbocyanine Molecular Beacons for Molecular Recognitions Yunpeng Ye, Sharon Bloch, and Samuel Achilefu pp 7740–7741 DOI: 10.1021/ja049441z Supporting Info

Organic Nitriles from Acid Chlorides:  An Isovalent N for (O)Cl Exchange Reaction Mediated by a Tungsten Nitride Complex Christopher R. Clough, Jane B. Greco, Joshua S. Figueroa, Paula L. Diaconescu, William M. Davis, and Christopher C. Cummins pp 7742–7743 DOI: 10.1021/ja0492438 Supporting Info

An Ultraviolet-Curable Mold for Sub-100-nm Lithography Se-Jin Choi, Pil J. Yoo, Seung J. Baek, Tae W. Kim, and Hong H. Lee pp 7744–7745 DOI: 10.1021/ja048972k Supporting Info

Measurement of Large Distances in Biomolecules Using Double-Quantum Filtered Refocused Electron Spin−Echoes Peter P. Borbat, Jared H. Davis, Samuel E. Butcher, and Jack H. Freed pp 7746–7747 DOI: 10.1021/ja049372o

Generation and Trapping of the 4-Biphenylyloxenium Ion by Water and Azide:  Comparisons with the 4-Biphenylylnitrenium Ion Michael Novak and Stephen A. Glover pp 7748–7749 DOI: 10.1021/ja047488e Supporting Info

Charge Storage Behavior of Nanowire Transistors Functionalized with Bis(terpyridine)−Fe(II) Molecules:  Dependence on Molecular Structure Chao Li, Wendy Fan, Daniel A. Straus, Bo Lei, Sylvia Asano, Daihua Zhang, Jie Han, M. Meyyappan, and Chongwu Zhou pp 7750–7751 DOI: 10.1021/ja049368c Supporting Info

Multipoint Recognition of Basic Proteins at a Membrane Model R. Zadmard, M. Arendt, and T. Schrader pp 7752–7753 DOI: 10.1021/ja049191m Supporting Info

Labeling Proteins with Small Molecules by Site-Specific Posttranslational Modification Jun Yin, Fei Liu, Xiaohua Li, and Christopher T. Walsh pp 7754–7755 DOI: 10.1021/ja047749k Supporting Info

The Inelastic Neutron Scattering Spectrum of H3B:NH3 and the Reproduction of Its Solid-State Features by Periodic DFT Damian G. Allis, Mark E. Kosmowski, and Bruce S. Hudson pp 7756–7757 DOI: 10.1021/ja048215m

Detection-Dependent Kinetics as a Probe of Folding Landscape Microstructure Wei Yuan Yang and Martin Gruebele pp 7758–7759 DOI: 10.1021/ja0493751 Supporting Info

Local Dynamic Amplitudes on the Protein Backbone from Dipolar Couplings: Toward the Elucidation of Slower Motions in Biomolecules Pau Bernadó and Martin Blackledge pp 7760–7761 DOI: 10.1021/ja048785m Supporting Info

Effect of Halo Substitution on the Geometry of Arenethiol Films on Cu(111) Kin Wong, Ki-Young Kwon, Bommisetty V. Rao, Anwei Liu, and Ludwig Bartels pp 7762–7763 DOI: 10.1021/ja048660h

Closer to the “Ideal Recoverable Catalyst” for Atom Transfer Radical Polymerization Using a Molecular Non-Fluorous Thermomorphic System Guillaume Barré, Daniel Taton, Dominique Lastécouères, and Jean-Marc Vincent pp 7764–7765 DOI: 10.1021/ja048096a Supporting Info

The Mechanism of Water Exchange in AmO2(H2O)52+ and in the Isoelectronic UO2(H2O)5+ and NpO2(H2O)52+ Complexes as Studied by Quantum Chemical Methods Valérie Vallet, Timofei Privalov, Ulf Wahlgren, and Ingmar Grenthe pp 7766–7767 DOI: 10.1021/ja0483544 Supporting Info

Enantio- and Diastereoselective, Stereospecific Mannich-Type Reactions in Water Tomoaki Hamada, Kei Manabe, and Shū Kobayashi pp 7768–7769 DOI: 10.1021/ja048607t Supporting Info

A Simple but Remarkably Effective Device for Forming the C8−C14 Polycyclic Ring System of Halichondrin B Kosuke Namba, Hyuk-Sang Jun, and Yoshito Kishi pp 7770–7771 DOI: 10.1021/ja047826b Supporting Info

Experimental Study of Water−Ice Catalyzed Thermal Isomerization of Cyanamide into Carbodiimide:  Implication for Prebiotic Chemistry Fabrice Duvernay, Thierry Chiavassa, Fabien Borget, and Jean-Pierre Aycard pp 7772–7773 DOI: 10.1021/ja048721b Supporting Info

Higher Valency Ion Substitution into the Manganese Oxide Framework Mihai Polverejan, Josanlet C. Villegas, and Steven L. Suib pp 7774–7775 DOI: 10.1021/ja048985y

Stereospecific Living Ziegler−Natta Polymerization via Rapid and Reversible Chloride Degenerative Transfer between Active and Dormant Sites Yonghui Zhang and Lawrence R. Sita pp 7776–7777 DOI: 10.1021/ja0492889 Supporting Info

Rapid Diffusion of CH4/H2 Mixtures in Single-Walled Carbon Nanotubes Haibin Chen and David S. Sholl pp 7778–7779 DOI: 10.1021/ja039462d Supporting Info

Reduced Reactivity of Aged Au Nanoparticles in Ligand Exchange Reactions Victor Chechik pp 7780–7781 DOI: 10.1021/ja048879w Supporting Info

Direct Catalytic Asymmetric Aldol-Tishchenko Reaction Vijay Gnanadesikan, Yoshihiro Horiuchi, Takashi Ohshima, and Masakatsu Shibasaki pp 7782–7783 DOI: 10.1021/ja047906f Supporting Info

Surface Passivation of Luminescent Colloidal Quantum Dots with Poly(Dimethylaminoethyl methacrylate) through a Ligand Exchange Process Xiao-Song Wang, Tieneke E. Dykstra, Mayrose R. Salvador, Ian Manners, Gregory D. Scholes, and Mitchell A. Winnik pp 7784–7785 DOI: 10.1021/ja0489339 Supporting Info

Radical Reactions of a Stable N-Heterocyclic Silylene:  EPR Study and DFT Calculation Boris Tumanskii, Pauline Pine, Yitzhak Apeloig, Nicholas J. Hill, and Robert West pp 7786–7787 DOI: 10.1021/ja049114r Supporting Info

Nickel-Catalyzed Cross-Couplings of Organosilicon Reagents with Unactivated Secondary Alkyl Bromides David A. Powell and Gregory C. Fu pp 7788–7789 DOI: 10.1021/ja047433c Supporting Info

Growth of Submicrometer-Scale Rectangular Parallelepiped Rutile TiO2 Films in Aqueous TiCl3 Solutions under Hydrothermal Conditions Eiji Hosono, Shinobu Fujihara, Keita Kakiuchi, and Hiroaki Imai pp 7790–7791 DOI: 10.1021/ja048820p Supporting Info

Highly Efficient Luminescent Organic Clusters with Quantum Dot-Like Properties Chaobin He, Yang Xiao, Junchao Huang, Tingting Lin, Khine Y. Mya, and Xinhai Zhang pp 7792–7793 DOI: 10.1021/ja049650j Supporting Info

Graphitic Molecules with Partial “Zig/Zag” Periphery Zhaohui Wang, Željko Tomović, Marcel Kastler, Ramona Pretsch, Fabrizia Negri, Volker Enkelmann, and Klaus Müllen pp 7794–7795 DOI: 10.1021/ja048580d Supporting Info

A Simultaneous Redox, Alkylation, Self-Assembly Reaction under Solvothermal Conditions Afforded a Luminescent Copper(I) Chain Polymer Constructed of Cu3I4- and EtS-4-C5H4N+Et Components (Et = CH3CH2) Jian-Kai Cheng, Yuan-Gen Yao, Jian Zhang, Zhao-Ji Li, Zong-Wei Cai, Xiang-You Zhang, Zhong-Ning Chen, Yu-Biao Chen, Yao Kang, Ye-Yan Qin, and Yi-Hang Wen pp 7796–7797 DOI: 10.1021/ja048624i Supporting Info

A New Ru Complex Capable of Catalytically Oxidizing Water to Molecular Dioxygen Cristina Sens, Isabel Romero, Montserrat Rodríguez, Antoni Llobet, Teodor Parella, and Jordi Benet-Buchholz pp 7798–7799 DOI: 10.1021/ja0486824 Supporting Info

Chemistry of Covalent Inhibition of the Gastric (H+, K+)-ATPase by Proton Pump Inhibitors Jai Moo Shin, Young Moon Cho, and George Sachs pp 7800–7811 DOI: 10.1021/ja049607w Supporting Info

A Cubic Arrangement of DNA Double Helices Based on Nickel−Guanine Interactions Núria Valls, Isabel Usón, Catherine Gouyette, and Juan A. Subirana pp 7812–7816 DOI: 10.1021/ja049393i

Selective Catalysis with Peptide Dendrimers Céline Douat-Casassus, Tamis Darbre, and Jean-Louis Reymond pp 7817–7826 DOI: 10.1021/ja049276n Supporting Info

Molecular Imprinting Made Easy Martha Sibrian-Vazquez and David A. Spivak pp 7827–7833 DOI: 10.1021/ja038961b Supporting Info

How Delocalized Is N,N,N‘,N‘-Tetraphenylphenylenediamine Radical Cation? An Experimental and Theoretical Study on the Electronic and Molecular Structure Adriana V. Szeghalmi, Marco Erdmann, Volker Engel, Michael Schmitt, Stephan Amthor, Volker Kriegisch, Gilbert Nöll, Rainer Stahl, Christoph Lambert, Dirk Leusser, Dietmar Stalke, Manfred Zabel, and Jürgen Popp pp 7834–7845 DOI: 10.1021/ja0395386 Supporting Info

Generation and Photoreactions of 2,4,6-Trinitreno-1,3,5-triazine, a Septet Trinitrene Tadatake Sato, Aiko Narazaki, Yoshizo Kawaguchi, Hiroyuki Niino, Götz Bucher, Dirk Grote, J. Jens Wolff, Hans Henning Wenk, and Wolfram Sander pp 7846–7852 DOI: 10.1021/ja031794v Supporting Info

Revelation of the Nature of the Reducing Species in Titanocene Halide-Promoted Reductions Rasmus Juel Enemærke, Jens Larsen, Troels Skrydstrup, and Kim Daasbjerg pp 7853–7864 DOI: 10.1021/ja0491230 Supporting Info

Oxidation of 2-Deoxyribose by Benzotriazinyl Radicals of Antitumor 3-Amino-1,2,4-benzotriazine 1,4-Dioxides Sujata S. Shinde, Robert F. Anderson, Michael P. Hay, Swarna A. Gamage, and William A. Denny pp 7865–7874 DOI: 10.1021/ja048740l

Rhodium-Catalyzed Reductive Cyclization of 1,6-Diynes and 1,6-Enynes Mediated by Hydrogen:  Catalytic C−C Bond Formation via Capture of Hydrogenation Intermediates Hye-Young Jang and Michael J. Krische pp 7875–7880 DOI: 10.1021/ja048498i Supporting Info

New Efficient Synthesis of Resorcinylic Macrolides via Ynolides:  Establishment of Cycloproparadicicol as Synthetically Feasible Preclinical Anticancer Agent Based on Hsp90 as the Target Zhi-Qiang Yang, Xudong Geng, David Solit, Christine A. Pratilas, Neal Rosen, and Samuel J. Danishefsky pp 7881–7889 DOI: 10.1021/ja0484348 Supporting Info

Photoaddition of Water and Alcohols to the Anthracene Moiety of 9-(2‘-Hydroxyphenyl)anthracene via Formal Excited State Intramolecular Proton Transfer Mitchel Flegel, Matthew Lukeman, Lawrence Huck, and Peter Wan pp 7890–7897 DOI: 10.1021/ja039078g

Energy Transfer Followed by Electron Transfer in a Supramolecular Triad Composed of Boron Dipyrrin, Zinc Porphyrin, and Fullerene:  A Model for the Photosynthetic Antenna-Reaction Center Complex Francis D'Souza, Phillip M. Smith, Melvin E. Zandler, Amy L. McCarty, Mitsunari Itou, Yasuyuki Araki, and Osamu Ito pp 7898–7907 DOI: 10.1021/ja030647u Supporting Info

Polymer Microgels:  Reactors for Semiconductor, Metal, and Magnetic Nanoparticles Jiguang Zhang, Shengqing Xu, and Eugenia Kumacheva pp 7908–7914 DOI: 10.1021/ja031523k Supporting Info

The Epitaxial Growth of Cholesterol Crystals from Bile Solutions on Calcite Substrates M. Crina Frincu, Sean D. Fleming, Andrew L. Rohl, and Jennifer A. Swift pp 7915–7924 DOI: 10.1021/ja0488030 Supporting Info

Structural Criteria for the Rational Design of Selective Ligands:  Convergent Hydrogen Bonding Sites for the Nitrate Anion Benjamin P. Hay, Maciej Gutowski, David A. Dixon, Jorge Garza, Rubicelia Vargas, and Bruce A. Moyer pp 7925–7934 DOI: 10.1021/ja0487980 Supporting Info

Doughnut-Shaped Peptide Nano-Assemblies and Their Applications as Nanoreactors Ramin Djalali, Jacopo Samson, and Hiroshi Matsui pp 7935–7939 DOI: 10.1021/ja0319691

Synthesis and Utilization of Monodisperse Hollow Polymeric Particles in Photonic Crystals Xiangling Xu and Sanford A. Asher pp 7940–7945 DOI: 10.1021/ja049453k

Orientational Distribution of CO before and after Photolysis of MbCO and HbCO:  A Determination Using Time-Resolved Polarized Mid-IR Spectroscopy Manho Lim, Timothy A. Jackson, and Philip A. Anfinrud pp 7946–7957 DOI: 10.1021/ja035475f Supporting Info

NMR Structure of a Cyclic Polyamide−DNA Complex Qing Zhang, Tammy J. Dwyer, Vickie Tsui, David A. Case, Junhyeong Cho, Peter B. Dervan, and David E. Wemmer pp 7958–7966 DOI: 10.1021/ja0373622 Supporting Info

A Computational Model Relating Structure and Reactivity in Enantioselective Oxidations of Secondary Alcohols by (−)-Sparteine−PdII Complexes Robert J. Nielsen, Jason M. Keith, Brian M. Stoltz, and William A. Goddard, III pp 7967–7974 DOI: 10.1021/ja031911m Supporting Info

Existence of Doubly Charged Lead Monohydrate:  Experimental Evidence and Theoretical Examination Tujin Shi, Galina Orlova, Jingzhong Guo, Diethard K. Bohme, Alan C. Hopkinson, and K. W. Michael Siu pp 7975–7980 DOI: 10.1021/ja049921q Supporting Info

Two-Dimensional Infrared Spectroscopy of Antiparallel β-Sheet Secondary Structure Nurettin Demirdöven, Christopher M. Cheatum, Hoi Sung Chung, Munira Khalil, Jasper Knoester, and Andrei Tokmakoff pp 7981–7990 DOI: 10.1021/ja049811j Supporting Info

Hydration Free Energies and Entropies for Water in Protein Interiors L. Renee Olano and Steven W. Rick pp 7991–8000 DOI: 10.1021/ja049701c

Proton-Coupled Electron Transfer of Flavodoxin Immobilized on Nanostructured Tin Dioxide Electrodes:  Thermodynamics versus Kinetics Control of Protein Redox Function Yeni Astuti, Emmanuel Topoglidis, Paul B. Briscoe, Andrea Fantuzzi, Gianfranco Gilardi, and James R. Durrant pp 8001–8009 DOI: 10.1021/ja0496470

Determinants of the Relative Reduction Potentials of Type-1 Copper Sites in Proteins Hui Li, Simon P. Webb, Joseph Ivanic, and Jan H. Jensen pp 8010–8019 DOI: 10.1021/ja049345y

Effect of Adlayer Structure on the Host−Guest Recognition between Calcium and Crown-Ether-Substituted Phthalocyanine Arrays on Au Single-Crystal Surfaces Soichiro Yoshimoto, Koji Suto, Akinori Tada, Nagao Kobayashi, and Kingo Itaya pp 8020–8027 DOI: 10.1021/ja048760n Supporting Info

Size-Selected Synthesis of PtRu Nano-Catalysts:  Reaction and Size Control Mechanism Christina Bock, Chantal Paquet, Martin Couillard, Gianluigi A. Botton, and Barry R. MacDougall pp 8028–8037 DOI: 10.1021/ja0495819

Selective Inhibition of Bovine Plasma Amine Oxidase by Homopropargylamine, a New Inactivator Motif Chunhua Qiao, Heung-Bae Jeon, and Lawrence M. Sayre pp 8038–8045 DOI: 10.1021/ja049568o

Selective Coupling of Methylene Groups at a Rh/Os Core, Yielding C2, C3, or C4 Fragments:  Roles of the Adjacent Metals in Carbon−Carbon Bond Formation Steven J. Trepanier, James N. L. Dennett, Brian T. Sterenberg, Robert McDonald, and Martin Cowie pp 8046–8058 DOI: 10.1021/ja040054z Supporting Info

Variation of Ser-L223 Hydrogen Bonding with the QB Redox State in Reaction Centers from Rhodobacter sphaeroides Hiroshi Ishikita and Ernst-Walter Knapp pp 8059–8064 DOI: 10.1021/ja038092q

Issue 26

Hydrogen Atom Transfer from Iron(II)−Tris[2,2‘-bi(tetrahydropyrimidine)] to TEMPO:  A Negative Enthalpy of Activation Predicted by the Marcus Equation Elizabeth A. Mader, Anna S. Larsen, and James M. Mayer pp 8066–8067 DOI: 10.1021/ja049246k Supporting Info

Carbonic Acid:  An Important Intermediate in the Surface Chemistry of Calcium Carbonate Hashim A. Al-Hosney and Vicki H. Grassian pp 8068–8069 DOI: 10.1021/ja0490774 Supporting Info

XANES Evidence Against a Manganyl Species in the S3 State of the Oxygen-Evolving Complex Tsu-Chien Weng, Wen-Yuan Hsieh, Erich S. Uffelman, Scott W. Gordon-Wylie, Terrence J. Collins, Vincent L. Pecoraro, and James E. Penner-Hahn pp 8070–8071 DOI: 10.1021/ja0494104 Supporting Info

Reaction of [2-(SiH3)C6H4]2SiH2 with Ni(Et2PCH2CH2PEt2)(PEt3)2: Characterization of η2-(Si−H)Ni and NiIV−H Complexes Wanzhi Chen, Shigeru Shimada, Masato Tanaka, Yuka Kobayashi, and Kazuhiko Saigo pp 8072–8073 DOI: 10.1021/ja039244k Supporting Info

Exceptionally Long-Range Self-Assembly of Hexa-peri-hexabenzocoronene with Dove-Tailed Alkyl Substituents Wojciech Pisula, Marcel Kastler, Daniel Wasserfallen, Tadeusz Pakula, and Klaus Müllen pp 8074–8075 DOI: 10.1021/ja048351r Supporting Info

The Role of Nonbonded Sulfur−Oxygen Interaction in the Dissociative Electron Transfer to Nitro-Substituted Arenesulfenyl Chlorides Chang Ji, John D. Goddard, and Abdelaziz Houmam pp 8076–8077 DOI: 10.1021/ja049575c Supporting Info

Adaptability at a Protein−DNA Interface:  Re-engineering the Engrailed Homeodomain to Recognize an Unnatural Nucleotide Matthew D. Simon and Kevan M. Shokat pp 8078–8079 DOI: 10.1021/ja048113w Supporting Info

Hydrogenation of Carbon Dioxide and Aryl Isocyanates by a Tetranuclear Tetrahydrido Yttrium Complex. Isolation, Structures, and CO2 Insertion Reactions of Methylene Diolate and μ3-Oxo Yttrium Complexes Olivier Tardif, Daisuke Hashizume, and Zhaomin Hou pp 8080–8081 DOI: 10.1021/ja047889u Supporting Info

Supramolecular Reactor from Self-Assembly of Rod−Coil Molecule in Aqueous Environment Myongsoo Lee, Cheong-Jin Jang, and Ja-Hyoung Ryu pp 8082–8083 DOI: 10.1021/ja048264z Supporting Info

Catalytic O2 Evolution from Water Induced by Adsorption of [(OH2)(Terpy)Mn(μ-O)2Mn(Terpy)(OH2)]3+ Complex onto Clay Compounds Masayuki Yagi and Komei Narita pp 8084–8085 DOI: 10.1021/ja039780c Supporting Info

On the Mechanism of Cs Promotion in Ethylene Epoxidation on Ag Suljo Linic and Mark A. Barteau pp 8086–8087 DOI: 10.1021/ja048462q Supporting Info

Biological Bottom-Up Assembly of Antibody Nanotubes on Patterned Antigen Arrays Nurxat Nuraje, Ipsita A. Banerjee, Robert I. MacCuspie, Lingtao Yu, and Hiroshi Matsui pp 8088–8089 DOI: 10.1021/ja048617u Supporting Info

Determination of Protein Structures Consistent with NMR Order Parameters Robert B. Best and Michele Vendruscolo pp 8090–8091 DOI: 10.1021/ja0396955 Supporting Info

Fabrication of “Hairy” Colloidosomes with Shells of Polymeric Microrods Paul F. Noble, Olivier J. Cayre, Rossitza G. Alargova, Orlin D. Velev, and Vesselin N. Paunov pp 8092–8093 DOI: 10.1021/ja047808u Supporting Info

Direct Observation of Competitive Adsorption between Methanol and Water on TiO2:  An in Situ Sum-Frequency Generation Study Chuan-yi Wang, Henning Groenzin, and Mary Jane Shultz pp 8094–8095 DOI: 10.1021/ja048165l Supporting Info

Actively Controlled Self-Assembly of Colloidal Crystals in Microfluidic Networks by Electrocapillary Forces Jau-Ye Shiu, Chun-Wen Kuo, and Peilin Chen pp 8096–8097 DOI: 10.1021/ja048059j Supporting Info

Nanometric Protein Arrays on Protein-Resistant Monolayers on Silicon Surfaces Jianhua Gu, Chi Ming Yam, Sha Li, and Chengzhi Cai pp 8098–8099 DOI: 10.1021/ja048405x Supporting Info

Evidence for a NiI Active Species in the Catalytic Cross-Coupling of Alkyl Electrophiles Thomas J. Anderson, Gavin D. Jones, and David A. Vicic pp 8100–8101 DOI: 10.1021/ja0483903 Supporting Info

Radio Frequency Magnetic Field Effects on a Radical Recombination Reaction:  A Diagnostic Test for the Radical Pair Mechanism Kevin B. Henbest, Philipp Kukura, Christopher T. Rodgers, P. J. Hore, and Christiane R. Timmel pp 8102–8103 DOI: 10.1021/ja048220q Supporting Info

Semiquinone Footprinting Chia-Hung Yang, Wen-Fu Chen, Ming-Chu Jong, Boh-Jun Jong, Jung-Cheng Chang, Michael J. Waring, Lin Ma, and Leung Sheh pp 8104–8105 DOI: 10.1021/ja040051m Supporting Info

Highly Enantioselective Cyanosilylation of Aldehydes Catalyzed by a Chiral Oxazaborolidinium Ion Do Hyun Ryu and E. J. Corey pp 8106–8107 DOI: 10.1021/ja0475959 Supporting Info

EXAFS Spectroscopic Evidence for an FeO Unit in the Fe(IV) Intermediate Observed during Oxygen Activation by Taurine:α-Ketoglutarate Dioxygenase Pamela J. Riggs-Gelasco, John C. Price, Robert B. Guyer, Jessica H. Brehm, Eric W. Barr, J. Martin Bollinger, Jr., and Carsten Krebs pp 8108–8109 DOI: 10.1021/ja048255q Supporting Info

Ring Synthesis by Stereoselective, Methylene-Free Enyne Cross Metathesis Amol A. Kulkarni and Steven T. Diver pp 8110–8111 DOI: 10.1021/ja0476922 Supporting Info

Observation of Selenium-77 Nuclear Magnetic Resonance in Octaneselenol-Protected Gold Nanoparticles Brian S. Zelakiewicz, Tetsu Yonezawa, and YuYe Tong pp 8112–8113 DOI: 10.1021/ja049532w

A Versatile Ruthenium Precursor for Biphasic Catalysis and Its Application in Ionic Liquid Biphasic Transfer Hydrogenation:  Conventional vs Task-Specific Catalysts Tilmann J. Geldbach and Paul J. Dyson pp 8114–8115 DOI: 10.1021/ja048886k Supporting Info

A General Solution-Phase Approach to Oriented Nanostructured Films of Metal Chalcogenides on Metal Foils:  The Case of Nickel Sulfide Lizhi Zhang, Jimmy C. Yu, Maosong Mo, Ling Wu, Quan Li, and Kwan Wai Kwong pp 8116–8117 DOI: 10.1021/ja0484505 Supporting Info

Spontaneous Formation of an Exfoliated Polystyrene−Clay Nanocomposite Using a Star-Shaped Polymer Douglas R. Robello, Nori Yamaguchi, Thomas Blanton, and Craig Barnes pp 8118–8119 DOI: 10.1021/ja048211h Supporting Info

Asymmetric Construction of Quaternary Stereocenters by Direct Organocatalytic Amination of α-Substituted α-Cyanoacetates and β-Dicarbonyl Compounds Steen Saaby, Marco Bella, and Karl Anker Jørgensen pp 8120–8121 DOI: 10.1021/ja047704j Supporting Info

The Perfect Penicillin? Inhibition of a Bacterial DD-Peptidase by Peptidoglycan-Mimetic β-Lactams Helen R. Josephine, Ish Kumar, and R. F. Pratt pp 8122–8123 DOI: 10.1021/ja048850s Supporting Info

Mesoscale Organization of CuO Nanoribbons:  Formation of “Dandelions” Bin Liu and Hua Chun Zeng pp 8124–8125 DOI: 10.1021/ja048195o Supporting Info

Catalytic Generation of Activated Carboxylates:  Direct, Stereoselective Synthesis of β-Hydroxyesters from Epoxyaldehydes Kenneth Yu-Kin Chow and Jeffrey W. Bode pp 8126–8127 DOI: 10.1021/ja047407e Supporting Info

N-Boc-l-Valine-Connected Amidomonophosphane Rhodium(I) Catalyst for Asymmetric Arylation of N-Tosylarylimines with Arylboroxines Masami Kuriyama, Takahiro Soeta, Xinyu Hao, Qian Chen, and Kiyoshi Tomioka pp 8128–8129 DOI: 10.1021/ja0475398 Supporting Info

Self-Assembled Tin-Based Bridged Hybrid Materials Hicham Elhamzaoui, Bernard Jousseaume, Hocine Riague, Thierry Toupance, Philippe Dieudonné, Cécile Zakri, Maryse Maugey, and Hassan Allouchi pp 8130–8131 DOI: 10.1021/ja048272f Supporting Info

Synthesis, Structure, and Reactivity of a Dinuclear Metal Complex with Linear M−H−M Bonding David A. Vicic, Thomas J. Anderson, John A. Cowan, and Arthur J. Schultz pp 8132–8133 DOI: 10.1021/ja047956k Supporting Info

Catalytic Enantioselective Synthesis of Sulfinate Esters through the Dynamic Resolution of tert-Butanesulfinyl Chloride Jared W. Evans, Matthew B. Fierman, Scott J. Miller, and Jonathan A. Ellman pp 8134–8135 DOI: 10.1021/ja047845l Supporting Info

Transamination Reactions with Multiple Turnovers Catalyzed by Hydrophobic Pyridoxamine Cofactors in the Presence of Polyethylenimine Polymers Lei Liu, Wenjun Zhou, Jason Chruma, and Ronald Breslow pp 8136–8137 DOI: 10.1021/ja048671a Supporting Info

Perfluoropentacene:  High-Performance p−n Junctions and Complementary Circuits with Pentacene Youichi Sakamoto, Toshiyasu Suzuki, Masafumi Kobayashi, Yuan Gao, Yasushi Fukai, Youji Inoue, Fumio Sato, and Shizuo Tokito pp 8138–8140 DOI: 10.1021/ja0476258 Supporting Info

De Novo Design of a D2-Symmetrical Protein that Reproduces the Diheme Four-Helix Bundle in Cytochrome bc1 Giovanna Ghirlanda, Artur Osyczka, Weixia Liu, Michael Antolovich, Kevin M. Smith, P. Leslie Dutton, A. Joshua Wand, and William F. DeGrado pp 8141–8147 DOI: 10.1021/ja039935g

Effects of the Photooxidant on DNA-Mediated Charge Transport Tashica T. Williams, Chikara Dohno, Eric D. A. Stemp, and Jacqueline K. Barton pp 8148–8158 DOI: 10.1021/ja049869y Supporting Info

Conformational Properties of Shape Modified Nucleosides − Fleximers Matjaž Polak, Katherine L. Seley, and Janez Plavec pp 8159–8166 DOI: 10.1021/ja0498078 Supporting Info

Spectroscopic and Computational Studies on the Adenosylcobalamin-Dependent Methylmalonyl-CoA Mutase:  Evaluation of Enzymatic Contributions to Co−C Bond Activation in the Co3+ Ground State Amanda J. Brooks, Monica Vlasie, Ruma Banerjee, and Thomas C. Brunold pp 8167–8180 DOI: 10.1021/ja039114b Supporting Info

A Study of α-Helix Hydration in Polypeptides, Proteins, and Viruses Using Vibrational Raman Optical Activity Iain H. McColl, Ewan W. Blanch, Lutz Hecht, and Laurence D. Barron pp 8181–8188 DOI: 10.1021/ja048991u

Reaction of the 1,8-Bis(diphenylmethylium)naphthalenediyl Dication with Fluoride:  Formation of a Cation Containing a C−F→C Bridge Huadong Wang, Charles Edwin Webster, Lisa M. Pérez, Michael B. Hall, and François P. Gabbaï pp 8189–8196 DOI: 10.1021/ja048501y Supporting Info

Nonspecific Medium Effects versus Specific Group Positioning in the Antibody and Albumin Catalysis of the Base-Promoted Ring-Opening Reactions of Benzisoxazoles Yunfeng Hu, K. N. Houk, Kazuya Kikuchi, Kinya Hotta, and Donald Hilvert pp 8197–8205 DOI: 10.1021/ja0490727

DNA-Mediated Exciton Coupling and Electron Transfer between Donor and Acceptor Stilbenes Separated by a Variable Number of Base Pairs Frederick D. Lewis, Yansheng Wu, Ligang Zhang, Xiaobing Zuo, Ryan T. Hayes, and Michael R. Wasielewski pp 8206–8215 DOI: 10.1021/ja048664m

Kinetic Resolution of Chiral α-Olefins Using Optically Active ansa-Zirconocene Polymerization Catalysts Cliff R. Baar, Christopher J. Levy, Endy Y.-J. Min, Lawrence M. Henling, Michael W. Day, and John E. Bercaw pp 8216–8231 DOI: 10.1021/ja040021j Supporting Info

Benzylidene Acetal Fragmentation Route to 6-Deoxy Sugars:  Direct Reductive Cleavage in the Presence of Ether Protecting Groups, Permitting the Efficient, Highly Stereocontrolled Synthesis of β-d-Rhamnosides from d-Mannosyl Glycosyl Donors. Total Synthesis of α-d-Gal-(1→3)-α-d-Rha-(1→3)- β-d-Rha-(1→4)-β-d-Glu-OMe, the Repeating Unit of the Antigenic Lipopolysaccharide from Escherichia hermannii ATCC 33650 and 33652 David Crich and Qingjia Yao pp 8232–8236 DOI: 10.1021/ja048070j Supporting Info

Kinetic and Thermodynamic Analysis of the Hydrolytic Ring-Opening of the Malondialdehyde−Deoxyguanosine Adduct, 3-(2‘-Deoxy-β-d-erythro-pentofuranosyl)- pyrimido[1,2-α]purin-10(3H)-one James N. Riggins, J. Scott Daniels, Carol A. Rouzer, and Lawrence J. Marnett pp 8237–8243 DOI: 10.1021/ja040009r Supporting Info

Pressure-Induced Buckling of Spin Ladder in SrCu2O3 Masaki Azuma, Hirofumi Yoshida, Takashi Saito, Takahiro Yamada, and Mikio Takano pp 8244–8246 DOI: 10.1021/ja049212c

Pyridinium-Derived N-Heterocyclic Carbene Complexes of Platinum:  Synthesis, Structure and Ligand Substitution Kinetics Jonathan S. Owen, Jay A. Labinger, and John E. Bercaw pp 8247–8255 DOI: 10.1021/ja040075t Supporting Info

Bistabilities in 1,3,2-Dithiazolyl Radicals Jaclyn L. Brusso, Owen P. Clements, Robert C. Haddon, Mikhail E. Itkis, Alicea A. Leitch, Richard T. Oakley, Robert W. Reed, and John F. Richardson pp 8256–8265 DOI: 10.1021/ja048618m Supporting Info

Activation of C−H / H−H Bonds by Rhodium(II) Porphyrin Bimetalloradicals Weihong Cui and Bradford B. Wayland pp 8266–8274 DOI: 10.1021/ja049291s Supporting Info

Hydration of Alumina Cluster Anions in the Gas Phase Anita K. Gianotto, Jennifer W. Rawlinson, Kevin C. Cossel, John E. Olson, Anthony D. Appelhans, and Gary S. Groenewold pp 8275–8283 DOI: 10.1021/ja0492945 Supporting Info

Self-Assembly of Supramolecular Light-Harvesting Arrays from Covalent Multi-Chromophore Perylene-3,4:9,10-bis(dicarboximide) Building Blocks Michael J. Ahrens, Louise E. Sinks, Boris Rybtchinski, Wenhao Liu, Brooks A. Jones, Jovan M. Giaimo, Alexy V. Gusev, Andrew J. Goshe, David M. Tiede, and Michael R. Wasielewski pp 8284–8294 DOI: 10.1021/ja039820c Supporting Info

Planar Nets of Ti Atoms Comprising Squares and Rhombs in the New Binary Antimonide Ti2Sb Shahab Derakhshan, Abdeljalil Assoud, Katja M. Kleinke, Enkhtsetseg Dashjav, Xiangyun Qiu, Simon J. L. Billinge, and Holger Kleinke pp 8295–8302 DOI: 10.1021/ja048262e Supporting Info

Electronically-Coupled Tungsten−Tungsten Quadruple Bonds:  Comparisons of Electron Delocalization in 3,6-Dioxypyridazine and Oxalate-Bridged Compounds Malcolm H. Chisholm, Robin J. H. Clark, Judith Gallucci, Christopher M. Hadad, and Nathan J. Patmore pp 8303–8313 DOI: 10.1021/ja048768x Supporting Info

Tunable Photonic Band Gap Crystals Based on a Liquid Crystal-Infiltrated Inverse Opal Structure Shoichi Kubo, Zhong-Ze Gu, Kazuyuki Takahashi, Akira Fujishima, Hiroshi Segawa, and Osamu Sato pp 8314–8319 DOI: 10.1021/ja0495056 Supporting Info

Ligand K-Edge X-ray Absorption Spectroscopy of [Fe4S4]1+,2+,3+ Clusters:  Changes in Bonding and Electronic Relaxation upon Redox Abhishek Dey, Thorsten Glaser, Manon M.-J. Couture, Lindsay D. Eltis, R. H. Holm, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 8320–8328 DOI: 10.1021/ja0484956 Supporting Info

Selective Reductive Desorption of a SAM-Coated Gold Electrode Revealed Using Fluorescence Microscopy Jeff L. Shepherd, Arnold Kell, Emily Chung, Chad W. Sinclar, Mark S. Workentin, and Dan Bizzotto pp 8329–8335 DOI: 10.1021/ja0494095 Supporting Info

Supramolecular Polymerization and Gel Formation of Bis(Merocyanine) Dyes Driven by Dipolar Aggregation Sheng Yao, Uwe Beginn, Tobias Gress, Marina Lysetska, and Frank Würthner pp 8336–8348 DOI: 10.1021/ja0496367 Supporting Info

Solvent Resistant Photocurable “Liquid Teflon” for Microfluidic Device Fabrication  [J. Am. Chem. Soc. 2004, 126, 2322−2323].  Jason P. Rolland, R. Michael Van Dam, Derek A. Schorzman, Stephen R. Quake, and Joseph M. DeSimone p 8349 DOI: 10.1021/ja040811t

The Theories of Chemistry By Jan C. A. Boeyens (University of Pretoria, South Africa) Elsevier:  Amsterdam. 2003. xiv + 556 pp. $190.00. ISBN 0-444-51491-0. Joel F. Liebman p 8350 DOI: 10.1021/ja0409006

Nonlinear Dynamics in Polymeric Systems Edited by John A. Pojman (University of Southern Mississippi) and Qui Tran-Cong-Miyata (Kyoto Institute of Technology). American Chemical Society (Distributed by Oxford University Press):  Washington, DC. 2004. xi + 352 pp. $145.00. ISBN:  0-8412-3850-2. p 8350 DOI: 10.1021/ja040922s

Issue 27

Asymmetric 1,4-Hydrosilylations of α,β-Unsaturated Esters Bruce H. Lipshutz, Jeff M. Servesko, and Benjamin R. Taft pp 8352–8353 DOI: 10.1021/ja049135l Supporting Info

An Unusual Mechanism of Glycoside Hydrolysis Involving Redox and Elimination Steps by a Family 4 β-Glycosidase from Thermotoga maritima Vivian L. Y. Yip, Annabelle Varrot, Gideon J. Davies, Shyamala S. Rajan, Xiaojing Yang, John Thompson, Wayne F. Anderson, and Stephen G. Withers pp 8354–8355 DOI: 10.1021/ja047632w Supporting Info

A Surprising Dipolar Cycloaddition Provides Ready Access to Aminoglycosides Russell S. Dahl and Nathaniel S. Finney pp 8356–8357 DOI: 10.1021/ja0319238 Supporting Info

Strong Blue Photoluminescence and ECL from OH-Terminated PAMAM Dendrimers in the Absence of Gold Nanoparticles Wan In Lee, Yoonjung Bae, and Allen J. Bard pp 8358–8359 DOI: 10.1021/ja0475914 Supporting Info

Time-Resolved Electrochemical Detection of Discrete Adsorption Events Bernadette M. Quinn, Pieter G. van 't Hof, and Serge G. Lemay pp 8360–8361 DOI: 10.1021/ja0478577 Supporting Info

A Predictive Pattern of Computed Barriers for C−H Hydroxylation by Compound I of Cytochrome P450 Sam P. de Visser, Devesh Kumar, Shimrit Cohen, Ronen Shacham, and Sason Shaik pp 8362–8363 DOI: 10.1021/ja048528h Supporting Info

Pyrene-Labeled Oligodeoxynucleotide Probe for Detecting Base Insertion by Excimer Fluorescence Emission Akimitsu Okamoto, Tomohisa Ichiba, and Isao Saito pp 8364–8365 DOI: 10.1021/ja049061d Supporting Info

Bridging the Gap between Homogeneous and Heterogeneous Catalysis:  Ortho/Para H2 Conversion, Hydrogen Isotope Scrambling, and Hydrogenation of Olefins by Ir(CO)Cl(PPh3)2 Jochen Matthes, Tal Pery, Stephan Gründemann, Gerd Buntkowsky, Sylviane Sabo-Etienne, Bruno Chaudret, and Hans-Heinrich Limbach pp 8366–8367 DOI: 10.1021/ja0475961 Supporting Info

A Four-Electron O2-Electroreduction Biocatalyst Superior to Platinum and a Biofuel Cell Operating at 0.88 V Valentine Soukharev, Nicolas Mano, and Adam Heller pp 8368–8369 DOI: 10.1021/ja0475510

A Small Aptamer with Strong and Specific Recognition of the Triphosphate of ATP Peter L. Sazani, Rosa Larralde, and Jack W. Szostak pp 8370–8371 DOI: 10.1021/ja049171k Supporting Info

A Polysaccharide Carrier for Immunostimulatory CpG DNAs To Enhance Cytokine Secretion Masami Mizu, Kazuya Koumoto, Takahisa Anada, Takahiro Matsumoto, Munenori Numata, Seiji Shinkai, Takeshi Nagasaki, and Kazuo Sakurai pp 8372–8373 DOI: 10.1021/ja031978+ Supporting Info

AFM-Induced Amine Deprotection:  Triggering Localized Bond Cleavage by Application of Tip/Substrate Voltage Bias for the Surface Self-Assembly of Nanosized Dendritic Objects Zachary M. Fresco, Itai Suez, Scott A. Backer, and Jean M. J. Fréchet pp 8374–8375 DOI: 10.1021/ja047774q Supporting Info

Direct Measurement of the Transbilayer Movement of Phospholipids by Sum-Frequency Vibrational Spectroscopy Jin Liu and John C. Conboy pp 8376–8377 DOI: 10.1021/ja048245p Supporting Info

57Fe ENDOR Spectroscopy on the Iron−Sulfur Cluster Involved in Substrate Reduction of Heterodisulfide Reductase Marina Bennati, Norbert Weiden, Klaus-P. Dinse, and Reiner Hedderich pp 8378–8379 DOI: 10.1021/ja0498179 Supporting Info

Hydrogen Titanate Nanofibers Covered with Anatase Nanocrystals:  A Delicate Structure Achieved by the Wet Chemistry Reaction of the Titanate Nanofibers Huaiyong Zhu, Xueping Gao, Ying Lan, Deying Song, Yingxin Xi, and Jincai Zhao pp 8380–8381 DOI: 10.1021/ja048204t Supporting Info

Iridium Complex-Catalyzed Highly Enantio- and Diastereoselective [2+2+2] Cycloaddition for the Synthesis of Axially Chiral Teraryl Compounds Takanori Shibata, Takayoshi Fujimoto, Kazuhisa Yokota, and Kentaro Takagi pp 8382–8383 DOI: 10.1021/ja048131d Supporting Info

First Principles Investigation of Vancomycin and Teicoplanin Binding to Bacterial Cell Wall Termini Jung-Goo Lee, Celeste Sagui, and Christopher Roland pp 8384–8385 DOI: 10.1021/ja048645c Supporting Info

All-Optical Orientation of Photoisomerizable Octupolar Zinc(II) Complexes in Polymer Films Lydie Viau, Sébastien Bidault, Olivier Maury, Sophie Brasselet, Isabelle Ledoux, Joseph Zyss, Eléna Ishow, Keitaro Nakatani, and Hubert Le Bozec pp 8386–8387 DOI: 10.1021/ja048143z Supporting Info

New Beginnings for Matrix Metalloproteinase Inhibitors:  Identification of High-Affinity Zinc-Binding Groups David T. Puerta, Jana A. Lewis, and Seth M. Cohen pp 8388–8389 DOI: 10.1021/ja0485513 Supporting Info

A Diversity-Oriented Strategy for the Construction of Tetrasubstituted Pyrroles via Coupled Domino Processes David Tejedor, David González-Cruz, Fernando García-Tellado, José Juan Marrero-Tellado, and Matías López Rodríguez pp 8390–8391 DOI: 10.1021/ja047396p Supporting Info

Isotopomeric Polymorphism Jun Zhou, Young-Sik Kye, and Gerard S. Harbison pp 8392–8393 DOI: 10.1021/ja0479843

One-Step Synthesis of FePt Nanoparticles with Tunable Size Min Chen, J. P. Liu, and Shouheng Sun pp 8394–8395 DOI: 10.1021/ja047648m Supporting Info

Total Synthesis, Structure Revision, and Absolute Configuration of (+)-Yatakemycin Mark S. Tichenor, David B. Kastrinsky, and Dale L. Boger pp 8396–8398 DOI: 10.1021/ja0472735 Supporting Info

Evidence for a Post-Translational Modification, Aspartyl Aldehyde, in a Photosynthetic Membrane Protein Lorraine B. Anderson, Anthony J. A. Ouellette, Julian Eaton-Rye, Melissa Maderia, Michael J. MacCoss, John R. Yates, III, and Bridgette A. Barry pp 8399–8405 DOI: 10.1021/ja0478781

Mononuclear Nickel(III) and Nickel(II) Thiolate Complexes with Intramolecular S−H Proton Interacting with Both Sulfur and Nickel:  Relevance to the [NiFe]/[NiFeSe] Hydrogenases Chien-Ming Lee, Chien-Hong Chen, Shyue-Chu Ke, Gene-Hsiang Lee, and Wen-Feng Liaw pp 8406–8412 DOI: 10.1021/ja048568l Supporting Info

Sequential Oxidation of the Cubane [4Fe−4S] Cluster from [4Fe−4S]- to [4Fe−4S]3+ in Fe4S4Ln- Complexes Hua-Jin Zhai, Xin Yang, You-Jun Fu, Xue-Bin Wang, and Lai-Sheng Wang pp 8413–8420 DOI: 10.1021/ja0498437

Effects of Glycosylation on Peptide Conformation:  A Synergistic Experimental and Computational Study Carlos J. Bosques, Sarah M. Tschampel, Robert J. Woods, and Barbara Imperiali pp 8421–8425 DOI: 10.1021/ja0496266 Supporting Info

Quantifying the Roughness on the Free Energy Landscape:  Entropic Bottlenecks and Protein Folding Rates Leslie L. Chavez, José N. Onuchic, and Cecilia Clementi pp 8426–8432 DOI: 10.1021/ja049510+ Supporting Info

UV Raman Demonstrates that α-Helical Polyalanine Peptides Melt to Polyproline II Conformations Sanford A. Asher, Alexander V. Mikhonin, and Sergei Bykov pp 8433–8440 DOI: 10.1021/ja049518j

Critical Role of Magnesium Ions in DNA Polymerase β's Closing and Active Site Assembly Linjing Yang, Karunesh Arora, William A. Beard, Samuel H. Wilson, and Tamar Schlick pp 8441–8453 DOI: 10.1021/ja049412o Supporting Info

Water Molecule Adsorption on Short Alanine Peptides:  How Short Is the Shortest Gas-Phase Alanine-Based Helix? Motoya Kohtani and Martin F. Jarrold pp 8454–8458 DOI: 10.1021/ja049298+

Functional Self-Assembling Bolaamphiphilic Polydiacetylenes as Colorimetric Sensor Scaffolds Jie Song, Justin S. Cisar, and Carolyn R. Bertozzi pp 8459–8465 DOI: 10.1021/ja039825+

Rearrangements Concerted with Fragmentation of Cyclopropylmethoxychlorocarbene and Cyclobutoxychlorocarbene in Hydrocarbon Solvents and Ar Matrices Robert A. Moss, Ronald R. Sauers, Fengmei Zheng, Xiaolin Fu, Thomas Bally, and Alexander Maltsev pp 8466–8476 DOI: 10.1021/ja049421x Supporting Info

Transparent Conducting Oxides:  Texture and Microstructure Effects on Charge Carrier Mobility in MOCVD-Derived CdO Thin Films Grown with A Thermally Stable, Low-Melting Precursor Andrew W. Metz, John R. Ireland, Jian-Guo Zheng, Ricardo P. S. M. Lobo, Yu Yang, Jun Ni, Charlotte L. Stern, Vinayak P. Dravid, Nicole Bontemps, Carl R. Kannewurf, Kenneth R. Poeppelmeier, and Tobin J. Marks pp 8477–8492 DOI: 10.1021/ja039232z Supporting Info

“Polysiloxane-Pd” Nanocomposites as Recyclable Chemoselective Hydrogenation Catalysts Bhanu P. S. Chauhan, Jitendra S. Rathore, and Tariq Bandoo pp 8493–8500 DOI: 10.1021/ja049604j Supporting Info

Cytochrome P450CAM Enzymatic Catalysis Cycle:  A Quantum Mechanics/Molecular Mechanics Study Victor Guallar and Richard A. Friesner pp 8501–8508 DOI: 10.1021/ja036123b

Mechanism, Selectivity Promotion, and New Ultraselective Pathways in Ag-Catalyzed Heterogeneous Epoxidation Federico J. Williams, Daniel P. C. Bird, Alejandra Palermo, Ashok K. Santra, and Richard M. Lambert pp 8509–8514 DOI: 10.1021/ja039378y

Structural Mining:  Self-Consistent Design on Flexible Protein−Peptide Docking and Transferable Binding Affinity Potential Zhijie Liu, Brian N. Dominy, and Eugene I. Shakhnovich pp 8515–8528 DOI: 10.1021/ja032018q Supporting Info

Ab Initio Study of 13Cα Chemical Shift Anisotropy Tensors in Peptides Jeff Birn, Alan Poon, Y. Mao, and A. Ramamoorthy pp 8529–8534 DOI: 10.1021/ja049879z Supporting Info

Fast Intramolecular Charge Transfer with a Planar Rigidized Electron Donor/Acceptor Molecule Toshitada Yoshihara, Sergey I. Druzhinin, and Klaas A. Zachariasse pp 8535–8539 DOI: 10.1021/ja049809s

Two-Dimensional Supramolecular Organization of Copper Octaethylporphyrin and Cobalt Phthalocyanine on Au(111):  Molecular Assembly Control at an Electrochemical Interface Soichiro Yoshimoto, Norihito Higa, and Kingo Itaya pp 8540–8545 DOI: 10.1021/ja0485210

Correlation between Crystal Structure and Mobility in Organic Field-Effect Transistors Based on Single Crystals of Tetrathiafulvalene Derivatives Marta Mas-Torrent, Peter Hadley, Stefan T. Bromley, Xavi Ribas, Judit Tarrés, Montserrat Mas, Elies Molins, Jaume Veciana, and Concepció Rovira pp 8546–8553 DOI: 10.1021/ja048342i Supporting Info

A Molecularly Imprinted Polymer-Based Synthetic Transaminase Johan Svenson, Ning Zheng, and Ian A. Nicholls pp 8554–8560 DOI: 10.1021/ja039622l Supporting Info

Incorporation of Fullerene Derivatives into Smectite Clays:  A New Family of Organic−Inorganic Nanocomposites Dimitrios Gournis, Vasilios Georgakilas, Michael A. Karakassides, Thomas Bakas, Konstantinos Kordatos, Maurizio Prato, Marianna Fanti, and Francesco Zerbetto pp 8561–8568 DOI: 10.1021/ja049237b Supporting Info

Highly Efficient Transfer of Chirality from Macrocyclic Conformation in the Tandem Oxy-Cope/Claisen/Ene Reaction Effiette L. O. Sauer and Louis Barriault pp 8569–8575 DOI: 10.1021/ja048301m Supporting Info

Structure and Reactivity of Ru Nanoparticles Supported on Modified Graphite Surfaces:  A Study of the Model Catalysts for Ammonia Synthesis Zhen Song, Tanhong Cai, Jonathan C. Hanson, Jose A. Rodriguez, and Jan Hrbek pp 8576–8584 DOI: 10.1021/ja031718s

Photoelectron Spectroscopy of Isolated Multiply Negatively Charged Oligonucleotides J. Mathias Weber, Ilya N. Ioffe, Katerina M. Berndt, Daniel Löffler, Jochen Friedrich, Oli T. Ehrler, Allison S. Danell, Joel H. Parks, and Manfred M. Kappes pp 8585–8589 DOI: 10.1021/ja049736c

Efficient Nickel-Catalyzed [2 + 2 + 2] Cycloaddition of CO2 and Diynes [J. Am. Chem. Soc. 2002, 124, 15188−15189]. Janis Louie, John E. Gibby, Marc V. Farnworth, and Thomas N. Tekavec p 8590 DOI: 10.1021/ja046854r

Issue 28

A Coordination Gelator That Shows a Reversible Chromatic Change and Sol−Gel Phase-Transition Behavior upon Oxidative/Reductive Stimuli Shin-ichiro Kawano, Norifumi Fujita, and Seiji Shinkai pp 8592–8593 DOI: 10.1021/ja048943+ Supporting Info

Integrated Nanoreactor Systems:  Triggering the Release and Mixing of Compounds Inside Single Vesicles Pierre-Yves Bolinger, Dimitrios Stamou, and Horst Vogel pp 8594–8595 DOI: 10.1021/ja049023u

A Simple Thermodynamic Test To Discriminate between Two-State and Downhill Folding Fabiana Y. Oliva and Victor Muñoz pp 8596–8597 DOI: 10.1021/ja048309w Supporting Info

Bridging the Gap between in Vitro and in Vivo Imaging:  Isostructural Re and 99mTc Complexes for Correlating Fluorescence and Radioimaging Studies Karin A. Stephenson, Sangeeta Ray Banerjee, Travis Besanger, Oyebola O. Sogbein, Murali K. Levadala, Nicole McFarlane, Jennifer A. Lemon, Douglas R. Boreham, Kevin P. Maresca, John D. Brennan, John W. Babich, Jon Zubieta, and John F. Valliant pp 8598–8599 DOI: 10.1021/ja047751b Supporting Info

Tailor-Made Functionalization of Silicon Nitride Surfaces Ahmed Arafat, Karin Schroën, Louis C. P. M. de Smet, Ernst J. R. Sudhölter, and Han Zuilhof pp 8600–8601 DOI: 10.1021/ja0483746 Supporting Info

Direct Dynamics Trajectory Study of Vibrational Effects:  Can Polanyi Rules Be Generalized to a Polyatomic System? Jianbo Liu, Kihyung Song, William L. Hase, and Scott L. Anderson pp 8602–8603 DOI: 10.1021/ja048635b Supporting Info

Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Dissociation Energy Victor N. Nemykin, Julia Laskin, and Partha Basu pp 8604–8605 DOI: 10.1021/ja049121f Supporting Info

Synthesis of DNA Triangles with Vertexes of Bis(terpyridine)iron(II) Complexes Jin Seok Choi, Chang Won Kang, Kisung Jung, Jung Woon Yang, Yang-Gyun Kim, and Hogyu Han pp 8606–8607 DOI: 10.1021/ja048537q Supporting Info

A New Type of Square Columnar Liquid Crystalline Phases Formed by Facial Amphiphilic Triblock Molecules Bin Chen, Ute Baumeister, Siegmar Diele, Malay Kumar Das, Xiangbing Zeng, Goran Ungar, and Carsten Tschierske pp 8608–8609 DOI: 10.1021/ja0480015 Supporting Info

Refinement of the Conformation of UDP−Galactose Bound to Galactosyltransferase Using the STD NMR Intensity-Restrained CORCEMA Optimization V. Jayalakshmi, Thorsten Biet, Thomas Peters, and N. Rama Krishna pp 8610–8611 DOI: 10.1021/ja048703u Supporting Info

Toward the Development of Ionically Controlled Nanoscopic Molecular Gates Rosa Casasús, María Dolores Marcos, Ramón Martínez-Máñez, José V. Ros-Lis, Juan Soto, Luis A. Villaescusa, Pedro Amorós, Daniel Beltrán, Carmen Guillem, and Julio Latorre pp 8612–8613 DOI: 10.1021/ja048095i Supporting Info

X-ray Crystal Structure and EPR Spectra of “Arsenite-Inhibited” Desulfovibrio gigas Aldehyde Dehydrogenase:  A Member of the Xanthine Oxidase Family D. Roeland Boer, Anders Thapper, Carlos D. Brondino, Maria J. Romão, and José J. G. Moura pp 8614–8615 DOI: 10.1021/ja0490222 Supporting Info

Fabrication of Magnetically Separable Mesostructured Silica with an Open Pore System An-Hui Lu, Wen-Cui Li, Andreas Kiefer, Wolfgang Schmidt, Eckhard Bill, Gerhard Fink, and Ferdi Schüth pp 8616–8617 DOI: 10.1021/ja0486521 Supporting Info

Reaction of Silyldihalomethyllithiums with Nitriles:  Formation of α-Keto Acylsilanes via Azirines and 1,3-Rearrangement of Silyl Group from C to N Kazunari Yagi, Takayuki Tsuritani, Kazuaki Takami, Hiroshi Shinokubo, and Koichiro Oshima pp 8618–8619 DOI: 10.1021/ja047708o Supporting Info

Following the Solvent Directly during Ultrafast Excited State Proton Transfer Sarah J. Schmidtke, David F. Underwood, and David A. Blank pp 8620–8621 DOI: 10.1021/ja048639g Supporting Info

Highly Enantioselective Separation Using a Supported Liquid Membrane Encapsulating Surfactant−Enzyme Complex Eijiro Miyako, Tatsuo Maruyama, Noriho Kamiya, and Masahiro Goto pp 8622–8623 DOI: 10.1021/ja049378d

Highly Symmetric Networks Derived from Cubane-Related Octametallic Complexes of a New Oxyanion of Carbon, C4O74-, Each Molecule Attached to Eight Neighbors by 24 Equivalent Hydrogen Bonds Brendan F. Abrahams, Timothy A. Hudson, and Richard Robson pp 8624–8625 DOI: 10.1021/ja048293+ Supporting Info

Putting a Brake on an Autonomous DNA Nanomotor Yi Chen and Chengde Mao pp 8626–8627 DOI: 10.1021/ja047991r Supporting Info

Gallium Cluster “Magic Melters” Gary A. Breaux, Damon A. Hillman, Colleen M. Neal, Robert C. Benirschke, and Martin F. Jarrold pp 8628–8629 DOI: 10.1021/ja0477423

Bifunctional Rhodium Intercalator Conjugates as Mismatch-Directing DNA Alkylating Agents Ulrich Schatzschneider and Jacqueline K. Barton pp 8630–8631 DOI: 10.1021/ja048543m Supporting Info

High-Temperature Electrocatalysis Using Thermophilic P450 CYP119:  Dehalogenation of CCl4 to CH4 Emek Blair, John Greaves, and Patrick J. Farmer pp 8632–8633 DOI: 10.1021/ja0488333 Supporting Info

QM/MM Determination of Kinetic Isotope Effects for COMT-Catalyzed Methyl Transfer Does Not Support Compression Hypothesis Giuseppe D. Ruggiero and Ian H. WilliamsMaite Roca and Vicent MolinerIñaki Tuñón pp 8634–8635 DOI: 10.1021/ja048055e

Photochemistry of Diketones:  Observation of a Triplet State−Oxygen Adduct Gonzalo Cosa and Juan C. Scaiano pp 8636–8637 DOI: 10.1021/ja048174u Supporting Info

Rotaxanated Conjugated Sensory Polymers Phoebe H. Kwan, Mark J. MacLachlan, and Timothy M. Swager pp 8638–8639 DOI: 10.1021/ja048506v Supporting Info

Covalent Display of Oligosaccharide Arrays in Microtiter Plates Marian C. Bryan, Fabio Fazio, Hing-Ken Lee, Cheng-Yuan Huang, Aileen Chang, Michael D. Best, Daniel A. Calarese, Ola Blixt, James C. Paulson, Dennis Burton, Ian A. Wilson, and Chi-Huey Wong pp 8640–8641 DOI: 10.1021/ja048433f Supporting Info

Regio- and Diastereoselective Rhodium-Catalyzed Allylic Substitution with Acyclic α-Alkoxy-Substituted Copper(I) Enolates:  Stereodivergent Approach to 2,3,6-Trisubstituted Dihydropyrans P. Andrew Evans and Michael J. Lawler pp 8642–8643 DOI: 10.1021/ja049080n Supporting Info

Assembly of an Antiparallel Homo-Adenine DNA Duplex by Small-Molecule Binding Özgül Persil, Catherine T. Santai, Swapan S. Jain, and Nicholas V. Hud pp 8644–8645 DOI: 10.1021/ja0492891 Supporting Info

Lithium-Catalyzed Hydroxide Attack at the Carbon Atom of Methyl Phosphate Richard Wolfenden and Frances Zhao pp 8646–8647 DOI: 10.1021/ja0473586

Room Temperature, High-Yield Synthesis of Multiple Shapes of Gold Nanoparticles in Aqueous Solution Tapan K. Sau and Catherine J. Murphy pp 8648–8649 DOI: 10.1021/ja047846d Supporting Info

Ordered SBA-15 Nanorod Arrays Inside a Porous Alumina Membrane Qingyi Lu, Feng Gao, Sridhar Komarneni, and Thomas E. Mallouk pp 8650–8651 DOI: 10.1021/ja0488378 Supporting Info

Highly Stereoselective Prins Cyclization of Silylmethyl-Substituted Cyclopropyl Carbinols to 2,4,6-Trisubstituted Tetrahydropyrans Veejendra K. Yadav and Naganaboina Vijaya Kumar pp 8652–8653 DOI: 10.1021/ja048000c Supporting Info

Platinum- and Gold-Catalyzed Cycloisomerization Reactions of Hydroxylated Enynes Victor Mamane, Tobias Gress, Helga Krause, and Alois Fürstner pp 8654–8655 DOI: 10.1021/ja048094q Supporting Info

PtCl2-Catalyzed Cycloisomerizations of 5-En-1-yn-3-ol Systems Youssef Harrak, Christophe Blaszykowski, Matthieu Bernard, Kevin Cariou, Emily Mainetti, Virginie Mouriès, Anne-Lise Dhimane, Louis Fensterbank, and Max Malacria pp 8656–8657 DOI: 10.1021/ja0474695 Supporting Info

Palladium-Catalyzed Reaction of 2-Hydroxy-2-methylpropiophenone with Aryl Bromides:  A Unique Multiple Arylation via Successive C−C and C−H Bond Cleavages Hiroyuki Wakui, Satoshi Kawasaki, Tetsuya Satoh, Masahiro Miura, and Masakatsu Nomura pp 8658–8659 DOI: 10.1021/ja0477874 Supporting Info

Simple Synthesis of an Allenylidene Heptavalent Rhenium(d0) Complex Xiaoyan Li, Markus Schopf, Jürgen Stephan, Jennifer Kippe, Klaus Harms, and Jörg Sundermeyer pp 8660–8661 DOI: 10.1021/ja048030f Supporting Info

Polyborane Reactions in Ionic Liquids:  New Efficient Routes to Functionalized Decaborane and o-Carborane Clusters Upal Kusari, Yuqi Li, Mark G. Bradley, and Larry G. Sneddon pp 8662–8663 DOI: 10.1021/ja048018n

Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides David M. Hodgson, Ying Kit Chung, and Jean-Marc Paris pp 8664–8665 DOI: 10.1021/ja047346k Supporting Info

Unidirectional Current in a Polyacetylene Hetero-ionic Junction Calvin H. W. Cheng, Shannon W. Boettcher, Dean H. Johnston, and Mark C. Lonergan pp 8666–8667 DOI: 10.1021/ja0493695 Supporting Info

Light-Harvesting Macroring Accommodating a Tetrapodal Ligand Based on Complementary and Cooperative Coordinations Yusuke Kuramochi, Akiharu Satake, and Yoshiaki Kobuke pp 8668–8669 DOI: 10.1021/ja048118t Supporting Info

Synthesis, Reactivity, and Ligand Properties of a Stable Alkyl Carbene Vincent Lavallo, John Mafhouz, Yves Canac, Bruno Donnadieu, Wolfgand W. Schoeller, and Guy Bertrand pp 8670–8671 DOI: 10.1021/ja047503f Supporting Info

Direct Evidence for Ferromagnetism of Nanometer-Scale Palladium by Contact with Perovskite Manganite Young Nam Kim, Eun Kwang Lee, Yong Bok Lee, Heejae Shim, Nam Hwi Hur, and Wan Seop Kim pp 8672–8673 DOI: 10.1021/ja047949w Supporting Info

Significant pKa Perturbation of Nucleobases Is an Intrinsic Property of the Sequence Context in DNA and RNA Sandipta Acharya, Jharna Barman, Pradeep Cheruku, Subhrangsu Chatterjee, Parag Acharya, Johan Isaksson, and Jyoti Chattopadhyaya pp 8674–8681 DOI: 10.1021/ja048484c Supporting Info

Biliverdin Reduction by Cyanobacterial Phycocyanobilin:Ferredoxin Oxidoreductase (PcyA) Proceeds via Linear Tetrapyrrole Radical Intermediates Shih-Long Tu, Alexander Gunn, Michael D. Toney, R. David Britt, and J. Clark Lagarias pp 8682–8693 DOI: 10.1021/ja049280z Supporting Info

Complexed Nitrogen Heterosuperbenzene:  The Coordinating Properties of a Remarkable Ligand Sylvia M. Draper, Daniel J. Gregg, Emma R. Schofield, Wesley R. Browne, Marco Duati, Johannes G. Vos, and Paolo Passaniti pp 8694–8701 DOI: 10.1021/ja0491634 Supporting Info

The Dynamic Character of the G-Quadruplex Element in the c-MYC Promoter and Modification by TMPyP4 Jeyaprakashnarayanan Seenisamy, Evonne M. Rezler, Tiffanie J. Powell, Denise Tye, Vijay Gokhale, Chandana Sharma Joshi, Adam Siddiqui-Jain, and Laurence H. Hurley pp 8702–8709 DOI: 10.1021/ja040022b

Propeller-Type Parallel-Stranded G-Quadruplexes in the Human c-myc Promoter Anh Tuân Phan, Yasha S. Modi, and Dinshaw J. Patel pp 8710–8716 DOI: 10.1021/ja048805k Supporting Info

Basicity of Nucleophilic Carbenes in Aqueous and Nonaqueous SolventsTheoretical Predictions Alison M. Magill, Kingsley J. Cavell, and Brian F. Yates pp 8717–8724 DOI: 10.1021/ja038973x Supporting Info

Creation of Hoop- and Bowl-Shaped Benzenoid Systems by Selective Detraction of [60]Fullerene Conjugation. [10]Cyclophenacene and Fused Corannulene Derivatives Yutaka Matsuo, Kazukuni Tahara, Masaya Sawamura, and Eiichi Nakamura pp 8725–8734 DOI: 10.1021/ja048683w Supporting Info

Characterization, Supramolecular Assembly, and Nanostructures of Thiophene Dendrimers Chuanjun Xia, Xiaowu Fan, Jason Locklin, Rigoberto C. Advincula, Anthony Gies, and William Nonidez pp 8735–8743 DOI: 10.1021/ja0484404 Supporting Info

Palladium(0)-Catalyzed Synthesis of Medium-Sized Heterocycles by Using Bromoallenes as an Allyl Dication Equivalent Hiroaki Ohno, Hisao Hamaguchi, Miyo Ohata, Shohei Kosaka, and Tetsuaki Tanaka pp 8744–8754 DOI: 10.1021/ja048693x Supporting Info

Development of a Catalytic Electron Transfer System Mediated by Transition Metal Ate Complexes:  Applicability and Tunability of Electron-Releasing Potential for Organic Transformations Masanobu Uchiyama, Yotaro Matsumoto, Shinji Nakamura, Tomohiko Ohwada, Nagao Kobayashi, Natsuno Yamashita, Atsushi Matsumiya, and Takao Sakamoto pp 8755–8759 DOI: 10.1021/ja039674a Supporting Info

Photoisomerization and Photodissociation of Aniline and 4-Methylpyridine Chien-Ming Tseng, Yuri A. Dyakov, Cheng-Liang Huang, Alexander M. Mebel, Sheng Hsien Lin, Yuan T. Lee, and Chi-Kung Ni pp 8760–8768 DOI: 10.1021/ja0483894

Sequential Arrangement of γ-Valerolactone Enantiomers Enclathrated in Cholic Acid Channels as Studied by 13C Solid-State NMR:  Elucidation of the Optical Resolution Mechanism Shinji Nakamura, F. Imashiro, K. Takegoshi, and Takehiko Terao pp 8769–8776 DOI: 10.1021/ja049463l

Direct Catalytic Asymmetric Mannich-type Reaction of Hydroxyketone Using a Et2Zn/Linked-BINOL Complex:  Synthesis of Either anti- or syn-β-Amino Alcohols Shigeki Matsunaga, Takamasa Yoshida, Hiroyuki Morimoto, Naoya Kumagai, and Masakatsu Shibasaki pp 8777–8785 DOI: 10.1021/ja0482435 Supporting Info

Me2AlCH2PMe2: A New, Bifunctional Cocatalyst for the Ni(II)-Catalyzed Oligomerization of PhSiH3 Frédéric-Georges Fontaine and Davit Zargarian pp 8786–8794 DOI: 10.1021/ja048911m

Double Geminal C−H Activation and Reversible α-Elimination in 2-Aminopyridine Iridium(III) Complexes:  The Role of Hydrides and Solvent in Flattening the Free Energy Surface Eric Clot, Junyi Chen, Dong-Heon Lee, So Young Sung, Leah N. Appelhans, Jack W. Faller, Robert H. Crabtree, and Odile Eisenstein pp 8795–8804 DOI: 10.1021/ja048473j Supporting Info

Single-Molecule Magnets of Ferrous Cubes:  Structurally Controlled Magnetic Anisotropy Hiroki Oshio, Norihisa Hoshino, Tasuku Ito, and Motohiro Nakano pp 8805–8812 DOI: 10.1021/ja0487933 Supporting Info

Synthesis and Properties of Compressed Dihydride Complexes of Iridium:  Theoretical and Spectroscopic Investigations Ricard Gelabert, Miquel Moreno, José M. Lluch, Agustí Lledós, Vincent Pons, and D. Michael Heinekey pp 8813–8822 DOI: 10.1021/ja048775l Supporting Info

A Fast Photoswitch for Minimally Perturbed Peptides:  Investigation of the trans → cis Photoisomerization of N-Methylthioacetamide Jan Helbing, Harald Bregy, Jens Bredenbeck, Rolf Pfister, Peter Hamm, Robert Huber, Josef Wachtveitl, Luca De Vico, and Massimo Olivucci pp 8823–8834 DOI: 10.1021/ja049227a Supporting Info

Direct Electrochemiluminescence Detection of Oxidized DNA in Ultrathin Films Containing [Os(bpy)2(PVP)10]2+ Lynn Dennany, Robert J. Forster, Blanaid White, Malcolm Smyth, and James F. Rusling pp 8835–8841 DOI: 10.1021/ja048615+ Supporting Info

Nature of the Peroxo Intermediate of the W48F/D84E Ribonucleotide Reductase Variant:  Implications for O2 Activation by Binuclear Non-Heme Iron Enzymes Andrew J. Skulan, Thomas C. Brunold, Jeffrey Baldwin, Lana Saleh, J. Martin Bollinger, Jr., and Edward I. Solomon pp 8842–8855 DOI: 10.1021/ja049106a Supporting Info

CAChe 6.1 WorkSystem Pro plus Active Site Add-On. CAChe Group, Fujitsu America, Inc., 15244 Greenbriar Parkway, Beaverton, OR 97006. http://www.cachesoftware.com/. Contact CAChe group for pricing information. Ramkumar Rajamani pp 8856–8857 DOI: 10.1021/ja033646a

The Chemical Physics of Solid Surfaces, Volume 11, Surface Dynamics Edited by D. P. Woodruff (University of Warwick). Elsevier:  Amsterdam. 2003. xvi + 378 pp. $250.00. ISBN 0-444-51437-6. Melissa A. Hines p 8858 DOI: 10.1021/ja033668x

Advances in Quantum Chemistry, Vol. 44:  Manifestations of Vibronic Coupling in Chemistry and Physics Edited by John R. Sabin (University of Florida) and Erkki Brändas (Uppsala University, Sweden). With Guest Editors:  Arnout Ceulemans, Liviu Chibotaru, and Eugene Kryachko (Katholieke Universiteit, Leuven, Belgium). Elsevier Academic Press:  San Diego, CA. 2003. xxxvi + 674 pp. $175.00. ISBN:  0-12-034844-6. p 8858 DOI: 10.1021/ja040923k

Handbook of Zeolite Science and Technology Edited by Scott M. Auerbach (University of Massachusetts, Amherst), Kathleen A. Carrado (Argonne National Laboratory), Prabir K. Dutta (The Ohio State University). Marcel Dekker, Inc.:  New York, Basel. 2003. xii + 1184 pp. $235.00. ISBN 0-8247-4020-3. Kendall T. Thomson pp 8858–8859 DOI: 10.1021/ja0336067

Macromolecules Containing Metal and Metal-Like Elements, Volume 2:  Organoiron Polymers Edited by Alaa S. Abd-El-Aziz (University of Winnipeg), Charles E. Carraher, Jr. (Florida Atlantic University), Charles U. Pittman, Jr. (Mississippi State University), John E. Sheats (Rider University), and Martel Zeldin (Hobart and William Smith Colleges). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xvi + 287 pp. $125.00. ISBN 0-471-45078-2. Gary J. Long p 8859 DOI: 10.1021/ja040907n

Handbook of Spectroscopy, Volumes 1 and 2 Edited by Günter Gauglitz (University of Tübingen) and Tuan Vo-Dinh (Oak Ridge National Laboratory). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. 1168 pp. $435.00. ISBN:  3-527-29782-0. Gang Ma and Heather C. Allen pp 8859–8860 DOI: 10.1021/ja033666c

Issue 29

A Fluorogenic Probe for the Copper(I)-Catalyzed Azide−Alkyne Ligation Reaction:  Modulation of the Fluorescence Emission via 3(n,π*)−1(π,π*) Inversion Zhen Zhou and Christoph J. Fahrni pp 8862–8863 DOI: 10.1021/ja049684r Supporting Info

Sequence- and Base-Specific Delivery of Nitric Oxide to Cytidine and 5-Methylcytidine Leading to Efficient Deamination Md. Monsur Ali, Md. Rowshon Alam, Takeshi Kawasaki, Shizuka Nakayama, Fumi Nagatsugi, and Shigeki Sasaki pp 8864–8865 DOI: 10.1021/ja0498888 Supporting Info

Double C−H Activation during Functionalization of Phenyl(methyl)ketene on Iridium(I) Using Alkynes. Synthesis of 1,4-Dien-3-ones Douglas B. Grotjahn, Justin M. Hoerter, and John L. Hubbard pp 8866–8867 DOI: 10.1021/ja048489+ Supporting Info

Kinetic Isotope Effects Implicate the Iron−Oxene as the Sole Oxidant in P450-Catalyzed N-Dealkylation Tamara S. Dowers, Dan A. Rock, Denise A. Rock, and Jeffrey P. Jones pp 8868–8869 DOI: 10.1021/ja0486364

Activation Energies for the Singlet Excited State Processes of Substituted Benzenes:  para, meta, and ortho Isomers of Methylbenzonitrile and Methylanisole in Acetonitrile Carlos M. González and James A. Pincock pp 8870–8871 DOI: 10.1021/ja048780p Supporting Info

Site-Directed Electrostatic Measurements with a Thiol-Specific pH-Sensitive Nitroxide:  Differentiating Local pK and Polarity Effects by High-Field EPR Alex I. Smirnov, Andres Ruuge, Vladimir A. Reznikov, Maxim A. Voinov, and Igor A. Grigor'ev pp 8872–8873 DOI: 10.1021/ja048801f Supporting Info

Generation of Fullerenyl Cation (EtO)2P+(OH)CH2−C60+ from RC60−H and from RC60−C60R (R = CH2P(O)(OEt)2) Yasujiro Murata, Fuyong Cheng, Toshikazu Kitagawa, and Koichi Komatsu pp 8874–8875 DOI: 10.1021/ja047483h Supporting Info

Enantioselective Synthesis of Quaternary Stereocenters via a Catalytic Asymmetric Stetter Reaction Mark S. Kerr and Tomislav Rovis pp 8876–8877 DOI: 10.1021/ja047644h Supporting Info

The Mechanism of the Reaction Catalyzed by ADP-β-l-glycero-d-manno-heptose 6-Epimerase Jay A. Read, Raef A. Ahmed, James P. Morrison, William G. Coleman, Jr., and Martin E. Tanner pp 8878–8879 DOI: 10.1021/ja0485659 Supporting Info

Photochemical Ligation of DNA Conjugates through Anthracene Cyclodimer Formation and Its Fidelity to the Template Sequences Toshihiro Ihara, Tomohiro Fujii, Motoko Mukae, Yusuke Kitamura, and Akinori Jyo pp 8880–8881 DOI: 10.1021/ja047784r Supporting Info

Microemulsion-Based Synthesis of Titanium Phosphate Nanotubes via Amine Extraction System Zhilei Yin, Yasuhiro Sakamoto, Jihong Yu, Sixiu Sun, Osamu Terasaki, and Ruren Xu pp 8882–8883 DOI: 10.1021/ja047684l

The Second Triannulenylene:  Tri-[8]annulenylene Matthew K. Kiesewetter, Richard C. Reiter, and Cheryl D. Stevenson pp 8884–8885 DOI: 10.1021/ja049020h Supporting Info

Preparation and Structural Characterization of RuS2 Nanoislands on Au(111) Tanhong Cai, Zhen Song, Jose A. Rodriguez, and Jan Hrbek pp 8886–8887 DOI: 10.1021/ja047634g

Enzymatic Resolution of Chiral Phosphinate Esters Yingchun Li, Sarah D. Aubert, Eugene G. Maes, and Frank M. Raushel pp 8888–8889 DOI: 10.1021/ja048457m Supporting Info

Reactivity of Secondary Metallocene Alkyls and the Question of Dormant Sites in Catalytic Alkene Polymerization Clark R. Landis, Douglass R. Sillars, and Jeanine M. Batterton pp 8890–8891 DOI: 10.1021/ja047547o Supporting Info

Fluorescent GTP-Sensing in Aqueous Solution of Physiological pH Ji Young Kwon, N. Jiten Singh, Ha Na Kim, Sook Kyung Kim, Kwang S. Kim, and Juyoung Yoon pp 8892–8893 DOI: 10.1021/ja0492440 Supporting Info

Phase Transition of a Single Lipid Bilayer Measured by Sum-Frequency Vibrational Spectroscopy Jin Liu and John C. Conboy pp 8894–8895 DOI: 10.1021/ja031570c Supporting Info

Specific Labeling of Cell Surface Proteins with Chemically Diverse Compounds Nathalie George, Horst Pick, Horst Vogel, Nils Johnsson, and Kai Johnsson pp 8896–8897 DOI: 10.1021/ja048396s Supporting Info

Dipeptide Binding in Water by a de Novo Designed Guanidiniocarbonylpyrrole Receptor Carsten Schmuck and Lars Geiger pp 8898–8899 DOI: 10.1021/ja048587v Supporting Info

The Observation of Superparamagnetic Behavior in Molecular Nanowires Shi Wang, Jing-Lin Zuo, Song Gao, You Song, Hong-Cai Zhou, Yuan-Zhu Zhang, and Xiao-Zeng You pp 8900–8901 DOI: 10.1021/ja0483995 Supporting Info

Attomolar Sensitivity in Bioassays Based on Surface Plasmon Fluorescence Spectroscopy Fang Yu, Björn Persson, Stefan Löfås, and Wolfgang Knoll pp 8902–8903 DOI: 10.1021/ja048583q

Reversible Control of Free Energy and Topography of Nanostructured Surfaces Qiang Fu, G. V. Rama Rao, Solomon B. Basame, David J. Keller, Kateryna Artyushkova, Julia E. Fulghum, and Gabriel P. López pp 8904–8905 DOI: 10.1021/ja047895q Supporting Info

Interaction-Controlled HPLC for Block Copolymer Analysis and Separation Soojin Park, Insun Park, Taihyun Chang, and Chang Y. Ryu pp 8906–8907 DOI: 10.1021/ja047385w Supporting Info

Differential Binding of Mg2+, Zn2+, and Cd2+ at Two Sites in a Hammerhead Ribozyme Motif, Determined by 15N NMR Gang Wang, Barbara L. Gaffney, and Roger A. Jones pp 8908–8909 DOI: 10.1021/ja049804v Supporting Info

Catalytic Enantioselective Allylboration of Ketones Reiko Wada, Kounosuke Oisaki, Motomu Kanai, and Masakatsu Shibasaki pp 8910–8911 DOI: 10.1021/ja047200l Supporting Info

An Undoped, Single-Phase Oxide Photocatalyst Working under Visible Light Hyun Gyu Kim, Dong Won Hwang, and Jae Sung Lee pp 8912–8913 DOI: 10.1021/ja049676a Supporting Info

The Direct Amino Acid-Catalyzed Asymmetric Incorporation of Molecular Oxygen to Organic Compounds Armando Córdova, Henrik Sundén, Magnus Engqvist, Ismail Ibrahem, and Jesús Casas pp 8914–8915 DOI: 10.1021/ja047930t Supporting Info

A New Chiral Rh(II) Catalyst for Enantioselective [2 + 1]-Cycloaddition. Mechanistic Implications and Applications Yan Lou, Manabu Horikawa, Robin A. Kloster, Natalie A. Hawryluk, and E. J. Corey pp 8916–8918 DOI: 10.1021/ja047064k Supporting Info

Mechanism for Catechol Ring-Cleavage by Non-Heme Iron Extradiol Dioxygenases Per E. M. Siegbahn and Fredrik Haeffner pp 8919–8932 DOI: 10.1021/ja0493805

A Simple Method for Improving Protein Solubility and Long-Term Stability Alexander P. Golovanov, Guillaume M. Hautbergue, Stuart A. Wilson, and Lu-Yun Lian pp 8933–8939 DOI: 10.1021/ja049297h

Interfacial Nano-structuring of Designed Peptides Regulated by Solution pH Jian R. Lu, Shiamalee Perumal, Ian Hopkinson, John R. P. Webster, Jeff Penfold, Wonmuk Hwang, and Shuguang Zhang pp 8940–8947 DOI: 10.1021/ja049477r

Enantioselective DNA Alkylation by a Pyrrole−Imidazole S-CBI Conjugate Toshikazu Bando, Akihiko Narita, Ken Asada, Hirohito Ayame, and Hiroshi Sugiyama pp 8948–8955 DOI: 10.1021/ja049398f Supporting Info

Single Molecule Solvation and Its Effects on Tautomeric Equilibria in a Self-Assembled Capsule Alessandro Scarso and Julius Rebek, Jr. pp 8956–8960 DOI: 10.1021/ja0396091

Mediation of Conformationally Controlled Photodecarboxylations of Chiral and Cyclic Aryl Esters by Substrate Structure, Temperature, Pressure, and Medium Constraints Tadashi Mori, Richard G. Weiss, and Yoshihisa Inoue pp 8961–8975 DOI: 10.1021/ja049688w Supporting Info

Insights into Photodissociation Dynamics of Benzamide and Formanilide from ab Initio Calculations Xue-Bo Chen and Wei-Hai Fang pp 8976–8980 DOI: 10.1021/ja0494858 Supporting Info

Delocalized Carotenoid Cations in Relation to the Soliton Model Bjart Frode Lutnaes, Geir Kildahl-Andersen, Jostein Krane, and Synnøve Liaaen-Jensen pp 8981–8990 DOI: 10.1021/ja0492541 Supporting Info

Charge Separation in Ground-State 1,2,4,5-Tetra-Substituted Benzene Derivatives Yehuda Haas and Shmuel Zilberg pp 8991–8998 DOI: 10.1021/ja048872e Supporting Info

Water-Soluble Dendrimers as Photochemical Reaction Media:  Chemical Behavior of Singlet and Triplet Radical Pairs Inside Dendritic Reaction Cavities Lakshmi S. Kaanumalle, Jayaraj Nithyanandhan, Mahesh Pattabiraman, Narayanaswamy Jayaraman, and V. Ramamurthy pp 8999–9006 DOI: 10.1021/ja049492w

Controlled Polymer Grafting on Single Clay Nanoplatelets Pascal Viville, Roberto Lazzaroni, Eric Pollet, Michaël Alexandre, and Philippe Dubois pp 9007–9012 DOI: 10.1021/ja048657y

Tetrafluoroborate Salts as Site-Selective Promoters for Sol−Gel Synthesis of Mesoporous Silica Akihiro Okabe, Takanori Fukushima, Katsuhiko Ariga, Makiko Niki, and Takuzo Aida pp 9013–9016 DOI: 10.1021/ja0478532 Supporting Info

Tracing Kinetic Intermediates during Ligand Binding Tanja Mittag, Brian Schaffhausen, and Ulrich L. Günther pp 9017–9023 DOI: 10.1021/ja0392519 Supporting Info

Imaging the Binding Ability of Proteins Immobilized on Surfaces with Different Orientations by Using Liquid Crystals Yan-Yeung Luk, Matthew L. Tingey, Kimberly A. Dickson, Ronald T. Raines, and Nicholas L. Abbott pp 9024–9032 DOI: 10.1021/ja0398565

Elastic Properties of Single Amylose Chains in Water:  A Quantum Mechanical and AFM Study Zhenyu Lu, Wieslaw Nowak, Gwangrog Lee, Piotr E. Marszalek, and Weitao Yang pp 9033–9041 DOI: 10.1021/ja031940x Supporting Info

Two-Dimensional Crystallization:  Self-Assembly, Pseudopolymorphism, and Symmetry-Independent Molecules Katherine E. Plass, Kibum Kim, and Adam J. Matzger pp 9042–9053 DOI: 10.1021/ja0493446 Supporting Info

Steric Retardation of SN2 Reactions in the Gas Phase and Solution Grigoriy Vayner, K. N. Houk, William L. Jorgensen, and John I. Brauman pp 9054–9058 DOI: 10.1021/ja049070m Supporting Info

Catalytic Oligomerization of Ethylene to Higher Linear α-Olefins Promoted by the Cationic Group 4 [(η5-Cp-(CMe2-bridge)-Ph)MII(ethylene)2]+ (M = Ti, Zr, Hf) Active Catalysts:  A Density Functional Investigation of the Influence of the Metal on the Catalytic Activity and Selectivity Sven Tobisch and Tom Ziegler pp 9059–9071 DOI: 10.1021/ja048861l Supporting Info

Characterization of Superparamagnetic “Core−Shell” Nanoparticles and Monitoring Their Anisotropic Phase Transition to Ferromagnetic “Solid Solution” Nanoalloys Jong-Il Park, Min Gyu Kim, Young-wook Jun, Jae Sung Lee, Woo-ram Lee, and Jinwoo Cheon pp 9072–9078 DOI: 10.1021/ja049649k Supporting Info

Is the Allylpalladium Structure Altered between Solid and Solutions? Eric Clot, Odile Eisenstein, Tsu-Chien Weng, James Penner-Hahn, and Kenneth G. Caulton pp 9079–9084 DOI: 10.1021/ja049091g

Reversible Disulfur Monoxide (S2O)-Forming Retro-Diels−Alder Reaction. Disproportionation of S2O to Trithio-Ozone (S3) and Sulfur Dioxide (SO2) and Reactivities of S2O and S3 Juzo Nakayama, Satoshi Aoki, Jun Takayama, Akira Sakamoto, Yoshiaki Sugihara, and Akihiko Ishii pp 9085–9093 DOI: 10.1021/ja047729i Supporting Info

Effect of Sodium Sulfide on Ni-Containing Carbon Monoxide Dehydrogenases Jian Feng and Paul A. Lindahl pp 9094–9100 DOI: 10.1021/ja048811g

Aqueous Cholesteric Liquid Crystals Using Uncharged Rodlike Polypeptides Enrico G. Bellomo, Patrick Davidson, Marianne Impéror-Clerc, and Timothy J. Deming pp 9101–9105 DOI: 10.1021/ja047932d Supporting Info

Oxidative Cyclizations:  The Asymmetric Synthesis of (−)-Alliacol A John Mihelcic and Kevin D. Moeller pp 9106–9111 DOI: 10.1021/ja048085h Supporting Info

Poly-l-Lysine Templated Silicas:  Using Polypeptide Secondary Structure to Control Oxide Pore Architectures Kristy M. Hawkins, Steven S.-S. Wang, David M. Ford, and Daniel F. Shantz pp 9112–9119 DOI: 10.1021/ja049936o Supporting Info

Nonaqueous and Halide-Free Route to Crystalline BaTiO3, SrTiO3, and (Ba,Sr)TiO3 Nanoparticles via a Mechanism Involving C−C Bond Formation Markus Niederberger, Georg Garnweitner, Nicola Pinna, and Markus Antonietti pp 9120–9126 DOI: 10.1021/ja0494959 Supporting Info

Polyphosphate Ions Encapsulated in Oxothiomolybdate Rings:  Synthesis, Structure, and Behavior in Solution Emmanuel Cadot, Marie-José Pouet, Chantal Robert-Labarre, Charlotte du Peloux, Jérôme Marrot, and Francis Sécheresse pp 9127–9134 DOI: 10.1021/ja048746a Supporting Info

Effect of Ions on the Vibrational Relaxation of Liquid Water Michel F. Kropman and Huib J. Bakker pp 9135–9141 DOI: 10.1021/ja039147r

Deep Eutectic Solvents Formed between Choline Chloride and Carboxylic Acids:  Versatile Alternatives to Ionic Liquids Andrew P. Abbott, David Boothby, Glen Capper, David L. Davies, and Raymond K. Rasheed pp 9142–9147 DOI: 10.1021/ja048266j Supporting Info

Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes [J. Am. Chem. Soc. 2003, 125, 14276−14277]. Suzanne A. Blum, Patrick J. Walsh, and Robert G. Bergman p 9148 DOI: 10.1021/ja0408146

Issue 30

Thermally and Electrochemically Controllable Self-Complexing Molecular Switches Yi Liu, Amar H. Flood, and J. Fraser Stoddart pp 9150–9151 DOI: 10.1021/ja048164t Supporting Info

Discovery and Characterization of Catalysts for Azide−Alkyne Cycloaddition by Fluorescence Quenching Warren G. Lewis, Fernando G. Magallon, Valery V. Fokin, and M. G. Finn pp 9152–9153 DOI: 10.1021/ja048425z Supporting Info

On the Mechanism of [Rh(CO)2Cl]2-Catalyzed Intermolecular (5 + 2) Reactions between Vinylcyclopropanes and Alkynes Zhi-Xiang Yu, Paul A. Wender, and K. N. Houk pp 9154–9155 DOI: 10.1021/ja048739m Supporting Info

[60]Fullerene-Stoppered Porphyrinorotaxanes:  Pronounced Elongation of Charge-Separated-State Lifetimes Ke Li, Paul J. Bracher, Dirk M. Guldi, M. Ángeles Herranz, Luis Echegoyen, and David I. Schuster pp 9156–9157 DOI: 10.1021/ja047548g Supporting Info

Coordination-Driven Self-Assembly Directs a Single-Crystal-to-Single-Crystal Transformation that Exhibits Photocontrolled Fluorescence Giannis S. Papaefstathiou, Zhenming Zhong, Lei Geng, and Leonard R. MacGillivray pp 9158–9159 DOI: 10.1021/ja047819n Supporting Info

A Mechanism-Based Cross-Linker for the Identification of Kinase−Substrate Pairs Dustin J. Maly, Jasmina A. Allen, and Kevan M. Shokat pp 9160–9161 DOI: 10.1021/ja048659i Supporting Info

Efficient Use of Bifunctional Acid−Base Properties for Alkylammonium Formation in Amine-Substituted Zeolites David Lesthaeghe, Veronique Van Speybroeck, and Michel Waroquier pp 9162–9163 DOI: 10.1021/ja048305r

Isolation, Characterization, and Theoretical Study of La2@C78 Baopeng Cao, Takatsugu Wakahara, Takahiro Tsuchiya, Masahiro Kondo, Yutaka Maeda, G. M. Aminur Rahman, Takeshi Akasaka, Kaoru Kobayashi, Shigeru Nagase, and Kazunori Yamamoto pp 9164–9165 DOI: 10.1021/ja048599g Supporting Info

Defect Dynamics Observed by NMR of Quadrupolar Nuclei in Gallium Nitride James P. Yesinowski and Andrew P. Purdy pp 9166–9167 DOI: 10.1021/ja049603r Supporting Info

Doxorubicin Accumulation in Individually Electrophoresed Organelles Adrian B. Anderson, Guohua Xiong, and Edgar A. Arriaga pp 9168–9169 DOI: 10.1021/ja0492539 Supporting Info

Photogenerated Polyelectrolyte Bilayers from an Aqueous-Processible Photoresist for Multicomponent Protein Patterning Junsang Doh and Darrell J. Irvine pp 9170–9171 DOI: 10.1021/ja048261m Supporting Info

Alkane Oxidation via Photochemical Excitation of a Self-Assembled Molecular Cage Michito Yoshizawa, Sachiko Miyagi, Masaki Kawano, Katsuya Ishiguro, and Makoto Fujita pp 9172–9173 DOI: 10.1021/ja047612u Supporting Info

Topochemical Transketalization Reaction Driven by Hydrogen Bonding Kana M. Sureshan, Tomohiro Murakami, Tomomi Miyasou, and Yutaka Watanabe pp 9174–9175 DOI: 10.1021/ja0483847 Supporting Info

Chiral Recognition in Surface Explosion Bahar Behzadi, Sara Romer, Roman Fasel, and Karl-Heinz Ernst pp 9176–9177 DOI: 10.1021/ja048206d Supporting Info

Control of Metal Coordination Number in de Novo Designed Peptides through Subtle Sequence Modifications Kyung-Hoon Lee, Manolis Matzapetakis, Soumya Mitra, E. Neil G. Marsh, and Vincent L. Pecoraro pp 9178–9179 DOI: 10.1021/ja048839s Supporting Info

NMR Analysis of Enzyme-Catalyzed and Free-Equilibrium Mutarotation Kinetics of Monosaccharides Kyoung-Seok Ryu, Changhoon Kim, Chankyu Park, and Byong-Seok Choi pp 9180–9181 DOI: 10.1021/ja047911j Supporting Info

One Ligand Fits All:  Cationic Mono(amidinate) Alkyl Catalysts over the Full Size Range of the Group 3 and Lanthanide Metals Sergio Bambirra, Marco W. Bouwkamp, Auke Meetsma, and Bart Hessen pp 9182–9183 DOI: 10.1021/ja0475297 Supporting Info

Cobalt-Mediated Two-Carbon Ring Expansion of Five-Membered Rings. Electrophilic Carbon−Carbon Bond Activation in the Synthesis of Seven-Membered Rings Trevor L. Dzwiniel and Jeffrey M. Stryker pp 9184–9185 DOI: 10.1021/ja047852+ Supporting Info

Biaryl Synthesis via Direct Arylation:  Establishment of an Efficient Catalyst for Intramolecular Processes Louis-Charles Campeau, Mathieu Parisien, Melissa Leblanc, and Keith Fagnou pp 9186–9187 DOI: 10.1021/ja049017y Supporting Info

Catalytic Enantioselective Conjugate Addition of Carbamates Claudio Palomo, Mikel Oiarbide, Rajkumar Halder, Michael Kelso, Enrique Gómez-Bengoa, and Jesús M. García pp 9188–9189 DOI: 10.1021/ja047004e Supporting Info

Stepwise Bromination of Two Acetylene Molecules on a Butterfly-Type Tetrairon Core and Reactivity of the Resulting Bromoacetylene Fragment toward Nucleophiles Masato Takano, Masaaki Okazaki, and Hiromi Tobita pp 9190–9191 DOI: 10.1021/ja047569a Supporting Info

Catalytic Enantio- and Diastereoselective Aldol Reactions of Glycine-Derived Silicon Enolate with Aldehydes:  An Efficient Approach to the Asymmetric Synthesis of anti-β-Hydroxy-α-Amino Acid Derivatives Jun Kobayashi, Masayuki Nakamura, Yuichiro Mori, Yasuhiro Yamashita, and Shū Kobayashi pp 9192–9193 DOI: 10.1021/ja047597t Supporting Info

A Powerful Selection Assay for Mixture Libraries of DNA Alkylating Agents Young-Wan Ham and Dale L. Boger pp 9194–9195 DOI: 10.1021/ja0477930 Supporting Info

Deoxystreptamine Dimers Bind to RNA Hairpin Loops Xianjun Liu, Jason R. Thomas, and Paul J. Hergenrother pp 9196–9197 DOI: 10.1021/ja048936l Supporting Info

Amino Acid N-Carboxyanhydrides:  Activated Peptide Monomers Behaving as Phosphate-Activating Agents in Aqueous Solution Jean-Philippe Biron and Robert Pascal pp 9198–9199 DOI: 10.1021/ja048189s Supporting Info

Regio- and Enantiocontrol in the Room-Temperature Hydroboration of Vinyl Arenes with Pinacol Borane Cathleen M. Crudden, Yonek B. Hleba, and Austin C. Chen pp 9200–9201 DOI: 10.1021/ja049761i Supporting Info

Shape-Shifting Tetranuclear Oxo-Bridged Manganese Cluster:  Relevance to Photosystem II Water Oxidase Active Site Sumitra Mukhopadhyay, Henry J. Mok, Richard J. Staples, and William H. Armstrong pp 9202–9204 DOI: 10.1021/ja0475508 Supporting Info

The Disarming Effect of the 4,6-Acetal Group on Glycoside Reactivity:  Torsional or Electronic? Henrik Helligsø Jensen, Lars Ulrik Nordstrøm, and Mikael Bols pp 9205–9213 DOI: 10.1021/ja047578j Supporting Info

Biosynthesis of Lambertellols Based on the High Specific Incorporation of the 13C-Labeled Acetates and Their Biological Properties Takanori Murakami, Yukiko Takahashi, Eri Fukushi, Jun Kawabata, Masaru Hashimoto, Toshikatsu Okuno, and Yukio Harada pp 9214–9220 DOI: 10.1021/ja048345v Supporting Info

Nitroxides Scavenge Myeloperoxidase-Catalyzed Thiyl Radicals in Model Systems and in Cells Grigory G. Borisenko, Ian Martin, Qing Zhao, Andrew A. Amoscato, and Valerian E. Kagan pp 9221–9232 DOI: 10.1021/ja0495157

Resonance Raman Spectroscopy Reveals New Insight into the Electronic Structure of β-Hematin and Malaria Pigment Bayden R. Wood, Steven J. Langford, Brian M. Cooke, Janelle Lim, Fiona K. Glenister, Martin Duriska, Jessica K. Unthank, and Don McNaughton pp 9233–9239 DOI: 10.1021/ja038691x Supporting Info

Factors Influencing the Autoxidation of Fatty Acids:  Effect of Olefin Geometry of the Nonconjugated Diene Keri A. Tallman, Bill Roschek, Jr., and Ned A. Porter pp 9240–9247 DOI: 10.1021/ja049104q Supporting Info

Synthesis, Relaxometric and Photophysical Properties of a New pH-Responsive MRI Contrast Agent:  The Effect of Other Ligating Groups on Dissociation of a p-Nitrophenolic Pendant Arm Mark Woods, Garry E. Kiefer, Simon Bott, Aminta Castillo-Muzquiz, Carrie Eshelbrenner, Lydie Michaudet, Kenneth McMillan, Siva D. K. Mudigunda, Doug Ogrin, Gyula Tircsó, Shanrong Zhang, Piyu Zhao, and A. Dean Sherry pp 9248–9256 DOI: 10.1021/ja048299z Supporting Info

Mispair-Aligned N3T-alkyl-N3T Interstrand Cross-Linked DNA:  Synthesis and Characterization of Duplexes with Interstrand Cross-Links of Variable Lengths Christopher J. Wilds, Anne M. Noronha, Sebastien Robidoux, and Paul S. Miller pp 9257–9265 DOI: 10.1021/ja0498540

Modular Aptameric Sensors Milan N. Stojanovic and Dmitry M. Kolpashchikov pp 9266–9270 DOI: 10.1021/ja032013t Supporting Info

Amplification of Chirality from Molecules into Morphology of Crystals through Molecular Recognition Yuya Oaki and Hiroaki Imai pp 9271–9275 DOI: 10.1021/ja048661+

Formation of Branched Calixarene AggregatesA Time-Resolved Static Light Scattering Study Thomas Witte, Björn Decker, Jochen Mattay, and Klaus Huber pp 9276–9282 DOI: 10.1021/ja0493291 Supporting Info

Stereochemistry of Isoplagiochin C, A Macrocyclic Bisbibenzyl from Liverworts Gerhard Bringmann, Jörg Mühlbacher, Matthias Reichert, Michael Dreyer, Jürgen Kolz, and Andreas Speicher pp 9283–9290 DOI: 10.1021/ja0373162 Supporting Info

Metal-Ion Sensing Fluorophores with Large Two-Photon Absorption Cross Sections:  Aza-Crown Ether Substituted Donor−Acceptor−Donor Distyrylbenzenes Stephanie J. K. Pond, Osamu Tsutsumi, Mariacristina Rumi, Ohyun Kwon, Egbert Zojer, Jean-Luc Brédas, Seth R. Marder, and Joseph W. Perry pp 9291–9306 DOI: 10.1021/ja049013t Supporting Info

Total Synthesis of Formamicin Timothy B. Durham, Nicolas Blanchard, Brad M. Savall, Noel A. Powell, and William R. Roush pp 9307–9317 DOI: 10.1021/ja048493l Supporting Info

Nitro-Substituted Hoveyda−Grubbs Ruthenium Carbenes:  Enhancement of Catalyst Activity through Electronic Activation Anna Michrowska, Robert Bujok, Syuzanna Harutyunyan, Volodymyr Sashuk, Grigory Dolgonos, and Karol Grela pp 9318–9325 DOI: 10.1021/ja048794v Supporting Info

EPR Study of Dialkyl Nitroxides as Probes to Investigate the Exchange of Solutes between the Ligand Shell of Monolayers of Protected Gold Nanoparticles and Aqueous Solutions Marco Lucarini, Paola Franchi, Gian Franco Pedulli, Paolo Pengo, Paolo Scrimin, and Lucia Pasquato pp 9326–9329 DOI: 10.1021/ja048554f Supporting Info

Mechanistic Studies of the Transfer Dehydrogenation of Cyclooctane Catalyzed by Iridium Bis(phosphinite) p-XPCP Pincer Complexes Inigo Göttker-Schnetmann and Maurice Brookhart pp 9330–9338 DOI: 10.1021/ja048393f

Diastereoselective Formation of Chiral Tris-Cyclometalated Iridium (III) Complexes:  Characterization and Photophysical Properties Christine Schaffner-Hamann, Alexander von Zelewsky Andrea Barbieri, Francesco Barigelletti, Gilles Muller, James P. Riehl, and Antonia Neels pp 9339–9348 DOI: 10.1021/ja048655d Supporting Info

Design and Photochemical Characterization of a Biomimetic Light-Driven Z/E Switcher Diego Sampedro, Annapaola Migani, Alessandra Pepi, Elena Busi, Riccardo Basosi, Loredana Latterini, Fausto Elisei, Stefania Fusi, Fabio Ponticelli, Vinicio Zanirato and Massimo Olivucci pp 9349–9359 DOI: 10.1021/ja038859e Supporting Info

Agostic Interactions and Dissociation in the First Layer of Water on Pt(111) Timo Jacob and William A. Goddard III pp 9360–9368 DOI: 10.1021/ja049920y

Supercritical Self-Assembled Monolayer Growth James M. Mellott and Daniel K. Schwartz pp 9369–9373 DOI: 10.1021/ja0489588

Intermittent Single-Molecule Interfacial Electron Transfer Dynamics Vasudevanpillai Biju, Miodrag Micic, Dehong Hu, and H. Peter Lu pp 9374–9381 DOI: 10.1021/ja040057b

Hydration of Phenylketene Revisited:  A Counter-Intuitive Result Yvonne Chiang, Andrei V. Fedorov, A. Jerry Kresge, Ikenna Onyido, and Thomas T. Tidwell pp 9382–9386 DOI: 10.1021/ja040101n Supporting Info

Synthesis of Colloidal Mn2+:ZnO Quantum Dots and High-TC Ferromagnetic Nanocrystalline Thin Films Nick S. Norberg, Kevin R. Kittilstved, James E. Amonette, Ravi K. Kukkadapu, Dana A. Schwartz, and Daniel R. Gamelin pp 9387–9398 DOI: 10.1021/ja048427j Supporting Info

Synthesis and Optical Properties of Nanorattles and Multiple-Walled Nanoshells/Nanotubes Made of Metal Alloys Yugang Sun, Benjamin Wiley, Zhi-Yuan Li, and Younan Xia pp 9399–9406 DOI: 10.1021/ja048789r Supporting Info

Gas Hydrate Single-Crystal Structure Analyses Michael T. Kirchner, Roland Boese, W. Edward Billups, and Lewis R. Norman pp 9407–9412 DOI: 10.1021/ja049247c Supporting Info

Highly Luminescent, Triple- and Quadruple-Stranded, Dinuclear Eu, Nd, and Sm(III) Lanthanide Complexes Based on Bis-Diketonate Ligands Andrew P. Bassett, Steven W. Magennis, Peter B. Glover, David J. Lewis, Neil Spencer, Simon Parsons, René M. Williams, Luisa De Cola, and Zoe Pikramenou pp 9413–9424 DOI: 10.1021/ja048022z Supporting Info

Structure of a Surfactant-Templated Silicate Framework in the Absence of 3D Crystallinity Niklas Hedin, Robert Graf, Sean C. Christiansen, Christel Gervais, Ryan C. Hayward, Juergen Eckert, and Bradley F. Chmelka pp 9425–9432 DOI: 10.1021/ja040030s

Oxygen Gas-Induced Lip−Lip Interactions on a Double-Walled Carbon Nanotube Edge Yong Soo Choi, Kyung Ah Park, Changwook Kim, and Young Hee Lee pp 9433–9438 DOI: 10.1021/ja039917z

Hydrogen Bonding versus Coordination of Adsorbate Molecules on Ti-Silicalites:  A Density Functional Theory Study Nurbosyn U. Zhanpeisov and Masakazu Anpo pp 9439–9444 DOI: 10.1021/ja0385484

Functional Vibrational Spectroscopy of a Cytochrome c Monolayer:  SEIDAS Probes the Interaction with Different Surface-Modified Electrodes Kenichi Ataka and Joachim Heberle pp 9445–9457 DOI: 10.1021/ja048346n Supporting Info

DNA Logic Gates Akimitsu Okamoto, Kazuo Tanaka, and Isao Saito pp 9458–9463 DOI: 10.1021/ja047628k

Optical Rotation of Noncovalent Aggregates  [J. Am. Chem. Soc. 2003, 125, 15696−15697].  Michael-Rock Goldsmith, Nilu Jayasuriya, David N. Beratan, and Peter Wipf p 9464 DOI: 10.1021/ja047614e

Synthesis of Carbohydrates through Biotechnology Edited by Peng George Wang (Wayne State University) and Yoshi Ichikawa (Optimer Pharmaceuticals, Inc.). American Chemical Society (Distributed by Oxford University Press):  Washington, DC. 2004. xii + 196 pp. $115.00. ISBN:  0-8412-3865-0. p 9465 DOI: 10.1021/ja0409311

Thermodynamic Data, Models and Phase Diagrams in Multicomponent Oxide Systems:  An Assessment for Materials and Planetary Scientists Based on Calorimetric, Volumetric and Phase Equilibrium Data By Olga B. Fabrichnaya (Max-Planck-Institut für Metallforschung, Stuttgart), Pascal Richet (Institute de Physique du Globe de Paris), Surendra K. Saxena (Florida International University), and Edgar F. Westrum, Jr. (University of Michigan). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xxiv + 198 pp. $129.00. ISBN:  3-540-14018-2. p 9465 DOI: 10.1021/ja040932t

The Chemistry of 1,2,3-Thiadiazoles. The Chemistry of Heterocyclic Compounds, Volume 62 By Vasiliy A. Bakulev (The Urals State Technical University) and Wim Dehaen (University of Leuven). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xviii + 242 pp. $325.00. ISBN:  0-471-32662-3. p 9465 DOI: 10.1021/ja040943m

Inorganic Syntheses, Volume 34 Edited by John R. Shapley (University of Illinois, Urbana-Champaign). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xxii + 260 pp. $94.95. ISBN:  0-471-64750-0. p 9465 DOI: 10.1021/ja040944e

Electroanalytical Chemistry:  A Series of Advances, Volume 22 Edited by Allen J. Bard (University of Texas at Austin) and Israel Rubinstein (Weizmann Institute of Science). Marcel Dekker, Inc.:  New York, Basel. 2003. xx + 310 pp. $199.00. ISBN:  0-8247-4719-4. Jody Redepenning pp 9465–9466 DOI: 10.1021/ja0336729

Issue 31

Helical β-Peptide Inhibitors of the p53-hDM2 Interaction Joshua A. Kritzer, James D. Lear, Michael E. Hodsdon, and Alanna Schepartz pp 9468–9469 DOI: 10.1021/ja031625a Supporting Info

Synthesis and Properties of Tadpole-Shaped Gold Nanoparticles Jianqiang Hu, Yong Zhang, Bo Liu, Jinxuan Liu, Haihui Zhou, Yunfeng Xu, Yuxiong Jiang, Zhilin Yang, and Zhong-Qun Tian pp 9470–9471 DOI: 10.1021/ja049738x Supporting Info

Two Types of Intramolecular Addition of an Al−N Multiple-Bonded Monomer LAlNAr‘ Arising from the Reaction of LAl with N3Ar‘ (L = HC[(CMe)(NAr)]2, Ar‘ = 2,6-Ar2C6H3, Ar = 2,6-iPr2C6H3) Hongping Zhu, Jianfang Chai, Vadapalli Chandrasekhar, Herbert W. Roesky, Jörg Magull, Denis Vidovic, Hans-Georg Schmidt, Mathias Noltemeyer, Philip P. Power, and William A. Merrill pp 9472–9473 DOI: 10.1021/ja0475712 Supporting Info

Highly Conjugated (Polypyridyl)metal−(Porphinato)zinc(II) Compounds:  Long-Lived, High Oscillator Strength, Excited-State Absorbers Having Exceptional Spectral Coverage of the Near-Infrared Timothy V. Duncan, Igor V. Rubtsov, H. Tetsuo Uyeda, and Michael J. Therien pp 9474–9475 DOI: 10.1021/ja0400638 Supporting Info

Rapid Direct Nanowriting of Conductive Polymer via Electrochemical Oxidative Nanolithography Sung-Yeon Jang, Manuel Marquez, and Gregory A. Sotzing pp 9476–9477 DOI: 10.1021/ja047766+ Supporting Info

Screening Molecular Associations with Lipid Membranes Using Natural Abundance 13C Cross-Polarization Magic-Angle Spinning NMR and Principal Component Analysis David A. Middleton, Eleri Hughes, and Jillian Madine pp 9478–9479 DOI: 10.1021/ja048226f Supporting Info

Carbon−Nitrogen Bond Formation via the Reaction of Terminal Alkynes with a Dinuclear Side-on Dinitrogen Complex Lara Morello, Jason B. Love, Brian O. Patrick, and Michael D. Fryzuk pp 9480–9481 DOI: 10.1021/ja049490b Supporting Info

Synthesis and Isolation of Cobalt Hexacyanoferrate/Chromate Metal Coordination Nanopolymers Stabilized by Alkylamino Ligand with Metal Elemental Control Mami Yamada, Masaya Arai, Masato Kurihara, Masatomi Sakamoto, and Mikio Miyake pp 9482–9483 DOI: 10.1021/ja0476866 Supporting Info

Designer Ligands for Beryllium Timothy S. Keizer, Nancy N. Sauer, and T. Mark McCleskey pp 9484–9485 DOI: 10.1021/ja047637t Supporting Info

Polythiophene Containing Thermally Removable Solubilizing Groups Enhances the Interface and the Performance of Polymer−Titania Hybrid Solar Cells Jinsong Liu, Ekaterina N. Kadnikova, Yuxiang Liu, Michael D. McGehee, and Jean M. J. Fréchet pp 9486–9487 DOI: 10.1021/ja047452m Supporting Info

Intensely Luminescent Gold(I)−Silver(I) Cluster Complexes with Tunable Structural Features Quan-Ming Wang, Young-A. Lee, Olga Crespo, Joseph Deaton, Ching Tang, Henry J. Gysling, M. Concepción Gimeno, Carmen Larraz, M. Dolores Villacampa, Antonio Laguna, and Richard Eisenberg pp 9488–9489 DOI: 10.1021/ja048091d Supporting Info

Self-Assembly of Heterobimetallic d−f Hybrid Complexes:  Sensitization of Lanthanide Luminescence by d-Block Metal-to-Ligand Charge-Transfer Excited States Simon J. A. Pope, Benjamin J. Coe, Stephen Faulkner, Elena V. Bichenkova, Xuan Yu, and Kenneth T. Douglas pp 9490–9491 DOI: 10.1021/ja047523h Supporting Info

A Minimum Free Energy Reaction Path for the E2 Reaction between Fluoro Ethane and a Fluoride Ion Bernd Ensing, Alessandro Laio, Francesco L. Gervasio, Michele Parrinello, and Michael L. Klein pp 9492–9493 DOI: 10.1021/ja048285t Supporting Info

On the Mössbauer Spectra of Isopenicillin N Synthase and a Model {FeNO}7 (S = 3/2) System Yong Zhang and Eric Oldfield pp 9494–9495 DOI: 10.1021/ja0401242 Supporting Info

Specific Band Observed in VCD Predicts the Anomeric Configuration of Carbohydrates Kenji Monde, Tohru Taniguchi, Nobuaki Miura, and Shin-Ichiro Nishimura pp 9496–9497 DOI: 10.1021/ja048446t Supporting Info

Forced Folding and Structural Analysis of Metastable Proteins Ronald W. Peterson, Karthik Anbalagan, Cecilia Tommos, and A. Joshua Wand pp 9498–9499 DOI: 10.1021/ja047900q

Impact of Protein Flexibility on Hydride-Transfer Parameters in Thermophilic and Psychrophilic Alcohol Dehydrogenases Zhao-Xun Liang, Iason Tsigos, Vassilis Bouriotis, and Judith P. Klinman pp 9500–9501 DOI: 10.1021/ja047087z Supporting Info

Ultrathin “Bed-of-Nails” Membranes of Single-Wall Carbon Nanotubes Yuhuang Wang, Sean Da, Myung Jong Kim, Kevin F. Kelly, Wenhua Guo, Carter Kittrell, Robert H. Hauge, and Richard E. Smalley pp 9502–9503 DOI: 10.1021/ja048680j Supporting Info

Solid-State NMR Spectroscopic Studies of an Integral Membrane Protein Inserted into Aligned Phospholipid Bilayer Nanotube Arrays Gary A. Lorigan, Paresh C. Dave, Elvis K. Tiburu, Krishnan Damodaran, Shadi Abu-Baker, Ethan S. Karp, William J. Gibbons, and Robert E. Minto pp 9504–9505 DOI: 10.1021/ja047317+

Role of Membrane Potential and Hydrogen Bonding in the Mechanism of Translocation of Guanidinium-Rich Peptides into Cells Jonathan B. Rothbard, Theodore C. Jessop, Richard S. Lewis, Bryce A. Murray, and Paul A. Wender pp 9506–9507 DOI: 10.1021/ja0482536 Supporting Info

Synthesis of Isolable Thiirane-2-thione (α-Dithiolactone) from Thioketene S-Oxide Kentaro Okuma, Toshiyuki Shigetomi, Yoshinori Nibu, Kosei Shioji, Masato Yoshida, and Yoshinobu Yokomori pp 9508–9509 DOI: 10.1021/ja0480320 Supporting Info

Solvent Control of Spin-Dependent Charge Recombination Mechanisms within Donor−Conjugated Bridge−Acceptor Molecules Emily A. Weiss, Michael J. Ahrens, Louise E. Sinks, Mark A. Ratner, and Michael R. Wasielewski pp 9510–9511 DOI: 10.1021/ja047205i Supporting Info

Hydrogel Microparticles as Dynamically Tunable Microlenses Jongseong Kim, Michael J. Serpe, and L. Andrew Lyon pp 9512–9513 DOI: 10.1021/ja047274x Supporting Info

Dissociation of Acetaldehyde on β-Mo2C To Yield Ethylidene and Oxo Surface Groups:  A Possible Pathway for Active Site Formation in Heterogeneous Olefin Metathesis Mohamed Siaj, Corey Reed, S. Ted Oyama, Susannah L. Scott, and Peter H. McBreen pp 9514–9515 DOI: 10.1021/ja048640f

Activating the Phosphate Nucleophile at the Catalytic Site of Purine Nucleoside Phosphorylase:  A Vibrational Spectroscopic Study Hua Deng, Andrzej Lewandowicz, Vern L. Schramm, and Robert Callender pp 9516–9517 DOI: 10.1021/ja049296p Supporting Info

Conversion of α-Haloaldehydes into Acylating Agents by an Internal Redox Reaction Catalyzed by Nucleophilic Carbenes Nathan T. Reynolds, Javier Read de Alaniz, and Tomislav Rovis pp 9518–9519 DOI: 10.1021/ja046991o Supporting Info

IR Spectrum and Structure of Protonated Ethanol Dimer:  Implications for the Mobility of Excess Protons in Solution Nicola Solcà and Otto Dopfer pp 9520–9521 DOI: 10.1021/ja047760k

Formation and Utility of Oxasilacyclopentenes Derived from Functionalized Alkynes Timothy B. Clark and K. A. Woerpel pp 9522–9523 DOI: 10.1021/ja047498f Supporting Info

Tandem Cyclopropanation/Ring-Closing Metathesis of Dienynes Brian P. Peppers and Steven T. Diver pp 9524–9525 DOI: 10.1021/ja049079o Supporting Info

Formation of Dimers That Contain Unbridged W(IV)/W(IV) Double Bonds Lourdes Pia H. Lopez and Richard R. Schrock pp 9526–9527 DOI: 10.1021/ja0400988 Supporting Info

Just Add Water:  A New Fluorous Capping Reagent for Facile Purification of Peptides Synthesized on the Solid Phase Vittorio Montanari and Krishna Kumar pp 9528–9529 DOI: 10.1021/ja0479033 Supporting Info

Cyanogen Bromide Cleavage Generates Fragments Suitable for Expressed Protein and Glycoprotein Ligation Derek Macmillan and Lubna Arham pp 9530–9531 DOI: 10.1021/ja047855m Supporting Info

3-Nitro-3-deaza-2‘-deoxyadenosine as a Versatile Photocleavable 2‘-Deoxyadenosine Mimic Caroline Crey-Desbiolles, Jean Lhomme, Pascal Dumy, and Mitsuharu Kotera pp 9532–9533 DOI: 10.1021/ja047976m Supporting Info

Studying Lateral Diffusion in Lipid Bilayers by Combining a Magic Angle Spinning NMR Probe with a Microimaging Gradient System André Pampel, Klaus Zick, Hartmut Glauner, and Frank Engelke pp 9534–9535 DOI: 10.1021/ja0474042 Supporting Info

Platinum-Catalyzed Intramolecular Hydroalkoxylation of γ- and δ-Hydroxy Olefins to Form Cyclic Ethers Hua Qian, Xiaoqing Han, and Ross A. Widenhoefer pp 9536–9537 DOI: 10.1021/ja0477773 Supporting Info

Human Serum Albumin-Mediated Stereodifferentiation in the Triplet State Behavior of (S)- and (R)-Carprofen Virginie Lhiaubet-Vallet, Zaideth Sarabia, Francisco Boscá, and Miguel A. Miranda pp 9538–9539 DOI: 10.1021/ja048518g

Spermine Participates in Oxidative Damage of Guanosine and 8-Oxoguanosine Leading to Deoxyribosylurea Formation Mandy E. Hosford, James G. Muller, and Cynthia J. Burrows pp 9540–9541 DOI: 10.1021/ja047981q Supporting Info

Palladium-Catalyzed Oxygenation of Unactivated sp3 C−H Bonds Lopa V. Desai, Kami L. Hull, and Melanie S. Sanford pp 9542–9543 DOI: 10.1021/ja046831c Supporting Info

Enantioselective Nazarov Reactions through Catalytic Asymmetric Proton Transfer Guangxin Liang and Dirk Trauner pp 9544–9545 DOI: 10.1021/ja0476664 Supporting Info

Synthesis of Bistramide A Alexander V. Statsuk, Dong Liu, and Sergey A. Kozmin pp 9546–9547 DOI: 10.1021/ja046588h Supporting Info

Engineering Human Fhit, a Diadenosine Triphosphate Hydrolase, into an Efficient Dinucleoside Polyphosphate Synthase Kaisheng Huang and Perry A. Frey pp 9548–9549 DOI: 10.1021/ja0400640 Supporting Info

Aerobic Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone with Copper(II) Chloride as Catalyst in Ionic Liquid and Structure of the Active Species Hongjian Sun, Klaus Harms, and Joerg Sundermeyer pp 9550–9551 DOI: 10.1021/ja0391964 Supporting Info

The Total Synthesis of (+)-Dragmacidin F Neil K. Garg, Daniel D. Caspi, and Brian M. Stoltz pp 9552–9553 DOI: 10.1021/ja046695b Supporting Info

Highly Regio- and Stereoselective Rearrangement of Epoxides to Aldehydes Catalyzed by High-Valent Metalloporphyrin Complex, Cr(TPP)OTf Kohji Suda, Taketoshi Kikkawa, Shin-ichiro Nakajima, and Toshikatsu Takanami pp 9554–9555 DOI: 10.1021/ja047104k Supporting Info

Metal Latticeworks Formed by Self-Organization in Oscillatory Electrodeposition Shuji Nakanishi, Kazuhiro Fukami, Toshio Tada, and Yoshihiro Nakato pp 9556–9557 DOI: 10.1021/ja047042y

A New Class of Chiral Pyrrolidine−Pyridine Conjugate Base Catalysts for Use in Asymmetric Michael Addition Reactions Takaaki Ishii, Shingo Fujioka, Yusuke Sekiguchi, and Hiyoshizo Kotsuki pp 9558–9559 DOI: 10.1021/ja046871g Supporting Info

Toward Fully Synthetic Carbohydrate-Based HIV Antigen Design:  On the Critical Role of Bivalency Vadim Y. Dudkin, Marianna Orlova, Xudong Geng, Mihirbaran Mandal, William C. Olson, and Samuel J. Danishefsky pp 9560–9562 DOI: 10.1021/ja047720g Supporting Info

An Organometallic Intermediate during Alkyne Reduction by Nitrogenase Hong-In Lee, Robert Y. Igarashi, Mikhail Laryukhin, Peter E. Doan, Patricia C. Dos Santos, Dennis R. Dean, Lance C. Seefeldt, and Brian M. Hoffman pp 9563–9569 DOI: 10.1021/ja048714n Supporting Info

Structural and Energetic Consequences of Expanding a Highly Cooperative Stable DNA Hairpin Loop Ellen M. Moody and Philip C. Bevilacqua pp 9570–9577 DOI: 10.1021/ja048368+

Selective Derivatization and Sequestration of Ribose from a Prebiotic Mix Greg Springsteen and Gerald F. Joyce pp 9578–9583 DOI: 10.1021/ja0483692 Supporting Info

Amino Acid-Type Edited NMR Experiments for Methyl−Methyl Distance Measurement in 13C-Labeled Proteins Hélène Van Melckebeke, Jean-Pierre Simorre, and Bernhard Brutscher pp 9584–9591 DOI: 10.1021/ja0489644 Supporting Info

Origin of Enantioselectivity in the Asymmetric Ru-Catalyzed Metathesis of Olefins Chiara Costabile and Luigi Cavallo pp 9592–9600 DOI: 10.1021/ja0484303 Supporting Info

2,2,5,5-Tetramethylpyrrolidin-3-one-1-sulfinyl Group for 5‘-Hydroxyl Protection of Deoxyribonucleoside Phosphoramidites in the Solid-Phase Preparation of DNA Oligonucleotides Vicente Marchán, Jacek Cieślak, Victor Livengood, and Serge L. Beaucage pp 9601–9610 DOI: 10.1021/ja048377i Supporting Info

Silicate Complexes of Sugars in Aqueous Solution Joseph B. Lambert, Gang Lu, Stephanie R. Singer, and Vera M. Kolb pp 9611–9625 DOI: 10.1021/ja031748v Supporting Info

Isolable Anion Radical of Blue Disilene (tBu2MeSi)2SiSi(SiMetBu2)2 Formed upon One-Electron Reduction:  Synthesis and Characterization Akira Sekiguchi, Shigeyoshi Inoue, Masaaki Ichinohe, and Yoriko Arai pp 9626–9629 DOI: 10.1021/ja040079y Supporting Info

Supramolecular Control over Donor−Acceptor Photoinduced Charge Separation Alicia Marcos Ramos, Stefan C. J. Meskers, Edwin H. A. Beckers, Ryan B. Prince, Luc Brunsveld, and René A. J. Janssen pp 9630–9644 DOI: 10.1021/ja0390909 Supporting Info

Catalytic Regioselectivity Control in Ring-Opening Cycloisomerization of Methylene- or Alkylidenecyclopropyl Ketones Shengming Ma, Lianghua Lu, and Junliang Zhang pp 9645–9660 DOI: 10.1021/ja0494860 Supporting Info

Effect of meta Electron-Donating Groups on the Electronic Structure of Substituted Phenyl Nitrenium Ions Arthur H. Winter, Daniel E. Falvey, and Christopher J. Cramer pp 9661–9668 DOI: 10.1021/ja047677x Supporting Info

Encapsulated Guest Molecules in the Dimer of Octahydroxypyridine[4]arene Matthias C. Letzel, Björn Decker, Alexander B. Rozhenko, Wolfgang W. Schoeller, and Jochen Mattay pp 9669–9674 DOI: 10.1021/ja049128x Supporting Info

Assembling of Amphiphilic Highly Branched Molecules in Supramolecular Nanofibers Maryna Ornatska, Sergiy Peleshanko, Kirsten L. Genson, Beth Rybak, Kathy N. Bergman, and Vladimir V. Tsukruk pp 9675–9684 DOI: 10.1021/ja0498944 Supporting Info

Development of Highly Diastereo- and Enantioselective Direct Asymmetric Aldol Reaction of a Glycinate Schiff Base with Aldehydes Catalyzed by Chiral Quaternary Ammonium Salts Takashi Ooi, Minoru Kameda, Mika Taniguchi, and Keiji Maruoka pp 9685–9694 DOI: 10.1021/ja048865q Supporting Info

Antibody-Catalyzed Oxy-Cope Rearrangement:  Mechanism and Origins of Catalysis and Stereoselectivity from DFT Quantum Mechanics and Flexible Docking Kersey A. Black, Andrew G. Leach, M. Yashar S. Kalani, and K. N. Houk pp 9695–9708 DOI: 10.1021/ja048604g Supporting Info

Intermolecular Electron Transfer from Naphthalene Derivatives in the Higher Triplet Excited States Masanori Sakamoto, Xichen Cai, Michihiro Hara, Mamoru Fujitsuka, and Tetsuro Majima pp 9709–9714 DOI: 10.1021/ja049948+ Supporting Info

A Combined Computational and Experimental Study of Polynuclear Ru−TPPZ Complexes:  Insight into the Electronic and Optical Properties of Coordination Polymers Simona Fantacci, Filippo De Angelis, Jingjing Wang, Stefan Bernhard, and Annabella Selloni pp 9715–9723 DOI: 10.1021/ja048421u Supporting Info

Elucidating the Significance of β-Hydride Elimination and the Dynamic Role of Acid/Base Chemistry in a Palladium-Catalyzed Aerobic Oxidation of Alcohols Jaime A. Mueller, Christopher P. Goller, and Matthew S. Sigman pp 9724–9734 DOI: 10.1021/ja047794s Supporting Info

Spectroscopic and Computational Studies of Co2+Corrinoids:  Spectral and Electronic Properties of the Biologically Relevant Base-On and Base-Off Forms of Co2+Cobalamin Troy A. Stich, Nicole R. Buan, and Thomas C. Brunold pp 9735–9749 DOI: 10.1021/ja0481631 Supporting Info

Adsorption of Gases and Vapors on Nanoporous Ni2(4,4‘-Bipyridine)3(NO3)4 Metal−Organic Framework Materials Templated with Methanol and Ethanol:  Structural Effects in Adsorption Kinetics Ashleigh J. Fletcher, Edmund J. Cussen, Darren Bradshaw, Matthew J. Rosseinsky, and K. Mark Thomas pp 9750–9759 DOI: 10.1021/ja0490267 Supporting Info

Cooperative Bimetallic Reactivity:  Hydrogen Activation in Two-Electron Mixed-Valence Compounds Thomas G. Gray, Adam S. Veige, and Daniel G. Nocera pp 9760–9768 DOI: 10.1021/ja0491432 Supporting Info

Chemical Evaluation of Hypothetical Uninodal Zeolites Martin D. Foster, Olaf Delgado Friedrichs, Robert G. Bell, Filipe A. Almeida Paz, and Jacek Klinowski pp 9769–9775 DOI: 10.1021/ja037334j Supporting Info

Heterogeneous or Homogeneous Catalysis? Mechanistic Studies of the Rhodium-Catalyzed Dehydrocoupling of Amine-Borane and Phosphine-Borane Adducts Cory A. Jaska and Ian Manners pp 9776–9785 DOI: 10.1021/ja0478431 Supporting Info

Mechanisms of Water Oxidation Catalyzed by the cis,cis-[(bpy)2Ru(OH2)]2O4+ Ion Hiroshi Yamada, William F. Siems, Tohru Koike, and James K. Hurst pp 9786–9795 DOI: 10.1021/ja030594g

Strong Near-Infrared Luminescence in BaSnO3 Hiroshi Mizoguchi, Patrick M. Woodward, Cheol-Hee Park, and Douglas A. Keszler pp 9796–9800 DOI: 10.1021/ja048866i Supporting Info

Electron Transfer in Uranyl(VI)−Uranyl(V) Complexes in Solution Timofei Privalov, Peter Macak, Bernd Schimmelpfennig, Emmanuel Fromager, Ingmar Grenthe, and Ulf Wahlgren pp 9801–9808 DOI: 10.1021/ja049205o Supporting Info

Complex Mechanism of the Gas Phase Reaction between Formic Acid and Hydroxyl Radical. Proton Coupled Electron Transfer versus Radical Hydrogen Abstraction Mechanisms Josep M. Anglada pp 9809–9820 DOI: 10.1021/ja0481169 Supporting Info

Simultaneous Recording of Spin-State-Selective NMR Spectra for Different InS Spin Systems Teodor Parella and Margarida Gairí pp 9821–9826 DOI: 10.1021/ja0495866 Supporting Info

Stereospecific NMR Assignments of Prochiral Methyls, Rotameric States and Dynamics of Valine Residues in Malate Synthase G Vitali Tugarinov and Lewis E. Kay pp 9827–9836 DOI: 10.1021/ja048738u Supporting Info

Strong Interfullerene Electronic Communication in a Bisfullerene−Hexarhodium Sandwich Complex Kwangyeol Lee, Yoon Jeong Choi, Youn-Jaung Cho, Chang Yeon Lee, Hyunjoon Song, Chang Hoon Lee, Yoon Sup Lee, and Joon T. Park pp 9837–9844 DOI: 10.1021/ja047290u Supporting Info

High-Efficiency, Environment-Friendly Electroluminescent Polymers with Stable High Work Function Metal as a Cathode:  Green- and Yellow-Emitting Conjugated Polyfluorene Polyelectrolytes and Their Neutral Precursors Fei Huang, Lintao Hou, Hongbin Wu, Xiaohui Wang, Huilin Shen, Wei Cao, Wei Yang, and Yong Cao pp 9845–9853 DOI: 10.1021/ja0476765

Ab Initio Molecular Dynamics Simulations and g-Tensor Calculations of Aqueous Benzosemiquinone Radical Anion:  Effects of Regular and “T-Stacked” Hydrogen Bonds James R. Asher, Nikos L. Doltsinis, and Martin Kaupp pp 9854–9861 DOI: 10.1021/ja0485053 Supporting Info

Cation−π Interactions of a Thiocarbonyl Group and a Carbonyl Group with a Pyridinium Nucleus Shinji Yamada, Tomoko Misono, and Seiji Tsuzuki pp 9862–9872 DOI: 10.1021/ja0490119 Supporting Info

Synthesis of [l-Ala-1]RA-VII, [d-Ala-2]RA-VII, and [d-Ala-4]RA-VII by Epimerization of RA-VII, an Antitumor Bicyclic Hexapeptide from Rubia Plants, through Oxazoles [J. Am. Chem. Soc. 2003, 125, 7284−7290]. Yukio Hitotsuyanagi, Shin-ichi Sasaki, Yuji Matsumoto, Kentaro Yamaguchi, Hideji Itokawa, and Koichi Takeya p 9873 DOI: 10.1021/ja040812l Supporting Info

The Intrinsic Stability of the Noble Gas-Coordinated Transition-Metal Complex Ions [J. Am. Chem. Soc. 2001, 123, 2340−2343]. Wei-Ping Hu and Chun-Huei Huang p 9873 DOI: 10.1021/ja046800h

Monolithic Materials:  Preparation, Properties and Applications. Journal of Chromatography Library, Volume 67 Edited by František Švec (University of California, Berkeley), Tatiana B. Tennikova (Russian Academy of Sciences, St. Petersburg), and Zdeněk Deyl (Academy of Sciences of the Czech Republic, Prague). Elsevier:  Amsterdam. 2003. xx + 780 pp. $350.00. ISBN 0-444-50879-1. Edgar A. Arriaga p 9874 DOI: 10.1021/ja0335925

Progress in Inorganic Chemistry, Volume 52, Dithiolene Chemistry:  Synthesis, Properties, and Applications Volume Edited by Edward I. Stiefel (Princeton University). Series edited by K. D. Karlin (Johns Hopkins University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xii + 738 pp. $150.00. ISBN:  0-471-37829-1. R. H. Holm p 9874 DOI: 10.1021/ja033671g

Issue 32

The Crystal Structures of a Chiral Aminoalkoxide Cluster and Its Adduct with Benzyllithium Carsten Strohmann, Timo Seibel, and Daniel Schildbach pp 9876–9877 DOI: 10.1021/ja048216e Supporting Info

Guanidinium Groups Act as General-Acid Catalysts in Phosphoryl Transfer Reactions:  A Two-Proton Inventory on a Model System Anna M. Pitek, Mark Gray, and Eric V. Anslyn pp 9878–9879 DOI: 10.1021/ja046894v Supporting Info

A New Synthetic Method for Controlled Polymerization Using a Microfluidic System Tao Wu, Ying Mei, João T. Cabral, Chang Xu, and Kathryn L. Beers pp 9880–9881 DOI: 10.1021/ja048432n Supporting Info

Dendronized Protein Polymers:  Synthesis and Self-Assembly of Monodisperse Cylindrical Macromolecules Michael A. Zhuravel, Nicolynn E. Davis, SonBinh T. Nguyen, and Ilya Koltover pp 9882–9883 DOI: 10.1021/ja046965q Supporting Info

Switchable Neutral Bistable Rotaxanes Scott A. Vignon, Thibaut Jarrosson, Takahiro Iijima, Hsian-Rong Tseng, Jeremy K. M. Sanders, and J. Fraser Stoddart pp 9884–9885 DOI: 10.1021/ja048080k Supporting Info

Small-Molecule Dimerization Inhibitors of Wild-Type and Mutant HIV Protease:  A Focused Library Approach Michael D. Shultz, Young-Wan Ham, Song-Gil Lee, David A. Davis, Cara Brown, and Jean Chmielewski pp 9886–9887 DOI: 10.1021/ja048139n Supporting Info

Hybrid Photoactive Assemblies:  Electron Injection from Host−Guest Complexes into Semiconductor Nanoparticles Cynthia Pagba, Giovanni Zordan, Elena Galoppini, Eugene L. Piatnitski, Sarmimala Hore, Kurt Deshayes, and Piotr Piotrowiak pp 9888–9889 DOI: 10.1021/ja0475252 Supporting Info

Invertible Amphiphilic Homopolymers Subhadeep Basu, Dharma Rao Vutukuri, Subarana Shyamroy, Britto S. Sandanaraj, and S. Thayumanavan pp 9890–9891 DOI: 10.1021/ja047816a Supporting Info

Porphyrins As Photosensitizers To Enhance Night Vision Ilyas Washington, Celeste Brooks, Nicholas J. Turro, and Koji Nakanishi pp 9892–9893 DOI: 10.1021/ja0486317

Phase Transition of a Single Sheet of Sashlike Polydiacetylene Atomic Sash on a Solid Surface Osamu Endo, Hiroaki Ootsubo, Naoya Toda, Masanori Suhara, Hiroyuki Ozaki, and Yasuhiro Mazaki pp 9894–9895 DOI: 10.1021/ja047841g Supporting Info

The Turnover Rate for the Catalytic Combustion of Methane over Palladium Is Not Sensitive to the Structure of the Catalyst Guanghui Zhu, Jinyi Han, Dmitri Y. Zemlyanov, and Fabio H. Ribeiro pp 9896–9897 DOI: 10.1021/ja049406s Supporting Info

Probing the Interaction of HTI-286 with Tubulin Using a Stilbene Analogue Mei-Chu Lo, Ann Aulabaugh, Girija Krishnamurthy, Joshua Kaplan, Arie Zask, Robert P. Smith, and George Ellestad pp 9898–9899 DOI: 10.1021/ja048619e Supporting Info

Thermally-Induced Formation of Atomic Au Clusters and Conversion into Nanocubes Rongchao Jin, Shunji Egusa, and Norbert F. Scherer pp 9900–9901 DOI: 10.1021/ja0482482 Supporting Info

Small-Angle Neutron Scattering from Surfactant-Assisted Aqueous Dispersions of Carbon Nanotubes Koray Yurekli, Cynthia A. Mitchell, and Ramanan Krishnamoorti pp 9902–9903 DOI: 10.1021/ja047451u Supporting Info

Axial-Selective Prins Cyclizations by Solvolysis of α-Bromo Ethers Ramesh Jasti, Justin Vitale, and Scott D. Rychnovsky pp 9904–9905 DOI: 10.1021/ja046972e Supporting Info

Highly Enantioselective Conjugate Addition of Malonate and β-Ketoester to Nitroalkenes:  Asymmetric C−C Bond Formation with New Bifunctional Organic Catalysts Based on Cinchona Alkaloids Hongming Li, Yi Wang, Liang Tang, and Li Deng pp 9906–9907 DOI: 10.1021/ja047281l Supporting Info

Tropopause Chemistry Revisited:  HO2•-Initiated Oxidation as an Efficient Acetone Sink Ive Hermans, Thanh L. Nguyen, Pierre A. Jacobs, and Jozef Peeters pp 9908–9909 DOI: 10.1021/ja0467317 Supporting Info

Polymer-Anchored DNA Gene Monolayers Patrick A. Johnson, Mariafrancis A. Gaspar, and Rastislav Levicky pp 9910–9911 DOI: 10.1021/ja048415y Supporting Info

Identification of 4-Amino-4-deoxychorismate Synthase as the Molecular Target for the Antimicrobial Action of (6S)-6-Fluoroshikimate Esther M. M. Bulloch, Michelle A. Jones, Emily J. Parker, Andrew P. Osborne, Elaine Stephens, Gareth M. Davies, John R. Coggins, and Chris Abell pp 9912–9913 DOI: 10.1021/ja048312f Supporting Info

Nanoacorns:  Anisotropically Phase-Segregated CoPd Sulfide Nanoparticles Toshiharu Teranishi, Youhei Inoue, Masafumi Nakaya, Yasunori Oumi, and Tsuneji Sano pp 9914–9915 DOI: 10.1021/ja047606y Supporting Info

Glued Langmuir−Blodgett Bilayers from Porous versus Nonporous Surfactants Donald H. McCullough, III, Vaclav Janout, Junwei Li, James T. Hsu, Quoc Truong, Eugene Wilusz, and Steven L. Regen pp 9916–9917 DOI: 10.1021/ja047365u Supporting Info

Highly Efficient Synthesis of β-Amino Acid Derivatives via Asymmetric Hydrogenation of Unprotected Enamines Yi Hsiao, Nelo R. Rivera, Thorsten Rosner, Shane W. Krska, Eugenia Njolito, Fang Wang, Yongkui Sun, Joseph D. Armstrong, III, Edward J. J. Grabowski, Richard D. Tillyer, Felix Spindler, and Christophe Malan pp 9918–9919 DOI: 10.1021/ja047901i Supporting Info

Stereoselective Cyclization and Pyramidal Inversion Strategies for P-Chirogenic Phospholane Synthesis Garrett Hoge pp 9920–9921 DOI: 10.1021/ja048079l Supporting Info

Precursor Mediated Cycloaddition Reaction of Ethylene to the Si(100)c(4 × 2) Surface Masashi Nagao, Hirobumi Umeyama, Kozo Mukai, Yoshiyuki Yamashita, Jun Yoshinobu, Kazuto Akagi, and Shinji Tsuneyuki pp 9922–9923 DOI: 10.1021/ja047426o Supporting Info

Reconstitution and Characterization of a New Desosaminyl Transferase, EryCIII, from the Erythromycin Biosynthetic Pathway Ho Young Lee, Hak Suk Chung, Chao Hang, Chaitan Khosla, Christopher T. Walsh, Daniel Kahne, and Suzanne Walker pp 9924–9925 DOI: 10.1021/ja048836f Supporting Info

Inter- and Intramolecular [4 + 1]-Cycloadditions Between Electron-Poor Dienes and Electron-Rich Carbenes Claude Spino, Hadi Rezaei, Kristina Dupont-Gaudet, and Francis Bélanger pp 9926–9927 DOI: 10.1021/ja046344x Supporting Info

Cooperative Dual Catalysis:  Application to the Highly Enantioselective Conjugate Cyanation of Unsaturated Imides Glenn M. Sammis, Hiroshi Danjo, and Eric N. Jacobsen pp 9928–9929 DOI: 10.1021/ja046653n Supporting Info

Spin-Localized Cyclopentadienyl Radical Annelated with Homoadamantene Frameworks:  Isolation, X-ray Crystal Structure, and ESR Characterization Toshikazu Kitagawa, Kohei Ogawa, and Koichi Komatsu pp 9930–9931 DOI: 10.1021/ja046617o Supporting Info

The Unusual Bifunctional Catalysis of Epimerization and Desaturation by Carbapenem Synthase Maya Topf, Gregory M. Sandala, David M. Smith, Christopher J. Schofield, Christopher J. Easton, and Leo Radom pp 9932–9933 DOI: 10.1021/ja047899v Supporting Info

Gold(I) in Liquid Ammonia: Ab Initio QM/MM Molecular Dynamics Simulation Ria Armunanto, Christian F. Schwenk, and Bernd M. Rode pp 9934–9935 DOI: 10.1021/ja031740l Supporting Info

Low-Temperature Growth of Carbon Nanotubes from the Catalytic Decomposition of Carbon Tetrachloride Jason K. Vohs, Jonathan J. Brege, Jeffery E. Raymond, Allan E. Brown, Geoffrey L. Williams, and Bradley D. Fahlman pp 9936–9937 DOI: 10.1021/ja0478227 Supporting Info

Dopamine as A Robust Anchor to Immobilize Functional Molecules on the Iron Oxide Shell of Magnetic Nanoparticles Chenjie Xu, Keming Xu, Hongwei Gu, Rongkun Zheng, Hui Liu, Xixiang Zhang, Zhihong Guo, and Bing Xu pp 9938–9939 DOI: 10.1021/ja0464802 Supporting Info

Luminescent Heteronuclear AuI5AgI8 Complexes of {1,2,3-C6(C6H4R-4)3}3- (R = H, CH3, But) by Cyclotrimerization of Arylacetylides Qiao-Hua Wei, Li-Yi Zhang, Gang-Qiang Yin, Lin-Xi Shi, and Zhong-Ning Chen pp 9940–9941 DOI: 10.1021/ja047302b Supporting Info

Design and Synthesis of a 4-(2‘-Pyridyl)-1,2,3,5-Dithiadiazolyl Cobalt Complex Nigel G. R. Hearns, Kathryn E. Preuss, John F. Richardson, and Sofi Bin-Salamon pp 9942–9943 DOI: 10.1021/ja046304t Supporting Info

Long-Range Stereo-Relay:  Relative and Absolute Configuration of 1,n-Glycols from Circular Dichroism of Liposomal Porphyrin Esters John B. MacMillan and Tadeusz F. Molinski pp 9944–9945 DOI: 10.1021/ja047741a Supporting Info

The Electronic Structure of Mn in Oxides, Coordination Complexes, and the Oxygen-Evolving Complex of Photosystem II Studied by Resonant Inelastic X-ray Scattering Pieter Glatzel, Uwe Bergmann, Junko Yano, Hendrik Visser, John H. Robblee, Weiwei Gu, Frank M. F. de Groot, George Christou, Vincent L. Pecoraro, Stephen P. Cramer, and Vittal K. Yachandra pp 9946–9959 DOI: 10.1021/ja038579z Supporting Info

5-Cyanoimino-4-oxomethylene-4,5-dihydroimidazole and 5-Cyanoamino-4-imidazolecarboxylic Acid Intermediates in Nitrosative Guanosine Deamination:  Evidence from 18O-Labeling Experiments Sundeep Rayat, Papiya Majumdar, Peter Tipton, and Rainer Glaser pp 9960–9969 DOI: 10.1021/ja049835q

Single-Nucleotide-Specific PNA−Peptide Ligation on Synthetic and PCR DNA Templates Simon Ficht, Amos Mattes, and Oliver Seitz pp 9970–9981 DOI: 10.1021/ja048845o Supporting Info

Unexpectedly Small Ortho-Oxygen Substituent Effects on Stabilities of Benzylic Carbocations M. Fujio, J. R. Keeffe, R. A. More O'Ferrall, and A. C. O'Donoghue pp 9982–9992 DOI: 10.1021/ja030446q Supporting Info

Mechanism of Silver-Mediated Di-tert-butylsilylene Transfer from a Silacyclopropane to an Alkene Tom G. Driver and K. A. Woerpel pp 9993–10002 DOI: 10.1021/ja0306563 Supporting Info

Synthesis and Supramolecular Assemblies of Bipolar Archaeal Glycolipid Analogues Containing a cis-1,3-Disubstituted Cyclopentane Ring Mickaëlle Brard, Walter Richter, Thierry Benvegnu, and Daniel Plusquellec pp 10003–10012 DOI: 10.1021/ja049805n Supporting Info

Targeted Proton Delivery in the Catalyzed Reduction of Oxygen to Water by Bimetallic Pacman Porphyrins Christopher J. Chang, Zhi-Heng Loh, Chunnian Shi, Fred C. Anson, and Daniel G. Nocera pp 10013–10020 DOI: 10.1021/ja049115j Supporting Info

Synthesis of n-Type Perylene Bisimide Derivatives and Their Orthogonal Self-Assembly with p-Type Oligo(p-phenylene vinylene)s Jeroen van Herrikhuyzen, Asha Syamakumari, Albertus P. H. J. Schenning, and E. W. Meijer pp 10021–10027 DOI: 10.1021/ja048819q Supporting Info

A B3LYP Study of the Effects of Phenyl Substituents on 1,5-Hydrogen Shifts in 3-(Z)-1,3-Pentadiene Provides Evidence Against a Chameleonic Transition Structure Shuichi Hayase, David A. Hrovat, and Weston Thatcher Borden pp 10028–10034 DOI: 10.1021/ja048708r Supporting Info

Molecular Clips Form Isostructural Dimeric Aggregates from Benzene to Water Anxin Wu, Pritam Mukhopadhyay, Arindam Chakraborty, James C. Fettinger, and Lyle Isaacs pp 10035–10043 DOI: 10.1021/ja0486972 Supporting Info

Cytotoxicity, Hemolysis, and Acute in Vivo Toxicity of Dendrimers Based on Melamine, Candidate Vehicles for Drug Delivery Hui-Ting Chen, Michael F. Neerman, Alan R. Parrish, and Eric E. Simanek pp 10044–10048 DOI: 10.1021/ja048548j Supporting Info

Design of an Inversion Center between Two Helical Segments Victor Maurizot, Christel Dolain, Yoann Leydet, Jean-Michel Léger, Philippe Guionneau, and Ivan Huc pp 10049–10052 DOI: 10.1021/ja0481981 Supporting Info

13C NMR and Infrared Evidence of a Dioctyl−Disulfide Structure on Octanethiol-Protected Palladium Nanoparticle Surfaces Brian S. Zelakiewicz, Georgeta C. Lica, Morgan L. Deacon, and YuYe Tong pp 10053–10058 DOI: 10.1021/ja0491883

Preparation and Phase Segregation of Block Copolymer Nanotube Multiblocks Xiaohu Yan, Guojun Liu, and Zhao Li pp 10059–10066 DOI: 10.1021/ja0479890

Thermodynamic and Kinetic Stability of Synthetic Multifunctional Rigid-Rod β-Barrel Pores:  Evidence for Supramolecular Catalysis Svetlana Litvinchuk, Guillaume Bollot, Jiri Mareda, Abhigyan Som, Dawn Ronan, Muhammad Raza Shah, Philippe Perrottet, Naomi Sakai, and Stefan Matile pp 10067–10075 DOI: 10.1021/ja0481878 Supporting Info

Rational and Combinatorial Design of Peptide Capping Ligands for Gold Nanoparticles Raphaël Lévy, Nguyen T. K. Thanh, R. Christopher Doty, Irshad Hussain, Richard J. Nichols, David J. Schiffrin, Mathias Brust, and David G. Fernig pp 10076–10084 DOI: 10.1021/ja0487269 Supporting Info

Discrete Bridging and Terminal Copper Carbenes in Copper-Catalyzed Cyclopropanation Xuliang Dai and Timothy H. Warren pp 10085–10094 DOI: 10.1021/ja047935q Supporting Info

Probing the Structure and Dynamics of End-Grafted Flexible Polymer Chain Layers by Combined Atomic Force−Electrochemical Microscopy. Cyclic Voltammetry within Nanometer-Thick Macromolecular Poly(ethylene glycol) Layers Jeremy Abbou, Agnès Anne, and Christophe Demaille pp 10095–10108 DOI: 10.1021/ja0493502 Supporting Info

Photoisomerization Dynamics of Azobenzene in Solution with S1 Excitation:  A Femtosecond Fluorescence Anisotropy Study Chih-Wei Chang, Ying-Chih Lu, Tsai-Te Wang, and Eric Wei-Guang Diau pp 10109–10118 DOI: 10.1021/ja049215p Supporting Info

Double-Proton Transfer in Adenine−Thymine and Guanine−Cytosine Base Pairs. A Post-Hartree−Fock ab Initio Study Leonid Gorb, Yevgeniy Podolyan, Pawel Dziekonski, W. Andrzej Sokalski, and Jerzy Leszczynski pp 10119–10129 DOI: 10.1021/ja049155n

Surface Electrochemistry of CO on Reconstructed Gold Single Crystal Surfaces Studied by Infrared Reflection Absorption Spectroscopy and Rotating Disk Electrode Berislav B. Blizanac, Matthias Arenz, Philip N. Ross, and Nenad M. Marković pp 10130–10141 DOI: 10.1021/ja049038s

Accurate Interaction Energies of Hydrogen-Bonded Nucleic Acid Base Pairs Jiří Šponer, Petr Jureka, and Pavel Hobza pp 10142–10151 DOI: 10.1021/ja048436s Supporting Info

Free Energy of Adsorption of Water and Metal Ions on the {104} Calcite Surface Sebastien Kerisit and Stephen C. Parker pp 10152–10161 DOI: 10.1021/ja0487776 Supporting Info

Studies toward Diazonamide A:  Initial Synthetic Forays Directed toward the Originally Proposed Structure K. C. Nicolaou, Scott A. Snyder, Xianhai Huang, Klaus B. Simonsen, Alexandros E. Koumbis, and Antony Bigot pp 10162–10173 DOI: 10.1021/ja040090y Supporting Info

Studies toward Diazonamide A:  Development of a Hetero-Pinacol Macrocyclization Cascade for the Construction of the Bis-Macrocyclic Framework of the Originally Proposed Structure K. C. Nicolaou, Scott A. Snyder, Nicolas Giuseppone, Xianhai Huang, Marco Bella, Mali V. Reddy, Paraselli Bheema Rao, Alexandros E. Koumbis, Paraskevi Giannakakou, and Aurora O'Brate pp 10174–10182 DOI: 10.1021/ja040091q Supporting Info

Tuning Emissive States in Electrogenerated Chemiluminescence Jacob B. Ketter and R. Mark Wightman pp 10183–10189 DOI: 10.1021/ja047602t

Rhodium-Catalyzed Carbonylative [3+2+1] Cycloaddition Reaction:  Catalytic Formation of Bicyclic Cyclohexenones from Trienes and Carbon Monoxide [J. Am. Chem. Soc. 2004, 126, 2714−2715]. Sang Ick Lee, Ji Hoon Park, Young Keun Chung, and Sueg-Geun Lee p 10190 DOI: 10.1021/ja040813d Supporting Info

Isotope Effects on the Picosecond Time-Resolved Emission Spectroscopy of Tris(2,2‘-bipyridine)ruthenium (II) [J. Am. Chem. Soc. 2003, 125, 1706−1707]. Wesley R. Browne, Colin G. Coates, Clare Brady, Pavel Matousek, Michael Towrie, Stanley W. Botchway, Anthony W. Parker, Johannes G. Vos, and John J. McGarvey p 10190 DOI: 10.1021/ja040815y

Molecular Devices and Machines:  A Journey into the Nanoworld By Vincenzo Balzani, Margherita Venturi, and Alberto Credi (Universita di Bologna). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2003. xviii + 494 pp. $75.00. ISBN:  3-527-30506-8. T. Ross Kelly p 10191 DOI: 10.1021/ja033560h

Advances in Chemical Physics. Volume 127 Edited by I. Prigogine (University of Texas at Austin and Université Libre De Bruxelles, Belgium) and Stuart A. Rice (University of Chicago). John Wiley & Sons, Inc.:  Hoboken, NJ. 2003. x + 358 pp. $175.00. ISBN 0-471-23583-0. David S. Corti pp 10191–10192 DOI: 10.1021/ja033621b

Reactive Intermediate Chemistry Edited by Robert A. Moss (Rutgers University), Matthew S. Platz (Ohio State University), and Maitland Jones, Jr. (Princeton University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. viii + 1072 pp. $99.95. ISBN 0-471-23324-2. James A. Pincock p 10192 DOI: 10.1021/ja0409107

Issue 33

A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2 Hongping Zhu, Jianfang Chai, Qingjun Ma, Vojtech Jancik, Herbert W. Roesky, Hongjun Fan, and Regine Herbst-Irmer pp 10194–10195 DOI: 10.1021/ja049462t Supporting Info

Carbon Tunneling in the Ring Expansion of Noradamantylchlorocarbene Robert A. Moss, Ronald R. Sauers, Robert S. Sheridan, Jingzhi Tian, and Peter S. Zuev pp 10196–10197 DOI: 10.1021/ja0488939 Supporting Info

A Stable Four-Membered N-Heterocyclic Carbene Emmanuelle Despagnet-Ayoub and Robert H. Grubbs pp 10198–10199 DOI: 10.1021/ja047892d Supporting Info

Simple Method for Determining Nucleobase pKa Values by Indirect Labeling and Demonstration of a pKa of Neutrality in dsDNA Ellen M. Moody, Trevor S. Brown, and Philip C. Bevilacqua pp 10200–10201 DOI: 10.1021/ja047362h Supporting Info

Improving Solid-State NMR Dipolar Recoupling by Optimal Control Cindie T. Kehlet, Astrid C. Sivertsen, Morten Bjerring, Timo O. Reiss, Navin Khaneja, Steffen J. Glaser, and Niels Chr. Nielsen pp 10202–10203 DOI: 10.1021/ja048786e

Brønsted Acid-Promoted Cyclizations of Siloxyalkynes with Arenes and Alkenes Liming Zhang and Sergey A. Kozmin pp 10204–10205 DOI: 10.1021/ja046586x Supporting Info

Virtual Free Ion Magnetism and the Absence of Jahn−Teller Distortion in a Linear Two-Coordinate Complex of High-Spin Iron(II) William M. Reiff, Anne M. LaPointe, and Edward H. Witten pp 10206–10207 DOI: 10.1021/ja030632w

An Unusual Exchange between Alkylidyne Alkyl and Bis(alkylidene) Tungsten Complexes Promoted by Phosphine Coordination:  Kinetic, Thermodynamic, and Theoretical Studies Laurel A. Morton, Xin-Hao Zhang, Ruitao Wang, Zhenyang Lin, Yun-Dong Wu, and Zi-Ling Xue pp 10208–10209 DOI: 10.1021/ja0467263 Supporting Info

Relay Ring-Closing Metathesis (RRCM):  A Strategy for Directing Metal Movement Throughout Olefin Metathesis Sequences Thomas R. Hoye, Christopher S. Jeffrey, Manomi A. Tennakoon, Jizhou Wang, and Hongyu Zhao pp 10210–10211 DOI: 10.1021/ja046385t Supporting Info

Characterization of Peroxo and Hydroperoxo Intermediates in the Aerobic Oxidation of N-Heterocyclic-Carbene-Coordinated Palladium(0) Michael M. Konnick, Ilia A. Guzei, and Shannon S. Stahl pp 10212–10213 DOI: 10.1021/ja046884u Supporting Info

Steady-State Detection of Cholesterol Contained in the Plasma Membrane of a Single Cell Using Lipid Bilayer-Modified Microelectrodes Incorporating Cholesterol Oxidase Anando Devadoss and James D. Burgess pp 10214–10215 DOI: 10.1021/ja047856e Supporting Info

Reactive Sulfur Species:  Aqueous Chemistry of Sulfenyl Thiocyanates Michael T. Ashby and Halikhedkar Aneetha pp 10216–10217 DOI: 10.1021/ja048585a Supporting Info

Reduction of Dioxygen Catalyzed by Pyrene-Wired Heme Domain Cytochrome P450 BM3 Electrodes Andrew K. Udit, Michael G. Hill, V. Garrett Bittner, Frances H. Arnold, and Harry B. Gray pp 10218–10219 DOI: 10.1021/ja0466560 Supporting Info

Covalently Modified Silicon and Diamond Surfaces:  Resistance to Nonspecific Protein Adsorption and Optimization for Biosensing Tami L. Lasseter, Brian H. Clare, Nicholas L. Abbott, and Robert J. Hamers pp 10220–10221 DOI: 10.1021/ja047642x

Catalytic Deallylation of Allyl- and Diallylmalonates David Neas, Matyáš Turský, and Martin Kotora pp 10222–10223 DOI: 10.1021/ja047320t Supporting Info

Bivalent Cholesterol-Based Coupling of Oligonucletides to Lipid Membrane Assemblies Indriati Pfeiffer and Fredrik Höök pp 10224–10225 DOI: 10.1021/ja048514b

A Generic Organometallic Approach toward Ultra-Strong Carbon Nanotube Polymer Composites Rowan Blake, Yurii K. Gun'ko, Jonathan Coleman, Martin Cadek, Antonio Fonseca, Janos B. Nagy, and Werner J. Blau pp 10226–10227 DOI: 10.1021/ja0474805 Supporting Info

NMR Detection of Intermolecular NH···OP Hydrogen Bonds between Guanidinium Protons and Bisposphonate Moieties in an Artificial Arginine Receptor Ruth M. Gschwind, Marcia Armbrüster, and Igor Z. Zubrzycki pp 10228–10229 DOI: 10.1021/ja0483701 Supporting Info

Pseudohexagonal 2D DNA Crystals from Double Crossover Cohesion Baoquan Ding, Ruojie Sha, and Nadrian C. Seeman pp 10230–10231 DOI: 10.1021/ja047486u Supporting Info

Strongly Fluorescent Organogel System Comprising Fibrillar Self-Assembly of a Trifluoromethyl-Based Cyanostilbene Derivative Byeong-Kwan An, Deug-Sang Lee, Jong-Soon Lee, Yil-Sung Park, Hyung-Su Song, and Soo Young Park pp 10232–10233 DOI: 10.1021/ja046215g Supporting Info

Diminished Band-Gap Transitions of Single-Walled Carbon Nanotubes in Complexation with Aromatic Molecules K. A. Shiral Fernando, Yi Lin, Wei Wang, Satish Kumar, Bing Zhou, Su-Yuan Xie, LaShonda T. Cureton, and Ya-Ping Sun pp 10234–10235 DOI: 10.1021/ja047691+ Supporting Info

Mild, Aqueous, Aerobic, Catalytic Oxidation of Methane to Methanol and Acetaldehyde Catalyzed by a Supported Bipyrimidinylplatinum−Polyoxometalate Hybrid Compound Itsik Bar-Nahum, Alexander M. Khenkin, and Ronny Neumann pp 10236–10237 DOI: 10.1021/ja0493547 Supporting Info

Photoresponse of p-Type Zinc-Doped Iron(III) Oxide Thin Films William B. InglerJr., John P. Baltrus, and Shahed U. M. Khan pp 10238–10239 DOI: 10.1021/ja048461y Supporting Info

Catalytic Cross-Coupling of Alkylzinc Halides with α-Chloroketones Chrysa F. Malosh and Joseph M. Ready pp 10240–10241 DOI: 10.1021/ja0467768 Supporting Info

Regio- and Stereoselective Enyne Cross Metathesis of Silylated Internal Alkynes Mansuk Kim, Sangho Park, Sarah V. Maifeld, and Daesung Lee pp 10242–10243 DOI: 10.1021/ja0465909 Supporting Info

Desymmetrizing Hydroformylation with the Aid of a Planar Chiral Catalyst-Directing Group Bernhard Breit and Daniel Breuninger pp 10244–10245 DOI: 10.1021/ja0467364 Supporting Info

Total Synthesis of (−)-Strychnine Yosuke Kaburagi, Hidetoshi Tokuyama, and Tohru Fukuyama pp 10246–10247 DOI: 10.1021/ja046407b Supporting Info

A Palladium-Catalyzed Enantioselective Alkylative Desymmetrization of meso-Succinic Anhydrides Eric A. Bercot and Tomislav Rovis pp 10248–10249 DOI: 10.1021/ja046528b Supporting Info

Palladium-Catalyzed Cyclization/Carboalkoxylation of Alkenyl Indoles Cong Liu and Ross A. Widenhoefer pp 10250–10251 DOI: 10.1021/ja046810i Supporting Info

A Likely Biogenetic Gateway Linking 2-Aminoimidazolinone Metabolites of Sponges to Proline:  Spontaneous Oxidative Conversion of the Pyrrole-Proline-Guanidine Pseudo-peptide to Dispacamide A Nathalie Travert and Ali Al-Mourabit pp 10252–10253 DOI: 10.1021/ja047574e Supporting Info

Molecular Dynamics Simulation of a Reverse Micelle Self Assembly in Supercritical CO2 Lanyuan Lu and Max L. Berkowitz pp 10254–10255 DOI: 10.1021/ja048670i

Selective Tryptophan Modification with Rhodium Carbenoids in Aqueous Solution John M. Antos and Matthew B. Francis pp 10256–10257 DOI: 10.1021/ja047272c Supporting Info

Folate-Mediated Cell Targeting and Cytotoxicity Using Thermoresponsive Microgels Satish Nayak, Hsienming Lee, Jean Chmielewski, and L. Andrew Lyon pp 10258–10259 DOI: 10.1021/ja0474143 Supporting Info

Coiled-Coil Surface Presentation:  An Efficient HIV gp41 Binding Interface Mimic Nathan A. Schnarr and Alan J. Kennan pp 10260–10261 DOI: 10.1021/ja047022w Supporting Info

Ruthenium-Catalyzed [3 + 2] Intramolecular Cycloaddition of Alk-5-ynylidenecyclopropanes Promoted by the “First-Generation” Grubbs Carbene Complex Fernando López, Alejandro Delgado, J. Ramón Rodríguez, Luis Castedo, and José L. Mascareñas pp 10262–10263 DOI: 10.1021/ja0480466 Supporting Info

An Intramolecular Diels−Alder Approach to the Eunicelins:  Enantioselective Total Synthesis of Ophirin B Michael T. Crimmins and Brandon H. Brown pp 10264–10266 DOI: 10.1021/ja046574b Supporting Info

Quantum Chemical Calculations of the NHA Bound Nitric Oxide Synthase Active Site:  O2 Binding and Implications for the Catalytic Mechanism Kyung-Bin Cho and James W. Gauld pp 10267–10270 DOI: 10.1021/ja049186i Supporting Info

Strategy in Inhibition of Cathepsin B, A Target in Tumor Invasion and Metastasis In Taek Lim, Samy O. Meroueh, Mijoon Lee, Mary Jane Heeg, and Shahriar Mobashery pp 10271–10277 DOI: 10.1021/ja0489240 Supporting Info

Design of Amino Acid Aldehydes as Transition-State Analogue Inhibitors of Arginase Hyunshun Shin, Evis Cama, and David W. Christianson pp 10278–10284 DOI: 10.1021/ja047788w

Site-Selective DNA Hydrolysis by Combining Ce(IV)/EDTA with Monophosphate-Bearing Oligonucleotides and Enzymatic Ligation of the Scission Fragments Wen Chen, Yoshihito Kitamura, Jing-Min Zhou, Jun Sumaoka, and Makoto Komiyama pp 10285–10291 DOI: 10.1021/ja048953a Supporting Info

Vibrational Circular Dichroism of Protein Films Ganesh Shanmugam and Prasad L. Polavarapu pp 10292–10295 DOI: 10.1021/ja048343a

Oxyanion Selectivity in Sulfate and Molybdate Transport Proteins:  An ab Initio/CDM Study Todor Dudev and Carmay Lim pp 10296–10305 DOI: 10.1021/ja047951n

Oxygenase Activity in the Self-Hydroxylation of (S)-2-Hydroxypropylphosphonic Acid Epoxidase Involved in Fosfomycin Biosynthesis Pinghua Liu, Mark P. Mehn, Feng Yan, Zongbao Zhao, Lawrence Que, Jr., and Hung-wen Liu pp 10306–10312 DOI: 10.1021/ja0475050

Formal Total Synthesis of Oximidine II via a Suzuki-Type Cross-Coupling Macrocyclization Employing Potassium Organotrifluoroborates Gary A. Molander and Florian Dehmel pp 10313–10318 DOI: 10.1021/ja047190o Supporting Info

Alkylation of Alkenes:  Ethylaluminum Sesquichloride-Mediated Hydro-Alkyl Additions with Alkyl Chloroformates and Di-tert-butylpyrocarbonate Ursula Biermann and Jürgen O. Metzger pp 10319–10330 DOI: 10.1021/ja048904y

Ni-Catalyzed, ZnCl2-Assisted Domino Coupling of Enones, Alkynes, and Alkenes Shin-ichi Ikeda, Reiko Sanuki, Hiroko Miyachi, Hitoshi Miyashita, Masami Taniguchi, and Kazunori Odashima pp 10331–10338 DOI: 10.1021/ja047580a Supporting Info

Expanding the Repertoire of Heterocycle Ring Pairs for Programmable Minor Groove DNA Recognition Michael A. Marques, Raymond M. Doss, Shane Foister, and Peter B. Dervan pp 10339–10349 DOI: 10.1021/ja0486465

A Controlled, Iterative Synthesis and the Electronic Properties of Oligo[(p-phenyleneethynylene)-alt-(2,5-siloleneethynylene)]s Andrew J. Boydston, Youshi Yin, and Brian L. Pagenkopf pp 10350–10354 DOI: 10.1021/ja047983a Supporting Info

Optimizing Saccharide-Directed Molecular Delivery to Biological Receptors:  Design, Synthesis, and Biological Evaluation of Glycodendrimer−Cyclodextrin Conjugates Juan M. Benito, Marta Gómez-García, Carmen Ortiz Mellet, Isabelle Baussanne, Jacques Defaye, and José M. García Fernández pp 10355–10363 DOI: 10.1021/ja047864v Supporting Info

A New Approach to Natural Products Discovery Exemplified by the Identification of Sulfated Nucleosides in Spider Venom Andrew E. Taggi, Jerrold Meinwald, and Frank C. Schroeder pp 10364–10369 DOI: 10.1021/ja047416n Supporting Info

Unexpected Change in Charge Transfer Behavior in a Cobalt(II) Porphyrin−Fullerene Conjugate That Stabilizes Radical Ion Pair States Liam R. Sutton, Michael Scheloske, Kristina S. Pirner, Andreas Hirsch, Dirk M. Guldi, and Jean-Paul Gisselbrecht pp 10370–10381 DOI: 10.1021/ja048983d Supporting Info

Layer-by-Layer Assembled Multilayer Films of Titanate Nanotubes, Ag- or Au-Loaded Nanotubes, and Nanotubes/Nanosheets with Polycations Renzhi Ma, Takayoshi Sasaki, and Yoshio Bando pp 10382–10388 DOI: 10.1021/ja048855p

Metal-Assisted Assembly of Pyridine-Containing Arylene Ethynylene Strands to Enantiopure Double Helicates Akihiro Orita, Takehiro Nakano, De Lie An, Kazumi Tanikawa, Kan Wakamatsu, and Junzo Otera pp 10389–10396 DOI: 10.1021/ja048327d Supporting Info

Luminescence Temperature Antiquenching of Water-Soluble CdTe Quantum Dots:  Role of the Solvent Sander F. Wuister, Celso de Mello Donegá, and Andries Meijerink pp 10397–10402 DOI: 10.1021/ja048222a Supporting Info

Synthesis and Crystal Structure of As-Synthesized and Calcined Pure Silica Zeolite ITQ-12 Xiaobo Yang, Miguel A. Camblor, Yongjae Lee, Haiming Liu, and David H. Olson pp 10403–10409 DOI: 10.1021/ja0481474 Supporting Info

Photoluminescent Layered Lanthanide Silicates Duarte Ananias, Mariya Kostova, Filipe A. Almeida Paz, Artur Ferreira, Luís D. Carlos, Jacek Klinowski, and João Rocha pp 10410–10417 DOI: 10.1021/ja047905n Supporting Info

Contrasting Linear and Quadratic Nonlinear Optical Behavior of Dipolar Pyridinium Chromophores with 4-(Dimethylamino)phenyl or Ruthenium(II) Ammine Electron Donor Groups Benjamin J. Coe, James A. Harris, Bruce S. Brunschwig, Javier Garín, Jesús Orduna, Simon J. Coles, and Michael B. Hursthouse pp 10418–10427 DOI: 10.1021/ja047650d

Silylene Hydride Complexes of Molybdenum with Silicon−Hydrogen Interactions:  Neutron Structure of (η5-C5Me5)(Me2PCH2CH2PMe2)Mo(H)(SiEt2) Benjamin V. Mork, T. Don Tilley, Arthur J. Schultz, and John A. Cowan pp 10428–10440 DOI: 10.1021/ja040026g Supporting Info

Mechanism of Four-Electron Reduction of Dioxygen to Water by Ferrocene Derivatives in the Presence of Perchloric Acid in Benzonitrile, Catalyzed by Cofacial Dicobalt Porphyrins Shunichi Fukuzumi, Ken Okamoto, Claude P. Gros, and Roger Guilard pp 10441–10449 DOI: 10.1021/ja048403c

Xe Chemical Shift Tensor in Silicalite and SSZ-24 Cynthia J. Jameson pp 10450–10456 DOI: 10.1021/ja040012a

Theoretical Study of Trans-metalation Process in Palladium-Catalyzed Borylation of Iodobenzene with Diboron Michinori Sumimoto, Naoki Iwane, Tomohiko Takahama, and Shigeyoshi Sakaki pp 10457–10471 DOI: 10.1021/ja040020r Supporting Info

Thermodynamic Clarification of the Curious Ferric/Potassium Ion Exchange Accompanying the Electrochromic Redox Reactions of Prussian Blue, Iron(III) Hexacyanoferrate(II) David R. Rosseinsky, Leslie Glasser, and H. Donald Brooke Jenkins pp 10472–10477 DOI: 10.1021/ja040055r Supporting Info

Discriminating the Helical Forms of Peptides by NMR and Molecular Dynamics Simulation Darón I. Freedberg, Richard M. Venable, Angelo Rossi, Thomas E. Bull, and Richard W. Pastor pp 10478–10484 DOI: 10.1021/ja0484146

Persistent Photo-Reversible Transition-Metal Methylidene System Generated from Reaction of Methyl Fluoride with Laser-Ablated Zirconium Atoms and Isolated in a Solid Argon Matrix Han-Gook Cho and Lester Andrews pp 10485–10492 DOI: 10.1021/ja0486115

Iridium Luminophore Complexes for Unimolecular Oxygen Sensors [J. Am. Chem. Soc. 2004, 126, 7619−7626]. Maria C. DeRosa, Derek J. Hodgson, Gary D. Enright, Brian Dawson, Christopher E. B. Evans, Robert J. Crutchley p 10493 DOI: 10.1021/ja040816q

Polarizing the Nazarov Cyclization:  Efficient Catalysis under Mild Conditions [J. Am. Chem. Soc. 2003, 125, 14278−14279]. Wei He, Xiufeng Sun, and Alison J. Frontier p 10493 DOI: 10.1021/ja0457258

Oligoacenes:  Theoretical Prediction of Open-Shell Singlet Diradical Ground States  [J. Am. Chem. Soc. 2004, 126, 7416−7417]. Michael Bendikov, Hieu M. Duong, Kyle Starkey, K. N. Houk, Emily A. Carter, and Fred Wudl p 10493 DOI: 10.1021/ja045878v

Platinum-Catalyzed Intramolecular Alkylation of Indoles with Unactivated Olefins [J. Am. Chem. Soc. 2004, 126, 3700−3701]. Cong Liu, Xiaoqing Han, Xiang Wang, and Ross A. Widenhoefer p 10493 DOI: 10.1021/ja0470362

Interactions in Molecules:  Electronic and Steric Effects Edited by Sigrid D. Peyerimhoff (Universität Bonn). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2003. xii + 364 pp. $160.00. ISBN 3-527-27732-3. Richard L. Redington p 10494 DOI: 10.1021/ja0336473

Issue 34

Direct Carbon Detection in Paramagnetic Metalloproteins To Further Exploit Pseudocontact Shift Restraints Elena Babini, Ivano Bertini, Francesco Capozzi, Isabella C. Felli, Moreno Lelli, and Claudio Luchinat pp 10496–10497 DOI: 10.1021/ja047573m Supporting Info

Temperature and Solvent Control of the Stereoselectivity in the Reactions of Singlet Oxygen with Oxazolidinone-Substituted Enecarbamates Thomas Poon, J. Sivaguru, Roberto Franz, Steffen Jockusch, Claudia Martinez, Ilyas Washington, Waldemar Adam, Yoshihisa Inoue, and Nicholas J. Turro pp 10498–10499 DOI: 10.1021/ja048438c Supporting Info

Parallel Identification of O-GlcNAc-Modified Proteins from Cell Lysates Hwan-Ching Tai, Nelly Khidekel, Scott B. Ficarro, Eric C. Peters, and Linda C. Hsieh-Wilson pp 10500–10501 DOI: 10.1021/ja047872b Supporting Info

Reversible Repositioning of Zinc Atoms within Single Crystals of a Zinc Polycarboxylate with an Open-Framework Structure Kenneth Hanson, Nathalie Calin, Daniel Bugaris, Michael Scancella, and Slavi C. Sevov pp 10502–10503 DOI: 10.1021/ja0474190 Supporting Info

A Small Molecule Transcriptional Activation Domain Aaron R. Minter, Brian B. Brennan, and Anna K. Mapp pp 10504–10505 DOI: 10.1021/ja0473889 Supporting Info

Terminal Vanadium−Neopentylidyne Complexes and Intramolecular Cross-Metathesis Reactions to Generate Azametalacyclohexatrienes Falguni Basuli, Brad C. Bailey, Douglas Brown, John Tomaszewski, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola pp 10506–10507 DOI: 10.1021/ja0472376 Supporting Info

Direct Determination of Thiol pKa by Isothermal Titration Microcalorimetry Stephen G. Tajc, Blanton S. Tolbert, Ravi Basavappa, and Benjamin L. Miller pp 10508–10509 DOI: 10.1021/ja047929u Supporting Info

Microcontact Printing of Colloidal Crystals Xin Yan, Jimin Yao, Guang Lu, Xin Chen, Kai Zhang, and Bai Yang pp 10510–10511 DOI: 10.1021/ja0479078 Supporting Info

Micropatterns of Spores Displaying Heterologous Proteins Tae Jung Park, Kyung-Bok Lee, Seok Jae Lee, Jong Pil Park, Zee-Won Lee, Sang Yup Lee, and Insung S. Choi pp 10512–10513 DOI: 10.1021/ja047894y Supporting Info

Hydrophobic Core Repacking in a Coiled-Coil Dimer via Phage Display:  Insights into Plasticity and Specificity at a Protein−Protein Interface Jonathan R. Lai, John D. Fisk, Bernard Weisblum, and Samuel H. Gellman pp 10514–10515 DOI: 10.1021/ja047710f Supporting Info

Role of Hydrogen-Bond Network in Energy Storage of Bacteriorhodopsin's Light-Driven Proton Pump Revealed by ab Initio Normal-Mode Analysis Shigehiko Hayashi, Emad Tajkhorshid, Hideki Kandori, and Klaus Schulten pp 10516–10517 DOI: 10.1021/ja047506s Supporting Info

Observation of Three-Dimensional Fermi Surfaces in a Single-Component Molecular Metal, [Ni(tmdt)2] Hisashi Tanaka, Madoka Tokumoto, Shoji Ishibashi, David Graf, Eun Sang Choi, James S. Brooks, Syuma Yasuzuka, Yoshinori Okano, Hayao Kobayashi, and Akiko Kobayashi pp 10518–10519 DOI: 10.1021/ja046895n

A Simple Chemical Route To Selectively Eliminate Metallic Carbon Nanotubes in Nanotube Network Devices Lei An, Qiang Fu, Chenguang Lu, and Jie Liu pp 10520–10521 DOI: 10.1021/ja046482m

On the Mechanism of the Hofmeister Effect Marc C. Gurau, Soon-Mi Lim, Edward T. Castellana, Fernando Albertorio, Sho Kataoka, and Paul S. Cremer pp 10522–10523 DOI: 10.1021/ja047715c Supporting Info

Self-Supported Heterogeneous Catalysts for Enantioselective Hydrogenation Xingwang Wang and Kuiling Ding pp 10524–10525 DOI: 10.1021/ja047372i Supporting Info

Regio- and Chemoselective Direct Generation of Functionalized Aromatic Aluminum Compounds Using Aluminum Ate Base Masanobu Uchiyama, Hiroshi Naka, Yotaro Matsumoto, and Tomohiko Ohwada pp 10526–10527 DOI: 10.1021/ja0473236 Supporting Info

Synthesis of Block Copolymer Segments Containing Different Ratios of Ethylene and 5-Norbornen-2-yl Acetate Steve J. Diamanti, Vikram Khanna, Atsushi Hotta, Diane Yamakawa, Fumihiko Shimizu, Edward J. Kramer, Glenn H. Fredrickson, and Guillermo C. Bazan pp 10528–10529 DOI: 10.1021/ja047231g Supporting Info

Reduction of Digermenes with Alkali Metals:  Salts of Formula M2[{Ge(H)Ar‘}2] (M = Li, Na, or K, Ar‘ = Terphenyl) with Three Different Structures Anne F. Richards, Marcin Brynda, and Philip P. Power pp 10530–10531 DOI: 10.1021/ja047090i Supporting Info

Identification of Inhibitors for UDP-Galactopyranose Mutase Michelle Soltero-Higgin, Erin E. Carlson, John H. Phillips, and Laura L. Kiessling pp 10532–10533 DOI: 10.1021/ja048017v Supporting Info

Hierarchical Porous Silica Materials with a Trimodal Pore System Using Surfactant Templates Daibin Kuang, Torsten Brezesinski, and Bernd Smarsly pp 10534–10535 DOI: 10.1021/ja0470618 Supporting Info

A Conjugated Polymer pn Junction Calvin H. W. Cheng and Mark C. Lonergan pp 10536–10537 DOI: 10.1021/ja046880p Supporting Info

Claisen-Type Addition of Glycine to Pyridoxal in Water Krisztina Toth, Tina L. Amyes, John P. Richard, J. Paul G. Malthouse, and Máire E. NíBeilliú pp 10538–10539 DOI: 10.1021/ja047501v

Nickel-Catalyzed Intermolecular [3 + 2 + 2] Cocyclization of Ethyl Cyclopropylideneacetate and Alkynes Shinichi Saito, Manami Masuda, and Shinsuke Komagawa pp 10540–10541 DOI: 10.1021/ja0494306 Supporting Info

Biomimetic Catalytic System Driven by Electron Transfer for Selective Oxygenation of Hydrocarbon Guanyu Yang, Yinfa Ma, and Jie Xu pp 10542–10543 DOI: 10.1021/ja047297b Supporting Info

How to Design Linear Allenic-Type Trisilaallenes and Trigermaallenes Monica Kosa, Miriam Karni, and Yitzhak Apeloig pp 10544–10545 DOI: 10.1021/ja048292h Supporting Info

Intramolecular C−N Bond Addition of Amides to Alkynes Using Platinum Catalyst Tomohiro Shimada, Itaru Nakamura, and Yoshinori Yamamoto pp 10546–10547 DOI: 10.1021/ja047542r Supporting Info

Pulstrodes:  Triple Pulse Control of Potentiometric Sensors Sergey Makarychev-Mikhailov, Alexey Shvarev, and Eric Bakker pp 10548–10549 DOI: 10.1021/ja047728q Supporting Info

Metal Allyl Complexes with Bulky Ligands:  Stabilization of Homoleptic Thorium Compounds, [(SiMe3)nC3H5-n]4Th (n = 1, 2) Christin N. Carlson, Timothy P. Hanusa, and William W. Brennessel pp 10550–10551 DOI: 10.1021/ja047770l Supporting Info

A New Direction in Carbon-Rich Organometallic Wires:  Diruthenium Compounds Bridged by E-Hex-3-ene-1,5-diyn-diyl Yanhui Shi, Gordon T. Yee, Guangbin Wang, and Tong Ren pp 10552–10553 DOI: 10.1021/ja0466614 Supporting Info

Preparation of Stable Alkyl Complexes of Ni(I) and Their One-Electron Oxidation to Ni(II) Complex Cations Kristina D. Kitiachvili, Daniel J. Mindiola, and Gregory L. Hillhouse pp 10554–10555 DOI: 10.1021/ja047052z Supporting Info

Highly Efficient Dendrimer-Based Mimic of Glutathione Peroxidase Xi Zhang, Huaping Xu, Zeyuan Dong, Yapei Wang, Junqiu Liu, and Jiacong Shen pp 10556–10557 DOI: 10.1021/ja048890w Supporting Info

Highly Enantioselective Catalytic Acyl-Pictet−Spengler Reactions Mark S. Taylor and Eric N. Jacobsen pp 10558–10559 DOI: 10.1021/ja046259p Supporting Info

Relaxation-Optimized NMR Spectroscopy of Methylene Groups in Proteins and Nucleic Acids Emeric Miclet, David C. Williams Jr., G. Marius Clore, David L. Bryce, Jérôme Boisbouvier, and Ad Bax pp 10560–10570 DOI: 10.1021/ja047904v Supporting Info

Kinetics and Mechanism of the General-Acid-Catalyzed Ring-Closure of the Malondialdehyde−DNA Adduct, N2-(3-Oxo-1-propenyl)deoxyguanosine (N2OPdG-), to 3-(2‘-Deoxy-β-d-erythro-pentofuranosyl)pyrimido[1,2-α]purin- 10(3H)-one (M1dG) James N. Riggins, Derek A. Pratt, Markus Voehler, J. Scott Daniels, and Lawrence J. Marnett pp 10571–10581 DOI: 10.1021/ja040010q Supporting Info

Evidence for Separate Binding and Scaffolding Domains in the Immunosuppressive and Antitumor Marine Natural Product, Pateamine A:  Design, Synthesis, and Activity Studies Leading to a Potent Simplified Derivative Daniel Romo, Nam Song Choi, Shukun Li, Ingrid Buchler, Zonggao Shi, and Jun O. Liu pp 10582–10588 DOI: 10.1021/ja040065s Supporting Info

Medium-Dependent Electron and H Atom Transfer between 2‘-Deoxyadenosine and Menadione:  A Magnetic Field Effect Study Tamal Sengupta, Sharmistha Dutta Choudhury, and Samita Basu pp 10589–10593 DOI: 10.1021/ja0490976

Self-Organized, Highly Luminescent CdSe Nanorod−DNA Complexes Mikhail Artemyev, Dmitry Kisiel, Sergey Abmiotko, Maria N. Antipina, Gennady B. Khomutov, Vladimir V. Kislov, and Anna A. Rakhnyanskaya pp 10594–10597 DOI: 10.1021/ja048069k Supporting Info

Presentation and Detection of Azide Functionality in Bacterial Cell Surface Proteins A. James Link, Mandy K. S. Vink, and David A. Tirrell pp 10598–10602 DOI: 10.1021/ja047629c

Recognition of Duplex RNA by Helix-Threading Peptides Barry D. Gooch and Peter A. Beal pp 10603–10610 DOI: 10.1021/ja047818v Supporting Info

Supramolecular p−n-Heterojunctions by Co-Self-Organization of Oligo(p-phenylene Vinylene) and Perylene Bisimide Dyes Frank Würthner, Zhijian Chen, Freek J. M. Hoeben, Peter Osswald, Chang-Cheng You, Pascal Jonkheijm, Jeroen v. Herrikhuyzen, Albertus P. H. J. Schenning, Paul P. A. M. van der Schoot, E. W. Meijer, Edwin H. A. Beckers, Stefan C. J. Meskers, and René A. J. Janssen pp 10611–10618 DOI: 10.1021/ja0475353 Supporting Info

In Vitro Demonstration of the Heavy-Atom Effect for Photodynamic Therapy Aoife Gorman, John Killoran, Caroline O'Shea, Tony Kenna, William M. Gallagher, and Donal F. O'Shea pp 10619–10631 DOI: 10.1021/ja047649e Supporting Info

Ab Initio Study of the SN1Ar and SN2Ar Reactions of Benzenediazonium Ion with Water. On the Conception of “Unimolecular Dediazoniation” in Solvolysis Reactions Zhengyu Wu and Rainer Glaser pp 10632–10639 DOI: 10.1021/ja047620a Supporting Info

Supramolecular Assemblies Based on Copolymers of PEG600 and Functionalized Aromatic Diesters for Drug Delivery Applications Rajesh Kumar, Ming-Hsiung Chen, Virinder S. Parmar, Lynne A. Samuelson, Jayant Kumar, Robert Nicolosi, Subbiah Yoganathan, and Arthur C. Watterson pp 10640–10644 DOI: 10.1021/ja039651w

Self-Assembly of Flexible Supramolecular Metallacyclic Ensembles:  Structures and Adsorption Properties of Their Nanoporous Crystalline Frameworks Biswaroop Chatterjee, Juan C. Noveron, Marino J. E. Resendiz, Jie Liu, Takuya Yamamoto, Daniel Parker, Martin Cinke, Cattien V. Nguyen, Atta M. Arif, and Peter J. Stang pp 10645–10656 DOI: 10.1021/ja0388919 Supporting Info

Hydroxyapatite-Supported Palladium Nanoclusters:  A Highly Active Heterogeneous Catalyst for Selective Oxidation of Alcohols by Use of Molecular Oxygen Kohsuke Mori, Takayoshi Hara, Tomoo Mizugaki, Kohki Ebitani, and Kiyotomi Kaneda pp 10657–10666 DOI: 10.1021/ja0488683 Supporting Info

O−H Bond Dissociation Enthalpies in Oximes:  Order Restored Derek A. Pratt, Jessie A. Blake, Peter Mulder, John C. Walton, Hans-Gert Korth, and Keith U. Ingold pp 10667–10675 DOI: 10.1021/ja047566y Supporting Info

Cu-Catalyzed Asymmetric Allylic Alkylations of Aromatic and Aliphatic Phosphates with Alkylzinc Reagents. An Effective Method for Enantioselective Synthesis of Tertiary and Quaternary Carbons Monica A. Kacprzynski and Amir H. Hoveyda pp 10676–10681 DOI: 10.1021/ja0478779 Supporting Info

Enantioselective Synthesis of (−)-Terpestacin and Structural Revision of Siccanol Using Catalytic Stereoselective Fragment Couplings and Macrocyclizations Johann Chan and Timothy F. Jamison pp 10682–10691 DOI: 10.1021/ja0470968 Supporting Info

Reactivity, Chemoselectivity, and Diastereoselectivity of the Oxyfunctionalization of Chiral Allylic Alcohols and Derivatives in Microemulsions: Comparison of the Chemical Oxidation by the Hydrogen Peroxide/Sodium Molybdate System with the Photooxygenation Véronique Nardello, Laurent Caron, Jean-Marie Aubry, Sabine Bouttemy, Thomas Wirth, R. Saha-Möller Chantu, and Waldemar Adam pp 10692–10700 DOI: 10.1021/ja048589f Supporting Info

Iron Catalyzed Polyethylene Chain Growth on Zinc:  A Study of the Factors Delineating Chain Transfer versus Catalyzed Chain Growth in Zinc and Related Metal Alkyl Systems George J. P. Britovsek, Steven A. Cohen, Vernon C. Gibson, and Martin van Meurs pp 10701–10712 DOI: 10.1021/ja0485560 Supporting Info

Unraveling the Photochemistry of Fe(CO)5 in Solution:  Observation of Fe(CO)3 and the Conversion between 3Fe(CO)4 and 1Fe(CO)4(Solvent) Peter Portius, Jixin Yang, Xue-Zhong Sun, David C. Grills, Pavel Matousek, Anthony W. Parker, Michael Towrie, and Michael W. George pp 10713–10720 DOI: 10.1021/ja048411t

Biomimetic Monoacylation of Diols in Water. Lanthanide-Promoted Reactions of Methyl Benzoyl Phosphate Lisa L. Cameron, Sheila C. Wang, and Ronald Kluger pp 10721–10726 DOI: 10.1021/ja049538l Supporting Info

The Nature of the Rapid Relaxation of Excited Charge-Transfer Complexes D. Levy and B. R. Arnold pp 10727–10731 DOI: 10.1021/ja049387m

TEM Investigation of Formation Mechanism of Monocrystal-Thick b-Oriented Pure Silica Zeolite MFI Film Shuang Li, Zijian Li, Krassimir N. Bozhilov, Zhongwei Chen, and Yushan Yan pp 10732–10737 DOI: 10.1021/ja0478429 Supporting Info

An Investigation on the Analytical Potential of Polymerized Liposomes Bound to Lanthanide Ions for Protein Analysis Marina Santos, Bidhan C. Roy, Héctor Goicoechea, Andres D. Campiglia, and Sanku Mallik pp 10738–10745 DOI: 10.1021/ja048963b

Car Exhaust Catalysis from First Principles:  Selective NO Reduction under Excess O2 Conditions on Ir Zhi-Pan Liu, Stephen J. Jenkins, and David A. King pp 10746–10756 DOI: 10.1021/ja0481833

Self-Assembled Linear Bundles of Single Wall Carbon Nanotubes and Their Alignment and Deposition as a Film in a dc Field Prashant V. Kamat, K. George Thomas, Said Barazzouk, G. Girishkumar, K. Vinodgopal, and Dan Meisel pp 10757–10762 DOI: 10.1021/ja0479888 Supporting Info

Photoinduced Intramolecular Electron Transfer in Ruthenium and Osmium Polyads:  Insights from Theory Ilaria Ciofini, Philippe P. Lainé, Fethi Bedioui, and Carlo Adamo pp 10763–10777 DOI: 10.1021/ja0482278 Supporting Info

Observation of Dynamic Solvent Effect for Electron Tunneling in U-Shaped Molecules Min Liu, David H. Waldeck, Anna M. Oliver, Nicholas J. Head, and Michael N. Paddon-Row pp 10778–10786 DOI: 10.1021/ja049539d Supporting Info

Benzene on Au{111} at 4 K:  Monolayer Growth and Tip-Induced Molecular Cascades Patrick Han, Brent A. Mantooth, E. Charles H. Sykes, Zachary J. Donhauser, and Paul S. Weiss pp 10787–10793 DOI: 10.1021/ja049113z Supporting Info

The Conformation of Tetraalanine in Water Determined by Polarized Raman, FT-IR, and VCD Spectroscopy [J. Am. Chem. Soc. 2004, 126, 2768−2776]. Reinhard Schweitzer-Stenner, Fatma Eker, Kai Griebenow, Xiaolin Cao, and Laurence A. Nafie p 10794 DOI: 10.1021/ja045638f

Carbohydrate Chips for Studying High-Throughput Carbohydrate−Protein Interactions [J. Am. Chem. Soc. 2004, 126, 4812−4819]. Sungjin Park, Myung-ryul Lee, Soon-Jin Pyo, Injae Shin p 10794 DOI: 10.1021/ja045923z

Viscosimetry of Polymers and Polyelectrolyes By Werner-Michael Kulicke and Christian Clasen (Universität Hamburg). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xviii + 120 pp. $59.95. ISBN:  3-540-40760-X. Guy C. Berry p 10795 DOI: 10.1021/ja040940+

Handbook of Metalloproteins, Volume 3 Edited by Albrecht Messerschmidt (Max-Planck-Institute for Biochemistry, Martinsried and University of Konstanz), Wolfram Bode (Max-Planck-Institute for Biochemistry, Martinsried), and Mirek Cygler (McGill University). John Wiley and Sons, Inc.:  Hoboken, NJ. 2004. 768 pp. $545.00. ISBN 0-470-84984-3. p 10795 DOI: 10.1021/ja040949b

Advanced Free Radical Reactions for Organic Synthesis By Hideo Togo (Chiba University). Elsevier:  Amsterdam. 2004. xii + 258 pp. $178.00. ISBN 0-08-044374-5. Dennis P. Curran pp 10795–10796 DOI: 10.1021/ja0409255

Issue 35

Gel Permeation Chromatography as a Combinatorial Screening Method:  Identification of Highly Active Heteroligated Phenoxyimine Polymerization Catalysts Andrew F. Mason and Geoffrey W. Coates pp 10798–10799 DOI: 10.1021/ja047236d Supporting Info

2,9-Di-(2‘-pyridyl)-1,10-phenanthroline:  A Tetradentate Ligand for Ru(II) Ruifa Zong and Randolph P. Thummel pp 10800–10801 DOI: 10.1021/ja047410y Supporting Info

Reactivity of Amido Ligands on a Dinuclear Ru(II) Center:  Formation of Imido Complexes and C−N Coupling Reaction with Alkyne Shin Takemoto, Tomoharu Kobayashi, and Hiroyuki Matsuzaka pp 10802–10803 DOI: 10.1021/ja047920s Supporting Info

Coacervate Formation from Natural Glycolipid:  One Acetyl Group on the Headgroup Triggers Coacervate-to-Vesicle Transition T. Imura, H. Yanagishita, and D. Kitamoto pp 10804–10805 DOI: 10.1021/ja0400281 Supporting Info

Recognition and Stabilization of Peptide α-Helices Using Templatable Nanoparticle Receptors Ayush Verma, Hiroshi Nakade, Joseph M. Simard, and Vincent M. Rotello pp 10806–10807 DOI: 10.1021/ja047719h Supporting Info

Arrays for the Combinatorial Exploration of Cell Adhesion Brendan P. Orner, Ratmir Derda, Rachel L. Lewis, James A. Thomson, and Laura L. Kiessling pp 10808–10809 DOI: 10.1021/ja0474291 Supporting Info

Ultrafast Aggregate-to-Aggregate Energy Transfer within Self-assembled Light-Harvesting Columns of Zinc Phthalocyanine Tetrakis(Perylenediimide) Xiyou Li, Louise E. Sinks, Boris Rybtchinski, and Michael R. Wasielewski pp 10810–10811 DOI: 10.1021/ja047176b Supporting Info

A Site-Selective Dual Anchoring Strategy for Artificial Metalloprotein Design James R. Carey, Steven K. Ma, Thomas D. Pfister, Dewain K. Garner, Hyeon K. Kim, Joseph A. Abramite, Zhilin Wang, Zijian Guo, and Yi Lu pp 10812–10813 DOI: 10.1021/ja046908x Supporting Info

DNA-PEG-DNA Triblock Macromolecules for Reagentless DNA Detection Chad E. Immoos, Stephen J. Lee, and Mark W. Grinstaff pp 10814–10815 DOI: 10.1021/ja046634d Supporting Info

Stereocontrol within Confined Spaces:  Enantioselective Photooxidation of Enecarbamates Inside Zeolite Supercages J. Sivaguru, Thomas Poon, Roberto Franz, Steffen Jockusch, Waldemar Adam, and Nicholas J. Turro pp 10816–10817 DOI: 10.1021/ja046115a Supporting Info

A 3.5-nm Coordination Nanotube Takumi Yamaguchi, Shohei Tashiro, Masahide Tominaga, Masaki Kawano, Tomoji Ozeki, and Makoto Fujita pp 10818–10819 DOI: 10.1021/ja047048n Supporting Info

Experimental and Theoretical Determination of Nucleic Acid Magnetic Susceptibility:  Importance for the Study of Dynamics by Field-Induced Residual Dipolar Couplings David L. Bryce, Jérôme Boisbouvier, and Ad Bax pp 10820–10821 DOI: 10.1021/ja047179o Supporting Info

Direct Patterning of Copper on Polyimide Using Ion Exchangeable Surface Templates Generated by Site-Selective Surface Modification Kensuke Akamatsu, Shingo Ikeda, Hidemi Nawafune, and Hiroshi Yanagimoto pp 10822–10823 DOI: 10.1021/ja047700e Supporting Info

Crystallographic Structures of Two Bisphosphonate:1-Deoxyxylulose-5-Phosphate Reductoisomerase Complexes Shunsuke Yajima, Kodai Hara, John M. Sanders, Fenglin Yin, Kanju Ohsawa, Jochen Wiesner, Hassan Jomaa, and Eric Oldfield pp 10824–10825 DOI: 10.1021/ja040126m Supporting Info

Dye-Activated Hybrid Organic/Inorganic Mesostructured Titania Waveguides Michael H. Bartl, Shannon W. Boettcher, Evelyn L. Hu, and Galen D. Stucky pp 10826–10827 DOI: 10.1021/ja0480771 Supporting Info

Stabilization of Yeast Cytochrome c Covalently Immobilized on Fused Silica Surfaces Yo-Yuan Cheng, Huan-Cheng Chang, Geoffrey Hoops, and Meng-Chih Su pp 10828–10829 DOI: 10.1021/ja048321o Supporting Info

Edge Spreading Lithography and Its Application to the Fabrication of Mesoscopic Gold and Silver Rings Joseph M. McLellan, Matthias Geissler, and Younan Xia pp 10830–10831 DOI: 10.1021/ja0470766 Supporting Info

Discrete Nanostructures of Quantum Dots/Au with DNA Aihua Fu, Christine M. Micheel, Jennifer Cha, Hauyee Chang, Haw Yang, and A. Paul Alivisatos pp 10832–10833 DOI: 10.1021/ja046747x Supporting Info

A Synthetic DNA Walker for Molecular Transport Jong-Shik Shin and Niles A. Pierce pp 10834–10835 DOI: 10.1021/ja047543j Supporting Info

Electron Transfer between Cytochrome c and Cytochome c Peroxidase in Single Crystals Seong A. Kang, Pieti J. Marjavaara, and Brian R. Crane pp 10836–10837 DOI: 10.1021/ja049230u Supporting Info

Dramatic Effects of Boryl Substituents on Thermal Ring-Closing Reaction of Vinylallenes Masahiro Murakami, Shinji Ashida, and Takanori Matsuda pp 10838–10839 DOI: 10.1021/ja046429y Supporting Info

Formation of a Hydrogen-Bonded Receptor Assembly in Niosomal Membranes Mattijs G. J. ten Cate, Mercedes Crego-Calama, and David N. Reinhoudt pp 10840–10841 DOI: 10.1021/ja0476563

Nanosizing Drug Particles in Supercritical Fluid Processing Pankaj Pathak, Mohammed J. Meziani, Tarang Desai, and Ya-Ping Sun pp 10842–10843 DOI: 10.1021/ja046914t

Dynamic Nuclear Polarization with Biradicals Kan-Nian Hu, Hsiao-hua Yu, Timothy M. Swager, and Robert G. Griffin pp 10844–10845 DOI: 10.1021/ja039749a Supporting Info

Complete Control of the Chemoselectivity in Catalytic Carbene Transfer Reactions from Ethyl Diazoacetate:  An N-Heterocyclic Carbene−Cu System That Suppresses Diazo Coupling Manuel R. Fructos, Tomás R. Belderrain, M. Carmen Nicasio, Steven P. Nolan, Harneet Kaur, M. Mar Díaz-Requejo, and Pedro J. Pérez pp 10846–10847 DOI: 10.1021/ja047284y Supporting Info

Fast Cleavage Kinetics of a Natural Hammerhead Ribozyme Marella D. Canny, Fiona M. Jucker, Elizabeth Kellogg, Anastasia Khvorova, Sumedha D. Jayasena, and Arthur Pardi pp 10848–10849 DOI: 10.1021/ja046848v Supporting Info

Conical-Nanotube Ion-Current Rectifiers:  The Role of Surface Charge Zuzanna Siwy, Elizabeth Heins, C. Chad Harrell, Punit Kohli, and Charles R. Martin pp 10850–10851 DOI: 10.1021/ja047675c Supporting Info

Low-Temperature Stability and High-Temperature Reactivity of Iron-Based Core−Shell Nanoparticles Christopher E. Bunker and John J. Karnes pp 10852–10853 DOI: 10.1021/ja0473891

Single-Crystal Nanowires of Platinum Can Be Synthesized by Controlling the Reaction Rate of a Polyol Process Jingyi Chen, Thurston Herricks, Matthias Geissler, and Younan Xia pp 10854–10855 DOI: 10.1021/ja0468224 Supporting Info

Transbilayer Complementarity of Phospholipids. A Look beyond the Fluid Mosaic Model Jianbing Zhang, Bingwen Jing, Nobuya Tokutake, and Steven L. Regen pp 10856–10857 DOI: 10.1021/ja046892a Supporting Info

Catalaytic Isomerization of 1,5-Enynes to Bicyclo[3.1.0]hexenes Michael R. Luzung, Jordan P. Markham, and F. Dean Toste pp 10858–10859 DOI: 10.1021/ja046248w Supporting Info

Catalytic Coupling of Terminal Alkynes with Isonitriles Promoted by Organoactinide Complexes Eyal Barnea, Tamer Andrea, Moshe Kapon, Jean-Claude Berthet, Michel Ephritikhine, and Moris S. Eisen pp 10860–10861 DOI: 10.1021/ja046604a Supporting Info

Highly Diastereoselective and Enantioselective C−H Functionalization of 1,2-Dihydronaphthalenes:  A Combined C−H Activation/Cope Rearrangement Followed by a Retro-Cope Rearrangement Huw M. L. Davies and Qihui Jin pp 10862–10863 DOI: 10.1021/ja047185k Supporting Info

Atomic Level Control over Surface Species via a Molecular Precursor Approach:  Isolated Cu(I) Sites and Cu Nanoparticles Supported on Mesoporous Silica Kyle L. Fujdala, Ian J. Drake, Alexis T. Bell, and T. Don Tilley pp 10864–10866 DOI: 10.1021/ja048701+ Supporting Info

Bismercaptoethanediazacyclooctane as a N2S2 Chelating Agent and Cys−X−Cys Mimic for Fe(NO) and Fe(NO)2 Chao-Yi Chiang, Matthew L. Miller, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 10867–10874 DOI: 10.1021/ja049627y Supporting Info

Protein Surface-Assisted Enhancement in the Binding Affinity of an Inhibitor for Recombinant Human Carbonic Anhydrase-II Abir L. Banerjee, Michael Swanson, Bidhan C. Roy, Xiao Jia, Manas K. Haldar, Sanku Mallik, and D. K. Srivastava pp 10875–10883 DOI: 10.1021/ja047557p

O-Selectivity and Utility of Phosphorylation Mediated by Phosphite Triester Intermediates in the N-Unprotected Phosphoramidite Method Akihiro Ohkubo, Yusuke Ezawa, Kohji Seio, and Mitsuo Sekine pp 10884–10896 DOI: 10.1021/ja048125h Supporting Info

Mechanism and Ligand-Transfer Selectivity of 1,2-Addition of Organozincate Complexes to Aldehyde Masanobu Uchiyama, Shinji Nakamura, Tomohiko Ohwada, Masaharu Nakamura, and Eiichi Nakamura pp 10897–10903 DOI: 10.1021/ja048663u Supporting Info

X-ray Crystal Structures of a Benzonorbornenyl Cation and of a Protonated Benzonorbornenol Thomas Laube pp 10904–10912 DOI: 10.1021/ja040115t Supporting Info

Discovery of (E)-9,10-Dehydroepothilones through Chemical Synthesis:  On the Emergence of 26-Trifluoro-(E)-9,10-dehydro-12,13-desoxyepothilone B as a Promising Anticancer Drug Candidate Alexey Rivkin, Fumihiko Yoshimura, Ana E. Gabarda, Young Shin Cho, Ting-Chao Chou, Huajin Dong, and Samuel J. Danishefsky pp 10913–10922 DOI: 10.1021/ja046992g Supporting Info

Metal-Cation-Mediated Hydrolysis of Phosphonoformate Diesters:  Chemoselectivity and Catalysis1 Robert A. Moss, Hugo Morales-Rojas, Saketh Vijayaraghavan, and Jingzhi Tian pp 10923–10936 DOI: 10.1021/ja030437h Supporting Info

Investigation on the Drying Induced Phase Transformation of Mesoporous Silica; A Comprehensive Understanding toward Mesophase Determination Masaru Ogura, Hayato Miyoshi, Sajo P. Naik, and Tatsuya Okubo pp 10937–10944 DOI: 10.1021/ja047785j

Supported Chiral Mo-Based Complexes as Efficient Catalysts for Enantioselective Olefin Metathesis Sarah J. Dolman, Kai C. Hultzsch, Frédéric Pezet, Xin Teng, Amir H. Hoveyda, and Richard R. Schrock pp 10945–10953 DOI: 10.1021/ja047663r Supporting Info

Combined Computational and Experimental Studies of the Mechanism and Scope of the Retro-Nazarov Reaction Michael Harmata, Peter R. Schreiner, Dong Reyoul Lee, and Patrick L. Kirchhoefer pp 10954–10957 DOI: 10.1021/ja048942h Supporting Info

Label-Free Colorimetric Detection of Specific Sequences in Genomic DNA Amplified by the Polymerase Chain Reaction Huixiang Li and Lewis J. Rothberg pp 10958–10961 DOI: 10.1021/ja048749n Supporting Info

Driving Forces for Self-Organized Coadsorption:  C6H6/2O and C6H6/2CO on Ni{111} S. Yamagishi, S. J. Jenkins, and D. A. King pp 10962–10971 DOI: 10.1021/ja048289y

Solid-State Ru-99 NMR Spectroscopy:  A Useful Tool for Characterizing Prototypal Diamagnetic Ruthenium Compounds Kristopher J. Ooms and Roderick E. Wasylishen pp 10972–10980 DOI: 10.1021/ja0400887

Vibrational Spectroscopy and Density Functional Theory of Transition-Metal Ion−Benzene and Dibenzene Complexes in the Gas Phase Todd D. Jaeger, Deniz van Heijnsbergen, Stephen J. Klippenstein, Gert von Helden, Gerard Meijer, and Michael A. Duncan pp 10981–10991 DOI: 10.1021/ja0477165 Supporting Info

Theoretical Study of the Stereoselective Additions of Chiral Alcohols to Ketenes Carina E. Cannizzaro and K. N. Houk pp 10992–11008 DOI: 10.1021/ja035899+ Supporting Info

Formation of an Interlocked Quadruplex Dimer by d(GGGT) Yamuna Krishnan-Ghosh, Dongsheng Liu, and Shankar Balasubramanian pp 11009–11016 DOI: 10.1021/ja049259y Supporting Info

Binding of Distamycin A to UV-Damaged DNA Aki Inase, Takashi S. Kodama, Jafar Sharif, Yan Xu, Hirohito Ayame, Hiroshi Sugiyama, and Shigenori Iwai pp 11017–11023 DOI: 10.1021/ja048851k

A Single Hydroxyl Group Governs Ligand Site Selectivity in Human Ileal Bile Acid Binding Protein Gregory P. Tochtrop, Gregory T. DeKoster, Douglas F. Covey, and David P. Cistola pp 11024–11029 DOI: 10.1021/ja047589c

Concerning the Mechanism of the Ring Opening of Propylene Oxide in the Copolymerization of Propylene Oxide and Carbon Dioxide To Give Poly(propylene carbonate) Malcolm H. Chisholm and Zhiping Zhou pp 11030–11039 DOI: 10.1021/ja0394232 Supporting Info

Hydrolytic Reactions of Guanosyl-(3‘,3‘)-uridine and Guanosyl-(3‘,3‘)-(2‘,5‘-di-O-methyluridine) Anu Kiviniemi, Tuomas Lönnberg, and Mikko Ora pp 11040–11045 DOI: 10.1021/ja047568i Supporting Info

Exploring CH-Activation Pathways in Bifunctional Zirconocene/Borane Systems Michael Hill, Gerhard Erker, Gerald Kehr, Roland Fröhlich, and Olga Kataeva pp 11046–11057 DOI: 10.1021/ja048447l Supporting Info

Catalytic Intermolecular Pauson−Khand-Type Reaction:  Strong Directing Effect of Pyridylsilyl and Pyrimidylsilyl Groups and Isolation of Ru Complexes Relevant to Catalytic Reaction Kenichiro Itami, Koichi Mitsudo, Kazuyoshi Fujita, Youichi Ohashi, and Jun-ichi Yoshida pp 11058–11066 DOI: 10.1021/ja047484+ Supporting Info

On the Reaction Mechanism of Adduct Formation in LOV Domains of the Plant Blue-Light Receptor Phototropin Erik Schleicher, Radoslaw M. Kowalczyk, Christopher W. M. Kay, Peter Hegemann, Adelbert Bacher, Markus Fischer, Robert Bittl, Gerald Richter, and Stefan Weber pp 11067–11076 DOI: 10.1021/ja049553q Supporting Info

“Through-Space” Nuclear Spin−Spin JPP Coupling in Tetraphosphine Ferrocenyl Derivatives:  A 31P NMR and X-ray Structure Correlation Study for Coordination Complexes Jean-Cyrille Hierso, Aziz Fihri, Vladimir V. Ivanov, Bernard Hanquet, Nadine Pirio, Bruno Donnadieu, Bertrand Rebière, Régine Amardeil, and Philippe Meunier pp 11077–11087 DOI: 10.1021/ja048907a Supporting Info

Magnetic Field Effects on Cytochrome c-Mediated Bioelectrocatalytic Transformations Eugenii Katz, Oleg Lioubashevski, and Itamar Willner pp 11088–11092 DOI: 10.1021/ja048699m Supporting Info

Nuclear Magnetic Shielding and Quadrupole Coupling Tensors in Liquid Water:  A Combined Molecular Dynamics Simulation and Quantum Chemical Study Teemu S. Pennanen, Juha Vaara, Perttu Lantto, Atte J. Sillanpää, Kari Laasonen, and Jukka Jokisaari pp 11093–11102 DOI: 10.1021/ja048049i

Direct Immobilization of Native Yeast Iso-1 Cytochrome c on Bare Gold:  Fast Electron Relay to Redox Enzymes and Zeptomole Protein-Film Voltammetry Hendrik A. Heering, Frank G. M. Wiertz, Cees Dekker, and Simon de Vries pp 11103–11112 DOI: 10.1021/ja046737w

Evidence for a NiI Active Species in the Catalytic Cross-Coupling of Alkyl Electrophiles [J. Am. Chem. Soc. 2004, 126, 8100−8101]. Thomas J. Anderson, Gavin D. Jones, and David A. Vicic p 11113 DOI: 10.1021/ja040817i

Hyphenated Techniques in Speciation Analysis By Joanna Szpunar (CNRS, Pau, France) and Ryszard Lobinski (CNRS, Pau, France and Warsaw University of Technology). Royal Society of Chemistry:  Cambridge. 2003. xvi + 220 pp. $219.00. ISBN:  0-85404-545-7. Diane Beauchemin p 11114 DOI: 10.1021/ja0409210

Issue 36

Enzyme Activity Fingerprinting with Substrate Cocktails Jean-Philippe Goddard and Jean-Louis Reymond pp 11116–11117 DOI: 10.1021/ja0478330 Supporting Info

Adenine Ribbon with Watson−Crick and Hoogsteen Motifs as the “Double-Sided Adhesive Tape” in the Supramolecular Structure of Adenine and Metal Carboxylate Danuta Dobrzyńska and Lucjan B. Jerzykiewicz pp 11118–11119 DOI: 10.1021/ja0470113 Supporting Info

Highly Efficient, One-Step Macrocyclizations Assisted by the Folding and Preorganization of Precursor Oligomers Lihua Yuan, Wen Feng, Kazuhiro Yamato, Adam R. Sanford, Dingguo Xu, Hua Guo, and Bing Gong pp 11120–11121 DOI: 10.1021/ja0474547 Supporting Info

A New Artificial Cyclase for Polyprenoids:  Enantioselective Total Synthesis of (−)-Chromazonarol, (+)-8-epi-Puupehedione, and (−)-11‘-Deoxytaondiol Methyl Ether Hideaki Ishibashi, Kazuaki Ishihara, and Hisashi Yamamoto pp 11122–11123 DOI: 10.1021/ja0472026 Supporting Info

Direct Time-Resolved and Spatially Resolved Monitoring of Molecular Transport in a Crystalline Nanochannel System Javier Marti-Rujas, Arnaud Desmedt, Kenneth D. M. Harris, and François Guillaume pp 11124–11125 DOI: 10.1021/ja040117d

Chromium(VI) Binding to Functionalized Silica/Water Interfaces Studied by Nonlinear Optical Spectroscopy Hind A. Al-Abadleh, Andrea B. Voges, Paul A. Bertin, SonBinh T. Nguyen, and Franz M. Geiger pp 11126–11127 DOI: 10.1021/ja048063v Supporting Info

Micellar Cobaltporphyrin Nanorods in Alcohols Makoto Yuasa, Kenichi Oyaizu, Aritomo Yamaguchi, and Michi Kuwakado pp 11128–11129 DOI: 10.1021/ja0486216 Supporting Info

Bidentate NHC-Based Chiral Ligands for Efficient Cu-Catalyzed Enantioselective Allylic Alkylations:  Structure and Activity of an Air-Stable Chiral Cu Complex Andrew O. Larsen, Wenhao Leu, Christina Nieto Oberhuber, John E. Campbell, and Amir H. Hoveyda pp 11130–11131 DOI: 10.1021/ja046245j Supporting Info

Polymer−Enzyme Conjugates Can Self-Assemble at Oil/Water Interfaces and Effect Interfacial Biotransformations Guangyu Zhu and Ping Wang pp 11132–11133 DOI: 10.1021/ja046853z Supporting Info

Highly Selective and Simple Synthesis of C2m−X−C2n Fullerene Dimers Yuliang Zhao, Zhenling Chen, Hui Yuan, Xingfa Gao, Li Qu, Zhifang Chai, Gengmei Xing, Soichiro Yoshimoto, Eishi Tsutsumi, and Kingo Itaya pp 11134–11135 DOI: 10.1021/ja048232b Supporting Info

Positioning Isolation and Biochemical Analysis of Single DNA Molecules Based on Nanomanipulation and Single-Molecule PCR Jun-hong Lü, Hai-kuo Li, Hong-jie An, Guo-hua Wang, Ying Wang, Min-qian Li, Yi Zhang, and Jun Hu pp 11136–11137 DOI: 10.1021/ja047124m Supporting Info

Pd(0)-Catalyzed Amphiphilic Activation of Bis-allyl Alcohol and Ether Ryutaro Mukai, Yoshikazu Horino, Shuji Tanaka, Yoshinao Tamaru, and Masanari Kimura pp 11138–11139 DOI: 10.1021/ja0479787 Supporting Info

Boolean Logic Functions of a Synthetic Peptide Network Gonen Ashkenasy and M. Reza Ghadiri pp 11140–11141 DOI: 10.1021/ja046745c Supporting Info

Inactivation of the Carbamoyltransferase Gene Refines Post-Polyketide Synthase Modification Steps in the Biosynthesis of the Antitumor Agent Geldanamycin Young-Soo Hong, Dongho Lee, Woncheol Kim, Jae-Kap Jeong, Chun-Gyu Kim, Jae Kyung Sohng, Jeong-Hyung Lee, Sang-Gi Paik, and Jung Joon Lee pp 11142–11143 DOI: 10.1021/ja047769m Supporting Info

Identification of an Adsorption Complex between an Alkane and Zeolite Active Sites Matthew J. Truitt, Stan S. Toporek, Rosimar Rovira-Hernandez, Kathleen Hatcher, and Jeffery L. White pp 11144–11145 DOI: 10.1021/ja046729f Supporting Info

Chemoselective Silylzincation of Functionalized Terminal Alkynes Using Dianion-Type Zincate (SiBNOL-Zn-ate):  Regiocontrolled Synthesis of Vinylsilanes Shinji Nakamura, Masanobu Uchiyama, and Tomohiko Ohwada pp 11146–11147 DOI: 10.1021/ja047144o Supporting Info

Catalytic Enantioselective Michael Addition of 1,3-Dicarbonyl Compounds to Nitroalkenes Catalyzed by Well-Defined Chiral Ru Amido Complexes Masahito Watanabe, Ayako Ikagawa, Hui Wang, Kunihiko Murata, and Takao Ikariya pp 11148–11149 DOI: 10.1021/ja046296g Supporting Info

Diastereoselective Intramolecular Temporary Silicon-Tethered Rhodium-Catalyzed [4+2+2] Cycloisomerization Reactions:  Regiospecific Incorporation of Substituted 1,3-Butadienes P. Andrew Evans and Erich W. Baum pp 11150–11151 DOI: 10.1021/ja046030+ Supporting Info

Multicatalytic Processes Using Diverse Transition Metals for the Synthesis of Alkenes Hélène Lebel and Valérie Paquet pp 11152–11153 DOI: 10.1021/ja0472681 Supporting Info

Strong Solvatochromic Fluorescence from the Intramolecular Charge-Transfer State Created by Excited-State Intramolecular Proton Transfer Jangwon Seo, Sehoon Kim, and Soo Young Park pp 11154–11155 DOI: 10.1021/ja047815i Supporting Info

Epoxide Hydrolase-Catalyzed Enantioselective Synthesis of Chiral 1,2-Diols via Desymmetrization of meso-Epoxides Lishan Zhao, Bin Han, Zilin Huang, Mark Miller, Hongjun Huang, Dan S. Malashock, Zuolin Zhu, Aileen Milan, Dan E. Robertson, David P. Weiner, and Mark J. Burk pp 11156–11157 DOI: 10.1021/ja0466210 Supporting Info

Water-Soluble, Exfoliated, Nonroping Single-Wall Carbon Nanotubes Jared L. Hudson, Michael J. Casavant, and James M. Tour pp 11158–11159 DOI: 10.1021/ja0467061

Synthesis and Reactivity of Dimethyl Platinum(IV) Hydrides in Water Andrei N. Vedernikov, James C. Fettinger, and Fabian Mohr pp 11160–11161 DOI: 10.1021/ja046310p Supporting Info

An Efficient [4 + 2 + 1] Entry to Seven-Membered Rings Yike Ni and John Montgomery pp 11162–11163 DOI: 10.1021/ja046147y Supporting Info

AuCl3-Catalyzed Synthesis of Highly Substituted Furans from 2-(1-Alkynyl)-2-alken-1-ones Tuanli Yao, Xiaoxia Zhang, and Richard C. Larock pp 11164–11165 DOI: 10.1021/ja0466964 Supporting Info

Electrocatalytic Reduction of ROOH by Iron Porphyrins James P. Collman, Marina Kaplun, Christopher J. Sunderland, and Roman Boulatov pp 11166–11167 DOI: 10.1021/ja046768r Supporting Info

A Pentacene with a 144° Twist Jun Lu, Douglas M. Ho, Nancy J. Vogelaar, Christina M. Kraml, and Robert A. Pascal, Jr. pp 11168–11169 DOI: 10.1021/ja046576w Supporting Info

Alkyne and Alkene Complexes of a d0 Zirconocene Aryl Cation Edward J. Stoebenau, III, and Richard F. Jordan pp 11170–11171 DOI: 10.1021/ja045794m Supporting Info

Backbone Thioester Exchange:  A New Approach to Evaluating Higher Order Structural Stability in Polypeptides Matthew G. Woll and Samuel H. Gellman pp 11172–11174 DOI: 10.1021/ja046891i Supporting Info

The Earliest Events in Protein Folding:  A Structural Requirement for Ultrafast Folding in Cytochrome c Eefei Chen, Robert A. Goldbeck, and David S. Kliger pp 11175–11181 DOI: 10.1021/ja0400077

Flow Linear Dichroism to Probe Binding of Aromatic Molecules and DNA to Single-Walled Carbon Nanotubes Jascindra Rajendra, Mark Baxendale, Laurence Georges Dit Rap, and Alison Rodger pp 11182–11188 DOI: 10.1021/ja048720j

Site-Specific Synthesis and Properties of Oligonucleotides Containing C8-Deoxyguanosine Adducts of the Dietary Mutagen IQ C. Eric Elmquist, James S. Stover, Zhiwei Wang, and Carmelo J. Rizzo pp 11189–11201 DOI: 10.1021/ja0487022 Supporting Info

Aromaticity of Organic Heterocyclothiazenes and Analogues Patrick W. Fowler, Charles W. Rees, and Alessandro Soncini pp 11202–11212 DOI: 10.1021/ja046399z Supporting Info

A Transition State Analogue for an RNA-Editing Reaction Brittany L. Haudenschild, Olena Maydanovych, Eduardo A. Véliz, Mark R. Macbeth, Brenda L. Bass, and Peter A. Beal pp 11213–11219 DOI: 10.1021/ja0472073 Supporting Info

Thermodynamics of Folding, Stabilization, and Binding in an Engineered Protein−Protein Complex Vildan Dincbas-Renqvist, Christofer Lendel, Jakob Dogan, Elisabet Wahlberg, and Torleif Härd pp 11220–11230 DOI: 10.1021/ja047727y

T7 RNA Polymerase Transcription with 5-Position Modified UTP Derivatives Jonathan D. Vaught, Torin Dewey, and Bruce E. Eaton pp 11231–11237 DOI: 10.1021/ja049009h Supporting Info

Modeling Branched Polyethylene:  Copolymers Possessing Precisely Placed Ethyl Branches John C. Sworen, Jason A. Smith, Jessica M. Berg, and Kenneth B. Wagener pp 11238–11246 DOI: 10.1021/ja047850p Supporting Info

Mineral-Assisted Pathways in Prebiotic Synthesis:  Photoelectrochemical Reduction of Carbon(+IV) by Manganese Sulfide Xiang V. Zhang, Scot T. Martin, Cynthia M. Friend, Martin A. A. Schoonen, and Heinrich D. Holland pp 11247–11253 DOI: 10.1021/ja0476415

Total Synthesis of Macquarimicins Using an Intramolecular Diels−Alder Approach Inspired by a Biosynthetic Pathway Ryosuke Munakata, Hironori Katakai, Tatsuo Ueki, Jun Kurosaka, Ken-ichi Takao, and Kin-ichi Tadano pp 11254–11267 DOI: 10.1021/ja048320w Supporting Info

Mechanistic Characterization of Aerobic Alcohol Oxidation Catalyzed by Pd(OAc)2/Pyridine Including Identification of the Catalyst Resting State and the Origin of Nonlinear [Catalyst] Dependence Bradley A. Steinhoff, Ilia A. Guzei, and Shannon S. Stahl pp 11268–11278 DOI: 10.1021/ja049962m Supporting Info

Zirconium-Catalyzed Enantioselective [3+2] Cycloaddition of Hydrazones to Olefins Leading to Optically Active Pyrazolidine, Pyrazoline, and 1,3-Diamine Derivatives Yasuhiro Yamashita and Shū Kobayashi pp 11279–11282 DOI: 10.1021/ja049498l Supporting Info

Electron Impact Ionization in Helium Nanodroplets:  Controlling Fragmentation by Active Cooling of Molecular Ions William K. Lewis, Brian E. Applegate, Judit Sztáray, Bálint Sztáray, Tomas Baer, Raymond J. Bemish, and Roger E. Miller pp 11283–11292 DOI: 10.1021/ja030653q

Experimental and Theoretical Analysis of the Photochemistry and Thermal Reactivity of Ethyl Diazomalonate and Its Diazirino Isomer. The Role of Molecular Geometry in the Decomposition of Diazocarbonyl Compounds Aneta Bogdanova and Vladimir V. Popik pp 11293–11302 DOI: 10.1021/ja047824r Supporting Info

Thermodynamics of Diamond Nucleation on the Nanoscale C. X. Wang, Y. H. Yang, N. S. Xu, and G. W. Yang pp 11303–11306 DOI: 10.1021/ja049333c

Superhelices of Poly[2-(acetoacetoxy)ethyl methacrylate] Helmut Schlaad, Theodora Krasia, and Markus Antonietti pp 11307–11310 DOI: 10.1021/ja047858z Supporting Info

Controlled Self-Assembly of Hexa-peri-hexabenzocoronenes in Solution Jishan Wu, Andreas Fechtenkötter, Jürgen Gauss, Mark D. Watson, Marcel Kastler, Chrys Fechtenkötter, Manfred Wagner, and Klaus Müllen pp 11311–11321 DOI: 10.1021/ja047577r Supporting Info

Quantum Dots Tailored with Poly(para-phenylene vinylene) Habib Skaff, Kevin Sill, and Todd Emrick pp 11322–11325 DOI: 10.1021/ja047260r Supporting Info

The Migrastatin Family:  Discovery of Potent Cell Migration Inhibitors by Chemical Synthesis Christoph Gaul, Jón T. Njardarson, Dandan Shan, David C. Dorn, Kai-Da Wu, William P. Tong, Xin-Yun Huang, Malcolm A. S. Moore, and Samuel J. Danishefsky pp 11326–11337 DOI: 10.1021/ja048779q Supporting Info

Short Lexitropsin that Recognizes the DNA Minor Groove at 5‘-ACTAGT-3‘:  Understanding the Role of Isopropyl-thiazole Nahoum G. Anthony, Blair F. Johnston, Abedawn I. Khalaf, Simon P. MacKay, John A. Parkinson, Colin J. Suckling, and Roger D. Waigh pp 11338–11349 DOI: 10.1021/ja030658n Supporting Info

Probing the Location and Distribution of Paramagnetic Centers in Alkali Metal-Loaded Zeolites through 7Li MAS NMR Victor V. Terskikh, Christopher I. Ratcliffe, John A. Ripmeester, Catherine J. Reinhold, Paul A. Anderson, and Peter P. Edwards pp 11350–11359 DOI: 10.1021/ja0491580 Supporting Info

Electronic Properties of Mononuclear, Dinuclear, and Polynuclear Cobaltacarboranes:  Electrochemical and Spectroelectrochemical Studies Fabrizia Fabrizi de Biani, Maddalena Corsini, Piero Zanello, Haijun Yao, Martin E. Bluhm, and Russell N. Grimes pp 11360–11369 DOI: 10.1021/ja047966l Supporting Info

A Homoleptic Molybdenum(IV) Enolate Complex:  Synthesis, Molecular and Electronic Structure, and NCN Group Transfer To Form a Terminal Cyanoimide of Molybdenum(VI) Han Sen Soo, Joshua S. Figueroa, and Christopher C. Cummins pp 11370–11376 DOI: 10.1021/ja0472533 Supporting Info

Understanding the Role of Sodium during Adsorption:  A Force Field for Alkanes in Sodium-Exchanged Faujasites Sofía Calero, David Dubbeldam, Rajamani Krishna, Berend Smit, Thijs J. H. Vlugt, Joeri F. M. Denayer, Johan A. Martens, and Theo L. M. Maesen pp 11377–11386 DOI: 10.1021/ja0476056

Charge Redistribution on Electronic Excitation. Dipole Moments of cis- and trans-3-Aminophenol in Their S0 and S1 Electronic States Jennifer A. Reese, Tri V. Nguyen, Timothy M. Korter, and David W. Pratt pp 11387–11392 DOI: 10.1021/ja0469683

The Photoinduced Triplet of Flavins and Its Protonation States Radoslaw M. Kowalczyk, Erik Schleicher, Robert Bittl, and Stefan Weber pp 11393–11399 DOI: 10.1021/ja049554i

Physical Properties of Polymers, 3rd ed By James E. Mark (University of Cincinnati), Kia L. Ngai (Navel Research Lab, Washington, DC), William W. Graessley (Princeton University), Leo Mandelkern (The Florida State University), Edward T. Samulski (University of North Carolina), Jack L. Koenig (Case Western Reserve University), and George D. Wignall (Oak Ridge National Laboratory). Cambridge University Press:  Cambridge. 2004. xvi + 520 pp. $65.00 (paperback). ISBN 0-521-53018-0. p 11400 DOI: 10.1021/ja040948j

Femtochemistry and Femtobiology:  Ultrafast Events in Molecular Science Edited by Monique M. Martin (UMR CNRS-ENS 8640, PASTEUR, Paris) and James T. Hynes (UMR CNRS-ENS 8640, PASTEUR, Paris and University of Colorado, Boulder). Elsevier:  Amsterdam. 2004. xviii + 570 pp. $175.00. ISBN 0-444-51656-5. p 11400 DOI: 10.1021/ja040957s

Modern Practice of Gas Chromatography, 4th ed Edited by Robert L. Grob (Villanova University) and Eugene F. Barry (University of Massachusetts, Lowell). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xii + 1046 pp. $150.00. ISBN 0-471-22983-0. p 11400 DOI: 10.1021/ja0409659

Issue 37

Imino Acids and Collagen Triple Helix Stability:  Characterization of Collagen-like Polypeptides Containing Hyp-Hyp-Gly Sequence Repeats Rita Berisio, Vincenzo Granata, Luigi Vitagliano, and Adriana Zagari pp 11402–11403 DOI: 10.1021/ja047069h Supporting Info

Alternating Copolymerization of Limonene Oxide and Carbon Dioxide Christopher M. Byrne, Scott D. Allen, Emil B. Lobkovsky, and Geoffrey W. Coates pp 11404–11405 DOI: 10.1021/ja0472580 Supporting Info

Chemical Waves and Pattern Formation in the 1,2-Dipalmitoyl-sn-glycero-3-phosphocholine/Water Lamellar System Agnese Magnani, Nadia Marchettini, Sandra Ristori, Claudio Rossi, Federico Rossi, Mauro Rustici, Olivier Spalla, and Enzo Tiezzi pp 11406–11407 DOI: 10.1021/ja047030c

Well-Defined, Organic Nanoenvironments in Water:  The Hydrophobic Effect Drives a Capsular Assembly Corinne L. D. Gibb and Bruce C. Gibb pp 11408–11409 DOI: 10.1021/ja0475611 Supporting Info

Molecular Gears:  A Pair of DNA Circles Continuously Rolls against Each Other Ye Tian and Chengde Mao pp 11410–11411 DOI: 10.1021/ja046507h Supporting Info

Simultaneous Freezing of Chirality and In−Out Conformation of a Macropentacyclic Cryptand by Protonation Clément Bonnot, Jean-Claude Chambron, and Enrique Espinosa pp 11412–11413 DOI: 10.1021/ja048441w Supporting Info

The Role of Odd-Electron Intermediates and In-Cage Electron Transfer in Ultrafast Photochemical Disproportionation Reactions in Lewis Bases Matthias F. Kling, James F. Cahoon, Elizabeth A. Glascoe, Jennifer E. Shanoski, and Charles B. Harris pp 11414–11415 DOI: 10.1021/ja046223x Supporting Info

Fabrication of Gold Microtubes and Microwires in High Aspect Ratio Capillary Arrays David J. Monk and David R. Walt pp 11416–11417 DOI: 10.1021/ja048115g Supporting Info

Construction of Supramolecular Polymers with Alternating α-, β-Cyclodextrin Units Using Conformational Change Induced by Competitive Guests Masahiko Miyauchi and Akira Harada pp 11418–11419 DOI: 10.1021/ja046562q Supporting Info

Organic Nanoparticles Whose Size and Rigidity Are Finely Tuned by Cross-Linking the End Groups of Dendrimers N. Gabriel Lemcoff, Tighe A. Spurlin, Andrew A. Gewirth, Steven C. Zimmerman, James B. Beil, Stephanie L. Elmer, and H. George Vandeveer pp 11420–11421 DOI: 10.1021/ja047055b Supporting Info

Site-Specific Backbone Dynamics from a Crystalline Protein by Solid-State NMR Spectroscopy Nicolas Giraud, Anja Böckmann, Anne Lesage, François Penin, Martin Blackledge, and Lyndon Emsley pp 11422–11423 DOI: 10.1021/ja046578g Supporting Info

Site-Specific Variations of Carbonyl Chemical Shift Anisotropies in Proteins Phineus R. L. Markwick and Michael Sattler pp 11424–11425 DOI: 10.1021/ja047859r Supporting Info

Helical, Nonracemic Inorganic−Organic Hybrid Polymers of Cadmium Halides with Pentadentate Bis(oxazoline) Ligands Michael Seitz, Anja Kaiser, Sabine Stempfhuber, Manfred Zabel, and Oliver Reiser pp 11426–11427 DOI: 10.1021/ja0469784 Supporting Info

Equilibrium Isotope Effects as a Probe of Nonbonding Attractions Yi-Lei Zhao, K. N. Houk, Dalit Rechavi, Alessandro Scarso, and Julius Rebek, Jr. pp 11428–11429 DOI: 10.1021/ja0471065 Supporting Info

Pose Scoring by NMR Bing Wang, Kaushik Raha, and Kenneth M. Merz, Jr. pp 11430–11431 DOI: 10.1021/ja047695e

Lyngbyatoxin Biosynthesis:  Sequence of Biosynthetic Gene Cluster and Identification of a Novel Aromatic Prenyltransferase Daniel J. Edwards and William H. Gerwick pp 11432–11433 DOI: 10.1021/ja047876g Supporting Info

Photolytic Living Anionic Ring-Opening Polymerization (ROP) of Silicon-Bridged [1]Ferrocenophanes via an Iron-Cyclopentadienyl Bond Cleavage Mechanism Makoto Tanabe and Ian Manners pp 11434–11435 DOI: 10.1021/ja046657s Supporting Info

In Situ Observations of Water Production and Distribution in an Operating H2/O2 PEM Fuel Cell Assembly Using 1H NMR Microscopy Kirk W. Feindel, Logan P.-A. LaRocque, Dieter Starke, Steven H. Bergens, and Roderick E. Wasylishen pp 11436–11437 DOI: 10.1021/ja0461116

Nickel-Catalyzed Cycloaddition of Alkynes and Isocyanates Hung A. Duong, Michael J. Cross, and Janis Louie pp 11438–11439 DOI: 10.1021/ja046477i Supporting Info

Decarboxylative Aldol Reactions of Allyl β-Keto Esters via Heterobimetallic Catalysis Sha Lou, John A. Westbrook, and Scott E. Schaus pp 11440–11441 DOI: 10.1021/ja045981k Supporting Info

Periodate-Triggered Cross-Linking of DOPA-Containing Peptide−Protein Complexes Lyle Burdine, Thomas G. Gillette, Hai-Jun Lin, and Thomas Kodadek pp 11442–11443 DOI: 10.1021/ja045982c Supporting Info

Hydrogen-Bonding-Induced Shifts of the Excitation Energies in Nucleic Acid Bases:  An Interplay between Electrostatic and Electron Density Overlap Effects Tomasz A. Wesolowski pp 11444–11445 DOI: 10.1021/ja048846g Supporting Info

Immunological Consequences of Methamphetamine Protein Glycation Tobin J. Dickerson, Noboru Yamamoto, Diana I. Ruiz, and Kim D. Janda pp 11446–11447 DOI: 10.1021/ja047690h Supporting Info

Constitutional Dynamic Self-Sensing in a ZincII/Polyiminofluorenes System Nicolas Giuseppone and Jean-Marie Lehn pp 11448–11449 DOI: 10.1021/ja0472883

Protease-Triggered Photosensitizing Beacon Based on Singlet Oxygen Quenching and Activation Juan Chen, Klara Stefflova, Mark J. Niedre, Brian C. Wilson, Britton Chance, Jerry D. Glickson, and Gang Zheng pp 11450–11451 DOI: 10.1021/ja047392k

Photoregulation of RNA Digestion by RNase H with Azobenzene-Tethered DNA Daijiro Matsunaga, Hiroyuki Asanuma, and Makoto Komiyama pp 11452–11453 DOI: 10.1021/ja0471976 Supporting Info

Designer Ribozymes:  Programming the tRNA Specificity into Flexizyme Krishna Ramaswamy, Hirohide Saito, Hiroshi Murakami, Kiyotaka Shiba, and Hiroaki Suga pp 11454–11455 DOI: 10.1021/ja046843y Supporting Info

Sila-Pummerer Rearrangement of Cyclic Sulfoxides:  Computational Study of the Mechanism Bagrat A. Shainyan, Svetlana V. Kirpichenko, and Fillmore Freeman pp 11456–11457 DOI: 10.1021/ja047083u Supporting Info

Shape-Controlled Synthesis and Shape-Induced Texture of MnFe2O4 Nanoparticles Hao Zeng, Philip M. Rice, Shan X. Wang, and Shouheng Sun pp 11458–11459 DOI: 10.1021/ja045911d Supporting Info

Enhancing Hoogsteen Interactions:  A Pyrrole-Containing Purine Nucleoside That Competes with Guanosine Self-Assembly Jonathan L. Sessler, Janarthanan Jayawickramarajah, Courtney L. Sherman, and Jennifer S. Brodbelt pp 11460–11461 DOI: 10.1021/ja046773v Supporting Info

The Structure of Aqueous Guanidinium Chloride Solutions Philip E. Mason, George W. Neilson, John E. Enderby, Marie-Louise Saboungi, Christopher E. Dempsey, Alexander D. MacKerell, Jr., and John W. Brady pp 11462–11470 DOI: 10.1021/ja040034x Supporting Info

DNA Charge Transport:  Conformationally Gated Hopping through Stacked Domains Melanie A. O'Neill and Jacqueline K. Barton pp 11471–11483 DOI: 10.1021/ja048956n Supporting Info

Synthesis, Physicochemical and Biochemical Studies of 1‘,2‘-Oxetane Constrained Adenosine and Guanosine Modified Oligonucleotides, and Their Comparison with Those of the Corresponding Cytidine and Thymidine Analogues Pushpangadan I. Pradeepkumar, Pradeep Cheruku, Oleksandr Plashkevych, Parag Acharya, Suresh Gohil, and Jyoti Chattopadhyaya pp 11484–11499 DOI: 10.1021/ja048417i Supporting Info

Phototriggered Self-Assembly of Hydrogen-Bonded Rosette Shiki Yagai, Toshiharu Nakajima, Takashi Karatsu, Ken-ichi Saitow, and Akihide Kitamura pp 11500–11508 DOI: 10.1021/ja047783z Supporting Info

In Silico Assembly of Alzheimer's Aβ16-22 Peptide into β-Sheets Sébastien Santini, Normand Mousseau, and Philippe Derreumaux pp 11509–11516 DOI: 10.1021/ja047286i

Combinatorial Synthesis of Star-Shaped Block Copolymers:  Host−Guest Chemistry of Unimolecular Reversed Micelles Michael A. R. Meier, Jean-François Gohy, Charles-André Fustin, and Ulrich S. Schubert pp 11517–11521 DOI: 10.1021/ja0488481 Supporting Info

γ-Hydroxyalkenals Are Oxidatively Cleaved through Michael Addition of Acylperoxy Radicals and Fragmentation of Intermediate β-Hydroxyperesters Yuvaraju N. Balamraju, Mingjiang Sun, and Robert G. Salomon pp 11522–11528 DOI: 10.1021/ja048060i

Two-Photon Absorption in Three-Dimensional Chromophores Based on [2.2]-Paracyclophane Glenn P. Bartholomew, Mariacristina Rumi, Stephanie J. K. Pond, Joseph W. Perry, Sergei Tretiak, and Guillermo C. Bazan pp 11529–11542 DOI: 10.1021/ja038743i

4,5-Dimethylthio-4‘-[2-(9-anthryloxy)ethylthio]tetrathiafulvalene, a Highly Selective and Sensitive Chemiluminescence Probe for Singlet Oxygen Xiaohua Li, Guanxin Zhang, Huimin Ma, Deqing Zhang, Jun Li, and Daoben Zhu pp 11543–11548 DOI: 10.1021/ja0481530 Supporting Info

Manipulating Solute Nucleophilicity with Room Temperature Ionic Liquids Lorna Crowhurst, N. Llewellyn Lancaster, Juan M. Pérez Arlandis, and Tom Welton pp 11549–11555 DOI: 10.1021/ja046757y Supporting Info

Self-Recognition, Structure, Stability, and Guest Affinity of Pyrogallol[4]arene and Resorcin[4]arene Capsules in Solution Liat Avram and Yoram Cohen pp 11556–11563 DOI: 10.1021/ja047698r

51V Magic Angle Spinning NMR Spectroscopy of Keggin Anions [PVnW12-nO40](3+n)-:  Effect of Countercation and Vanadium Substitution on Fine Structure Constants Wenlin Huang, Louis Todaro, Glenn P. A. Yap, Robert Beer, Lynn C. Francesconi, and Tatyana Polenova pp 11564–11573 DOI: 10.1021/ja0475499 Supporting Info

Chelating Ligands for Nanocrystals' Surface Functionalization Claudia Querner, Peter Reiss, Joël Bleuse, and Adam Pron pp 11574–11582 DOI: 10.1021/ja047882c

Temperature and Isotope Substitution Effects on the Structure and NMR Properties of the Pertechnetate Ion in Water Herman Cho, Wibe A. de Jong, Bruce K. McNamara, Brian M. Rapko, and Ingrid E. Burgeson pp 11583–11588 DOI: 10.1021/ja047447i Supporting Info

A Simple Thermodynamic Model for Rationalizing the Formation of Self-Assembled Multimetallic Edifices:  Application to Triple-Stranded Helicates Kornelia Zeckert, Josef Hamacek, Jean-Pierre Rivera, Sébastien Floquet, André Pinto, Michal Borkovec, and Claude Piguet pp 11589–11601 DOI: 10.1021/ja0483443 Supporting Info

Surface Chemistry and Electrical Properties of Germanium Nanowires Dunwei Wang, Ying-Lan Chang, Qian Wang, Jien Cao, Damon B. Farmer, Roy G. Gordon, and Hongjie Dai pp 11602–11611 DOI: 10.1021/ja047435x

A Homologous Series of Regioselectively Tetradeprotonated Group 8 Metallocenes:  New Inverse Crown Ring Compounds Synthesized via a Mixed Sodium−Magnesium Tris(diisopropylamide) Synergic Base Prokopis C. Andrikopoulos, David R. Armstrong, William Clegg, Carly J. Gilfillan, Eva Hevia, Alan R. Kennedy, Robert E. Mulvey, Charles T. O'Hara, John A. Parkinson, and Duncan M. Tooke pp 11612–11620 DOI: 10.1021/ja0472230 Supporting Info

Multielectron Photoreduction of a Bridged Ruthenium Dimer, [(phen)2Ru(tatpp)Ru(phen)2][PF6]4:  Aqueous Reactivity and Chemical and Spectroelectrochemical Identification of the Photoproducts Rama Konduri, Norma R. de Tacconi, Krishnan Rajeshwar, and Frederick M. MacDonnell pp 11621–11629 DOI: 10.1021/ja047931l

Diruthenium Tetraacetate Monocation, [RuII/III2(O2CMe)4]+, Building Blocks for 3-D Molecule-Based Magnets Thomas E. Vos, Yi Liao, William W. Shum, Jae-Hyuk Her, Peter W. Stephens, William M. Reiff, and Joel S. Miller pp 11630–11639 DOI: 10.1021/ja048135i Supporting Info

Strong Room-Temperature Ferromagnetism in Co2+-Doped TiO2 Made from Colloidal Nanocrystals J. Daniel Bryan, Steve M. Heald, Scott A. Chambers, and Daniel R. Gamelin pp 11640–11647 DOI: 10.1021/ja047381r Supporting Info

Stable Room-Temperature Molecular Negative Differential Resistance Based on Molecule−Electrode Interface Chemistry Adi Salomon, Rina Arad-Yellin, Abraham Shanzer, Amir Karton, and David Cahen pp 11648–11657 DOI: 10.1021/ja049584l

Mechanistic Analysis of Hydroarylation Catalysts Jonas Oxgaard, Roy A. Periana, and William A. Goddard, III pp 11658–11665 DOI: 10.1021/ja048841j Supporting Info

Infrared Multiphoton Dissociation Spectroscopy of Gas-Phase Mass-Selected Hydrocarbon−Fe+ Complexes Aude Simon, William Jones, Jean-Michel Ortega, Pierre Boissel, Joël Lemaire, and Philippe Maître pp 11666–11674 DOI: 10.1021/ja0488176

The Gas-Phase Structure of Alanine Susana Blanco, Alberto Lesarri, Juan C. López, and José L. Alonso pp 11675–11683 DOI: 10.1021/ja048317c Supporting Info

Catalytic Probe Lithography:  Catalyst-Functionalized Scanning Probes as Nanopens for Nanofabrication on Self-Assembled Monolayers Mária Péter, Xue-Mei Li, Jurriaan Huskens, and David N. Reinhoudt pp 11684–11690 DOI: 10.1021/ja048027w

Bulk versus Interfacial Aqueous Solvation of Dicarboxylate Dianions Babak Minofar, Martin Mucha, Pavel Jungwirth, Xin Yang, You-Jun Fu, Xue-Bin Wang, and Lai-Sheng Wang pp 11691–11698 DOI: 10.1021/ja047493i

A Computational Foray into the Formation and Reactivity of Metallabenzenes Mark A. Iron, André C. B. Lucassen, Hagai Cohen, Milko E. van der Boom, and Jan M. L. Martin pp 11699–11710 DOI: 10.1021/ja047125e Supporting Info

Macromolecular Helicity Induction on a Poly(phenylacetylene) with C2-Symmetric Chiral [60]Fullerene-Bisadducts Tatsuya Nishimura, Kayo Tsuchiya, Sousuke Ohsawa, Katsuhiro Maeda, Eiji Yashima, Yosuke Nakamura, and Jun Nishimura pp 11711–11717 DOI: 10.1021/ja046633l Supporting Info

Dynamic NMR Study of the Mechanisms of Double, Triple, and Quadruple Proton and Deuteron Transfer in Cyclic Hydrogen Bonded Solids of Pyrazole Derivatives Oliver Klein, Francisco Aguilar-Parrilla, Juan Miguel Lopez, Nadine Jagerovic, José Elguero, and Hans-Heinrich Limbach pp 11718–11732 DOI: 10.1021/ja0493650

Carboxylate Binding in Copper Histidine Complexes in Solution and in Zeolite Y:  X- and W-band Pulsed EPR/ENDOR Combined with DFT Calculations Debbie Baute, Dafna Arieli, Frank Neese, Herbert Zimmermann, Bert M. Weckhuysen, and Daniella Goldfarb pp 11733–11745 DOI: 10.1021/ja047761c Supporting Info

External Electric Field Will Control the Selectivity of Enzymatic-Like Bond Activations Sason Shaik, Sam P. de Visser, and Devesh Kumar pp 11746–11749 DOI: 10.1021/ja047432k Supporting Info

Organic Thin Film Transistors from a Soluble Oligothiophene Derivative Containing Thermally Removable Solubilizing Groups [J. Am. Chem. Soc. 2004, 126, 1596−1597]. Amanda R. Murphy, Jean M. J. Fréchet, Paul Chang, Josephine Lee, and Vivek Subramanian p 11750 DOI: 10.1021/ja0408193

Issue 38

Pushing the Band Gap Envelope:  Mid-Infrared Emitting Colloidal PbSe Quantum Dots Jeffrey M. Pietryga, Richard D. Schaller, Donald Werder, Michael H. Stewart, Victor I. Klimov, and Jennifer A. Hollingsworth pp 11752–11753 DOI: 10.1021/ja047659f Supporting Info

Interfacial Acidities, Charge Densities, Potentials, and Energies of Carboxylic Acid-Functionalized Silica/Water Interfaces Determined by Second Harmonic Generation Christopher T. Konek, Michael J. Musorrafiti, Hind A. Al-Abadleh, Paul A. Bertin, SonBinh T. Nguyen, and Franz M. Geiger pp 11754–11755 DOI: 10.1021/ja0474300

Sub-second 2D NMR Spectroscopy at Sub-millimolar Concentrations Boaz Shapira, Erel Morris, Karol A. Muszkat, and Lucio Frydman pp 11756–11757 DOI: 10.1021/ja0461668

Tetrakis(di-tert-butylmethylsilyl)distannene and Its Anion Radical Tomohide Fukawa, Vladimir Ya. Lee, Masaaki Nakamoto, and Akira Sekiguchi pp 11758–11759 DOI: 10.1021/ja040152k Supporting Info

Detection of Zinc Ions by Differential Circularly Polarized Fluorescence Excitation Zhaohua Dai, Gloria Proni, Danny Mancheno, Sasan Karimi, Nina Berova, and James W. Canary pp 11760–11761 DOI: 10.1021/ja047213z Supporting Info

Alkylated Polyethyleneimine/Polyoxometalate Synzymes as Catalysts for the Oxidation of Hydrophobic Substrates in Water with Hydrogen Peroxide Adina Haimov, Hagai Cohen, and Ronny Neumann pp 11762–11763 DOI: 10.1021/ja046349u

Computational Titration Analysis of a Multiprotic HIV-1 Protease−Ligand Complex Francesca Spyrakis, Micaela Fornabaio, Pietro Cozzini, Andrea Mozzarelli, Donald J. Abraham, and Glen E. Kellogg pp 11764–11765 DOI: 10.1021/ja0465754 Supporting Info

Measuring Masses of Single Bacterial Whole Cells with a Quadrupole Ion Trap Wen-Ping Peng, Yi-Chang Yang, Ming-Wei Kang, Yuan T. Lee, and Huan-Cheng Chang pp 11766–11767 DOI: 10.1021/ja046754l Supporting Info

Aptamer-Functionalized Au Nanoparticles for the Amplified Optical Detection of Thrombin Valeri Pavlov, Yi Xiao, Bella Shlyahovsky, and Itamar Willner pp 11768–11769 DOI: 10.1021/ja046970u Supporting Info

In Situ Catalyst Improvement in the Proline-Mediated α-Amination of Aldehydes Hiroshi Iwamura, Suju P. Mathew, and Donna G. Blackmond pp 11770–11771 DOI: 10.1021/ja046258x Supporting Info

Hybrid Organic−Inorganic, Rod-Shaped Nanoresistors and Diodes Sungho Park, Sung-Wook Chung, and Chad A. Mirkin pp 11772–11773 DOI: 10.1021/ja046077v Supporting Info

Miniature Organic Transistors with Carbon Nanotubes as Quasi-One-Dimensional Electrodes Pengfei Qi, Ali Javey, Marco Rolandi, Qian Wang, Erhan Yenilmez, and Hongjie Dai pp 11774–11775 DOI: 10.1021/ja045900k Supporting Info

Enzymatic Synthesis and 19F NMR Studies of 2-Fluoroadenine-Substituted RNA Lincoln G. Scott, Bernhard H. Geierstanger, James R. Williamson, and Mirko Hennig pp 11776–11777 DOI: 10.1021/ja047556x Supporting Info

Sequential Assembly Strategy for Tetrasubstituted Olefin Synthesis Using Vinyl 2-Pyrimidyl Sulfide as a Platform Kenichiro Itami, Masahiro Mineno, Nobuhiro Muraoka, and Jun-ichi Yoshida pp 11778–11779 DOI: 10.1021/ja045858t Supporting Info

Interwoven Pair of Open Frameworks in the Thiosphosphate K6Yb3(PS4)5 Jennifer A. Aitken and Mercouri G. Kanatzidis pp 11780–11781 DOI: 10.1021/ja0474648 Supporting Info

Delocalization in Platinum−Alkynyl Systems:  A Metal-Bridged Organic Mixed-Valence Compound Simon C. Jones, Veaceslav Coropceanu, Stephen Barlow, Tiffany Kinnibrugh, Tatiana Timofeeva, Jean-Luc Brédas, and Seth R. Marder pp 11782–11783 DOI: 10.1021/ja045869m Supporting Info

Geometrical Control of the Active Site Electronic Structure of Pyranopterin Enzymes by Metal-Dithiolate Folding:  Aldehyde Oxidase Hemant K. Joshi and John H. Enemark pp 11784–11785 DOI: 10.1021/ja046465x Supporting Info

Genetically Encoded FRET Probe for PKC Activity Based on Pleckstrin Andreas Schleifenbaum, Gunter Stier, Alexander Gasch, Michael Sattler, and Carsten Schultz pp 11786–11787 DOI: 10.1021/ja0460155 Supporting Info

Influence of Water on the Surface of Hydrophilic and Hydrophobic Room-Temperature Ionic Liquids Selimar Rivera-Rubero and Steven Baldelli pp 11788–11789 DOI: 10.1021/ja0464894

Highly Enantioselective Conjugate Addition of Nitroalkanes to Alkylidenemalonates Using Efficient Phase-Transfer Catalysis of N-Spiro Chiral Ammonium Bromides Takashi Ooi, Shingo Fujioka, and Keiji Maruoka pp 11790–11791 DOI: 10.1021/ja047047v Supporting Info

A Stable Distannirane Lise Baiget, Henri Ranaivonjatovo, Jean Escudié, and Heinz Gornitzka pp 11792–11793 DOI: 10.1021/ja0464239 Supporting Info

Simultaneous Determination of Structural and Thermodynamic Effects of Carbohydrate Solutes on the Thermal Stability of Ribonuclease A Thomas F. O'Connor, Pablo G. Debenedetti, and Jeffrey D. Carbeck pp 11794–11795 DOI: 10.1021/ja0481777 Supporting Info

Oligothiophene Isocyanides for Platinum-Based Molecular Electronic Applications Dennis Bong, Iris Tam, and Ronald Breslow pp 11796–11797 DOI: 10.1021/ja045904p Supporting Info

Shape Evolution and Self Assembly of Monodisperse PbTe Nanocrystals Weigang Lu, Jiye Fang, Kevin L. Stokes, and Jun Lin pp 11798–11799 DOI: 10.1021/ja0469131 Supporting Info

Unexpected Highly Chemoselective Deprotection of the Acetals from Aldehydes and Not Ketones:  TESOTf−2,6-Lutidine Combination Hiromichi Fujioka, Yoshinari Sawama, Nobutaka Murata, Takashi Okitsu, Ozora Kubo, Satoshi Matsuda, and Yasuyuki Kita pp 11800–11801 DOI: 10.1021/ja046103p Supporting Info

Direct Observation of Oxidative Cyclization of η2-Alkene and η2-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of Me3SiOTf Sensuke Ogoshi, Masa-aki Oka, and Hideo Kurosawa pp 11802–11803 DOI: 10.1021/ja0460716 Supporting Info

Organocatalytic Asymmetric Aza-Friedel−Crafts Alkylation of Furan Daisuke Uraguchi, Keiichi Sorimachi, and Masahiro Terada pp 11804–11805 DOI: 10.1021/ja046185h Supporting Info

Gold-Catalyzed Cycloisomerization of Siloxy Enynes to Cyclohexadienes Liming Zhang and Sergey A. Kozmin pp 11806–11807 DOI: 10.1021/ja046112y Supporting Info

New Entries in Lewis Acid−Lewis Base Bifunctional Asymmetric Catalyst:  Catalytic Enantioselective Reissert Reaction of Pyridine Derivatives Eiko Ichikawa, Masato Suzuki, Kazuo Yabu, Matthias Albert, Motomu Kanai, and Masakatsu Shibasaki pp 11808–11809 DOI: 10.1021/ja045966f Supporting Info

CuBr-Catalyzed Efficient Alkynylation of sp3 C−H Bonds Adjacent to a Nitrogen Atom Zhiping Li and Chao-Jun Li pp 11810–11811 DOI: 10.1021/ja0460763 Supporting Info

Remarkable Room-Temperature Insertion of Carbon Monoxide into an Aluminum−Carbon Bond of Tri-tert-butylaluminum Mark R. Mason, Bingxu Song, and Kristin Kirschbaum pp 11812–11813 DOI: 10.1021/ja046411n Supporting Info

Do Electrostatic Interactions with Positively Charged Active Site Groups Tighten the Transition State for Enzymatic Phosphoryl Transfer? Ivana Nikolic-Hughes, Douglas C. Rees, and Daniel Herschlag pp 11814–11819 DOI: 10.1021/ja0480421

α-Alkylation of Ketones by Addition of Zinc Enamides to Unactivated Olefins Masaharu Nakamura, Takuji Hatakeyama, and Eiichi Nakamura pp 11820–11825 DOI: 10.1021/ja0465193 Supporting Info

Expanded-Size Bases in Naturally Sized DNA:  Evaluation of Steric Effects in Watson−Crick Pairing Jianmin Gao, Haibo Liu, and Eric T. Kool pp 11826–11831 DOI: 10.1021/ja048499a Supporting Info

Enzymatic Catalysis of Urea Decomposition:  Elimination or Hydrolysis? Guillermina Estiu and Kenneth M. Merz, Jr. pp 11832–11842 DOI: 10.1021/ja047934y Supporting Info

The Effect of Mutation on RNA Diels−Alderases Theodore M. Tarasow, Elizabeth Kellogg, Benjamin L. Holley, Daniel Nieuwlandt, Sandra L. Tarasow, and Bruce E. Eaton pp 11843–11851 DOI: 10.1021/ja0494149

The Mechanism of Nitrogenase. Computed Details of the Site and Geometry of Binding of Alkyne and Alkene Substrates and Intermediates Ian Dance pp 11852–11863 DOI: 10.1021/ja0481070

Altered Mechanisms of Reactions of Phosphate Esters Bridging a Dinuclear Metal Center Tim Humphry, Marcello Forconi, Nicholas H. Williams, and Alvan C. Hengge pp 11864–11869 DOI: 10.1021/ja047110g Supporting Info

Thermodynamics of Binding of d-Galactose and Deoxy Derivatives thereof to the l-Arabinose-binding Protein Antonio Hernandez Daranas, Hiroki Shimizu, and Steve W. Homans pp 11870–11876 DOI: 10.1021/ja048054m Supporting Info

The Escape Process of Carbon Monoxide from Myoglobin to Solution at Physiological Temperature Yasutaka Nishihara, Masaaki Sakakura, Yoshifumi Kimura, and Masahide Terazima pp 11877–11888 DOI: 10.1021/ja038877w

Electronic Delocalization in Discotic Liquid Crystals:  A Joint Experimental and Theoretical Study Xavier Crispin, Jérôme Cornil, Rainer Friedlein, Koji Kamiya Okudaira, Vincent Lemaur, Annica Crispin, Gaël Kestemont, Matthias Lehmann, Mats Fahlman, Roberto Lazzaroni, Yves Geerts, Göran Wendin, Nobuo Ueno, Jean-Luc Brédas, and William R. Salaneck pp 11889–11899 DOI: 10.1021/ja048669j

Triplet Diphenylcarbenes Protected by o-Aryl Groups Kyoko Monguchi, Tetsuji Itoh, Katsuyki Hirai, and Hideo Tomioka pp 11900–11913 DOI: 10.1021/ja047738r Supporting Info

A Self-Assembled Multivalent Pseudopolyrotaxane for Binding Galectin-1 Alshakim Nelson, Jason M. Belitsky, Sébastien Vidal, C. Steven Joiner, Linda G. Baum, and J. Fraser Stoddart pp 11914–11922 DOI: 10.1021/ja0491073 Supporting Info

The Influence of Water on the Rates of 1,3-Dipolar Cycloaddition Reactions:  Trigger Points for Exponential Rate Increases in Water−Organic Solvent Mixtures. Water-Super versus Water-Normal Dipolarophiles Richard N. Butler, William J. Cunningham, Anthony G. Coyne, and Luke A. Burke pp 11923–11929 DOI: 10.1021/ja040119y

Bis-Histidyl Hexacoordination in Hemoglobins Facilitates Heme Reduction Kinetics Theodore R. Weiland, Suman Kundu, James T. Trent III, Julie A. Hoy, and Mark S. Hargrove pp 11930–11935 DOI: 10.1021/ja046990w

Stimuli-Responsive Supramolecular Assemblies of Linear-Dendritic Copolymers Elizabeth R. Gillies, Thomas B. Jonsson, and Jean M. J. Fréchet pp 11936–11943 DOI: 10.1021/ja0463738 Supporting Info

Characterization of Self-Assembled Monolayers of Porphyrins Bearing Multiple Thiol-Derivatized Rigid-Rod Tethers Amir A. Yasseri, Dennis Syomin, Vladimir L. Malinovskii, Robert S. Loewe, Jonathan S. Lindsey, Francisco Zaera, and David F. Bocian pp 11944–11953 DOI: 10.1021/ja047723t Supporting Info

Activation of Molecular Hydrogen over a Binuclear Complex with Rh2S2 Core:  DFT Calculations and NMR Mechanistic Studies Andrea Ienco, Maria José Calhorda, Joachim Reinhold, Francesca Reineri, Claudio Bianchini, Maurizio Peruzzini, Francesco Vizza, and Carlo Mealli pp 11954–11965 DOI: 10.1021/ja047992j Supporting Info

Synthesis of Chiral Chromans by the Pd-Catalyzed Asymmetric Allylic Alkylation (AAA):  Scope, Mechanism, and Applications Barry M. Trost, Hong C. Shen, Li Dong, Jean-Philippe Surivet, and Catherine Sylvain pp 11966–11983 DOI: 10.1021/ja048078t Supporting Info

Structure and Dynamics of Neutral β-H Agostic Nickel Alkyls:  A Combined Experimental and Theoretical Study Elzbieta Kogut, Alexander Zeller, Timothy H. Warren, and Thomas Strassner pp 11984–11994 DOI: 10.1021/ja0477221 Supporting Info

Hydration Energies in the Gas Phase of Select (MX)mM+ Ions, Where M+ = Na+, K+, Rb+, Cs+, NH4+ and X- = F-, Cl-, Br-, I-, NO2-, NO3-. Observed Magic Numbers of (MX)mM+ Ions and Their Possible Significance Arthur T. Blades, Michael Peschke, Udo H. Verkerk, and Paul Kebarle pp 11995–12003 DOI: 10.1021/ja030663r

The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H2 Production Electrocatalysts:  Iron Hydrogenase Model Complexes Rosario Mejia-Rodriguez, Daesung Chong, Joseph H. Reibenspies, Manuel P. Soriaga, and Marcetta Y. Darensbourg pp 12004–12014 DOI: 10.1021/ja039394v Supporting Info

Synchrotron X-ray Powder Diffraction and Computational Investigation of Purely Siliceous Zeolite Y under Pressure Marek Colligan, Paul M. Forster, Anthony K. Cheetham, Yongjae Lee, Thomas Vogt, and Joseph A. Hriljac pp 12015–12022 DOI: 10.1021/ja048685g Supporting Info

Living Copolymerization of Ethylene with Norbornene Catalyzed by Bis(Pyrrolide−Imine) Titanium Complexes with MAO Yasunori Yoshida, Jun-ichi Mohri, Sei-ichi Ishii, Makoto Mitani, Junji Saito, Shigekazu Matsui, Haruyuki Makio, Takashi Nakano, Hidetsugu Tanaka, Mitsuhiko Onda, Yukari Yamamoto, Akira Mizuno, and Terunori Fujita pp 12023–12032 DOI: 10.1021/ja048357g Supporting Info

Metal Cation−Methyl Interactions in CB11Me12- Salts of Me3Ge+, Me3Sn+, and Me3Pb+ Ilya Zharov, Tsu-Chien Weng, Anita M. Orendt, Dewey H. Barich, James Penner-Hahn, David M. Grant, Zdenek Havlas, and Josef Michl pp 12033–12046 DOI: 10.1021/ja0475205 Supporting Info

Nanoparticles Comprising a Mixed Monolayer for Specific Bindings with Biomolecules Ming Zheng and Xueying Huang pp 12047–12054 DOI: 10.1021/ja047029d Supporting Info

Fullerenols Revisited as Stable Radical Anions Lars O. Husebo, Balaji Sitharaman, Ko Furukawa, Tatsuhisa Kato, and Lon J. Wilson pp 12055–12064 DOI: 10.1021/ja047593o Supporting Info

Synthesis, Structure, and Molecular Dynamics of Gallium Complexes of Schizokinen and the Amphiphilic Siderophore Acinetoferrin Evgeny A. Fadeev, Minkui Luo, and John T. Groves pp 12065–12075 DOI: 10.1021/ja048145j Supporting Info

Single-Component Magnetic Conductors Based on Mo3S7 Trinuclear Clusters with Outer Dithiolate Ligands Rosa Llusar, Santiago Uriel, Cristian Vicent, Juan M. Clemente-Juan, Eugenio Coronado, Carlos J. Gómez-García, Benoit Braïda, and Enric Canadell pp 12076–12083 DOI: 10.1021/ja0474244 Supporting Info

Photosensitized Hydrogen Evolution from Water Using Conjugated Polymers Wrapped in Dendrimeric Electrolytes Dong-Lin Jiang, Cheol-Kyu Choi, Kayoko Honda, Wei-Shi Li, Tetsuro Yuzawa, and Takuzo Aida pp 12084–12089 DOI: 10.1021/ja048912e Supporting Info

Mixed 1D−2D Inorganic Polymeric Zinc Ferrocenylphosphonate:  Crystal Structure and Electrochemical Study Olivier Oms, Jean Le Bideau, Fabrice Leroux, Arie van der Lee, Dominique Leclercq, and André Vioux pp 12090–12096 DOI: 10.1021/ja049457p Supporting Info

Computational Study of the Structure-Directing Effect of Benzylpyrrolidine and Its Fluorinated Derivatives in the Synthesis of the Aluminophosphate AlPO-5 Luis Gómez-Hortigüela, Furio Corà, C. Richard A. Catlow, and Joaquín Pérez-Pariente pp 12097–12102 DOI: 10.1021/ja0481023

Detaching Thiolates from Copper and Gold Clusters:  Which Bonds to Break? Martin Konôpka, Roger Rousseau, Ivan Štich, and Dominik Marx pp 12103–12111 DOI: 10.1021/ja047946j Supporting Info

Theoretical Study on the Photochromic Cycloreversion Reactions of Dithienylethenes; on the Role of the Conical Intersections Yukako Asano, Akinori Murakami, Takao Kobayashi, Alexander Goldberg, Dominique Guillaumont, Satoshi Yabushita, Masahiro Irie, and Shinichiro Nakamura pp 12112–12120 DOI: 10.1021/ja035035o

On the 6-endo Selectivity in 4-Penten-1-oxyl Radical Cyclizations Jens Hartung, Rainer Kneuer, Christian Rummey, and Gerhard Bringmann pp 12121–12129 DOI: 10.1021/ja049010g Supporting Info

Electron-Vibrational Dynamics of Photoexcited Polyfluorenes Ignacio Franco and Sergei Tretiak pp 12130–12140 DOI: 10.1021/ja0489285 Supporting Info

Spontaneous Gas-Phase Generation of Needle-Shaped Clusters Which Violate the Isolated Square Rule:  A Facile Road to GaN Nanorods? Alexey Y. Timoshkin and Henry F. Schaefer III pp 12141–12154 DOI: 10.1021/ja0400483 Supporting Info

A New NMR Approach for the Assignment of Symmetric Isomers Lodovico Lunazzi and Andrea Mazzanti pp 12155–12157 DOI: 10.1021/ja047887+ Supporting Info

Degradation of N-Acetyl Tryptophan by Low-Energy (<12 eV) Electrons Hassan Abdoul-Carime, Sascha Gohlke, and Eugen Illenberger pp 12158–12161 DOI: 10.1021/ja047517l

Inhibition and Aerobic Inactivation Kinetics of Desulfovibrio fructosovorans NiFe Hydrogenase Studied by Protein Film Voltammetry Christophe Léger, Sébastien Dementin, Patrick Bertrand, Marc Rousset, and Bruno Guigliarelli pp 12162–12172 DOI: 10.1021/ja046548d Supporting Info

Gas-Phase Synthesis and Reactivity of the Organomagnesates [CH3MgL2]- (L = Cl and O2CCH3):  From Ligand Effects to Catalysis Richard A. J. O'Hair, Ana K. Vrkic, and Patrick F. James pp 12173–12183 DOI: 10.1021/ja048476w Supporting Info

Charge-Induced Unfolding of Multiply Charged Polyethylene Glycol Ions S. Ude, J. Fernández de la Mora, and B. A. Thomson pp 12184–12190 DOI: 10.1021/ja0381306

Introduction to Biophotonics By Paras N. Prasad (SUNY-Buffalo). J. Wiley & Sons, Inc.:  Hoboken, NJ. 2003. xviii + 594 pp. $99.95. ISBN:  0-471-28770-9. Thomas M. Jovin p 12191 DOI: 10.1021/ja033580j

Radical Reactions in Organic Synthesis By Samir Z. Zard (Ecole Polytechnique, Palaiseau, France). Oxford University Press, Inc.:  New York. 2003. xi + 256 pp. $64.50. ISBN:  0-19-850240-0. Derrick L. J. Clive pp 12191–12192 DOI: 10.1021/ja040924c

Issue 39

Univocal Demonstration of the Electrochemically Mediated Binding of Pb2+ by a Modified Surface Incorporating a TTF-Based Redox-Switchable Ligand Joël Lyskawa, Franck Le Derf, Eric Levillain, Miloud Mazari, Marc Sallé, Laetitia Dubois, Pascal Viel, Christophe Bureau, and Serge Palacin pp 12194–12195 DOI: 10.1021/ja047411q Supporting Info

Charge-Reversal Amphiphiles for Gene Delivery Carla A. H. Prata, Yuxing Zhao, Philippe Barthelemy, Yougen Li, Dan Luo, Thomas J. McIntosh, Stephen J. Lee, and Mark W. Grinstaff pp 12196–12197 DOI: 10.1021/ja0474906 Supporting Info

Hydrogen Bonding on the Surface of Poly(2-methoxyethyl acrylate) Guifeng Li, Shen Ye, Shigeaki Morita, Takuma Nishida, and Masatoshi Osawa pp 12198–12199 DOI: 10.1021/ja046183x Supporting Info

Multi-Maleimides Bearing Electron-Donating Chromophores:  Reversible Fluorescence and Aggregation Behavior Xin Zhang, Zi-Chen Li, Kai-Bo Li, Fu-Sheng Du, and Fu-Mian Li pp 12200–12201 DOI: 10.1021/ja0487527 Supporting Info

Electronic Substituent Effects on the Cleavage Specificity of a Non-Heme Fe2+-Dependent β-Diketone Dioxygenase and Their Mechanistic Implications Grit D. Straganz, Hannes Hofer, Walter Steiner, and Bernd Nidetzky pp 12202–12203 DOI: 10.1021/ja0460918 Supporting Info

Molecular Recognition in a Supramolecular Hydrogel to Afford a Semi-Wet Sensor Chip Ibuki Yoshimura, Yoshifumi Miyahara, Noriyuki Kasagi, Hiroki Yamane, Akio Ojida, and Itaru Hamachi pp 12204–12205 DOI: 10.1021/ja045962a Supporting Info

Suicide Inactivation of Dioldehydratase by Glycolaldehyde and Chloroacetaldehyde:  an Examination of the Reaction Mechanism Gregory M. Sandala, David M. Smith, Michelle L. Coote, and Leo Radom pp 12206–12207 DOI: 10.1021/ja047377f Supporting Info

Shape-Persistent Macromolecular Disks from Reactive Supramolecular Rod Bundles Long Yi Jin, Jong-Hyun Ahn, and Myongsoo Lee pp 12208–12209 DOI: 10.1021/ja0465552 Supporting Info

A Generic Basis for Some Simple Light-Operated Mechanical Molecular Machines Emilio M. Pérez, David T. F. Dryden, David A. Leigh, Gilberto Teobaldi, and Francesco Zerbetto pp 12210–12211 DOI: 10.1021/ja0484193 Supporting Info

Rational Design of an l-Histidine-Derived Minimal Artificial Acylase for the Kinetic Resolution of Racemic Alcohols Kazuaki Ishihara, Yuji Kosugi, and Matsujiro Akakura pp 12212–12213 DOI: 10.1021/ja045850j Supporting Info

Mediating Stochastic Switching of Single Molecules Using Chemical Functionality Penelope A. Lewis, Christina E. Inman, Yuxing Yao, James M. Tour, James E. Hutchison, and Paul S. Weiss pp 12214–12215 DOI: 10.1021/ja038622i Supporting Info

Diastereoselective Synthesis of 2,3,6-Trisubstituted Tetrahydropyran-4-ones via Prins Cyclizations of Enecarbamates: A Formal Synthesis of (+)-Ratjadone A Kimberly N. Cossey and Raymond L. Funk pp 12216–12217 DOI: 10.1021/ja046940r Supporting Info

High Efficiency of Dye-Sensitized Solar Cells Based on Metal-Free Indoline Dyes Tamotsu Horiuchi, Hidetoshi Miura, Kouichi Sumioka, and Satoshi Uchida pp 12218–12219 DOI: 10.1021/ja0488277 Supporting Info

Singlet Vinylcarbenes:  Spectroscopy and Photochemistry Peter S. Zuev and Robert S. Sheridan pp 12220–12221 DOI: 10.1021/ja046309q Supporting Info

A General Procedure for the Esterification of Carboxylic Acids with Diazoalkanes Generated in Situ by the Oxidation of N-tert-Butyldimethylsilylhydrazones with (Difluoroiodo)benzene Michael E. Furrow and Andrew G. Myers pp 12222–12223 DOI: 10.1021/ja0459779 Supporting Info

Protein Encapsulation in Mesoporous Silicate:  The Effects of Confinement on Protein Stability, Hydration, and Volumetric Properties Revanur Ravindra, Shuang Zhao, Hermann Gies, and Roland Winter pp 12224–12225 DOI: 10.1021/ja046900n

2,3-Dihydroimidazo[1,2-a]pyridines:  A New Class of Enantioselective Acyl Transfer Catalysts and Their Use in Kinetic Resolution of Alcohols Vladimir B. Birman, Eric W. Uffman, Hui Jiang, Ximin Li, and Corey J. Kilbane pp 12226–12227 DOI: 10.1021/ja0491477 Supporting Info

Group-Selective Ring-Closing Enyne Metathesis:  Concentration-Dependent Selectivity Profile of Alkynylsilyloxy-Tethered Dienynes Sarah V. Maifeld, Reagan L. Miller, and Daesung Lee pp 12228–12229 DOI: 10.1021/ja046043n Supporting Info

A New Class of CVD Precursors to Metal Borides:  Cr(B3H8)2 and Related Octahydrotriborate Complexes Dean M. Goedde and Gregory S. Girolami pp 12230–12231 DOI: 10.1021/ja046906c Supporting Info

A General Bifunctional Catalyst for the Anti-Markovnikov Hydration of Terminal Alkynes to Aldehydes Gives Enzyme-Like Rate and Selectivity Enhancements Douglas B. Grotjahn and Daniel A. Lev pp 12232–12233 DOI: 10.1021/ja046360u Supporting Info

Dispersion of the Third-Order Nonlinear Optical Properties of an Organometallic Dendrimer1 Clem E. Powell, Joseph P. Morrall, Simone A. Ward, Marie P. Cifuentes, Eleni G. A. Notaras, Marek Samoc, and Mark G. Humphrey pp 12234–12235 DOI: 10.1021/ja048608l Supporting Info

Catalytic Asymmetric Hydroxymethylation of Silicon Enolates Using an Aqueous Solution of Formaldehyde with a Chiral Scandium Complex Shunpei Ishikawa, Tomoaki Hamada, Kei Manabe, and Shū Kobayashi pp 12236–12237 DOI: 10.1021/ja047896i Supporting Info

A Diamondoid Network of Tetrakis(acetamidato)dirhodium in Mixed Oxidation States Linked by μ4-Iodide Having a 105 Enhancement of Its Electrical Conductivity by Water Molecules of Hydration Yasuhiro Fuma, Masahiro Ebihara, Shoichi Kutsumizu, and Takashi Kawamura pp 12238–12239 DOI: 10.1021/ja047421r Supporting Info

Highly Syndiospecific Polymerization of Styrene Catalyzed by Allyl Lanthanide Complexes Evgueni Kirillov, Christian W. Lehmann, Abbas Razavi, and Jean-François Carpentier pp 12240–12241 DOI: 10.1021/ja0455695 Supporting Info

A Unique Reaction Pathway of Fluorine-Substituted Ethyl Groups on Cu(111):  Successive α,α-Fluoride Elimination Chao-Ming Chiang, Deyi Lu, Jia-Tze Huang, Chi-Chau Hwang, Chia-Chin Cho, Liang-Jen Fan, and Yaw-Wen Yang pp 12242–12243 DOI: 10.1021/ja047831f

Unique Oxidative Metal−Metal Bond Formation of Linearly Aligned Tetranuclear Rh−Mo−Mo−Rh Clusters Tobias Rüffer, Masato Ohashi, Asuka Shima, Hitoshi Mizomoto, Yutaka Kaneda, and Kazushi Mashima pp 12244–12245 DOI: 10.1021/ja046552p Supporting Info

Palladium-Catalyzed Copolymerization of Ethene with Acrolein Dimethyl Acetal:  Catalyst Action and Deactivation Weidong Li, Xiaochun Zhang, Auke Meetsma, and Bart Hessen pp 12246–12247 DOI: 10.1021/ja045948y Supporting Info

Fe/Cr- and Co/Cr-Mediated Catalytic Asymmetric 2-Haloallylations of Aldehydes Michio Kurosu, Mei-Huey Lin, and Yoshito Kishi pp 12248–12249 DOI: 10.1021/ja045557j Supporting Info

Alkenes from Terminal Epoxides Using Lithium 2,2,6,6-Tetramethylpiperidide and Organolithiums or Grignard Reagents David M. Hodgson, Matthew J. Fleming, and Steven J. Stanway pp 12250–12251 DOI: 10.1021/ja045513a Supporting Info

A Highly Stable Short α-Helix Constrained by a Main-Chain Hydrogen-Bond Surrogate Ross N. Chapman, Gianluca Dimartino, and Paramjit S. Arora pp 12252–12253 DOI: 10.1021/ja0466659 Supporting Info

Measuring Brønsted Acid Densites in Zeolite HY with Diphosphine Molecules and Solid State NMR Spectroscopy Luming Peng, Peter J. Chupas, and Clare P. Grey pp 12254–12255 DOI: 10.1021/ja0467519 Supporting Info

Membrane-Bound Protein in Giant Vesicles:  Induced Contraction and Growth Victor A. Seredyuk and Fredric M. Menger pp 12256–12257 DOI: 10.1021/ja040151s

A Diruthenium-Substituted Polyoxometalate as an Electrocatalyst for Oxygen Generation Annette R. Howells, Anand Sankarraj, and Curtis Shannon pp 12258–12259 DOI: 10.1021/ja0495821 Supporting Info

Cascade Reactions of Substituted 1,2,4-Triazines:  Rapid Access to Nitrogen-Containing Polycycles Steven A. Raw and Richard J. K. Taylor pp 12260–12261 DOI: 10.1021/ja045780g Supporting Info

Oxidative Rearrangement Processes in the Biosynthesis of Gilvocarcin V Tao Liu, Carsten Fischer, Claus Beninga, and Jürgen Rohr pp 12262–12263 DOI: 10.1021/ja0467521 Supporting Info

Mechanism of Substitution Reaction on sp2-Carbon Center with Lithium Organocuprate Naohiko Yoshikai and Eiichi Nakamura pp 12264–12265 DOI: 10.1021/ja046616w Supporting Info

Binding Control and Stoichiometry of Ferrocenyl Dendrimers at a Molecular Printboard Christian A. Nijhuis, Jurriaan Huskens, and David N. Reinhoudt pp 12266–12267 DOI: 10.1021/ja048271n Supporting Info

Combining Light-Harvesting and Charge Separation in a Self-Assembled Artificial Photosynthetic System Based on Perylenediimide Chromophores Boris Rybtchinski, Louise E. Sinks, and Michael R. Wasielewski pp 12268–12269 DOI: 10.1021/ja0460514 Supporting Info

Ultrasensitive Electrocatalytic DNA Detection at Two- and Three-Dimensional Nanoelectrodes Rahela Gasparac, Bradford J. Taft, Melissa A. Lapierre-Devlin, Adam D. Lazareck, Jimmy M. Xu, and Shana O. Kelley pp 12270–12271 DOI: 10.1021/ja0458221 Supporting Info

Fluoride-Facilitated Deuterium Exchange from DMSO-d6 to Polyamide-Based Cryptands Sung Ok Kang, David VanderVelde, Douglas Powell, and Kristin Bowman-James pp 12272–12273 DOI: 10.1021/ja046078n Supporting Info

In Situ Cryocrystallization of Diphenyl Ether:  C−H···π Mediated Polymorphic Forms Angshuman R. Choudhury, Kabirul Islam, Michael T. Kirchner, Goverdhan Mehta, and Tayur N. Guru Row pp 12274–12275 DOI: 10.1021/ja046134k Supporting Info

Self-Assembly of Phospholipid Molecules at a Au(111) Electrode Surface Shimin Xu, Grzegorz Szymanski, and Jacek Lipkowski pp 12276–12277 DOI: 10.1021/ja045669a

α-Helical Peptides Are Not Protonated at the N-Terminus in the Gas Phase Robert Wieczorek and J. J. Dannenberg pp 12278–12279 DOI: 10.1021/ja048033s Supporting Info

Biscopper Complexes of meso-Aryl-Substituted Hexaphyrin:  Gable Structures and Varying Antiferromagnetic Coupling Soji Shimizu, Venkataramanarao G. Anand, Ryuichiro Taniguchi, Ko Furukawa, Tatsuhisa Kato, Toshihiko Yokoyama, and Atsuhiro Osuka pp 12280–12281 DOI: 10.1021/ja046102x Supporting Info

Control of Viscoelasticity Using Redox Reaction Koji Tsuchiya, Yoichi Orihara, Yukishige Kondo, Norio Yoshino, Takahiro Ohkubo, Hideki Sakai, and Masahiko Abe pp 12282–12283 DOI: 10.1021/ja0467162 Supporting Info

Tapping Mode AFM Evidence for an Amorphous Reticular Phase in a Condensation-Cured Hybrid Elastomer:  α,ω-Dihydroxypoly(dimethylsiloxane)/Poly(diethoxysiloxane)/Fumed Silica Nanoparticles Tomoki Ogoshi, Tomoko Fujiwara, Massimo Bertolucci, Giancarlo Galli, Emo Chiellini, Yoshiki Chujo, and Kenneth J. Wynne pp 12284–12285 DOI: 10.1021/ja0474345 Supporting Info

Reorganization and Growth of Metastable α-N2 Critical Nuclei into Stable β-N2 Crystals Jean-Marc Leyssale, Jerome Delhommelle, and Claude Millot pp 12286–12287 DOI: 10.1021/ja046700b Supporting Info

Efficient Enantioselective Synthesis of Functionalized Tetrahydropyrans by Ru-Catalyzed Asymmetric Ring-Opening Metathesis/Cross-Metathesis (AROM/CM) Dennis G. Gillingham, Osamu Kataoka, Steven B. Garber, and Amir H. Hoveyda pp 12288–12290 DOI: 10.1021/ja0458672 Supporting Info

Analysis of the Conserved P9-G10.1 Metal-Binding Motif in Hammerhead Ribozymes with an Extra Nucleotide Inserted between A9 and G10.1 Residues Masaki Warashina, Tomoko Kuwabara, Yuka Nakamatsu, Yasuomi Takagi, Yoshio Kato, and Kazunari Taira pp 12291–12297 DOI: 10.1021/ja049634m

Accelerated Color Change of Gold Nanoparticles Assembled by DNAzymes for Simple and Fast Colorimetric Pb2+ Detection Juewen Liu and Yi Lu pp 12298–12305 DOI: 10.1021/ja046628h Supporting Info

Chemoenzymatic Synthesis and High-Throughput Screening of an Aminoglycoside−Polyamine Library:  Identification of High-Affinity Displacers and DNA-Binding Ligands Kaushal Rege, Shanghui Hu, James A. Moore, Jonathan S. Dordick, and Steven M. Cramer pp 12306–12315 DOI: 10.1021/ja049437n Supporting Info

Magnetic Circular Dichroism and Cobalt(II) Binding Equilibrium Studies of Escherichia coli Methionyl Aminopeptidase James A. Larrabee, Chin Hin Leung, Rhonda L. Moore, Thun Thamrong-nawasawat, and Benjamin S. H. Wessler pp 12316–12324 DOI: 10.1021/ja0485006 Supporting Info

Substituent-Dependent Photoinduced Intramolecular Charge Transfer in N-Aryl-Substituted trans-4-Aminostilbenes Jye-Shane Yang, Kang-Ling Liau, Chin-Min Wang, and Chung-Yu Hwang pp 12325–12335 DOI: 10.1021/ja047604d Supporting Info

Ultrathin Polymer Film Formation by Collision-Induced Cross-Linking of Adsorbed Organic Molecules with Hyperthermal Protons Zhi Zheng, Xiangdong Xu, Xiaoli Fan, Woon Ming Lau, and Raymund Wai Man Kwok pp 12336–12342 DOI: 10.1021/ja046841d Supporting Info

Thiyl Radical-Mediated Cleavage of Allylic C−N Bonds: Scope, Limitations, and Theoretical Support to the Mechanism Stéphanie Escoubet, Stéphane Gastaldi, Vitaliy I. Timokhin, Michèle P. Bertrand, and Didier Siri pp 12343–12352 DOI: 10.1021/ja049859x Supporting Info

Fate of Diradicals in the Caldera:  Stereochemistry of Thermal Stereomutation and Ring Enlargement in cis- and trans-1-Cyano-2(E)-propenylcyclopropanes William von E. Doering and Edward Albert Barsa pp 12353–12362 DOI: 10.1021/ja0305961 Supporting Info

Cycloalkene Ozonolysis:  Collisionally Mediated Mechanistic Branching Bao Chuong, Jieyuan Zhang, and Neil M. Donahue pp 12363–12373 DOI: 10.1021/ja0485412 Supporting Info

Conformational Effects on Glycoside Reactivity:  Study of the High Reactive Conformer of Glucose Ciaran McDonnell, Oscar López, Paul Murphy, José G. Fernández Bolaños, Rita Hazell, and Mikael Bols pp 12374–12385 DOI: 10.1021/ja047476t Supporting Info

Hydrogen Bonded Oligohydrazide Foldamers and Their Recognition for Saccharides Jun-Li Hou, Xue-Bin Shao, Guang-Ju Chen, Yan-Xia Zhou, Xi-Kui Jiang, and Zhan-Ting Li pp 12386–12394 DOI: 10.1021/ja047436p Supporting Info

A Highly Efficient, Preorganized Macrobicyclic Receptor for Halides Based on CH··· and NH···Anion Interactions Christos A. Ilioudis, Derek A. Tocher, and Jonathan W. Steed pp 12395–12402 DOI: 10.1021/ja047070g Supporting Info

Tuning Organogels and Mesophases with Phenanthroline Ligands and Their Copper Complexes by Inter- to Intramolecular Hydrogen Bonds Raymond Ziessel, Guillaume Pickaert, Franck Camerel, Bertrand Donnio, Daniel Guillon, Michèle Cesario, and Thierry Prangé pp 12403–12413 DOI: 10.1021/ja047091a Supporting Info

Amine Attack on Coordinated Alkenes:  An Interconversion from Anti-Markovnikoff to Markovnikoff Products Ruslan Pryadun, Dinesh Sukumaran, Robert Bogadi, and Jim D. Atwood pp 12414–12420 DOI: 10.1021/ja0469939 Supporting Info

Solvent-Equilibrated Ion Pairs from Carbene Fragmentation Reactions Robert A. Moss, Fengmei Zheng, Jean-Marie Fedé, Lauren A. Johnson, and Ronald R. Sauers pp 12421–12431 DOI: 10.1021/ja040146o Supporting Info

Total Synthesis of (+)-Brasilenyne. Application of an Intramolecular Silicon-Assisted Cross-Coupling Reaction Scott E. Denmark and Shyh-Ming Yang pp 12432–12440 DOI: 10.1021/ja0466863 Supporting Info

Electrochemically Controlled Chemically Reversible Transformation of α-Tocopherol (Vitamin E) into Its Phenoxonium Cation Leodrina L. Williams and Richard D. Webster pp 12441–12450 DOI: 10.1021/ja046648j

Alkylating Agents Stronger than Alkyl Triflates Tsuyoshi Kato, Evgenii Stoyanov, Jens Geier, Hansjörg Grützmacher, and Christopher A. Reed pp 12451–12457 DOI: 10.1021/ja047357d Supporting Info

Synthesis of Alkylated Deoxynojirimycin and 1,5-Dideoxy-1,5-iminoxylitol Analogues:  Polar Side-Chain Modification, Sulfonium and Selenonium Heteroatom Variants, Conformational Analysis, and Evaluation as Glycosidase Inhibitors Monica G. Szczepina, Blair D. Johnston, Yue Yuan, Birte Svensson, and B. Mario Pinto pp 12458–12469 DOI: 10.1021/ja0482076 Supporting Info

Development of a Zinc Ion-Selective Luminescent Lanthanide Chemosensor for Biological Applications Kenjiro Hanaoka, Kazuya Kikuchi, Hirotatsu Kojima, Yasuteru Urano, and Tetsuo Nagano pp 12470–12476 DOI: 10.1021/ja0469333 Supporting Info

Spectroscopic and Computational Studies of the Azide-Adduct of Manganese Superoxide Dismutase:  Definitive Assignment of the Ligand Responsible for the Low-Temperature Thermochromism Timothy A. Jackson, Anush Karapetian, Anne-Frances Miller, and Thomas C. Brunold pp 12477–12491 DOI: 10.1021/ja0482583 Supporting Info

Unusual Ar−H/Rh−H JHH NMR Coupling in Complexes of Rhodium(III):  Experimental Evidence and Theoretical Support for an η1−Arene Structure Jennifer R. Krumper, Michael Gerisch, Alessandra Magistrato, Ursula Rothlisberger, Robert G. Bergman, and T. Don Tilley pp 12492–12502 DOI: 10.1021/ja047665b Supporting Info

Single-Molecule Magnets:  Preparation and Properties of Low Symmetry [Mn4O3(O2CPh-R)4(dbm)3] Complexes with S = 9/2 Núria Aliaga-Alcalde, Rachel S. Edwards, Stephen O. Hill, Wolfgang Wernsdorfer, Kirsten Folting, and George Christou pp 12503–12516 DOI: 10.1021/ja047527m Supporting Info

Ca2.5Sr0.5GaMn2O8:  Diamagnetic Ga in Control of the Structural and Electronic Properties of a Bilayered Manganate Peter D. Battle, Stephen J. Blundell, Michael L. Brooks, Maryvonne Hervieu, Czeslaw Kapusta, Tom Lancaster, Santhosh P. Nair, Colin J. Oates, Francis L. Pratt, Matthew J. Rosseinsky, Rocío Ruiz-Bustos, Marcin Sikora, and Christopher A. Steer pp 12517–12527 DOI: 10.1021/ja0465000 Supporting Info

Frustrated β-Chloride Elimination. Selective Arene Alkylation by α-Chloronorbornene Catalyzed by Electrophilic Metallocenium Ion Pairs Aswini K. Dash, Tryg R. Jensen, Charlotte L. Stern, and Tobin J. Marks pp 12528–12540 DOI: 10.1021/ja047828w Supporting Info

Molecular Understanding of the Formation of Surface Zirconium Hydrides upon Thermal Treatment under Hydrogen of [(SiO)Zr(CH2tBu)3] by Using Advanced Solid-State NMR Techniques Franck Rataboul, Anne Baudouin, Chloé Thieuleux, Laurent Veyre, Christophe Copéret, Jean Thivolle-Cazat, Jean-Marie Basset, Anne Lesage, and Lyndon Emsley pp 12541–12550 DOI: 10.1021/ja038486h Supporting Info

Deuterium-Labeling and NMR Study of the Dearomatization of N-Alkyl-N-benzyldiphenylphosphinamides through Anionic Cyclization:  Ortho and Benzylic Lithiation Directed by Complex-Induced Proximity Effects Ignacio Fernández, Javier González, and Fernando López-Ortiz pp 12551–12564 DOI: 10.1021/ja039863t Supporting Info

Biomimetic Enantioselective Total Synthesis of (−)-Siccanin via the Pd-Catalyzed Asymmetric Allylic Alkylation (AAA) and Sequential Radical Cyclizations Barry M. Trost, Hong C. Shen, and Jean-Philippe Surivet pp 12565–12579 DOI: 10.1021/ja048084p Supporting Info

Catalytic Asymmetric Allylation of Ketones and a Tandem Asymmetric Allylation/Diastereoselective Epoxidation of Cyclic Enones Jeung Gon Kim, Karen M. Waltz, Iliana F. Garcia, David Kwiatkowski, and Patrick J. Walsh pp 12580–12585 DOI: 10.1021/ja047758t Supporting Info

Spectroscopic Demonstration of a Large Antisymmetric Exchange Contribution to the Spin-Frustrated Ground State of a D3 Symmetric Hydroxy-Bridged Trinuclear Cu(II) Complex:  Ground-to-Excited State Superexchange Pathways Jungjoo Yoon, Liviu M. Mirica, T. Daniel P. Stack, and Edward I. Solomon pp 12586–12595 DOI: 10.1021/ja046380w Supporting Info

Structure−Reactivity Relationships in Oxidative Carbon−Carbon Bond Forming Reactions:  A Mild and Efficient Approach to Stereoselective Syntheses of 2,6-Disubstituted Tetrahydropyrones Lijun Wang, John R. Seiders, II, and Paul E. Floreancig pp 12596–12603 DOI: 10.1021/ja046125b Supporting Info

Strong Exchange Interactions between Two Radicals Attached to Nonaromatic Spacers Deduced from Magnetic, EPR, NMR, and Electron Density Measurements Raymond Ziessel Christophe Stroh, Henrike Heise, Frank H. Köhler, Philippe Turek, Nicolas Claiser, Mohamed Souhassou, and Claude Lecomte pp 12604–12613 DOI: 10.1021/ja0305959 Supporting Info

Acidities in Cyclohexanediols Enhanced by Intramolecular Hydrogen Bonds Xin Chen, David A. Walthall, and John I. Brauman pp 12614–12620 DOI: 10.1021/ja049780s

Gas-Phase Synthesis, Submillimeter Spectra, and Precise Structure of Monomeric, Solvent-Free CuCH3 Douglas B. Grotjahn, DeWayne T. Halfen, Lucy M. Ziurys, and Andrew L. Cooksy pp 12621–12627 DOI: 10.1021/ja0490166 Supporting Info

First-Principles Calculation of the 17O NMR Parameters in Ca Oxide and Ca Aluminosilicates:  the Partially Covalent Nature of the Ca−O Bond, a Challenge for Density Functional Theory Mickaël Profeta, Magali Benoit, Francesco Mauri, and Chris J. Pickard pp 12628–12635 DOI: 10.1021/ja0490830

Density Functional Theory Studies of the [2]Rotaxane Component of the Stoddart−Heath Molecular Switch Yun Hee Jang, Sungu Hwang, Yong-Hoon Kim, Seung Soon Jang, and William A. Goddard, III pp 12636–12645 DOI: 10.1021/ja0385437 Supporting Info

On the Interpretation of Residual Dipolar Couplings as Reporters of Molecular Dynamics Kai Fredriksson, Martti Louhivuori, Perttu Permi, and Arto Annila pp 12646–12650 DOI: 10.1021/ja048287d Supporting Info

H−Bonding Patterns in the Platinated Guanine−Cytosine Base Pair and Guanine−Cytosine−Guanine−Cytosine Base Tetrad:  an Electron Density Deformation Analysis and AIM Study Jiande Gu, Jing Wang, and Jerzy Leszczynski pp 12651–12660 DOI: 10.1021/ja0492337 Supporting Info

Water-Assisted Reaction Mechanism of Monozinc β-Lactamases Matteo Dal Peraro, Leticia I. Llarrull, Ursula Rothlisberger, Alejandro J. Vila, and Paolo Carloni pp 12661–12668 DOI: 10.1021/ja048071b Supporting Info

A Comparative Analysis of Localized and Propagating Surface Plasmon Resonance Sensors:  The Binding of Concanavalin A to a Monosaccharide Functionalized Self-Assembled Monolayer Chanda Ranjit Yonzon, Eunhee Jeoung, Shengli Zou, George C. Schatz, Milan Mrksich, and Richard P. Van Duyne pp 12669–12676 DOI: 10.1021/ja047118q

On the Role of the Conserved Aspartate in the Hydrolysis of the Phosphocysteine Intermediate of the Low Molecular Weight Tyrosine Phosphatase D. Asthagiri, Tiqing Liu, Louis Noodleman, Robert L. Van Etten, and Donald Bashford pp 12677–12684 DOI: 10.1021/ja048638o

Accurate and Efficient Method for Predicting Thermochemistry of Polycyclic Aromatic Hydrocarbons − Bond-Centered Group Additivity Joanna Yu, Raman Sumathi, and William H. Green, Jr. pp 12685–12700 DOI: 10.1021/ja048333+ Supporting Info

Excited-State Proton Transfer Reactions of 10-Hydroxycamptothecin1 Kyril M. Solntsev, Erica N. Sullivan, Laren M. Tolbert, Shay Ashkenazi, Pavel Leiderman, and Dan Huppert pp 12701–12708 DOI: 10.1021/ja047821e

NMR of Ordered Liquids Edited by E. Elliott Burnell (University of British Columbia) and Cornelis A. de Lange (University of Amsterdam). Kluwer Academic Publishers:  Dordrecht, Boston, London. 2003. xxvi + 456 pp. $163.00. ISBN 1-4020-1343-4. Michael F. Brown pp 12709–12710 DOI: 10.1021/ja033639m

Issue 40

Site-Selective Conjugation of Thiols with Aziridine-2-Carboxylic Acid-Containing Peptides Danica P. Galonić, Wilfred A. van der Donk, and David Y. Gin pp 12712–12713 DOI: 10.1021/ja046793x Supporting Info

Bulk Synthesis of Polypyrrole Nanofibers by a Seeding Approach Xinyu Zhang and Sanjeev K. Manohar pp 12714–12715 DOI: 10.1021/ja046359v Supporting Info

Heme/Cu/O2 Reactivity:  Change in FeIII−(O22-)−CuII Unit Peroxo Binding Geometry Effected by Tridentate Copper Chelation Eunsuk Kim, Jason Shearer, Shen Lu, Pierre Moënne-Loccoz, Matthew E. Helton, Susan Kaderli, Andreas D. Zuberbühler, and Kenneth D. Karlin pp 12716–12717 DOI: 10.1021/ja045941g Supporting Info

One-Electron Oxidation of a Hydrogen-Bonded Phenol Occurs by Concerted Proton-Coupled Electron Transfer Ian J. Rhile and James M. Mayer pp 12718–12719 DOI: 10.1021/ja031583q Supporting Info

Triggering DNAzymes with Light:  A Photoactive C8 Thioether-Linked Adenosine Richard Ting, Leonard Lermer, and David M. Perrin pp 12720–12721 DOI: 10.1021/ja046964y Supporting Info

Direct Electron Transfer to the Oxygenase Domain of Neuronal Nitric Oxide Synthase (NOS):  Exploring Unique Redox Properties of NOS Enzymes Mekki Bayachou and Jean A. Boutros pp 12722–12723 DOI: 10.1021/ja0482987 Supporting Info

Stimuli-Responsive Supramolecular Nanocapsules from Amphiphilic Calixarene Assembly Myongsoo Lee, Sun-Ja Lee, and Li-Hong Jiang pp 12724–12725 DOI: 10.1021/ja045918v Supporting Info

Electrostatic Interactions Dominate the Catalytic Contribution of Arg39 in 4-Oxalocrotonate Tautomerase Norman Metanis, Ashraf Brik, Philip E. Dawson, and Ehud Keinan pp 12726–12727 DOI: 10.1021/ja0463841 Supporting Info

Mechanically Regulated Rotation of a Guest in a Nanoscale Host Alessandro Scarso, Hideki Onagi, and Julius Rebek, Jr. pp 12728–12729 DOI: 10.1021/ja046703o Supporting Info

Plasmon Mode Imaging of Single Gold Nanorods Kohei Imura, Tetsuhiko Nagahara, and Hiromi Okamoto pp 12730–12731 DOI: 10.1021/ja047836c Supporting Info

Shape-Selective Sensing of Lipids in Aqueous Solution by a Designed Fluorescent Molecular Tube Berkeley J. Shorthill, Christopher T. Avetta, and Timothy E. Glass pp 12732–12733 DOI: 10.1021/ja047639d Supporting Info

Photochromic and Luminescence Switching Properties of a Versatile Diarylethene-Containing 1,10-Phenanthroline Ligand and Its Rhenium(I) Complex Vivian Wing-Wah Yam, Chi-Chiu Ko, and Nianyong Zhu pp 12734–12735 DOI: 10.1021/ja047446q Supporting Info

Electrophoretic Analysis and Purification of Fluorescent Single-Walled Carbon Nanotube Fragments Xiaoyou Xu, Robert Ray, Yunlong Gu, Harry J. Ploehn, Latha Gearheart, Kyle Raker, and Walter A. Scrivens pp 12736–12737 DOI: 10.1021/ja040082h Supporting Info

Coaxially Gated In-Wire Thin-Film Transistors Made by Template Assembly Nina I. Kovtyukhova, Brian K. Kelley, and Thomas E. Mallouk pp 12738–12739 DOI: 10.1021/ja046033m Supporting Info

A Photopatternable Pentacene Precursor for Use in Organic Thin-Film Transistors Kevin P. Weidkamp, Ali Afzali, Rudolf M. Tromp, and Robert J. Hamers pp 12740–12741 DOI: 10.1021/ja045228r Supporting Info

An Unusual Zwitterionic, Diradical Intermediate in Photochemical Electron-Transfer Substitution Reactions John B. Miller, Jeremy Breeding, and Thomas J. Smith pp 12742–12743 DOI: 10.1021/ja039563b Supporting Info

Dendritic Macromers as in Situ Polymerizing Biomaterials for Securing Cataract Incisions Michel Wathier, Pil J. Jung, Michael A. Carnahan, Terry Kim, and Mark W. Grinstaff pp 12744–12745 DOI: 10.1021/ja045870l Supporting Info

Sugar-Based Microemulsion Glass Templates Feng Gao, Chia-Chi Ho, and Carlos C. Co pp 12746–12747 DOI: 10.1021/ja0467115 Supporting Info

Modified DNA Analogues That Sense Light Exposure with Color Changes Jianmin Gao, Soichiro Watanabe, and Eric T. Kool pp 12748–12749 DOI: 10.1021/ja046910o Supporting Info

Site-Specific Assembly of DNA and Appended Cargo on Arrayed Carbon Nanotubes Bradford J. Taft, Adam D. Lazareck, Gary D. Withey, Aijun Yin, J. M. Xu, and Shana O. Kelley pp 12750–12751 DOI: 10.1021/ja045543d Supporting Info

Amino Acid Backbone Specificity of the Escherichia coli Translation Machinery Zhongping Tan, Anthony C. Forster, Stephen C. Blacklow, and Virginia W. Cornish pp 12752–12753 DOI: 10.1021/ja0472174 Supporting Info

Long-Range 1H−19F Distance Measurement in Peptides by Solid-State NMR Sungsool Wi, Neeraj Sinha, and Mei Hong pp 12754–12755 DOI: 10.1021/ja0462732 Supporting Info

Semiconductor-Encapsulated Peptide−Amphiphile Nanofibers Eli D. Sone and Samuel I. Stupp pp 12756–12757 DOI: 10.1021/ja0499344 Supporting Info

The Pseudouridine Synthases:  Revisiting a Mechanism That Seemed Settled Christopher J. Spedaliere, Joy M. Ginter, Murray V. Johnston, and Eugene G. Mueller pp 12758–12759 DOI: 10.1021/ja046375s Supporting Info

Rendering Poly(amidoamine) or Poly(propylenimine) Dendrimers Temperature Sensitive Yasuhiro Haba, Atsushi Harada, Toru Takagishi, and Kenji Kono pp 12760–12761 DOI: 10.1021/ja047755g Supporting Info

Nonionic Side Chains Modulate the Affinity and Specificity of Binding between Functionalized Polyamines and Structured RNA Graham R. Lawton and Daniel H. Appella pp 12762–12763 DOI: 10.1021/ja046436m Supporting Info

Organolanthanide-Catalyzed Synthesis of Phosphine-Terminated Polyethylenes Amber M. Kawaoka and Tobin J. Marks pp 12764–12765 DOI: 10.1021/ja045965n Supporting Info

Stepwise Hydration and Multibody Deprotonation with Steep Negative Temperature Dependence in the Benzene•+−Water System Yehia Ibrahim, Edreese Alsharaeh, Keith Dias, Michael Meot-Ner (Mautner), and M. Samy El-Shall pp 12766–12767 DOI: 10.1021/ja046512l Supporting Info

Competitive 15N Kinetic Isotope Effects of Nitrogenase-Catalyzed Dinitrogen Reduction Amandeep K. Sra, Yilin Hu, Glen E. Martin, Daniel D. Snow, Markus W. Ribbe, and Amnon Kohen pp 12768–12769 DOI: 10.1021/ja0458470 Supporting Info

Triplet (π,π*) Reactivity of the Guanine−Cytosine DNA Base Pair:  Benign Deactivation versus Double Tautomerization via Intermolecular Hydrogen Transfer Lluís Blancafort, Joan Bertran, and Mariona Sodupe pp 12770–12771 DOI: 10.1021/ja048230r Supporting Info

Perfluorocyclobutyl-Linked Hexa-peri-hexabenzocoronene Networks Bryan K. Spraul, S. Suresh, Sibylle Glaser, Dvora Perahia, John Ballato, and Dennis W. Smith, Jr. pp 12772–12773 DOI: 10.1021/ja046855j Supporting Info

An Experimental Strategy to Evaluate the Thermodynamic Stability of Highly Dynamic Binding Sites in Proteins Using Hydrogen Exchange Josephine C. Ferreon, James B. Hamburger, and Vincent J. Hilser pp 12774–12775 DOI: 10.1021/ja046255k Supporting Info

Stereoselective Synthesis of Highly Substituted Δ1-Pyrrolines:  exo-Selective 1,3-Dipolar Cycloaddition Reactions with Azlactones Satyamaheshwar Peddibhotla and Jetze J. Tepe pp 12776–12777 DOI: 10.1021/ja046149i Supporting Info

14-Electron Disilene Palladium Complex Having Strong π-Complex Character Mitsuo Kira, Yumiko Sekiguchi, Takeaki Iwamoto, and Chizuko Kabuto pp 12778–12779 DOI: 10.1021/ja046354y Supporting Info

Efficient Photocurrent Generation by Self-Assembled Monolayers Composed of 310-Helical Peptides Carrying Linearly Spaced Naphthyl Groups at the Side Chains Kazuyuki Yanagisawa, Tomoyuki Morita, and Shunsaku Kimura pp 12780–12781 DOI: 10.1021/ja0476011 Supporting Info

Fluorinated Carbon with Ordered Mesoporous Structure Zuojiang Li, Guillermo D. Del Cul, Wenfu Yan, Chengdu Liang, and Sheng Dai pp 12782–12783 DOI: 10.1021/ja046589+ Supporting Info

Copper-Catalyzed Enantioselective Conjugate Addition of Grignard Reagents to Acyclic Enones Fernando López, Syuzanna R. Harutyunyan, Adriaan J. Minnaard, and Ben L. Feringa pp 12784–12785 DOI: 10.1021/ja046632t Supporting Info

Influence of Electron Correlation Effects on the Solvation of Cu2+ Christian F. Schwenk and Bernd M. Rode pp 12786–12787 DOI: 10.1021/ja046784o Supporting Info

Resonance Raman Spectroscopy of the Neutral Radical Trp306 in DNA Photolyase Ullas Gurudas and Johannes P. M. Schelvis pp 12788–12789 DOI: 10.1021/ja047161d Supporting Info

Enantioselective Total Synthesis of (+)-Gigantecin:  Exploiting the Asymmetric Glycolate Aldol Reaction Michael T. Crimmins and Jin She pp 12790–12791 DOI: 10.1021/ja0455852 Supporting Info

Ru3(CO)12-Catalyzed Silylation of Benzylic C−H Bonds in Arylpyridines and Arylpyrazoles with Hydrosilanes via C−H Bond Cleavage Fumitoshi Kakiuchi, Kazuyuki Tsuchiya, Mitsutaka Matsumoto, Eiichiro Mizushima, and Naoto Chatani pp 12792–12793 DOI: 10.1021/ja047040d Supporting Info

DNA Cleavage Induced by Thermal Electron Transfer from a Dimeric NADH Analogue to Acridinium Ions in the Presence of Oxygen Shunichi Fukuzumi, Kazusa Yukimoto, and Kei Ohkubo pp 12794–12795 DOI: 10.1021/ja046955p Supporting Info

Arylene Ethynylene Macrocycles Prepared by Precipitation-Driven Alkyne Metathesis Wei Zhang and Jeffrey S. Moore p 12796 DOI: 10.1021/ja046531v Supporting Info

Structures and Dynamics of Self-Assembled Surface Monolayers Observed by Ultrafast Electron Crystallography Chong-Yu Ruan, Ding-Shyue Yang, and Ahmed H. Zewail pp 12797–12799 DOI: 10.1021/ja045441n

Characterization of Nonspecific Protein−DNA Interactions by 1H Paramagnetic Relaxation Enhancement Junji Iwahara, Charles D. Schwieters, and G. Marius Clore pp 12800–12808 DOI: 10.1021/ja046246b

In Situ Click Chemistry:  Enzyme Inhibitors Made to Their Own Specifications Roman Manetsch, Antoni Krasiński, Zoran Radić, Jessica Raushel, Palmer Taylor, K. Barry Sharpless, and Hartmuth C. Kolb pp 12809–12818 DOI: 10.1021/ja046382g Supporting Info

Photochemically Induced Dynamic Nuclear Polarization in Photosystem I of Plants Observed by 13C Magic-Angle Spinning NMR Alia, Esha Roy, Peter Gast, Hans J. van Gorkom, Huub J. M. de Groot, Gunnar Jeschke, and Jörg Matysik pp 12819–12826 DOI: 10.1021/ja048051+

Systematic Investigation of Saccharomyces cerevisiae Enzymes Catalyzing Carbonyl Reductions Iwona A. Kaluzna, Tomoko Matsuda, Aileen K. Sewell, and Jon D. Stewart pp 12827–12832 DOI: 10.1021/ja0469479 Supporting Info

Catalytic Unfolding and Proteolysis of Cytochrome c Induced by Synthetic Binding Agents Kevin Groves, Andrew J. Wilson, and Andrew D. Hamilton pp 12833–12842 DOI: 10.1021/ja0317731

Lifetime Regulation of the Charge-Separated State in DNA by Modulating the Oxidation Potential of Guanine in DNA through Hydrogen Bonding Kiyohiko Kawai, Yasuko Osakada, Tadao Takada, Mamoru Fujitsuka, and Tetsuro Majima pp 12843–12846 DOI: 10.1021/ja0475813

IspH Protein of Escherichia coli:  Studies on Iron−Sulfur Cluster Implementation and Catalysis Tobias Gräwert, Johannes Kaiser, Ferdinand Zepeck, Ralf Laupitz, Stefan Hecht, Sabine Amslinger, Nicholas Schramek, Erik Schleicher, Stefan Weber, Martin Haslbeck, Johannes Buchner, Christoph Rieder, Duilio Arigoni, Adelbert Bacher, Wolfgang Eisenreich, and Felix Rohdich pp 12847–12855 DOI: 10.1021/ja0471727 Supporting Info

Analysis on a Cooperative Pathway Involving Multiple Cations in Hammerhead Reactions Yasuomi Takagi, Atsushi Inoue, and Kazunari Taira pp 12856–12864 DOI: 10.1021/ja031991u

Oxidation of Carboxylic Acids by Horseradish Peroxidase Results in Prosthetic Heme Modification and Inactivation Liusheng Huang, Christophe Colas, and Paul R. Ortiz de Montellano pp 12865–12873 DOI: 10.1021/ja046455w

Induced Axial Chirality in the Biphenyl Core of the Cα-Tetrasubstituted α-Amino Acid Residue Bip and Subsequent Propagation of Chirality in (Bip)n/Val Oligopeptides Jean-Paul Mazaleyrat, Karen Wright, Anne Gaucher, Nathalie Toulemonde, Michel Wakselman, Simona Oancea, Cristina Peggion, Fernando Formaggio, Vladimir Setnika, Timothy A. Keiderling, and Claudio Toniolo pp 12874–12879 DOI: 10.1021/ja040100v Supporting Info

Chemistry of the Diazeniumdiolates. O- versus N-Alkylation of the RNH[N(O)NO]- Ion Joseph E. Saavedra, D. Scott Bohle, Kamilah N. Smith, Clifford George, Jeffrey R. Deschamps, Damon Parrish, Joseph Ivanic, Yan-Ni Wang, Michael L. Citro, and Larry K. Keefer pp 12880–12887 DOI: 10.1021/ja031538i Supporting Info

Chemistry and Biology of Diazonamide A:  First Total Synthesis and Confirmation of the True Structure K. C. Nicolaou, David Y.-K. Chen, Xianhai Huang, Taotao Ling, Marco Bella, and Scott A. Snyder pp 12888–12896 DOI: 10.1021/ja040092i Supporting Info

Chemistry and Biology of Diazonamide A:  Second Total Synthesis and Biological Investigations K. C. Nicolaou, Junliang Hao, Mali V. Reddy, Paraselli Bheema Rao, Gerasimos Rassias, Scott A. Snyder, Xianhai Huang, David Y.-K. Chen, William E. Brenzovich, Nicolas Giuseppone, Paraskevi Giannakakou, and Aurora O'Brate pp 12897–12906 DOI: 10.1021/ja040093a Supporting Info

Dendrimer Interior Functional Group Conversion and Dendrimer Metamorphosis−New Approaches to the Synthesis of Oligo(dibenzyl sulfone) and Oligo(phenylenevinylene) Dendrimers Hak-Fun Chow, Man-Kit Ng, Chi-Wing Leung, and Guo-Xin Wang pp 12907–12915 DOI: 10.1021/ja046557m Supporting Info

Aromatic Gold and Silver ‘Rings':  Hydrosilver(I) and Hydrogold(I) Analogues of Aromatic Hydrocarbons Constantinos A. Tsipis, Eustathios E. Karagiannis, Panagiota F. Kladou, and Athanassios C. Tsipis pp 12916–12929 DOI: 10.1021/ja0469277 Supporting Info

Liquid Crystalline Bolaamphiphiles with Semiperfluorinated Lateral Chains:  Competition between Layerlike and Honeycomb-Like Organization Xiaohong Cheng, Malay Kumar Das, Ute Baumeister, Siegmar Diele, and Carsten Tschierske pp 12930–12940 DOI: 10.1021/ja048224v Supporting Info

L-Shaped Three-Center Two-Electron (C−C−C)+ Bonding Array Naohiko Yoshikai, Salai Cheettu Ammal, and Eiichi Nakamura pp 12941–12948 DOI: 10.1021/ja0470416 Supporting Info

Synthesis and Characterization of Dendrimer Templated Supported Bimetallic Pt−Au Nanoparticles Huifang Lang, Stephen Maldonado, Keith J. Stevenson, and Bert D. Chandler pp 12949–12956 DOI: 10.1021/ja046542o Supporting Info

Gas-Phase Reactivity of Charged π-Type Biradicals Shane E. Tichy, Eric D. Nelson, F. Sedinam Amegayibor, and Hilkka I. Kenttämaa pp 12957–12967 DOI: 10.1021/ja049534g

Ab Initio Calculation of Optical Rotatory Dispersion (ORD) Curves:  A Simple and Reliable Approach to the Assignment of the Molecular Absolute Configuration Egidio Giorgio, Rosario G. Viglione, Riccardo Zanasi, and Carlo Rosini pp 12968–12976 DOI: 10.1021/ja046875l

Leaving Group Effects in Gas-Phase Substitutions and Eliminations Scott Gronert, Adelaide E. Fagin, Keiko Okamoto, Sudha Mogali, and Lawrence M. Pratt pp 12977–12983 DOI: 10.1021/ja047002u

CdSe and CdSe/CdS Nanorod Solids Dmitri V. Talapin, Elena V. Shevchenko, Christopher B. Murray, Andreas Kornowski, Stephan Förster, and Horst Weller pp 12984–12988 DOI: 10.1021/ja046727v Supporting Info

Rhenium-Based Molecular Rectangles as Frameworks for Ligand-Centered Mixed Valency and Optical Electron Transfer Peter H. Dinolfo, Mary Elizabeth Williams, Charlotte L. Stern, and Joseph T. Hupp pp 12989–13001 DOI: 10.1021/ja0473182 Supporting Info

Mechanistic Evidence for an α-Oxoketene Pathway in the Formation of β-Ketoamides/Esters via Meldrum's Acid Adducts Feng Xu, Joseph D. Armstrong III, George X. Zhou, Bryon Simmons, David Hughes, Zhihong Ge, and Edward J. J. Grabowski pp 13002–13009 DOI: 10.1021/ja046488b Supporting Info

Heats of Adsorption of Linear CO Species Adsorbed on the Au° and Ti+δ Sites of a 1% Au/TiO2 Catalyst Using in Situ FTIR Spectroscopy under Adsorption Equilibrium Salim Derrouiche, Paul Gravejat, and Daniel Bianchi pp 13010–13015 DOI: 10.1021/ja0470719

Distinct Electronic Effects on Reductive Eliminations of Symmetrical and Unsymmetrical Bis-Aryl Platinum Complexes Shashank Shekhar and John F. Hartwig pp 13016–13027 DOI: 10.1021/ja0480365 Supporting Info

An Extremely Active Catalyst for the Negishi Cross-Coupling Reaction Jacqueline E. Milne and Stephen L. Buchwald pp 13028–13032 DOI: 10.1021/ja0474493 Supporting Info

Stoichiometric and Catalytic H/D Incorporation by Cationic Iridium Complexes:  A Common Monohydrido-Iridium Intermediate Cathleen M. Yung, Marc B. Skaddan, and Robert G. Bergman pp 13033–13043 DOI: 10.1021/ja046825g

Highly Effective Pincer-Ligated Iridium Catalysts for Alkane Dehydrogenation. DFT Calculations of Relevant Thermodynamic, Kinetic, and Spectroscopic Properties Keming Zhu, Patrick D. Achord, Xiawei Zhang, Karsten Krogh-Jespersen, and Alan S. Goldman pp 13044–13053 DOI: 10.1021/ja047356l

Molybdenocene Trihydride Complexes:  Influence of a [Me2Si] Ansa Bridge on Classical versus Nonclassical Nature, Stability with Respect to Elimination of Dihydrogen, and Acidity Kevin E. Janak, Jun Ho Shin, and Gerard Parkin pp 13054–13070 DOI: 10.1021/ja047554c Supporting Info

Surface-Aligned Ion−Molecule Reaction on the Surface of a Molecular Crystal CD3+ + CD3I → C2D5+ + DI Jae-Gook Lee and John T. Yates, Jr. pp 13071–13078 DOI: 10.1021/ja030508c

Density Functional Calculations of the 13C NMR Chemical Shifts in (9,0) Single-Walled Carbon Nanotubes Eva Zurek and Jochen Autschbach pp 13079–13088 DOI: 10.1021/ja047941m

Variational Transition State Theory as a Tool To Determine Kinetic Selectivity in Reactions Involving a Valley-Ridge Inflection Point Àngels González-Lafont, Miquel Moreno, and José M. Lluch pp 13089–13094 DOI: 10.1021/ja039561r Supporting Info

The Location of Adsorbed Hydrogen in Graphite Nanostructures Xianwei Sha and Bret Jackson pp 13095–13099 DOI: 10.1021/ja0472836

Determination of Sugar Structures in Solution from Residual Dipolar Coupling Constants:  Methodology and Application to Methyl β-d-Xylopyranoside Tran N. Pham, Sarah L. Hinchley, David W. H. Rankin, Tibor Liptaj, and Dušan Uhrín pp 13100–13110 DOI: 10.1021/ja047242+ Supporting Info

Slow Motion, Trapping, and Sorting of Water- and Chloroform-Soluble Porphyrins in Nanowells Sheshanath Bhosale, Sidhanath Bhosale, Tianyu Wang, Guangtao Li, Ulrich Siggel, and Jürgen-Hinrich Fuhrhop pp 13111–13118 DOI: 10.1021/ja048310v Supporting Info

Electron-Deficient Bonding in Rhomboid Rings Musiri M. Balakrishnarajan and Roald Hoffmann pp 13119–13131 DOI: 10.1021/ja0467420 Supporting Info

Cooperative Motions of Protein and Hydration Water Molecules:  Molecular Dynamics Study of Scytalone Dehydratase Noriaki Okimoto, Takashi Nakamura, Atsushi Suenaga, Noriyuki Futatsugi, Yoshinori Hirano, Isamu Yamaguchi, and Toshikazu Ebisuzaki pp 13132–13139 DOI: 10.1021/ja048053u

Elastic Effects behind Cooperative Bonding in β-Sheets Jan Rossmeisl, Jens K. Nørskov, and Karsten W. Jacobsen pp 13140–13143 DOI: 10.1021/ja0490626

Hydration of the Amylopectin Branch Point. Evidence of Restricted Conformational Diversity of the α-(1→6) Linkage Francisco Corzana, Mohammed S. Motawia, Catherine Hervé du Penhoat, Frans van den Berg, Andreas Blennow, Serge Perez, and Søren B. Engelsen pp 13144–13155 DOI: 10.1021/ja048622y

Free Energy, Entropy, and Induced Fit in Host−Guest Recognition:  Calculations with the Second-Generation Mining Minima Algorithm Chia-En Chang and Michael K. Gilson pp 13156–13164 DOI: 10.1021/ja047115d Supporting Info

Progress in the Chemistry of Organic Natural Products, Volume 87 Edited by W. Herz (The Florida State University, Tallahassee, FL), H. Falk (Johannes-Kepler-Universität, Linz, Austria), and G. W. Kirby (The University of Glasgow, Scotland). Springer-Verlag:  Wien, New York. 2004. viii + 262 pp. $219. ISBN 3-211-02780-7. Bruce B. Jarvis p 13165 DOI: 10.1021/ja040933l

Advances in Antiviral Drug Design, Volume 4 Edited by E. De Clercq (Katholieke Universiteit Leuven). Elsevier B. V.:  Amsterdam. 2004. xii + 218 pp. $119.95. ISBN 0-444-50602-0. Thomas W. Bell pp 13165–13166 DOI: 10.1021/ja040903i

100 Years of Physical Chemistry:  A Collection of Landmark Papers Royal Society of Chemistry:  Cambridge. 2003. viii + 376 pp. $159.00. ISBN 0-85404-987-8. p 13166 DOI: 10.1021/ja0409661

Issue 41

Investigation of the Pathway for Inter-Copper Electron Transfer in Peptidylglycine α-Amidating Monooxygenase Wilson A. Francisco, Georg Wille, Alan J. Smith, David J. Merkler, and Judith P. Klinman pp 13168–13169 DOI: 10.1021/ja046888z

Toward Mimicking Viral Geometry with Metal-Organic Systems Jerry L. Atwood, Leonard J. Barbour, Scott J. Dalgarno, Michaele J. Hardie, Colin L. Raston, and Helen R. Webb pp 13170–13171 DOI: 10.1021/ja048058r Supporting Info

Spontaneous Assembly of Organic Thiocyanates on Gold Sufaces. Alternative Precursors for Gold Thiolate Assemblies Jacob W. Ciszek, Michael P. Stewart, and James M. Tour pp 13172–13173 DOI: 10.1021/ja0472477 Supporting Info

Direct Generation of Ti-Enolate of α-CF3 Ketone:  Theoretical Study and High-Yielding and Diastereoselective Aldol Reaction Yoshimitsu Itoh, Masahiro Yamanaka, and Koichi Mikami pp 13174–13175 DOI: 10.1021/ja046518a Supporting Info

Electric-Field-Induced Conductance Switching in FeCo Prussian Blue Analogues Osamu Sato, Tomoko Kawakami, Masanobu Kimura, Shoko Hishiya, Shoichi Kubo, and Yasuaki Einaga pp 13176–13177 DOI: 10.1021/ja046329s Supporting Info

Elucidating Reactivity Differences in Palladium-Catalyzed Coupling Processes:  The Chemistry of Palladium Hydrides Ivory D. Hills and Gregory C. Fu pp 13178–13179 DOI: 10.1021/ja0471424 Supporting Info

Indirect Covariance NMR Spectroscopy Fengli Zhang and Rafael Brüschweiler pp 13180–13181 DOI: 10.1021/ja047241h

Asymmetric Syntheses of Phosphatidylinositol-3-Phosphates with Saturated and Unsaturated Side Chains through Catalytic Asymmetric Phosphorylation Bianca R. Sculimbrene, Yingju Xu, and Scott J. Miller pp 13182–13183 DOI: 10.1021/ja0466098 Supporting Info

How Fluorous Is Poly(2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxide-co-tetrafluoroethylene) (Teflon AF)? Hong Zhao, Kamal Ismail, and Stephen G. Weber pp 13184–13185 DOI: 10.1021/ja047453e Supporting Info

Isothermal Titration Calorimetry Studies on the Binding of DNA Bases and PNA Base Monomers to Gold Nanoparticles A. Gourishankar, Sourabh Shukla, Krishna N. Ganesh, and Murali Sastry pp 13186–13187 DOI: 10.1021/ja046785g Supporting Info

Surprising Bacterial Nucleotidyltransferase Selectivity in the Conversion of Carbaglucose-1-phosphate Kwang-Seuk Ko, Corbin J. Zea, and Nicola L. Pohl pp 13188–13189 DOI: 10.1021/ja045522j Supporting Info

Radical Deoxygenation of Hydroxyl Groups via Phosphites Liming Zhang and Masato Koreeda pp 13190–13191 DOI: 10.1021/ja0462777 Supporting Info

Selective Addition to Iridium of Aryl C−H Bonds Ortho to Coordinating Groups. Not Chelation-Assisted Xiawei Zhang, Mira Kanzelberger, Thomas J. Emge, and Alan S. Goldman pp 13192–13193 DOI: 10.1021/ja046476q Supporting Info

Exploiting the Right Side of the Ramachandran Plot:  Substitution of Glycines by d-Alanine Can Significantly Increase Protein Stability Burcu Anil, Benben Song, Yuefeng Tang, and Daniel P. Raleigh pp 13194–13195 DOI: 10.1021/ja047119i Supporting Info

Aminoboranes as “Compatible” Iminium Ion Generators in Aminative C−C Bond Formations Michinori Suginome, Lars Uehlin, and Masahiro Murakami pp 13196–13197 DOI: 10.1021/ja045827y Supporting Info

Catalytic, Highly Enantio- and Diastereoselective Pinacol Coupling Reaction with a New Tethered Bis(8-quinolinolato) Ligand Norito Takenaka, Guoyao Xia, and Hisashi Yamamoto pp 13198–13199 DOI: 10.1021/ja045430u Supporting Info

Controlled Synthesis of Monodisperse Silver Nanocubes in Water Dabin Yu and Vivian Wing-Wah Yam pp 13200–13201 DOI: 10.1021/ja046037r Supporting Info

Ferromagnetism in One-Dimensional Vanadium−Benzene Sandwich Clusters Ken Miyajima, Atsushi Nakajima, Satoshi Yabushita, Mark B. Knickelbein, and Koji Kaya pp 13202–13203 DOI: 10.1021/ja046151+

Fluorescence Emission from Dendrimers and Its pH Dependence Dongjun Wang and Toyoko Imae pp 13204–13205 DOI: 10.1021/ja0454992 Supporting Info

Two-Prong Inhibitors for Human Carbonic Anhydrase II Bidhan C. Roy, Abir L. Banerjee, Michael Swanson, Xiao G. Jia, Manas K. Haldar, Sanku Mallik, and D. K. Srivastava pp 13206–13207 DOI: 10.1021/ja047271k Supporting Info

Control of A Multisubunit DNA Motor by a Thermoresponsive Polymer Switch Sivanand S. Pennadam, Matthieu D. Lavigne, Christina F. Dutta, Keith Firman, Darren Mernagh, Dariusz C. Górecki, and Cameron Alexander pp 13208–13209 DOI: 10.1021/ja045275j Supporting Info

Equilibrium Characteristic at Ordered−Disordered Phase Boundary in Centrifuged Nonequilibrium Colloidal−Crystal System Toshimitsu Kanai, Tsutomu Sawada, Junpei Yamanaka, and Kenji Kitamura pp 13210–13211 DOI: 10.1021/ja045601v

Nanopore Formation by Self-Assembly of the Model Genetically Engineered Elastin-like Polymer [(VPGVG)2(VPGEG)(VPGVG)2]15 Javier Reguera, Amir Fahmi, Philip Moriarty, Alessandra Girotti, and José Carlos Rodríguez-Cabello pp 13212–13213 DOI: 10.1021/ja047417f

Dihydrogen Activation by a Diruthenium Analogue of the Fe-Only Hydrogenase Active Site Aaron K. Justice, Rachel C. Linck, Thomas B. Rauchfuss, and Scott R. Wilson pp 13214–13215 DOI: 10.1021/ja0455594 Supporting Info

A Polyamidoamine Dendrimer-Capped Mesoporous Silica Nanosphere-Based Gene Transfection Reagent Daniela R. Radu, Cheng-Yu Lai, Ksenija Jeftinija, Eric W. Rowe, Srdija Jeftinija, and Victor S.-Y. Lin pp 13216–13217 DOI: 10.1021/ja046275m Supporting Info

A New Route to Supramolecular Isomers via Molecular Templating:  Nanosized Molecular Polygons of Copper(I) 2-Methylimidazolates Xiao-Chun Huang, Jie-Peng Zhang, and Xiao-Ming Chen pp 13218–13219 DOI: 10.1021/ja045249l Supporting Info

α-Aldehyde Terminally Functional Methacrylic Polymers from Living Radical Polymerization:  Application in Protein Conjugation “Pegylation” Lei Tao, Giuseppe Mantovani, Francois Lecolley, and David M. Haddleton pp 13220–13221 DOI: 10.1021/ja0456454 Supporting Info

Electronic Structure of the Water-Oxidation Catalyst [(bpy)2(OHx)RuORu(OHy)(bpy)2]z+:  Weak Coupling between the Metal Centers Is Preferred over Strong Coupling Xiaofan Yang and Mu-Hyun Baik pp 13222–13223 DOI: 10.1021/ja0462427 Supporting Info

FTIR Spectroscopy of Buried Interfaces in Molecular Junctions Yongseok Jun and X.-Y. Zhu pp 13224–13225 DOI: 10.1021/ja046431p Supporting Info

Raman Imaging of PLGA Microsphere Degradation Inside Macrophages Aart A. van Apeldoorn, Henk-Jan van Manen, Jeroen M. Bezemer, Joost D. de Bruijn, Clemens A. van Blitterswijk, and Cees Otto pp 13226–13227 DOI: 10.1021/ja0459936

Formation of Giant Solvation Shells around Fulleride Anions in Liquid Ammonia Christopher A. Howard, Helen Thompson, Jonathan C. Wasse, and Neal T. Skipper pp 13228–13229 DOI: 10.1021/ja046322a Supporting Info

Probing Proton−Proton Proximities in the Solid State:  High-Resolution Two-Dimensional 1H−1H Double-Quantum CRAMPS NMR Spectroscopy Steven P. Brown, Anne Lesage, Bénédicte Elena, and Lyndon Emsley pp 13230–13231 DOI: 10.1021/ja045461p Supporting Info

Site-Selective Abstraction in the Reaction of 5−20 eV O+ with a Self-Assembled Monolayer Xiangdong Qin, Tochko Tzvetkov, Xin Liu, Dong-Chan Lee, Luping Yu, and Dennis C. Jacobs pp 13232–13233 DOI: 10.1021/ja045475v Supporting Info

DNA-Mediated Charge Transport Requires Conformational Motion of the DNA Bases:  Elimination of Charge Transport in Rigid Glasses at 77 K Melanie A. O‘Neill and Jacqueline K. Barton pp 13234–13235 DOI: 10.1021/ja0455897 Supporting Info

Multiple Areas of Magnetic Bistability in the Topological Ferrimagnet [Co3(NC5H3(CO2)2-2,5)2(μ3-OH)2(OH2)2] Simon M. Humphrey and Paul T. Wood pp 13236–13237 DOI: 10.1021/ja046351l Supporting Info

Isolation of a Se-Nitrososelenol:  A New Class of Reactive Nitrogen Species Relevant to Protein Se-Nitrosation Keiichi Shimada, Kei Goto, Takayuki Kawashima, Nozomi Takagi, Yoong-Kee Choe, and Shigeru Nagase pp 13238–13239 DOI: 10.1021/ja0457009 Supporting Info

Reprogramming DNA-Directed Reactions on the Basis of a DNA Conformational Change Yi Chen and Chengde Mao pp 13240–13241 DOI: 10.1021/ja045718j Supporting Info

1,3-Bis(N,N-dialkylamino)imidazolin-2-ylidenes:  Synthesis and Reactivity of a New Family of Stable N-Heterocyclic Carbenes Manuel Alcarazo, Stephen J. Roseblade, Emma Alonso, Rosario Fernández, Eleuterio Alvarez, Fernando J. Lahoz, and José M. Lassaletta pp 13242–13243 DOI: 10.1021/ja0471119 Supporting Info

Oxidative C-Arylation of Free (NH)-Heterocycles via Direct (sp3) C−H Bond Functionalization Bengü Sezen and Dalibor Sames pp 13244–13246 DOI: 10.1021/ja045402b Supporting Info

Genetic Screens and Selections for Small Molecules Based on a Synthetic Riboswitch That Activates Protein Translation Shawn K. Desai and Justin P. Gallivan pp 13247–13254 DOI: 10.1021/ja048634j Supporting Info

Determining the Folding and Unfolding Rate Constants of Nucleic Acids by Biosensor. Application to Telomere G-Quadruplex Yong Zhao, Zhong-yuan Kan, Zhi-xiong Zeng, Yu-hua Hao, Hua Chen, and Zheng Tan pp 13255–13264 DOI: 10.1021/ja048398c Supporting Info

Kinetic and Regiospecific Interrogation of Covalent Intermediates in the Nonribosomal Peptide Synthesis of Yersiniabactin Shaun M. McLoughlin and Neil L. Kelleher pp 13265–13275 DOI: 10.1021/ja0470867 Supporting Info

Incorporating Protein Flexibility in Structure-Based Drug Discovery:  Using HIV-1 Protease as a Test Case Kristin L. Meagher and Heather A. Carlson pp 13276–13281 DOI: 10.1021/ja0469378 Supporting Info

Engineered Protein Cages for Nanomaterial Synthesis Ryan M. Kramer, Chester Li, Daniel C. Carter, Morley O. Stone, and Rajesh R. Naik pp 13282–13286 DOI: 10.1021/ja046735b Supporting Info

Independent Generation of the 5-Hydroxy-5,6-dihydrothymidin-6-yl Radical and Its Reactivity in Dinucleoside Monophosphates Qibin Zhang and Yinsheng Wang pp 13287–13297 DOI: 10.1021/ja048492t Supporting Info

A Two-Unnatural-Base-Pair System toward the Expansion of the Genetic Code Ichiro Hirao, Yoko Harada, Michiko Kimoto, Tsuneo Mitsui, Tsuyoshi Fujiwara, and Shigeyuki Yokoyama pp 13298–13305 DOI: 10.1021/ja047201d Supporting Info

Inhibition of Peptidylglycine α-Amidating Monooxygenase by Exploitation of Factors Affecting the Stability and Ease of Formation of Glycyl Radicals Brendon J. W. Barratt, Christopher J. Easton, David J. Henry, Iris H. W. Li, Leo Radom, and Jamie S. Simpson pp 13306–13311 DOI: 10.1021/ja046204n Supporting Info

p-Menthane-3-carboxaldehyde:  A Useful Chiral Auxiliary for the Synthesis of Chiral Quaternary Carbons of High Enantiomeric Purity Claude Spino, Cédrickx Godbout, Christian Beaulieu, Magali Harter, Topwe M. Mwene-Mbeja, and Luc Boisvert pp 13312–13319 DOI: 10.1021/ja046084j Supporting Info

Orientation and Alkylation Effects on Cation-π Interactions in Aqueous Solution Mark J. Rashkin, Robert M. Hughes, Nathaniel T. Calloway, and Marcey L. Waters pp 13320–13325 DOI: 10.1021/ja0498538 Supporting Info

Experimental and Theoretical Studies of the Propargyl-Allenylindium System Weishi Miao, Lung Wa Chung, Yun-Dong Wu, and Tak Hang Chan pp 13326–13334 DOI: 10.1021/ja049241n Supporting Info

Crystal Engineering Approach To Forming Cocrystals of Amine Hydrochlorides with Organic Acids. Molecular Complexes of Fluoxetine Hydrochloride with Benzoic, Succinic, and Fumaric Acids Scott L. Childs, Leonard J. Chyall, Jeanette T. Dunlap, Valeriya N. Smolenskaya, Barbara C. Stahly, and G. Patrick Stahly pp 13335–13342 DOI: 10.1021/ja048114o Supporting Info

Detection of Bacteria with Carbohydrate-Functionalized Fluorescent Polymers Matthew D. Disney, Juan Zheng, Timothy M. Swager, and Peter H. Seeberger pp 13343–13346 DOI: 10.1021/ja047936i Supporting Info

Impact of Molecular Speciation on Crystal Nucleation in Polymorphic Systems:  The Conundrum of γ Glycine and Molecular ‘Self Poisoning' Christopher S. Towler, Roger J. Davey, Robert W. Lancaster, and Christopher J. Price pp 13347–13353 DOI: 10.1021/ja047507k

Chiral Recognition of Dipeptides in a Biomembrane Model Cecilia Bombelli, Stefano Borocci, Federica Lupi, Giovanna Mancini, Luisa Mannina, Anna Laura Segre, and Stéphane Viel pp 13354–13362 DOI: 10.1021/ja0470057 Supporting Info

Electronic Modulation of Dithienothiophene (DTT) as π-Center of D-π-D Chromophores on Optical and Redox Properties:  Analysis by UV−Vis−NIR and Raman Spectroscopies Combined with Electrochemistry and Quantum Chemical DFT Calculations Rocío Ponce Ortiz, Mari Carmen Ruiz Delgado, Juan Casado, Víctor Hernández, Oh-Kil Kim, Han Young Woo, and Juan T. López Navarrete pp 13363–13376 DOI: 10.1021/ja047058o

Metal Chelation-Controlled Twisted Intramolecular Charge Transfer and Its Application to Fluorescent Sensing of Metal Ions and Anions Shin Aoki, Daisuke Kagata, Motoo Shiro, Kei Takeda, and Eiichi Kimura pp 13377–13390 DOI: 10.1021/ja040095v Supporting Info

Detailed Structural Investigation of the Grafting of [Ta(CHtBu)(CH2tBu)3] and [Cp*TaMe4] on Silica Partially Dehydroxylated at 700 °C and the Activity of the Grafted Complexes toward Alkane Metathesis Erwan Le Roux, Mathieu Chabanas, Anne Baudouin, Aimery de Mallmann, Christophe Copéret, E. Alessandra Quadrelli, Jean Thivolle-Cazat, Jean-Marie Basset, Wayne Lukens, Anne Lesage, Lyndon Emsley, and Glenn J. Sunley pp 13391–13399 DOI: 10.1021/ja046486r Supporting Info

Self-Assembly of Biocidal Nanotubes from a Single-Chain Diacetylene Amine Salt Sang Beom Lee, Richard Koepsel, Donna B. Stolz, Heidi E. Warriner, and Alan J. Russell pp 13400–13405 DOI: 10.1021/ja048463i Supporting Info

Photocatalytic H2 Evolution Reaction from Aqueous Solutions over Band Structure-Controlled (AgIn)xZn2(1-x)S2 Solid Solution Photocatalysts with Visible-Light Response and Their Surface Nanostructures Issei Tsuji, Hideki Kato, Hisayoshi Kobayashi, and Akihiko Kudo pp 13406–13413 DOI: 10.1021/ja048296m

Synthesis, Characterization, and Framework Heteroatom Localization in ITQ-21 Teresa Blasco, Avelino Corma, Maria José Díaz-Cabañas, Fernando Rey, Jordi Rius, German Sastre, and José A. Vidal-Moya pp 13414–13423 DOI: 10.1021/ja047990z Supporting Info

Catalytic Nanomotors:  Autonomous Movement of Striped Nanorods Walter F. Paxton, Kevin C. Kistler, Christine C. Olmeda, Ayusman Sen, Sarah K. St. Angelo, Yanyan Cao, Thomas E. Mallouk, Paul E. Lammert, and Vincent H. Crespi pp 13424–13431 DOI: 10.1021/ja047697z Supporting Info

Metal-Catalyzed Anaerobic Disproportionation of Hydroxylamine. Role of Diazene and Nitroxyl Intermediates in the Formation of N2, N2O, NO+, and NH3 Graciela E. Alluisetti, Alejandra E. Almaraz, Valentín T. Amorebieta, Fabio Doctorovich, and José A. Olabe pp 13432–13442 DOI: 10.1021/ja046724i Supporting Info

Local and Nanoscale Structure and Speciation in the PuO2+x-y(OH)2y·zH2O System Steven D. Conradson, Bruce D. Begg, David L. Clark, Christophe den Auwer, Mei Ding, Peter K. Dorhout, Francisco J. Espinosa-Faller, Pamela L. Gordon, Richard G. Haire, Nancy J. Hess, Ryan F. Hess, D. Webster Keogh, Luis A. Morales, Mary P. Neu, Patricia Paviet-Hartmann, Wolfgang Runde, C. Drew Tait, D. Kirk Veirs, and Phillip M. Villella pp 13443–13458 DOI: 10.1021/ja049192e Supporting Info

Electrostatic Influence on Rotational Mobilities of Sol−Gel-Encapsulated Solutes by NMR and EPR Spectroscopies Korin E. Wheeler, Nicholas S. Lees, Ryszard J. Gurbiel, Shelby L. Hatch, Judith M. Nocek, and Brian M. Hoffman pp 13459–13463 DOI: 10.1021/ja046659c

Dioxygen Activation by a Low-Valent Cobalt Complex Employing a Flexible Tripodal N-Heterocyclic Carbene Ligand Xile Hu, Ingrid Castro-Rodriguez, and Karsten Meyer pp 13464–13473 DOI: 10.1021/ja046048k Supporting Info

DNA Hybridization Assays Using Temperature Gradient Focusing and Peptide Nucleic Acids Karin M. Balss, David Ross, Heather C. Begley, Kimberly G. Olsen, and Michael J. Tarlov pp 13474–13479 DOI: 10.1021/ja030667w

Building Blocks for N-Type Molecular and Polymeric Electronics. Perfluoroalkyl- versus Alkyl-Functionalized Oligothiophenes (nTs; n = 2−6). Systematic Synthesis, Spectroscopy, Electrochemistry, and Solid-State Organization Antonio Facchetti, Myung-Han Yoon, Charlotte L. Stern, Geoffrey R. Hutchison, Mark A. Ratner, and Tobin J. Marks pp 13480–13501 DOI: 10.1021/ja048988a Supporting Info

A Sequential Molecular Mechanics/Quantum Mechanics Study of the Electronic Spectra of Amides Nicholas A. Besley, Mark T. Oakley, Alexander J. Cowan, and Jonathan D. Hirst pp 13502–13511 DOI: 10.1021/ja047603l

Helical Folding of Alkanes in a Self-Assembled, Cylindrical Capsule Alessandro Scarso, Laurent Trembleau, and Julius Rebek, Jr. pp 13512–13518 DOI: 10.1021/ja047952f Supporting Info

Enol−Enamine Tautomerism in Crystals of 1,3-Bis(pyridin-2-yl) Propan-2-one:  A Combined Crystallographic and Quantum-Chemical Investigation of the Effect of Packing on Tautomerization Processes Oded Godsi, Boaz Turner, Kinga Suwinska, Uri Peskin, and Yoav Eichen pp 13519–13525 DOI: 10.1021/ja046311h Supporting Info

Extensive Migration of Ni and Mn by Lithiation of Ordered LiMg0.1Ni0.4Mn1.5O4 Spinel Marnix Wagemaker, Frans G. B. Ooms, Erik M. Kelder, Joop Schoonman, Gordon J. Kearley, and Fokko M. Mulder pp 13526–13533 DOI: 10.1021/ja048319x Supporting Info

Amyloid-β Binds Cu2+ in a Mononuclear Metal Ion Binding Site Jesse W. Karr, Lauren J. Kaupp, and Veronika A. Szalai pp 13534–13538 DOI: 10.1021/ja0488028

Valence Bond Calculations of Hydrogen Transfer Reactions:  A General Predictive Pattern Derived from Theory Peifeng Su, Lingchun Song, Wei Wu, Philippe C. Hiberty, and Sason Shaik pp 13539–13549 DOI: 10.1021/ja048105f

Determination of Rate Constants for Charge Transfer and the Distribution of Semiconductor and Electrolyte Electronic Energy Levels in Dye-Sensitized Solar Cells by Open-Circuit Photovoltage Decay Method Juan Bisquert, Arie Zaban, Miri Greenshtein, and Iván Mora-Seró pp 13550–13559 DOI: 10.1021/ja047311k

Asymmetric Benzoin Condensation Catalyzed by Chiral Rotaxanes Tethering a Thiazolium Salt Moiety via the Cooperation of the Component:  Can Rotaxane Be an Effective Reaction Field?  [J. Am. Chem. Soc. 2004, 126, 3438−3439]. Yuya Tachibana, Nobuhiro Kihara, and Toshikazu Takata p 13560 DOI: 10.1021/ja0408202

Issue 42

Mechanism of the Stoddart−Heath Bistable Rotaxane Molecular Switch Wei-Qiao Deng, Richard P. Muller, and William A. Goddard III pp 13562–13563 DOI: 10.1021/ja036498x Supporting Info

A Theoretical Investigation of Ruthenium-Catalyzed Alkene Hydrosilation:  Evidence To Support an Exciting New Mechanistic Proposal Chad Beddie and Michael B. Hall pp 13564–13565 DOI: 10.1021/ja046525z Supporting Info

Photochemical Production of Nitric Oxide via Two-Photon Excitation with NIR Light Stephen Wecksler, Alexander Mikhailovsky, and Peter C. Ford pp 13566–13567 DOI: 10.1021/ja045710+ Supporting Info

Synthesis of [1]Rotaxane via Covalent Bond Formation and Its Unique Fluorescent Response by Energy Transfer in the Presence of Lithium Ion Kazuhisa Hiratani, Maiko Kaneyama, Yoshinobu Nagawa, Emiko Koyama, and Masatoshi Kanesato pp 13568–13569 DOI: 10.1021/ja046929r Supporting Info

Phagemid Encoded Small Molecules for High Throughput Screening of Chemical Libraries Jun Yin, Fei Liu, Martina Schinke, Christian Daly, and Christopher T. Walsh pp 13570–13571 DOI: 10.1021/ja045127t Supporting Info

Monolayer-Controlled Substrate Selectivity Using Noncovalent Enzyme−Nanoparticle Conjugates Rui Hong, Todd Emrick, and Vincent M. Rotello pp 13572–13573 DOI: 10.1021/ja0461163 Supporting Info

Reaction of CO with Molecularly Chemisorbed Oxygen on TiO2-Supported Gold Nanoclusters James D. Stiehl, Tae S. Kim, Sean M. McClure, and C. Buddie Mullins pp 13574–13575 DOI: 10.1021/ja046390x

On the Nature of Dendrimer Cross-Linking by Ring-Closing Metathesis James B. Beil, N. Gabriel Lemcoff, and Steven C. Zimmerman pp 13576–13577 DOI: 10.1021/ja045885j Supporting Info

An Atomic Mutation Cycle for Exploring RNA's 2‘-Hydroxyl Group James L. Hougland, Shirshendu K. Deb, Danijela Maric, and Joseph A. Piccirilli pp 13578–13579 DOI: 10.1021/ja0469129 Supporting Info

Optically Switchable Liquid Crystal Photonic Structures Augustine Urbas, Vincent Tondiglia, Lalgudi Natarajan, Richard Sutherland, Haiping Yu, J.-H. Li, and Timothy Bunning pp 13580–13581 DOI: 10.1021/ja045143q Supporting Info

Synthesis of a Calix[4]arene Derivative for Isolation of a Stable Cation Radical Salt for Use as a Colorimetric Sensor of Nitric Oxide Rajendra Rathore, Sameh H. Abdelwahed, and Ilia A. Guzei pp 13582–13583 DOI: 10.1021/ja0454900 Supporting Info

C2-Symmetric Bicyclo[2.2.2]octadienes as Chiral Ligands:  Their High Performance in Rhodium-Catalyzed Asymmetric Arylation of N-Tosylarylimines Norihito Tokunaga, Yusuke Otomaru, Kazuhiro Okamoto, Kazuhito Ueyama, Ryo Shintani, and Tamio Hayashi pp 13584–13585 DOI: 10.1021/ja044790e Supporting Info

Formation of a Stable 14-Helix in Short Oligomers of Furanoid cis-β-Sugar-Amino Acid Srivari Chandrasekhar, Marepally Srinivasa Reddy, Bharatam Jagadeesh, Anabathula Prabhakar, Mallem H. V. Ramana Rao, and Bulusu Jagannadh pp 13586–13587 DOI: 10.1021/ja0467667 Supporting Info

Cyclodextrin-Initiated Polymerization of Cyclic Esters in Bulk: Formation of Polyester-Tethered Cyclodextrins Yoshinori Takashima, Motofumi Osaki, and Akira Harada pp 13588–13589 DOI: 10.1021/ja047171e Supporting Info

Ambient Temperature Plastic Crystal Electrolyte for Efficient, All-Solid-State Dye-Sensitized Solar Cell Peng Wang, Qing Dai, Shaik M. Zakeeruddin, Maria Forsyth, Douglas R. MacFarlane, and Michael Grätzel pp 13590–13591 DOI: 10.1021/ja045013h

Synthetic Multifunctional Pores with External and Internal Active Sites for Ligand Gating and Noncompetitive Blockage Virginie Gorteau, Florent Perret, Guillaume Bollot, Jiri Mareda, Adina N. Lazar, Anthony W. Coleman, Duy-Hien Tran, Naomi Sakai, and Stefan Matile pp 13592–13593 DOI: 10.1021/ja045987+ Supporting Info

An Organometallic Inhibitor for Glycogen Synthase Kinase 3 Howard Bregman, Douglas S. Williams, G. Ekin Atilla, Patrick J. Carroll, and Eric Meggers pp 13594–13595 DOI: 10.1021/ja046049c Supporting Info

Direct Functionalization of Arenes by Primary Alcohol Sulfonate Esters Catalyzed by Gold(III) Zhangjie Shi and Chuan He pp 13596–13597 DOI: 10.1021/ja046890q Supporting Info

Unprecedented Reversible Migration of Amide to Schiff Base Ligands Attached to Tin:  Latent Single-Site Initiators for Lactide Polymerization Nonsee Nimitsiriwat, Edward L. Marshall, Vernon C. Gibson, Mark R. J. Elsegood, and Sophie H. Dale pp 13598–13599 DOI: 10.1021/ja0470315 Supporting Info

Synthesis of Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Tetrahydrofurans Using a Sulfoxonium Ylide Jennifer M. Schomaker, Veera Reddy Pulgam, and Babak Borhan pp 13600–13601 DOI: 10.1021/ja0469075 Supporting Info

Effects of Lipid Chain Lengths in α-Galactosylceramides on Cytokine Release by Natural Killer T Cells Randal D. Goff, Ying Gao, Jochen Mattner, Dapeng Zhou, Ning Yin, Carlos Cantu, III, Luc Teyton, Albert Bendelac, and Paul B. Savage pp 13602–13603 DOI: 10.1021/ja045385q Supporting Info

Remote Asymmetric Induction with Vinylketene Silyl N,O-Acetal Shin-ichi Shirokawa, Masato Kamiyama, Tomoaki Nakamura, Masakazu Okada, Atsuo Nakazaki, Seijiro Hosokawa, and Susumu Kobayashi pp 13604–13605 DOI: 10.1021/ja0465855 Supporting Info

Three-Component Condensation Leading to β-Amino Acid Diamides:  Convergent Assembly of β-Peptide Analogues Jennifer M. Oaksmith, Ulf Peters, and Bruce Ganem pp 13606–13607 DOI: 10.1021/ja0450152 Supporting Info

Highly Enantio- and Diastereoselective One-Pot Synthesis of Acyclic Epoxy Alcohols with Three Contiguous Stereocenters Alice E. Lurain, Aaron Maestri, Ann Rowley Kelly, Patrick J. Carroll, and Patrick J. Walsh pp 13608–13609 DOI: 10.1021/ja046750g Supporting Info

Chemistry of the Phosphinidene Oxide Ligand María Alonso, M. Esther García, Miguel A. Ruiz, Hayrullo Hamidov, and John C. Jeffery pp 13610–13611 DOI: 10.1021/ja045487g Supporting Info

Supramolecular Nanocarrier of siRNA from PEG-Based Block Catiomer Carrying Diamine Side Chain with Distinctive pKa Directed To Enhance Intracellular Gene Silencing Keiji Itaka, Naoki Kanayama, Nobuhiro Nishiyama, Woo-Dong Jang, Yuichi Yamasaki, Kozo Nakamura, Hiroshi Kawaguchi, and Kazunori Kataoka pp 13612–13613 DOI: 10.1021/ja047174r Supporting Info

Ruthenium-Catalyzed Hydrogenation of Alkynylstannanes with Migration of the Stannyl Group Eiji Shirakawa, Ryotaro Morita, Teruhisa Tsuchimoto, and Yusuke Kawakami pp 13614–13615 DOI: 10.1021/ja0458827 Supporting Info

De Novo Designed Peptidic Redox Potential Probe:  Linking Sensitized Emission to Disulfide Bond Formation Kyung Lee, Valerie Dzubeck, Lauren Latshaw, and Joel P. Schneider pp 13616–13617 DOI: 10.1021/ja047300r Supporting Info

Alkene−Alkyne Coupling as a Linchpin:  An Efficient and Convergent Synthesis of Amphidinolide P Barry M. Trost and Julien P. N. Papillon pp 13618–13619 DOI: 10.1021/ja045449x Supporting Info

A Biomimetic Approach to the Rocaglamides Employing Photogeneration of Oxidopyryliums Derived from 3-Hydroxyflavones Baudouin Gerard, Guilford Jones II, and John A. Porco, Jr. pp 13620–13621 DOI: 10.1021/ja044798o Supporting Info

Dirhodium(II) Caprolactamate:  An Exceptional Catalyst for Allylic Oxidation Arthur J. Catino, Raymond E. Forslund, and Michael P. Doyle pp 13622–13623 DOI: 10.1021/ja045330o Supporting Info

Carbon and SiC Macroscopic Beads from Ion-Exchange Resin Templates Lubomira Tosheva, Julien Parmentier, Seifedine Saadallah, Cathie Vix-Guterl, Valentin Valtchev, and Joël Patarin pp 13624–13625 DOI: 10.1021/ja0461217 Supporting Info

Copper(II)-Quenched Oligonucleotide Probes for Fluorescent DNA Sensing Jens Brunner and Roland Kraemer pp 13626–13627 DOI: 10.1021/ja047252a Supporting Info

Iron Complexes of (E)- and (Z)-1,2-Dichlorodisilenes Hisako Hashimoto, Katsunori Suzuki, Wataru Setaka, Chizuko Kabuto, and Mitsuo Kira pp 13628–13629 DOI: 10.1021/ja048100i Supporting Info

Orientational Control of Electronic Coupling in Mixed-Valence, Binuclear Ruthenium(II)−Bis(2,2‘:6‘,2‘ ‘-Terpyridine) Complexes Andrew C. Benniston, Anthony Harriman, Peiyi Li, Craig A. Sams, and Michael D. Ward pp 13630–13631 DOI: 10.1021/ja0451968 Supporting Info

Cooperative Catalysis of a Cationic Ruthenium Complex, Amine Base, and Na Salt:  Catalytic Activation of Acetonitrile as a Nucleophile Naoya Kumagai, Shigeki Matsunaga, and Masakatsu Shibasaki pp 13632–13633 DOI: 10.1021/ja0450509 Supporting Info

The Dithianyl Group as a Synthon in Porphyrin Chemistry:  Condensation Reactions and Preparation of Formylporphyrins under Basic Conditions Mathias O. Senge, Sabine S. Hatscher, Arno Wiehe, Katja Dahms, and Andrea Kelling pp 13634–13635 DOI: 10.1021/ja045223u Supporting Info

Glycosidic Torsional Motions in a Bicelle-associated Disaccharide from Residual Dipolar Couplings Xiaobing Yi, André Venot, John Glushka, and James H. Prestegard pp 13636–13638 DOI: 10.1021/ja045697t Supporting Info

Control of Protein Adsorption:  Molecular Level Structural and Spatial Variables David J. Vanderah, Hongly La, Jessica Naff, Vitalii Silin, and Kenneth A. Rubinson pp 13639–13641 DOI: 10.1021/ja047744n Supporting Info

Origins of Cell Selectivity of Cationic Steroid Antibiotics Bangwei Ding, Ning Yin, Yang Liu, Jaime Cardenas-Garcia, Richard Evanson, Thomas Orsak, Mingjin Fan, Gracija Turin, and Paul B. Savage pp 13642–13648 DOI: 10.1021/ja046909p

QM/MM Studies of the Enzyme-Catalyzed Dechlorination of 4-Chlorobenzoyl-CoA Provide Insight into Reaction Energetics Dingguo Xu, Yanseng Wei, Jingbo Wu, Debra Dunaway-Mariano, Hua Guo, Qiang Cui, and Jiali Gao pp 13649–13658 DOI: 10.1021/ja0460211

Thiophene-Based Diamidine Forms a “Super” AT Binding Minor Groove Agent Sirish Mallena, Michael P. H. Lee, Christian Bailly, Stephen Neidle, Arvind Kumar, David W. Boykin, and W. David Wilson pp 13659–13669 DOI: 10.1021/ja048175m Supporting Info

Thermodynamic Characterization of the Binding of Tetrahydropterins to Phenylalanine Hydroxylase Angel Luis Pey, Matthías Thórólfsson, Knut Teigen, Magdalena Ugarte, and Aurora Martínez pp 13670–13678 DOI: 10.1021/ja047713s

The Helical Alanine Controversy:  An (Ala)6 Insertion Dramatically Increases Helicity Jasper C. Lin, Bipasha Barua, and Niels H. Andersen pp 13679–13684 DOI: 10.1021/ja047265o Supporting Info

Amplified Quenching of a Conjugated Polyelectrolyte by Cyanine Dyes Chunyan Tan, Evrim Atas, Jürgen G. Müller, Mauricio R. Pinto, Valeria D. Kleiman, and Kirk S. Schanze pp 13685–13694 DOI: 10.1021/ja046856b Supporting Info

Synthesis and Properties of Monodisperse Oligofluorene-Functionalized Truxenes:  Highly Fluorescent Star-Shaped Architectures Alexander L. Kanibolotsky, Rory Berridge, Peter J. Skabara, Igor F. Perepichka, Donal D. C. Bradley, and Mattijs Koeberg pp 13695–13702 DOI: 10.1021/ja039228n Supporting Info

A New Rearrangement Process in tert-Amyl Cation Valerije Vrek, Martin Saunders, and Olga Kronja pp 13703–13707 DOI: 10.1021/ja046004b Supporting Info

Application of Chiral Cationic Catalysts to Several Classical Syntheses of Racemic Natural Products Transforms Them into Highly Enantioselective Pathways Qi-Ying Hu, Gang Zhou, and E. J. Corey pp 13708–13713 DOI: 10.1021/ja046154m Supporting Info

Calix[4]phyrins. Effect of Peripheral Substituents on Conformational Mobility and Structure within a Series of Related Systems Bohumil Dolenský, Jiří Kroulík, Vladimír Král, Jonathan L. Sessler, Hana Dvořáková, Petr Bouř, Markéta Bernátková, Christophe Bucher, and Vincent Lynch pp 13714–13722 DOI: 10.1021/ja048075g Supporting Info

pH-Sensitive Bipolar Ion-Permselective Ultrathin Films Mi-Kyoung Park, Suxiang Deng, and Rigoberto C. Advincula pp 13723–13731 DOI: 10.1021/ja0484707

Photochemical Study of [33](1,3,5)Cyclophane and Emission Spectral Properties of [3n]Cyclophanes (n = 2−6) Rika Nogita, Kumi Matohara, Minoru Yamaji, Takuma Oda, Youichi Sakamoto, Tsutomu Kumagai, Chultack Lim, Mikio Yasutake, Tetsuro Shimo, Charles W. Jefford, and Teruo Shinmyozu pp 13732–13741 DOI: 10.1021/ja030032x Supporting Info

In Situ Disorder−Order Transformation in Synthetic Gallosilicate Zeolites with the NAT Topology Suk Bong Hong, Song-Ho Lee, Chae-Ho Shin, Ae Ja Woo, Luis J. Alvarez, Claudio M. Zicovich-Wilson, and Miguel A. Camblor pp 13742–13751 DOI: 10.1021/ja046921h Supporting Info

Stereoselective Tandem 1,4-Addition Reactions for Benzenes:  A Comparison of Os(II), Re(I), and W(0) Systems Fei Ding and W. Dean Harman pp 13752–13756 DOI: 10.1021/ja047108p Supporting Info

Reactivity of Aqueous Fe(IV) in Hydride and Hydrogen Atom Transfer Reactions Oleg Pestovsky and Andreja Bakac pp 13757–13764 DOI: 10.1021/ja0457112 Supporting Info

High-Resolution 31P Field Cycling NMR as a Probe of Phospholipid Dynamics Mary F. Roberts and Alfred G. Redfield pp 13765–13777 DOI: 10.1021/ja046658k

Large-Scale Fabrication of Wafer-Size Colloidal Crystals, Macroporous Polymers and Nanocomposites by Spin-Coating Peng Jiang and Michael J. McFarland pp 13778–13786 DOI: 10.1021/ja0470923 Supporting Info

Dopant Ion Size and Electronic Structure Effects on Transparent Conducting Oxides. Sc-Doped CdO Thin Films Grown by MOCVD Shu Jin, Yu Yang, Julia E. Medvedeva, John R. Ireland, Andrew W. Metz, Jun Ni, Carl R. Kannewurf, Arthur J. Freeman, and Tobin J. Marks pp 13787–13793 DOI: 10.1021/ja0467925

Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation Suzanne C. Bart, Emil Lobkovsky, and Paul J. Chirik pp 13794–13807 DOI: 10.1021/ja046753t Supporting Info

Mechanistic Studies of the Copolymerization Reaction of Aziridines and Carbon Monoxide to Produce Poly-β-peptoids Donald J. Darensbourg, Andrea L. Phelps, Nathalie Le Gall, and Li Jia pp 13808–13815 DOI: 10.1021/ja046225h Supporting Info

Molecular Architecture of Nanocapsules, Bilayer-Enclosed Solid Particles of Cisplatin Vladimir Chupin, Anton I. P. M. de Kroon, and Ben de Kruijff pp 13816–13821 DOI: 10.1021/ja0468933 Supporting Info

Chirality Control in Optically Active Polysilane Aggregates Wenqing Peng, Masao Motonaga, and Julian R. Koe pp 13822–13826 DOI: 10.1021/ja046235i Supporting Info

Optical Properties of Silicon Clusters in the Presence of Water:  A First Principles Theoretical Analysis David Prendergast, Jeffrey C. Grossman, Andrew J. Williamson, Jean-Luc Fattebert, and Giulia Galli pp 13827–13837 DOI: 10.1021/ja048038p

Single-Molecule Spectroscopy Studies of Microenvironmental Acidity in Silicate Thin Films Yi Fu, Maryanne M. Collinson, and Daniel A. Higgins pp 13838–13844 DOI: 10.1021/ja046527j

Endohedral Silicon Fullerenes SiN (27 ≤ N ≤ 39) Soohaeng Yoo, Jijun Zhao, Jinlan Wang, and Xiao Cheng Zeng pp 13845–13849 DOI: 10.1021/ja046861f Supporting Info

Intermolecular π-to-π Bonding between Stacked Aromatic Dyads. Experimental and Theoretical Binding Energies and Near-IR Optical Transitions for Phenalenyl Radical/Radical versus Radical/Cation Dimerizations David Small, Vladimir Zaitsev, Yousung Jung, Sergiy V. Rosokha, Martin Head-Gordon, and Jay K. Kochi pp 13850–13858 DOI: 10.1021/ja046770i Supporting Info

Building Blocks for n-Type Molecular and Polymeric Electronics. Perfluoroalkyl- versus Alkyl-Functionalized Oligothiophenes (nT; n = 2−6). Systematics of Thin Film Microstructure, Semiconductor Performance, and Modeling of Majority Charge Injection in Field-Effect Transistors Antonio Facchetti, Melissa Mushrush, Myung-Han Yoon, Geoffrey R. Hutchison, Mark A. Ratner, and Tobin J. Marks pp 13859–13874 DOI: 10.1021/ja0489846 Supporting Info

Relativistic Electronic Structure Theory, Part 2:  Applications Edited by Peter Schwerdtfeger (The University of Auckland). Elsevier:  Amsterdam. 2004. xvi + 788 pp. $305.00. ISBN 0-444-51299-3. Russell M. Pitzer p 13875 DOI: 10.1021/ja0409356

Comprehensive Asymmetric Catalysis:  Supplement 2 Edited by Eric N. Jacobsen (Harvard University), Andreas Pfaltz (University of Basel), and Hisashi Yamamoto (University of Chicago). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xvi + 136 pp. $139.00. ISBN 3-540-20983-2. p 13875 DOI: 10.1021/ja040967t

Polyelectrolytes with Defined Molecular Architecture I. Advances in Polymer Science, Volume 165 Edited by Manfred Schmidt (Johannes Gutenberg-Universität Mainz). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. x + 267 pp. $249.00. ISBN 3-540-00528-5. David Hoagland pp 13875–13876 DOI: 10.1021/ja040934d

Polyelectrolytes with Defined Molecular Architecture II. Advances in Polymer Science, Volume 166 Edited by Manfred Schmidt (Johannes Gutenberg-Universität Mainz). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xii + 226 pp. $249.00. ISBN 3-540-00556-0. Françoise M. Winnik p 13876 DOI: 10.1021/ja040939a

Issue 43

Scanning Probe Lithography on Fluid Lipid Membranes Bryan L. Jackson and Jay T. Groves pp 13878–13879 DOI: 10.1021/ja046040a Supporting Info

A High-Nuclearity “Celtic-Ring” Isopolyoxotungstate, [H12W36O120]12-, That Captures Trace Potassium Ions De-Liang Long, Hamera Abbas, Paul Kögerler, and Leroy Cronin pp 13880–13881 DOI: 10.1021/ja046410v Supporting Info

Phosphatidylethanolamine-Induced Cholesterol Domains Chemically Identified with Mass Spectrometric Imaging Audra G. Sostarecz, Carolyn M. McQuaw, Andrew G. Ewing, and Nicholas Winograd pp 13882–13883 DOI: 10.1021/ja0472127 Supporting Info

Design and STM Investigation of Intramolecular Folding in Self-Assembled Monolayers on the Surface Norbert Schuurmans, Hiroshi Uji-i, Wael Mamdouh, Frans C. De Schryver, Ben L. Feringa, Jan van Esch, and Steven De Feyter pp 13884–13885 DOI: 10.1021/ja046124j Supporting Info

Photochemically Knocking Out Glutamate Receptors in Vivo James J. Chambers, Hiroaki Gouda, David M. Young, Irwin D. Kuntz, and Pamela M. England pp 13886–13887 DOI: 10.1021/ja048331p Supporting Info

Long-Range Electron Transfer Across Peptide Bridges:  The Transition from Electron Superexchange to Hopping Rouba Abdel Malak, Zhinong Gao, James F. Wishart, and Stephan S. Isied pp 13888–13889 DOI: 10.1021/ja0401040

High Velocity Interparticle Collisions Driven by Ultrasound Tanya Prozorov, Ruslan Prozorov, and Kenneth S. Suslick pp 13890–13891 DOI: 10.1021/ja049493o Supporting Info

Chelation-Assisted Hydrative Dimerization of 1-Alkyne Forming α,β-Enones by an Rh(I) Catalyst Young Jun Park, Bong-Il Kwon, Jeong-Ae Ahn, Hyuk Lee, and Chul-Ho Jun pp 13892–13893 DOI: 10.1021/ja045789i Supporting Info

One-Step Preparation of Highly Monodisperse Micron-Size Particles in Organic Solvents Hua Hu and Ronald G. Larson pp 13894–13895 DOI: 10.1021/ja046523e Supporting Info

Complete Selection of a Self-Assembling Homo- or Hetero-Cavitand Cage via Metal Coordination Based on Ligand Tuning Kenji Kobayashi, Yoshifumi Yamada, Masamichi Yamanaka, Yoshihisa Sei, and Kentaro Yamaguchi pp 13896–13897 DOI: 10.1021/ja0465799 Supporting Info

Synthesis of Pyridinylpyrrole Derivatives via the Palladium-Catalyzed Reaction of Acetylpyridines with Methyleneaziridines Amal I. Siriwardana, Kalum K. A. D. S. Kathriarachchi, Itaru Nakamura, Ilya D. Gridnev, and Yoshinori Yamamoto pp 13898–13899 DOI: 10.1021/ja0455401 Supporting Info

Enantioselective Construction of Carbobicyclic Scaffolds Douglass F. Taber, Yigang He, and Ming Xu pp 13900–13901 DOI: 10.1021/ja045849k Supporting Info

Orientation-Selected 15N-HYSCORE Detection of Weakly Coupled Nitrogens around the Archaeal Rieske [2Fe−2S] Center Toshio Iwasaki, Asako Kounosu, Taketoshi Uzawa, Rimma I. Samoilova, and Sergei A. Dikanov pp 13902–13903 DOI: 10.1021/ja045898x

Nickel-Catalyzed Arylcyanation of Alkynes Yoshiaki Nakao, Shinichi Oda, and Tamejiro Hiyama pp 13904–13905 DOI: 10.1021/ja0448723 Supporting Info

Palladium-Catalyzed Synthesis of N-Aryl-2-benzylindolines via Tandem Arylation of 2-Allylaniline:  Control of Selectivity through in Situ Catalyst Modification Ricardo Lira and John P. Wolfe pp 13906–13907 DOI: 10.1021/ja0460920 Supporting Info

Highly Versatile Organostibine Mediators for Living Radical Polymerization Shigeru Yamago, Biswajit Ray, Kazunori Iida, Jun-ichi Yoshida, Tomofumi Tada, Kazunari Yoshizawa, Yungwan Kwak, Atsushi Goto, and Takeshi Fukuda pp 13908–13909 DOI: 10.1021/ja044787v Supporting Info

Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene−Ethylene Copolymerization:  Unprecedented Incorporation of Syndiotactic Styrene−Styrene Sequences in Styrene−Ethylene Copolymers Yunjie Luo, Jens Baldamus, and Zhaomin Hou pp 13910–13911 DOI: 10.1021/ja046063p Supporting Info

Origins of Selectivities in Proline-Catalyzed α-Aminoxylations Paul Ha-Yeon Cheong and K. N. Houk pp 13912–13913 DOI: 10.1021/ja0464746 Supporting Info

A Designed Protein Interface That Blocks Fibril Formation Ushma J. Shukla, Heather Marino, Po-Ssu Huang, Stephen L. Mayo, and John J. Love pp 13914–13915 DOI: 10.1021/ja0456858

Phosphaalkynes from Acid Chlorides via P for O(Cl) Metathesis:  A Recyclable Niobium Phosphide (P3-) Reagent that Effects C−P Triple-Bond Formation Joshua S. Figueroa and Christopher C. Cummins pp 13916–13917 DOI: 10.1021/ja0461522 Supporting Info

Enantioselective Synthesis of ansa-Zirconocenes Matthew D. LoCoco and Richard F. Jordan pp 13918–13919 DOI: 10.1021/ja045245g Supporting Info

Reaction Pathway of the [4 + 2] Diels−Alder Adduct Formation on Si(100)-2×1 Peter Minary and Mark E. Tuckerman pp 13920–13921 DOI: 10.1021/ja046522m Supporting Info

An Yttrium Ion-Selective Fluorescence Sensor Based on Metal Ion-Controlled Photoinduced Electron Transfer in Zinc Porphyrin−Quinone Dyad Ken Okamoto and Shunichi Fukuzumi pp 13922–13923 DOI: 10.1021/ja045374x Supporting Info

DNA Triangles and Self-Assembled Hexagonal Tilings Nickolas Chelyapov, Yuriy Brun, Manoj Gopalkrishnan, Dustin Reishus, Bilal Shaw, and Leonard Adleman pp 13924–13925 DOI: 10.1021/ja0458120 Supporting Info

Rare Beryllium Icosahedra in the Intermediate Valence Compound CeBe13 Zakiya S. Wilson, Robin T. Macaluso, E. D. Bauer, J. L. Smith, J. D. Thompson, Z. Fisk, George G. Stanley, and Julia Y. Chan pp 13926–13927 DOI: 10.1021/ja045861c Supporting Info

Lamination Method for the Study of Interfaces in Polymeric Thin Film Transistors Michael L. Chabinyc, Alberto Salleo, Yiliang Wu, Ping Liu, Beng S. Ong, Martin Heeney, and Iain McCulloch pp 13928–13929 DOI: 10.1021/ja044884o Supporting Info

Direct Measurement of Attractive van der Waals' Forces between Regenerated Cellulose Surfaces in an Aqueous Environment Shannon M. Notley, Bert Pettersson, and Lars Wågberg pp 13930–13931 DOI: 10.1021/ja045992d

Photodissociation of Heme Distal Methionine in Ferrous Cytochrome c Revealed by Subpicosecond Time-Resolved Resonance Raman Spectroscopy Simona Cianetti, Michel Négrerie, Marten H. Vos, Jean-Louis Martin, and Sergei G. Kruglik pp 13932–13933 DOI: 10.1021/ja046442i

Modulation of the Folding Energy Landscape of Cytochrome c with Salt Shi Zhong, Denis L. Rousseau, and Syun-Ru Yeh pp 13934–13935 DOI: 10.1021/ja0459431

A New Convergent Strategy for the Synthesis of Calixarenes via a Triple Annulation of Fischer Carbene Complexes Vijay Gopalsamuthiram and William D. Wulff pp 13936–13937 DOI: 10.1021/ja0454236 Supporting Info

Fulvenes, Fulvalenes, and Azulene:  Are They Aromatic Chameleons? Helene Möllerstedt, Mari Carmen Piqueras, Raül Crespo, and Henrik Ottosson pp 13938–13939 DOI: 10.1021/ja045729c Supporting Info

Metalloform-Selective Inhibitors of Escherichia coli Methionine Aminopeptidase and X-ray Structure of a Mn(II)-Form Enzyme Complexed with an Inhibitor Qi-Zhuang Ye, Sheng-Xue Xie, Min Huang, Wei-Jun Huang, Jing-Ping Lu, and Ze-Qiang Ma pp 13940–13941 DOI: 10.1021/ja045864p Supporting Info

Synthetic Stitching with Silicon:  Geminal Alkylation−Hydroxylation of Alkynyl Carbonyl Compounds Barry M. Trost and Zachary T. Ball pp 13942–13944 DOI: 10.1021/ja045971j Supporting Info

X-ray Crystal Structure of the Acylated β-Lactam Sensor Domain of BlaR1 from Staphylococcus aureus and the Mechanism of Receptor Activation for Signal Transduction Catherine Birck, Joo Young Cha, Jason Cross, Clemens Schulze-Briese, Samy O. Meroueh, H. Bernhard Schlegel, Shahriar Mobashery, and Jean-Pierre Samama pp 13945–13947 DOI: 10.1021/ja044742u Supporting Info

Characterization of Protein−Ligand Interactions by High-Resolution Solid-State NMR Spectroscopy Stephan G. Zech, Edward Olejniczak, Philip Hajduk, Jamey Mack, and Ann E. McDermott pp 13948–13953 DOI: 10.1021/ja040086m

Mimicking Protein−Protein Electron Transfer:  Voltammetry of Pseudomonas aeruginosa Azurin and the Thermus thermophilus CuA Domain at ω-Derivatized Self-Assembled-Monolayer Gold Electrodes Kyoko Fujita, Nobufumi Nakamura, Hiroyuki Ohno, Brian S. Leigh, Katsumi Niki, Harry B. Gray, and John H. Richards pp 13954–13961 DOI: 10.1021/ja047875o

Direct Photochemical Patterning and Refunctionalization of Supported Phospholipid Bilayers Chanel K. Yee, Meri L. Amweg, and Atul N. Parikh pp 13962–13972 DOI: 10.1021/ja047714k

Binol Quinone Methides as Bisalkylating and DNA Cross-Linking Agents Sara N. Richter, Stefano Maggi, Stefano Colloredo Mels, Manlio Palumbo, and Mauro Freccero pp 13973–13979 DOI: 10.1021/ja047655a Supporting Info

Destabilizing Universal Linkers for Signal Amplification in Self-Ligating Probes for RNA Hiroshi Abe and Eric T. Kool pp 13980–13986 DOI: 10.1021/ja046791c Supporting Info

Tunable Reactivation of Nanoparticle-Inhibited β-Galactosidase by Glutathione at Intracellular Concentrations Ayush Verma, Joseph M. Simard, Joseph W. E. Worrall, and Vincent M. Rotello pp 13987–13991 DOI: 10.1021/ja046572r Supporting Info

Rupture Force between the Third Strand and the Double Strand within a Triplex DNA Liansheng Ling, Hans-Jürgen Butt, and Rüdiger Berger pp 13992–13997 DOI: 10.1021/ja046341k

A Chemoenzymatic Approach to Glycopeptide Antibiotics Hening Lin and Christopher T. Walsh pp 13998–14003 DOI: 10.1021/ja045147v Supporting Info

Domain-Specific Incorporation of Noninvasive Optical Probes into Recombinant Proteins Vasant Muralidharan, Jaehyun Cho, Michelle Trester-Zedlitz, Lukasz Kowalik, Brian T. Chait, Daniel P. Raleigh, and Tom W. Muir pp 14004–14012 DOI: 10.1021/ja0466199

Glycoinsulins:  Dendritic Sialyloligosaccharide-Displaying Insulins Showing a Prolonged Blood-Sugar-Lowering Activity Masaaki Sato, Tetsuya Furuike, Reiko Sadamoto, Naoki Fujitani, Taku Nakahara, Kenichi Niikura, Kenji Monde, Hirosato Kondo, and Shin-Ichiro Nishimura pp 14013–14022 DOI: 10.1021/ja046426l

Two-Metal Ion, Ni(II) and Cu(II), Binding α-Helical Coiled Coil Peptide Toshiki Tanaka, Toshihisa Mizuno, Souhei Fukui, Hidekazu Hiroaki, Jun-ichi Oku, Kenji Kanaori, Kunihiko Tajima, and Masahiro Shirakawa pp 14023–14028 DOI: 10.1021/ja047945r Supporting Info

A Method for Solid-Phase Synthesis of Oligonucleotide 5‘-Peptide-Conjugates Using Acid-Labile α-Amino Protections Simone Zaramella, Esther Yeheskiely, and Roger Strömberg pp 14029–14035 DOI: 10.1021/ja046945o Supporting Info

NMR Structural Analysis of a Modular Threading Tetraintercalator Bound to DNA Jeeyeon Lee, Vladimir Guelev, Steven Sorey, David W. Hoffman, and Brent L. Iverson pp 14036–14042 DOI: 10.1021/ja046335o

Asymmetric Synthesis of Pyrrolidinoindolines. Application for the Practical Total Synthesis of (−)-Phenserine Audris Huang, Jeremy J. Kodanko, and Larry E. Overman pp 14043–14053 DOI: 10.1021/ja046690e Supporting Info

Structural Characterization of Modular Supramolecular Architectures in Solution David M. Tiede*, Ruitian Zhang, Lin X. Chen, Lianhe Yu, and Jonathan S. Lindsey pp 14054–14062 DOI: 10.1021/ja048209q Supporting Info

Guest Shape-Responsive Fitting of Porous Coordination Polymer with Shrinkable Framework Ryotaro Matsuda, Ryo Kitaura, Susumu Kitagawa, Yoshiki Kubota, Tatsuo C. Kobayashi, Satoshi Horike, and Masaki Takata pp 14063–14070 DOI: 10.1021/ja046925m Supporting Info

Barrierless Electron Transfer Bond Fragmentation Reactions Edward D. Lorance, Wolfgang H. Kramer, and Ian R. Gould pp 14071–14078 DOI: 10.1021/ja030438+ Supporting Info

Rational Principles for Modulating Fluorescence Properties of Fluorescein Tasuku Ueno, Yasuteru Urano, Ken-ichi Setsukinai, Hideo Takakusa, Hirotatsu Kojima, Kazuya Kikuchi, Kei Ohkubo, Shunichi Fukuzumi, and Tetsuo Nagano pp 14079–14085 DOI: 10.1021/ja048241k

Nanosecond Redox Equilibrium Method for Determining Oxidation Potentials in Organic Media Gonzalo Guirado, Cavan N. Fleming, Thor G. Lingenfelter, Michelle L. Williams, Han Zuilhof, and Joseph P. Dinnocenzo pp 14086–14094 DOI: 10.1021/ja046946g Supporting Info

A Synthesis Strategy Yielding Skeletally Diverse Small Molecules Combinatorially Martin D. Burke, Eric M. Berger, and Stuart L. Schreiber pp 14095–14104 DOI: 10.1021/ja0457415 Supporting Info

Pentadienyls vs Cyclopentadienyls and Reversal of Metal−Ligand Bonding Affinity with Metal Oxidation State:  Synthesis, Molecular Structures, and Electronic Structures of High-Valent Zirconium Pentadienyl Complexes Asha Rajapakshe, Nadine E. Gruhn, Dennis L. Lichtenberger, Rehan Basta, Atta M. Arif, and Richard D. Ernst pp 14105–14116 DOI: 10.1021/ja040123+ Supporting Info

Self-Assembled Polymer Membrane Capsules Inflated by Osmotic Pressure Vernita D. Gordon, Xi Chen, John W. Hutchinson, Andreas R. Bausch, Manuel Marquez, and David A. Weitz pp 14117–14122 DOI: 10.1021/ja0474749

Covalently Bonded [Pt]- Chains in BaPt:  Extension of the Zintl−Klemm Concept to Anionic Transition Metals? Andrey Karpov, Jürgen Nuss, Ulrich Wedig, and Martin Jansen pp 14123–14128 DOI: 10.1021/ja0401186 Supporting Info

Accelerated Luminophore Discovery through Combinatorial Synthesis Michael S. Lowry, William R. Hudson, Robert A. Pascal, Jr., and Stefan Bernhard pp 14129–14135 DOI: 10.1021/ja047156+ Supporting Info

Five-Coordinate FeIIINO and FeIICO Porphyrinates:  Where Are the Electrons and Why Does It Matter? Douglas P. Linder, Kenton R. Rodgers, Jennifer Banister, Graeme R. A. Wyllie, Mary K. Ellison, and W. Robert Scheidt pp 14136–14148 DOI: 10.1021/ja046942b

Hydrogen-Bonded Encapsulation Complexes in Protic Solvents Toru Amaya and Julius Rebek, Jr. pp 14149–14156 DOI: 10.1021/ja0467770 Supporting Info

Roles of Anionic and Cationic Template Components in Biomineralization of CdS Nanorods Using Self-Assembled DNA−Membrane Complexes Hongjun Liang, Thomas E. Angelini, Paul V. Braun, and Gerard C. L. Wong pp 14157–14165 DOI: 10.1021/ja046718m

Organotellurium(VI) Azides and Halides Thomas M. Klapötke, Burkhard Krumm, Kurt Polborn, and Ingo Schwab pp 14166–14175 DOI: 10.1021/ja046637q Supporting Info

A Combined Experimental and Computational Study of Dihydrido(phosphinooxazoline)iridium Complexes Clément Mazet, Sebastian P. Smidt, Markus Meuwly, and Andreas Pfaltz pp 14176–14181 DOI: 10.1021/ja046318z Supporting Info

Oscillation of Conductance in Molecular Junctions of Carbon Ladder Compounds Tomofumi Tada, Daijiro Nozaki, Masakazu Kondo, Shinya Hamayama, and Kazunari Yoshizawa pp 14182–14189 DOI: 10.1021/ja031736+ Supporting Info

Calculation of trans-Hydrogen-Bond 13C−15N Three-Bond and Other Scalar J-Couplings in Cooperative Peptide Models. A Density Functional Theory Study Pedro Salvador, Nadya Kobko, Robert Wieczorek, and J. J. Dannenberg pp 14190–14197 DOI: 10.1021/ja0492788 Supporting Info

Comparison of Fully Optimized α- and 310-Helices with Extended β-Strands. An ONIOM Density Functional Theory Study Robert Wieczorek and J. J. Dannenberg pp 14198–14205 DOI: 10.1021/ja048831i Supporting Info

Perturbations by Phenyl on the 1,5-Hydrogen Shift in 1,3(Z)-Pentadiene. Another Chameleonic Transition Region? William von E. Doering, Edmund J. Keliher, and Xin Zhao pp 14206–14216 DOI: 10.1021/ja040106k Supporting Info

Effects of Benzyl Ether Type Dendrons as Hole-Harvesting Antennas, and Shielding for the Neutralization of Stilbene Core Radical Cations with Chloride Ion during Two-Photon Ionization of Stilbene Dendrimers Having Stilbene Core and Benzyl Ether Type Dendrons Michihiro Hara, Shingo Samori, Xichen Cai, Sachiko Tojo, Tatsuo Arai, Atsuya Momotake, Junpei Hayakawa, Mayuko Uda, Kiyohiko Kawai, Masayuki Endo, Mamoru Fujitsuka, and Tetsuro Majima pp 14217–14223 DOI: 10.1021/ja046650a

Factors Controlling the Complex Architecture of Native and Modified Cyclodextrins with Dipeptide (Z-Glu-Tyr) Studied by Microcalorimetry and NMR Spectroscopy:  Critical Effects of Peripheral Bis-trimethylamination and Cavity Size Hatsuo Yamamura, Mikhail V. Rekharsky, Yoko Ishihara, Masao Kawai, and Yoshihisa Inoue pp 14224–14233 DOI: 10.1021/ja046612r Supporting Info

Adsorption-Induced Asymmetric Assembly from an Achiral Adsorbate Yuguang Cai and Steven L. Bernasek pp 14234–14238 DOI: 10.1021/ja045769g

Carbon Monoxide as an Intrinsic Ligand to Iron in the Active Site of the Iron−Sulfur-Cluster-Free Hydrogenase H2-Forming Methylenetetrahydromethanopterin Dehydrogenase As Revealed by Infrared Spectroscopy Erica J. Lyon, Seigo Shima, Reinhard Boecher, Rudolf K. Thauer, Friedrich-Wilhelm Grevels, Eckhard Bill, Winfried Roseboom, and Simon P. J. Albracht pp 14239–14248 DOI: 10.1021/ja046818s

Effect of Weak Interactions on the H···H Distance in Stretched Dihydrogen Complexes Dmitry G. Gusev pp 14249–14257 DOI: 10.1021/ja0465956 Supporting Info

Epitope Mapping and Competitive Binding of HSA Drug Site II Ligands by NMR Diffusion Measurements Laura H. Lucas, Kristin E. Price, and Cynthia K. Larive pp 14258–14266 DOI: 10.1021/ja0479538 Supporting Info

Importance of Structural Tightening, as Opposed to Partially Bound States, in the Determination of Chemical Shift Changes at Noncovalently Bonded Interfaces Dudley H. Williams, Nichola L. Davies, and Jari J. Koivisto pp 14267–14272 DOI: 10.1021/ja047198y Supporting Info

Direct Sticking and Differential Adsorption Heats as Probes of Structural Transitions:  O2 on the Stepped Ni{211} Surface Andrew D. Karmazyn, Vittorio Fiorin, and David A. King pp 14273–14277 DOI: 10.1021/ja047165i

Computer Simulation of Solid and Liquid Benzene with an Atomistic Interaction Potential Derived from ab Initio Calculations Ivo Cacelli, Giorgio Cinacchi, Giacomo Prampolini, and Alessandro Tani pp 14278–14286 DOI: 10.1021/ja046642u

Length-Dependent Transport in Molecular Junctions Based on SAMs of Alkanethiols and Alkanedithiols:  Effect of Metal Work Function and Applied Bias on Tunneling Efficiency and Contact Resistance Vincent B. Engelkes, Jeremy M. Beebe, and C. Daniel Frisbie pp 14287–14296 DOI: 10.1021/ja046274u

Light-Mediated C−C σ-Bond Driven Crystallization of a Phenalenyl Radical Dimer Puhong Liao, Mikhail E. Itkis, Richard T. Oakley, Fook S. Tham, and Robert C. Haddon pp 14297–14302 DOI: 10.1021/ja046243z Supporting Info

Issue 44

Dioxygenation of Human Serum Albumin Having a Prosthetic Heme Group in a Tailor-Made Heme Pocket Teruyuki Komatsu, Naomi Ohmichi, Patricia A. Zunszain, Stephen Curry, and Eishun Tsuchida pp 14304–14305 DOI: 10.1021/ja046022t Supporting Info

A Genetically Encoded Photocaged Amino Acid Ning Wu, Alexander Deiters, T. Ashton Cropp, David King, and Peter G. Schultz pp 14306–14307 DOI: 10.1021/ja040175z Supporting Info

Rationally Designed Ligands for Asymmetric Iridium-Catalyzed Hydrogenation of Olefins Klas Källström, Christian Hedberg, Peter Brandt, Annette Bayer, and Pher G. Andersson pp 14308–14309 DOI: 10.1021/ja0464241 Supporting Info

Fluorescence Lifetimes and Emission Patterns Probe the 3D Orientation of the Emitting Chromophore in a Multichromophoric System Wouter Schroeyers, Renaud Vallée, Digambara Patra, Johan Hofkens, Satoshi Habuchi, Tom Vosch, Mircea Cotlet, Klaus Müllen, Jörg Enderlein, and Frans C. De Schryver pp 14310–14311 DOI: 10.1021/ja0474603 Supporting Info

Banana-Shaped Liquid Crystals with Two Oligosiloxane End-Groups:  Field-Induced Switching of Supramolecular Chirality Christina Keith, R. Amaranatha Reddy, Ute Baumeister, and Carsten Tschierske pp 14312–14313 DOI: 10.1021/ja046138p Supporting Info

3,3,3-Trichloropropyl-1-triphenylphosphorane:  A Reagent for the Synthesis of (Z)-1,3-Enynes, (Z,Z)-1-Chloro-1,3-dienes, and 1,3-Diynes Maheswaran S. Karatholuvhu and Philip L. Fuchs pp 14314–14315 DOI: 10.1021/ja045112v Supporting Info

Halide-Induced Supramolecular Ligand Rearrangement Aaron M. Brown, Maxim V. Ovchinnikov, Charlotte L. Stern, and Chad A. Mirkin pp 14316–14317 DOI: 10.1021/ja045316b Supporting Info

Photochemical Attachment of Organic Monolayers onto H-Terminated Si(111):  Radical Chain Propagation Observed via STM Studies Brian J. Eves, Qiao-Yu Sun, Gregory P. Lopinski, and Han Zuilhof pp 14318–14319 DOI: 10.1021/ja045777x

Absorption and Fluorescence Spectra of Uracil in the Gas Phase and in Aqueous Solution:  A TD-DFT Quantum Mechanical Study Roberto Improta and Vincenzo Barone pp 14320–14321 DOI: 10.1021/ja0460561 Supporting Info

Studying Nanoparticle-Induced Structural Changes within Fatty Acid Multilayer Films Using Sum Frequency Generation Vibrational Spectroscopy Jasper Holman, Shen Ye, David J. Neivandt, and Paul B. Davies pp 14322–14323 DOI: 10.1021/ja046954x Supporting Info

Zeolite Nanoclusters Coated onto the Mesopore Walls of SBA-15 Trong-On Do, Andrei Nossov, Marie-Anne Springuel-Huet, Celine Schneider, Jeremy L. Bretherton, Colin A. Fyfe, and Serge Kaliaguine pp 14324–14325 DOI: 10.1021/ja0462124 Supporting Info

On the Origin of Dinitrogen Hydrogenation Promoted by [(η5-C5Me4H)2Zr]2(μ2,η2,η2-N2) Jaime A. Pool, Wesley H. Bernskoetter, and Paul J. Chirik pp 14326–14327 DOI: 10.1021/ja045566s Supporting Info

Synthesis and Single-Molecule Studies of a Well-Defined Biomimetic Modular Multidomain Polymer Using a Peptidomimetic β-Sheet Module Jason T. Roland and Zhibin Guan pp 14328–14329 DOI: 10.1021/ja0448871 Supporting Info

The Effect of Molecular Crowding with Nucleotide Length and Cosolute Structure on DNA Duplex Stability Shu-ichi Nakano, Hisae Karimata, Tatsuo Ohmichi, Junji Kawakami, and Naoki Sugimoto pp 14330–14331 DOI: 10.1021/ja0463029 Supporting Info

DFT Prediction and Experimental Observation of Substrate-Induced Catalyst Decomposition in Ruthenium-Catalyzed Olefin Metathesis Werner Janse van Rensburg, Petrus J. Steynberg, Wolfgang H. Meyer, Megan M. Kirk, and Grant S. Forman pp 14332–14333 DOI: 10.1021/ja0453174 Supporting Info

Large Structural Modification with Conserved Conformation:  Analysis of Δ3-Fused Aryl Prolines in Model β-Turns Guillaume Jeannotte and William D. Lubell pp 14334–14335 DOI: 10.1021/ja0471222 Supporting Info

One-Pot Synthesis of High-Quality Zinc-Blende CdS Nanocrystals Y. Charles Cao and Jianhui Wang pp 14336–14337 DOI: 10.1021/ja0459678 Supporting Info

Three-Component Coupling Based on the “Cation Pool” Method Seiji Suga, Tomoaki Nishida, Daisuke Yamada, Aiichiro Nagaki, and Jun-ichi Yoshida pp 14338–14339 DOI: 10.1021/ja0455704 Supporting Info

Versatile Organic (Fullerene)−Inorganic (CdTe Nanoparticle) Nanoensembles Dirk M. Guldi, Israel Zilbermann, Greg Anderson, Nicholas A Kotov, Nikos Tagmatarchis, and Maurizio Prato pp 14340–14341 DOI: 10.1021/ja048065f Supporting Info

Preparation of Benzolactams by Pd(OAc)2-Catalyzed Direct Aromatic Carbonylation Kazuhiko Orito, Akiyoshi Horibata, Takatoshi Nakamura, Harumi Ushito, Hideo Nagasaki, Motoki Yuguchi, Satoshi Yamashita, and Masao Tokuda pp 14342–14343 DOI: 10.1021/ja045342+ Supporting Info

Sequential Coupling of Zincated Hydrazone, Alkenylboronate, and Electrophile That Creates Several Contiguous Stereogenic Centers Masaharu Nakamura, Takuji Hatakeyama, Kenji Hara, Hiroki Fukudome, and Eiichi Nakamura pp 14344–14345 DOI: 10.1021/ja044878s Supporting Info

Enhanced Catalytic Activity of Hemoglobin in Organic Solvents by Layered Titanate Immobilization Qigang Wang, Qiuming Gao, and Jianlin Shi pp 14346–14347 DOI: 10.1021/ja047224s Supporting Info

Simple Synthesis Route to Monodispersed SBA-15 Silica Rods Abdelhamid Sayari, Bao-Hang Han, and Yong Yang pp 14348–14349 DOI: 10.1021/ja0478734 Supporting Info

Dissolution and Regeneration of Bombyx mori Silk Fibroin Using Ionic Liquids David M. Phillips, Lawrence F. Drummy, Deborah G. Conrady, Douglas M. Fox, Rajesh R. Naik, Morley O. Stone, Paul C. Trulove, Hugh C. De Long, and Robert A. Mantz pp 14350–14351 DOI: 10.1021/ja046079f

Identification and Characterization of Monoanionic Tripodal Tetradentate Ligand Complexes of Copper(I) and Copper(II) Involved in Halogen Atom Transfer Reactions Jocelyn M. Goodwin, Marilyn M. Olmstead, and Timothy E. Patten pp 14352–14353 DOI: 10.1021/ja045003g Supporting Info

Specific Synthesis of 1,2- and 1,3-Dialkylidenecycloheptanes by [3+2+2] Cyclization of Alkenyl Fischer Carbene Complexes and Allenes José Barluenga, Rubén Vicente, Pablo Barrio, Luis A. López, Miguel Tomás, and Javier Borge pp 14354–14355 DOI: 10.1021/ja045459y Supporting Info

Vibration−Rotation Emission Spectra of Gaseous ZnH2 and ZnD2 Alireza Shayesteh, Dominique R. T. Appadoo, Iouli E. Gordon, and Peter F. Bernath pp 14356–14357 DOI: 10.1021/ja046050b

Total Synthesis of (±)-Jiadifenin, a Non-peptidyl Neurotrophic Modulator Young Shin Cho, David A. Carcache, Yuan Tian, Yue-Ming Li, and Samuel J. Danishefsky pp 14358–14359 DOI: 10.1021/ja045939p Supporting Info

Highly Stereo- and Regioselective Ni-Catalyzed Homoallylation of Aldimines with Conjugated Dienes Promoted by Diethylzinc Masanari Kimura, Atsuko Miyachi, Keisuke Kojima, Shuji Tanaka, and Yoshinao Tamaru pp 14360–14361 DOI: 10.1021/ja0450354 Supporting Info

Drug Binding Revealed by Tandem Mass Spectrometry of a Protein−Micelle Complex Leopold L. Ilag, Iban Ubarretxena-Belandia, Christopher G. Tate, and Carol V. Robinson pp 14362–14363 DOI: 10.1021/ja0450307 Supporting Info

Energy Transfer Rates and Pathways of Single Donor Chromophores in a Multichromophoric Dendrimer Built around a Central Acceptor Core Rémi Métivier, Florian Kulzer, Tanja Weil, Klaus Müllen, and Thomas Basché pp 14364–14365 DOI: 10.1021/ja047996o

Controlling Photochemistry with Distinct Hydrophobic Nanoenvironments Lakshmi S. Kaanumalle, Corinne L. D. Gibb, Bruce C. Gibb, and V. Ramamurthy pp 14366–14367 DOI: 10.1021/ja0450197 Supporting Info

Unidirectionally Aligned Copper Hydroxide Crystalline Nanorods from Two-Dimensional Copper Hydroxy Nitrate Seong-Hun Park and Hae Jin Kim pp 14368–14369 DOI: 10.1021/ja047425w Supporting Info

N-Heterocyclic Carbene-Catalyzed Generation of Homoenolates:  γ-Butyrolactones by Direct Annulations of Enals and Aldehydes Stephanie S. Sohn, Evelyn L. Rosen, and Jeffrey W. Bode pp 14370–14371 DOI: 10.1021/ja044714b Supporting Info

Crystal Orientation-Ordered ZnS Nanowire Bundles Daniel F. Moore, Yong Ding, and Zhong Lin Wang pp 14372–14373 DOI: 10.1021/ja0451057 Supporting Info

Total Synthesis of Brevetoxin-B Goh Matsuo, Koji Kawamura, Nobuyuki Hori, Hiroko Matsukura, and Tadashi Nakata pp 14374–14376 DOI: 10.1021/ja0449269 Supporting Info

Mass Spectrometry Assisted Assignment of NMR Resonances in 15N Labeled Proteins Lianmei Feng, Ron Orlando, and James H. Prestegard pp 14377–14379 DOI: 10.1021/ja0457664 Supporting Info

Deciphering the Origins of Observed Heat Capacity Changes for Aminoglycoside Binding to Prokaryotic and Eukaryotic Ribosomal RNA A-Sites:  A Calorimetric, Computational, and Osmotic Stress Study Christopher M. Barbieri, Annankoil R. Srinivasan, and Daniel S. Pilch pp 14380–14388 DOI: 10.1021/ja0457516 Supporting Info

Spectroscopic Identification of Different Types of Copper Centers Generated in Synthetic Four-Helix Bundle Proteins Robert Schnepf, Wolfgang Haehnel, Karl Wieghardt, and Peter Hildebrandt pp 14389–14399 DOI: 10.1021/ja0484294

Interactions of Alkyltin Salts with Biological Dithiols:  Dealkylation and Induction of a Regular β-Turn Structure in Peptides Bethany A. Buck, Alessandro Mascioni, Christopher J. Cramer, and Gianluigi Veglia pp 14400–14410 DOI: 10.1021/ja046093s Supporting Info

Artificial Metalloenzymes:  (Strept)avidin as Host for Enantioselective Hydrogenation by Achiral Biotinylated Rhodium−Diphosphine Complexes Myriem Skander, Nicolas Humbert, Jérôme Collot, Julieta Gradinaru, Gérard Klein, Andreas Loosli, Jérôme Sauser, Andrea Zocchi, François Gilardoni, and Thomas R. Ward pp 14411–14418 DOI: 10.1021/ja0476718 Supporting Info

Optimization of Interstrand Hydrophobic Packing Interactions within Unnatural DNA Base Pairs Shigeo Matsuda and Floyd E. Romesberg pp 14419–14427 DOI: 10.1021/ja047291m Supporting Info

The Structure of Ba@C74 Andreas Reich, Martin Panthöfer, Hartwig Modrow, Ulrich Wedig, and Martin Jansen pp 14428–14434 DOI: 10.1021/ja0401693 Supporting Info

Developing Photoactive Affinity Probes for Proteomic Profiling:  Hydroxamate-based Probes for Metalloproteases Elaine W. S. Chan, Souvik Chattopadhaya, Resmi C. Panicker, Xuan Huang, and Shao Q. Yao pp 14435–14446 DOI: 10.1021/ja047044i Supporting Info

Strand Orientation by Steric Matching:  A Designed Antiparallel Coiled-Coil Trimer Nathan A. Schnarr and Alan J. Kennan pp 14447–14451 DOI: 10.1021/ja047496v Supporting Info

Synthesis, Self-Assembly, and Characterization of Supramolecular Polymers from Electroactive Dendron Rodcoil Molecules Benjamin W. Messmore, James F. Hulvat, Eli D. Sone, and Samuel I. Stupp pp 14452–14458 DOI: 10.1021/ja049325w Supporting Info

Simulated Evolution of Emergent Chiral Structures in Polyalanine Vikas Nanda and William F. DeGrado pp 14459–14467 DOI: 10.1021/ja0461825

Bimolecular Homolytic Substitution (SH2) Reactions with Hydrogen Atoms. Time-Resolved Electron Spin Resonance Detection in the Pulse Radiolysis of α-(Methylthio)acetamide Pawel Wisniowski, Krzysztof Bobrowski, Ian Carmichael, and Gordon L. Hug pp 14468–14474 DOI: 10.1021/ja0458625

Palladium- and Copper-Catalyzed Synthesis of Medium- and Large-Sized Ring-Fused Dihydroazaphenanthrenes and 1,4-Benzodiazepine-2,5-diones. Control of Reaction Pathway by Metal-Switching Guylaine Cuny, Michèle Bois-Choussy, and Jieping Zhu pp 14475–14484 DOI: 10.1021/ja047472o Supporting Info

Detection of Transient Radical Cations in Electron Transfer-Initiated Diels−Alder Reactions by Electrospray Ionization Mass Spectrometry Sven Fürmeier and Jürgen O. Metzger pp 14485–14492 DOI: 10.1021/ja046157z Supporting Info

Spirocyclic Zwitterionic λ5Si-Silicates with Two Bidentate Ligands Derived from α-Amino Acids or α-Hydroxycarboxylic Acids:  Synthesis, Structure, and Stereodynamics Reinhold Tacke, Rüdiger Bertermann, Christian Burschka, Simona Dragota, Martin Penka, and Ingo Richter pp 14493–14505 DOI: 10.1021/ja047248z Supporting Info

Evidence for Through-Space Electron Transfer in the Distance Dependence of Normal and Inverted Electron Transfer in Oligoproline Arrays Scafford A. Serron, W. Stephen Aldridge III, Cavan N. Fleming, Ryan M. Danell, Mu-Hyun Baik, Milan Sykora, Dana M. Dattelbaum, and Thomas J. Meyer pp 14506–14514 DOI: 10.1021/ja030659f Supporting Info

Dihydrogen and Methane Elimination from Adducts Formed by the Interaction of Carbenium and Silylium Cations with Nucleophiles Igor S. Ignatyev and Henry F. Schaefer III pp 14515–14526 DOI: 10.1021/ja040127e

A Spectroscopic Investigation of Carbon−Carbon Bond Formation by Methylene Insertion on a Ag(111) Surface:  Mechanism and Kinetics Weixin Huang and John M. White pp 14527–14532 DOI: 10.1021/ja047423b

Structure, Reactivity, and Density Functional Theory Analysis of the Six-Electron Reductant, [(C5Me5)2U]2(μ-η6:η6-C6H6), Synthesized via a New Mode of (C5Me5)3M Reactivity William J. Evans, Stosh A. Kozimor, Joseph W. Ziller, and Nikolas Kaltsoyannis pp 14533–14547 DOI: 10.1021/ja0463886 Supporting Info

Envisaging the Physicochemical Processes during the Preparation of Supported Catalysts:  Raman Microscopy on the Impregnation of Mo onto Al2O3 Extrudates Jaap A. Bergwerff, Tom Visser, Bob R. G. Leliveld, Brenda D. Rossenaar, Krijn P. de Jong, and Bert M. Weckhuysen pp 14548–14556 DOI: 10.1021/ja040107c

Noncovalent Anchoring of Homogeneous Catalysts to Silica Supports with Well-Defined Binding Sites Ruifang Chen, Raymond P. J. Bronger, Paul C. J. Kamer, Piet W. N. M. van Leeuwen, and Joost N. H. Reek pp 14557–14566 DOI: 10.1021/ja046956h

Concomitant Length and Diameter Separation of Single-Walled Carbon Nanotubes Daniel A. Heller, Rebecca M. Mayrhofer, Seunghyun Baik, Yelena V. Grinkova, Monica L. Usrey, and Michael S. Strano pp 14567–14573 DOI: 10.1021/ja046450z Supporting Info

Expanding Dinitrogen Reduction Chemistry to Trivalent Lanthanides via the LnZ3/Alkali Metal Reduction System:  Evaluation of the Generality of Forming Ln2(μ-η2:η2-N2) Complexes via LnZ3/K William J. Evans, David S. Lee, Daniel B. Rego, Jeremy M. Perotti, Stosh A. Kozimor, Ericka K. Moore, and Joseph W. Ziller pp 14574–14582 DOI: 10.1021/ja046047s Supporting Info

Magnetic, Electronic, and Structural Characterization of Nonstoichiometric Iron Oxides at the Nanoscale Franz X. Redl, Charles T. Black, Georgia C. Papaefthymiou, Robert L. Sandstrom, Ming Yin, Hao Zeng, Christopher B. Murray, and Stephen P. O'Brien pp 14583–14599 DOI: 10.1021/ja046808r Supporting Info

Cation−π Interactions:  Structures and Energetics of Complexation of Na+ and K+ with the Aromatic Amino Acids, Phenylalanine, Tyrosine, and Tryptophan Chunhai Ruan and M. T. Rodgers pp 14600–14610 DOI: 10.1021/ja048297e Supporting Info

On the Competition between Linear and Cyclic Isomers in Second-Row Dicarbides Antonio Largo, Pilar Redondo, and Carmen Barrientos pp 14611–14619 DOI: 10.1021/ja046017p

Interfacial Electron-Transfer Kinetics of Ferrocene through Oligophenyleneethynylene Bridges Attached to Gold Electrodes as Constituents of Self-Assembled Monolayers:  Observation of a Nonmonotonic Distance Dependence John F. Smalley, Sandra B. Sachs, Christopher E. D. Chidsey, Stephen P. Dudek, Hadley D. Sikes, Stephen E. Creager, C. J. Yu, Stephen W. Feldberg, and Marshall D. Newton pp 14620–14630 DOI: 10.1021/ja047458b

Theoretical Studies on the Deacylation Step of Serine Protease Catalysis in the Gas Phase, in Solution, and in Elastase Maya Topf and W. Graham Richards pp 14631–14641 DOI: 10.1021/ja047010a

Theoretical Study of the Guanine → 6-Thioguanine Substitution in Duplexes, Triplexes, and Tetraplexes Nad'a Špaková, Elena Cubero, Jiří Šponer, and Modesto Orozco pp 14642–14650 DOI: 10.1021/ja0468628 Supporting Info

Predicting 9Be Nuclear Magnetic Resonance Chemical Shielding Tensors Utilizing Density Functional Theory Paul G. Plieger, Kevin D. John, Timothy S. Keizer, T. Mark McCleskey, Anthony K. Burrell, and Richard L. Martin pp 14651–14658 DOI: 10.1021/ja046712x Supporting Info

Opening Mechanism of G·T/U Pairs in DNA and RNA Duplexes:  A Combined Study of Imino Proton Exchange and Molecular Dynamics Simulation Péter Várnai, Muriel Canalia, and Jean-Louis Leroy pp 14659–14667 DOI: 10.1021/ja0470721

Key Role of Electrostatic Interactions in Bacteriorhodopsin Proton Transfer Ana-Nicoleta Bondar, Stefan Fischer, Jeremy C. Smith, Marcus Elstner, and Sándor Suhai pp 14668–14677 DOI: 10.1021/ja047982i

Elemental Sulfur and Sulfur-Rich Compounds II. Topics in Current Chemistry, 231 Edited by Ralf Steudel (Technische Universität Berlin). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. x + 248 pp. $229.00. ISBN 3-540-40378-7. Pavel Afanasiev p 14678 DOI: 10.1021/ja0409199

Chemometrics in Analytical Spectroscopy, 2nd ed By Mike J. Adams (RMIT University, Melbourne, Australia). Royal Society of Chemistry:  Cambridge. 2004. xi + 224 pp. $229.00. ISBN 0-85404-595-3. Mark A. Arnold pp 14678–14679 DOI: 10.1021/ja040928h

Nanostructures and Nanomaterials:  Synthesis, Properties and Applications By Guozhang Cao (University of Washington). Imperial College Press (distributed by World Scientific):  London. 2004. xiv + 434 pp. $78.00. ISBN 1-86094-415-9. Stephanie L. Brock p 14679 DOI: 10.1021/ja0409457

Modern Trends in Chemical Reaction Dynamics:  Experiment and Theory (Part I). Advanced Series in Physical Chemistry, Volume 14 Edited by Xueming Yang and Kopin Liu (Academia Sinica, Taiwan). World Scientific Publishing Co. Pte. Ltd:  Singapore, River Edge, NJ, London. 2004. xii + 638 pp. $98.00. ISBN 981-238-568-1. C. Patrick Collier pp 14679–14680 DOI: 10.1021/ja0409560

Chiral Pollutants:  Distribution, Toxicity and Analysis by Chromatography and Capillary Electrophoresis By Imran Ali (National Institute of Hydrology, Roorkee, India) and Hassan Y. Aboul-Enein (King Faisal Specialist Hospital, Riyadh, Saudi Arabia). John Wiley & Sons:  Chichester, U.K. 2004. xx + 344 pp. $175.00. ISBN 0-470-86780-9. Marianna Anderson Busch p 14680 DOI: 10.1021/ja040952v

Issue 45

Catalytic Signal Amplification Using a Heck Reaction. An Example in the Fluorescence Sensing of Cu(II) Qiaoyin Wu and Eric V. Anslyn pp 14682–14683 DOI: 10.1021/ja0401038 Supporting Info

Complete Thermal-Unfolding Profiles of Oxidized and Reduced Cytochromes c Susumu Uchiyama, Atsushi Ohshima, Shota Nakamura, Jun Hasegawa, Norifumi Terui, Shin-ichi Joseph Takayama, Yasuhiko Yamamoto, Yoshihiro Sambongi, and Yuji Kobayashi pp 14684–14685 DOI: 10.1021/ja046667t Supporting Info

Two-State Folding Observed in Individual Protein Molecules Elizabeth Rhoades, Mati Cohen, Benjamin Schuler, and Gilad Haran pp 14686–14687 DOI: 10.1021/ja046209k Supporting Info

Dinitrogen Activation by Titanium Sandwich Complexes Tamara E. Hanna, Emil Lobkovsky, and Paul J. Chirik pp 14688–14689 DOI: 10.1021/ja045884r Supporting Info

Stretched Poly(dimethylsiloxane) Gels as NMR Alignment Media for Apolar and Weakly Polar Organic Solvents:  An Ideal Tool for Measuring RDCs at Low Molecular Concentrations J. Christoph Freudenberger, Peter Spiteller, Reinhard Bauer, Horst Kessler, and Burkhard Luy pp 14690–14691 DOI: 10.1021/ja046155e Supporting Info

Bistability and the Phase Transition in 1,3,2-Dithiazolo[4,5-b]pyrazin-2-yl Jaclyn L. Brusso, Owen P. Clements, Robert C. Haddon, Mikhail E. Itkis, Alicea A. Leitch, Richard T. Oakley, Robert W. Reed, and John F. Richardson pp 14692–14693 DOI: 10.1021/ja044979q Supporting Info

Not Ions Alone:  Barriers to Ion Permeation in Nanopores and Channels Oliver Beckstein, Kaihsu Tai, and Mark S. P. Sansom pp 14694–14695 DOI: 10.1021/ja045271e Supporting Info

In Situ Dual-Beam Coincidence Second Harmonic Generation as a Probe of Spatially Resolved Dynamics at Electrochemical Interfaces Boguslaw Pozniak and Daniel A. Scherson pp 14696–14697 DOI: 10.1021/ja046809j

OMP Decarboxylase:  An Experimental Test of Electrostatic Destabilization of the Enzyme−Substrate Complex Brian P. Callahan and Richard Wolfenden pp 14698–14699 DOI: 10.1021/ja0450049

Formation of Benzynes from 2,6-Dihaloaryllithiums:  Mechanistic Basis of the Regioselectivity Antonio Ramírez, John Candler, Crystal G. Bashore, Michael C. Wirtz, Jotham W. Coe, and David B. Collum pp 14700–14701 DOI: 10.1021/ja044899m Supporting Info

Cation Pool-Initiated Controlled/Living Polymerization Using Microsystems Aiichiro Nagaki, Kohsuke Kawamura, Seiji Suga, Tsuyoshi Ando, Mitsuo Sawamoto, and Jun-ichi Yoshida pp 14702–14703 DOI: 10.1021/ja044879k Supporting Info

Nickel(II)-Catalyzed Highly Enantioselective Hydrophosphination of Methacrylonitrile Aaron D. Sadow, Isabelle Haller, Luca Fadini, and Antonio Togni pp 14704–14705 DOI: 10.1021/ja0449574 Supporting Info

Molecule-Bridged Mixed-Valent Intermediates Involving the RuI Oxidation State Biprajit Sarkar, Wolfgang Kaim, Jan Fiedler, and Carole Duboc pp 14706–14707 DOI: 10.1021/ja046397e Supporting Info

Ordered Mesoporous Ceramics Stable up to 1500 °C from Diblock Copolymer Mesophases Marleen Kamperman, Carlos B. W. Garcia, Phong Du, Hooisweng Ow, and Ulrich Wiesner pp 14708–14709 DOI: 10.1021/ja046795h

Acidity of Secondary Hydroxyls in ATP and Adenosine Analogues and the Question of a 2‘,3‘-Hydrogen Bond in Ribonucleosides Hans Åström, Ethel Limén, and Roger Strömberg pp 14710–14711 DOI: 10.1021/ja0477468 Supporting Info

Ethylene Tetramerization:  A New Route to Produce 1-Octene in Exceptionally High Selectivities Annette Bollmann, Kevin Blann, John T. Dixon, Fiona M. Hess, Esna Killian, Hulisani Maumela, David S. McGuinness, David H. Morgan, Arno Neveling, Stefanus Otto, Matthew Overett, Alexandra M. Z. Slawin, Peter Wasserscheid, and Sven Kuhlmann pp 14712–14713 DOI: 10.1021/ja045602n Supporting Info

Structural Models of the Bimetallic Subunit at the A-Cluster of Acetyl Coenzyme A Synthase/CO Dehydrogenase:  Binuclear Sulfur-Bridged Ni−Cu and Ni−Ni Complexes and Their Reactions with CO Todd C. Harrop, Marilyn M. Olmstead, and Pradip K. Mascharak pp 14714–14715 DOI: 10.1021/ja045284s Supporting Info

Design of Catalytic Carbonylative Polymerizations of Heterocycles. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s Guosheng Liu and Li Jia pp 14716–14717 DOI: 10.1021/ja0454182 Supporting Info

Bromoporphyrins as Versatile Synthons for Modular Construction of Chiral Porphyrins:  Cobalt-Catalyzed Highly Enantioselective and Diastereoselective Cyclopropanation Ying Chen, Kimberly B. Fields, and X. Peter Zhang pp 14718–14719 DOI: 10.1021/ja044889l Supporting Info

Total Synthesis of Kendomycin:  A Macro−C−Glycosidation Approach Yu Yuan, Hongbin Men, and Chulbom Lee pp 14720–14721 DOI: 10.1021/ja0447154 Supporting Info

A Trimeric HIV-1 Fusion Peptide Construct Which Does Not Self-Associate in Aqueous Solution and Which Has 15-Fold Higher Membrane Fusion Rate Rong Yang, Mary Prorok, Francis J. Castellino, and David P. Weliky pp 14722–14723 DOI: 10.1021/ja045612o Supporting Info

Enantioselective Formal Hydration of α,β-Unsaturated Imides by Al-Catalyzed Conjugate Addition of Oxime Nucleophiles Christopher D. Vanderwal and Eric N. Jacobsen pp 14724–14725 DOI: 10.1021/ja045563f Supporting Info

Gas-Phase IR Spectroscopy of Anionic Iron Carbonyl Clusters David T. Moore, Jos Oomens, John R. Eyler, Gerard Meijer, Gert von Helden, and Douglas P. Ridge pp 14726–14727 DOI: 10.1021/ja0449527 Supporting Info

Tuning the DNA Reactivity of cis-Platinum:  Conjugation to a Mismatch-Specific Metallointercalator Anne Petitjean and Jacqueline K. Barton pp 14728–14729 DOI: 10.1021/ja047235l Supporting Info

Chemoselective Attachment of Biologically Active Proteins to Surfaces by Expressed Protein Ligation and Its Application for “Protein Chip” Fabrication Julio A. Camarero, Youngeun Kwon, and Matthew A. Coleman pp 14730–14731 DOI: 10.1021/ja0456611 Supporting Info

Photostimulated Hole Transport through a DNA Duplex Immobilized on a Gold Electrode Akimitsu Okamoto, Taku Kamei, Kazuo Tanaka, and Isao Saito pp 14732–14733 DOI: 10.1021/ja0449067 Supporting Info

Effects of H2O and D2O on Polyproline II Helical Structure Brian W. Chellgren and Trevor P. Creamer pp 14734–14735 DOI: 10.1021/ja045425q

Enantioselective Sensing of Chiral Carboxylic Acids Xuefeng Mei and Christian Wolf pp 14736–14737 DOI: 10.1021/ja0459781 Supporting Info

Formation of a Supramolecular Hyperbranched Polymer from Self-Organization of an AB2 Monomer Containing a Crown Ether and Two Paraquat Moieties Feihe Huang and Harry W. Gibson pp 14738–14739 DOI: 10.1021/ja044830e Supporting Info

Relationship of Stereochemical and Skeletal Diversity of Small Molecules to Cellular Measurement Space Young-kwon Kim, Midori A. Arai, Takayoshi Arai, Julia O. Lamenzo, Elton F. Dean, III, Nick Patterson, Paul A. Clemons, and Stuart L. Schreiber pp 14740–14745 DOI: 10.1021/ja048170p Supporting Info

Probing Molecular Interfaces Using 2D Magic-Angle-Spinning NMR on Protein Mixtures with Different Uniform Labeling Manuel Etzkorn, Anja Böckmann, Adam Lange, and Marc Baldus, pp 14746–14751 DOI: 10.1021/ja0479181 Supporting Info

Kinetic Studies of AMP-Dependent Phosphorolysis of Amylopectin Catalyzed by Phosphorylase b on a 27 MHz Quartz-Crystal Microbalance Hidekazu Nishino, Akiko Murakawa, Toshiaki Mori, and Yoshio Okahata pp 14752–14757 DOI: 10.1021/ja046583k

HIV Fusion Inhibitor Peptide T-1249 Is Able To Insert or Adsorb to Lipidic Bilayers. Putative Correlation with Improved Efficiency A. Salomé Veiga, Nuno C. Santos, Luís M. S. Loura, Aleksandre Fedorov, and Miguel A. R. B. Castanho pp 14758–14763 DOI: 10.1021/ja0459882 Supporting Info

Dynamics and Mechanisms of the Multiphoton Gated Photochromic Reaction of Diarylethene Derivatives Masataka Murakami, Hiroshi Miyasaka, Tadashi Okada, Seiya Kobatake, and Masahiro Irie pp 14764–14772 DOI: 10.1021/ja049177+

Recognition-Induced Transformation of Microspheres into Vesicles:  Morphology and Size Control Oktay Uzun, Amitav Sanyal, Hiroshi Nakade, Raymond J. Thibault, and Vincent M. Rotello pp 14773–14777 DOI: 10.1021/ja047643p Supporting Info

Crankshaft Motion in a Highly Congested Bis(triarylmethyl)peroxide Tinh-Alfredo V. Khuong, Gerardo Zepeda, Carlos N. Sanrame, Hung Dang, Michael D. Bartberger, K. N. Houk, and Miguel A. Garcia-Garibay pp 14778–14786 DOI: 10.1021/ja046987c Supporting Info

Why Are Proton Transfers at Carbon Slow? Self-Exchange Reactions Cyrille Costentin and Jean-Michel Savéant pp 14787–14795 DOI: 10.1021/ja046467h Supporting Info

The Mechanism of Aluminum-Catalyzed Meerwein−Schmidt−Ponndorf−Verley Reduction of Carbonyls to Alcohols Revital Cohen, Christopher R. Graves, SonBinh T. Nguyen, Jan M. L. Martin, and Mark A. Ratner pp 14796–14803 DOI: 10.1021/ja047613m Supporting Info

Synthesis and Reactivity of the Hydrido- and Alkylrhenium Methylidene Complexes Cp*(PMe3)2(R)ReCH2 (R = H, CH3) Jennifer R. Krumper, Richard L. Martin, P. Jeffrey Hay, Cathleen M. Yung, John Veltheer, and Robert G. Bergman pp 14804–14815 DOI: 10.1021/ja0468877 Supporting Info

Perfect Orientation Ordered in-Situ One-Dimensional Self-Assembly of Mn-Doped PbSe Nanocrystals Weigang Lu, Puxian Gao, Wen Bin Jian, Zhong Lin Wang, and Jiye Fang pp 14816–14821 DOI: 10.1021/ja046769j Supporting Info

Strong Electronic Coupling between Dimolybdenum Units Linked by the N,N‘-Dimethyloxamidate Anion in a Molecule Having a Heteronaphthalene-like Structure F. Albert Cotton, Chun Y. Liu, Carlos A. Murillo, Dino Villagrán, and Xiaoping Wang pp 14822–14831 DOI: 10.1021/ja046775f Supporting Info

“Inverse-Electron-Demand” Ligand Substitution:  Experimental and Computational Insights into Olefin Exchange at Palladium(0) Brian V. Popp, Joseph L. Thorman, Christine M. Morales, Clark R. Landis, and Shannon S. Stahl pp 14832–14842 DOI: 10.1021/ja0459734 Supporting Info

Digital Photoswitching of Fluorescence Based on the Photochromism of Diarylethene Derivatives at a Single-Molecule Level Tuyoshi Fukaminato, Takatoshi Sasaki, Tsuyoshi Kawai, Naoto Tamai, and Masahiro Irie pp 14843–14849 DOI: 10.1021/ja047169n Supporting Info

Selective Dispersion of Single-Walled Carbon Nanotubes in the Presence of Polymers:  the Role of Molecular and Colloidal Length Scales Rina Shvartzman-Cohen, Einat Nativ-Roth, Ezhil Baskaran, Yael Levi-Kalisman, Igal Szleifer, and Rachel Yerushalmi-Rozen pp 14850–14857 DOI: 10.1021/ja046377c Supporting Info

Marked Effect of Aromatic Solvent on Unfolding Rate of Helical Ethynylhelicene Oligomer Hiroki Sugiura, Yasuko Nigorikawa, Yuto Saiki, Keiichi Nakamura, and Masahiko Yamaguchi pp 14858–14864 DOI: 10.1021/ja0478882 Supporting Info

Foliacenes:  Ab Initio Modeling of Metallocomplexes Exhibiting a Unique Form of 16-Electron, Metal-Induced Aromaticity James R. Hutchison and Henry S. Rzepa pp 14865–14870 DOI: 10.1021/ja046734j Supporting Info

Properties of Fullerene[50] and D5h Decachlorofullerene[50]:  A Computational Study Xin Lu, Zhongfang Chen, Walter Thiel, Paul von Ragué Schleyer, Rongbin Huang, and Lansun Zheng pp 14871–14878 DOI: 10.1021/ja046725a Supporting Info

Catalytic Mechanism of Yeast Cytosine Deaminase:  An ONIOM Computational Study Stepan Sklenak, Lishan Yao, Robert I. Cukier, and Honggao Yan pp 14879–14889 DOI: 10.1021/ja046462k Supporting Info

What Makes the Trifluoride Anion F3- So Special? A Breathing-Orbital Valence Bond ab Initio Study Benoît Braïda and Philippe C. Hiberty pp 14890–14898 DOI: 10.1021/ja046443a

Electrochemical Potential-Step Investigations of the Aerobic Interconversions of [NiFe]-Hydrogenase from Allochromatium vinosum:  Insights into the Puzzling Difference between Unready and Ready Oxidized Inactive States Sophie E. Lamle, Simon P. J. Albracht, and Fraser A. Armstrong pp 14899–14909 DOI: 10.1021/ja047939v

Redox Inactivation of Human 15-Lipoxygenase by Marine-Derived Meroditerpenes and Synthetic Chromanes:  Archetypes for a Unique Class of Selective and Recyclable Inhibitors Robert H. Cichewicz, Victor A. Kenyon, Stephanie Whitman, Nancy M. Morales, Joanne F. Arguello, Theodore R. Holman, and Phillip Crews pp 14910–14920 DOI: 10.1021/ja046082z Supporting Info

FeCl3-Activated Oxidation of Alkanes by [Os(N)O3]- Shek-Man Yiu, Zhi-Biao Wu, Chi-Keung Mak, and Tai-Chu Lau pp 14921–14929 DOI: 10.1021/ja0487832 Supporting Info

Direct Chemical Synthesis of the β-d-Mannans: The β-(1→2) and β-(1→4) Series David Crich, Abhisek Banerjee, and Qingjia Yao pp 14930–14934 DOI: 10.1021/ja047194t Supporting Info

Synthesis of Eu3+-Doped Core and Core/Shell Nanoparticles and Direct Spectroscopic Identification of Dopant Sites at the Surface and in the Interior of the Particles Olaf Lehmann, Karsten Kömpe, and Markus Haase pp 14935–14942 DOI: 10.1021/ja031826e Supporting Info

Highly Efficient Dye-Sensitized Solar Cells with a Titania Thin-Film Electrode Composed of a Network Structure of Single-Crystal-like TiO2 Nanowires Made by the “Oriented Attachment” Mechanism Motonari Adachi, Yusuke Murata, Jun Takao, Jinting Jiu, Masaru Sakamoto, and Fumin Wang pp 14943–14949 DOI: 10.1021/ja048068s

Hypervalency Avoided:  Simple Substituted BrF3 and BrF5 Molecules. Structures, Thermochemistry, and Electron Affinities of the Bromine Hydrogen Fluorides HBrF2 and HBrF4 Qianshu Li, Liangfa Gong, Yaoming Xie, and Henry F. Schaefer III pp 14950–14959 DOI: 10.1021/ja040110w Supporting Info

Site-Isolation Effects in a Dendritic Nickel Catalyst for the Oligomerization of Ethylene Christian Müller, Lily J. Ackerman, Joost N. H. Reek, Paul C. J. Kamer, and Piet W. N. M. van Leeuwen pp 14960–14963 DOI: 10.1021/ja046901f Supporting Info

Luminescence Quenching of a Phosphorescent Conjugated Polyelectrolyte Ksenija Haskins-Glusac, Mauricio R. Pinto, Chunyan Tan, and Kirk S. Schanze pp 14964–14971 DOI: 10.1021/ja046160i Supporting Info

Supramolecular Polymer Formation by Metal−Ligand Complexation:  Monte Carlo Simulations and Analytical Modeling Chun-Chung Chen and Elena E. Dormidontova pp 14972–14978 DOI: 10.1021/ja047521x Supporting Info

Kinetics of Radical Heterolysis Reactions Forming Alkene Radical Cations John H. Horner, Laurent Bagnol, and Martin Newcomb pp 14979–14987 DOI: 10.1021/ja046089g Supporting Info

Enantioselective Separation on a Naturally Chiral Surface Joshua D. Horvath, Anjanette Koritnik, Preeti Kamakoti, David S. Sholl, and Andrew J. Gellman pp 14988–14994 DOI: 10.1021/ja045537h

Perturbation of Conjugation in Allylic Lithium Compounds Due to Stereochemical Control of Internal Lithium Coordination:  Crystallography, NMR, and Calculational Studies [J. Am. Chem. Soc. 2004, 126, 3983−3995]. Gideon Fraenkel, Albert Chow, Roland Fleischer, and Hua Liu p 14995 DOI: 10.1021/ja040821u

CrystalMaker 6.3 CrystalMaker Software, Begbroke Science Park, Building 5, Sandy Lane, Yarnton OX5 1P5, U.K. http://www.crystalmaker.com. $599.00 (single user), $415.00 (academic, single user). Contact company for other pricing options. Yuhui Whitney Yin p 14996 DOI: 10.1021/ja040947r

Energetic Materials, Part 1:  Decomposition, Crystal and Molecular Properties Edited by Peter A. Politzer and Jane S. Murray (University of New Orleans). From the series:  Theoretical and Computational Chemistry, Volume 12. Elsevier:  Amsterdam. 2003. xx + 466 pp. $210.00. ISBN 0-444-51518-6. C. J. Eckhardt p 14997 DOI: 10.1021/ja040901y

Oxazoles:  Synthesis, Reactions, and Spectroscopy, Part B. The Chemistry of Heterocyclic Compounds, Volume 60 Edited by David C. Palmer (Johnson & Johnson Pharmaceutical Research & Development, L. L. C., Raritan, NJ). John Wiley & Sons, Inc.:  Hoboken, NJ. 2004. xxii + 692 pp. $325. ISBN 0-471-21925-8. Ellen W. Baxter pp 14997–14998 DOI: 10.1021/ja0409309

Issue 46

Oxygen-Sensing Mechanism of HemAT from Bacillus subtilis:  A Resonance Raman Spectroscopic Study Takehiro Ohta, Hideaki Yoshimura, Shiro Yoshioka, Shigetoshi Aono, and Teizo Kitagawa pp 15000–15001 DOI: 10.1021/ja046896f Supporting Info

A Slippery Slope:  Mechanistic Analysis of the Intramolecular Scholl Reaction of Hexaphenylbenzene Pawel Rempala, Jiří Kroulík, and Benjamin T. King pp 15002–15003 DOI: 10.1021/ja046513d Supporting Info

Molecular Cube of ReII and MnII That Exhibits Single-Molecule Magnetism Eric J. Schelter, Andrey V. Prosvirin, and Kim R. Dunbar pp 15004–15005 DOI: 10.1021/ja047088r Supporting Info

Structural Rationalization of a Large Difference in RNA Affinity Despite a Small Difference in Chemistry between Two 2‘-O-Modified Nucleic Acid Analogues Rekha Pattanayek, Latsavongsakda Sethaphong, Chongle Pan, Marija Prhavc, Thazha P. Prakash, Muthiah Manoharan, and Martin Egli pp 15006–15007 DOI: 10.1021/ja044637k Supporting Info

Optically Active Sum Frequency Generation from Molecules with a Chiral Center:  Amino Acids as Model Systems Na Ji and Yuen-Ron Shen pp 15008–15009 DOI: 10.1021/ja045708i

Electron Transfer Rates in DNA Films as a Function of Tether Length T. Gregory Drummond, Michael G. Hill, and Jacqueline K. Barton pp 15010–15011 DOI: 10.1021/ja044910i Supporting Info

Lipid-Based Nanotubes as Functional Architectures with Embedded Fluorescence and Recognition Capabilities George John, Megan Mason, Pulickel M. Ajayan, and Jonathan S. Dordick pp 15012–15013 DOI: 10.1021/ja0446449 Supporting Info

How Many Hydrogen Atoms Can Be Bound to a Metal? Predicted MH12 Species Laura Gagliardi and Pekka Pyykkö pp 15014–15015 DOI: 10.1021/ja045991l Supporting Info

Dimeric Molecular Capsules under Redox Control Kwangyul Moon and Angel E. Kaifer pp 15016–15017 DOI: 10.1021/ja045587m Supporting Info

General Method for Suppression of Diagonal Peaks in Heteronuclear-Edited NOESY Spectroscopy Jihui Wu, Jing-song Fan, Steven M. Pascal, and Daiwen Yang pp 15018–15019 DOI: 10.1021/ja045300l Supporting Info

Dendronized Linear Polymers via “Click Chemistry” Brett Helms, Justin L. Mynar, Craig J. Hawker, and Jean M. J. Fréchet pp 15020–15021 DOI: 10.1021/ja044744e Supporting Info

Fabrication of Nanocables by Electrochemical Deposition Inside Metal Nanotubes Jie-Ren Ku, Ruxandra Vidu, Raisa Talroze, and Pieter Stroeve pp 15022–15023 DOI: 10.1021/ja0450657 Supporting Info

Time-Dependent DFT Study of [Fe(CN)6]4- Sensitization of TiO2 Nanoparticles Filippo De Angelis, Antonio Tilocca, and Annabella Selloni pp 15024–15025 DOI: 10.1021/ja045152z Supporting Info

In Situ Control of Cellular Growth and Migration on Substrates Using Microelectrodes Hirokazu Kaji, Kazuto Tsukidate, Tomokazu Matsue, and Matsuhiko Nishizawa pp 15026–15027 DOI: 10.1021/ja045702t Supporting Info

Molecular Recognition Remolds the Self-Assembly of Hydrogelators and Increases the Elasticity of the Hydrogel by 106-Fold Yan Zhang, Zhimou Yang, Fang Yuan, Hongwei Gu, Ping Gao, and Bing Xu pp 15028–15029 DOI: 10.1021/ja044401g Supporting Info

Metal-assisted Assembly and Stabilization of Collagen-like Triple Helices Weibo Cai, Sen Wai Kwok, Joseph P. Taulane, and Murray Goodman pp 15030–15031 DOI: 10.1021/ja0442062 Supporting Info

Li4C60:  A Polymeric Fulleride with a Two-Dimensional Architecture and Mixed Interfullerene Bonding Motifs Serena Margadonna, Daniele Pontiroli, Matteo Belli, Toni Shiroka, Mauro Riccò, and Michela Brunelli pp 15032–15033 DOI: 10.1021/ja044838o Supporting Info

Kinetic and Thermodynamic Preferences in Aryl vs Benzylic C−H Bond Activation with Cationic Pt(II) Complexes Alan F. Heyduk, Tom G. Driver, Jay A. Labinger, and John E. Bercaw pp 15034–15035 DOI: 10.1021/ja045078k Supporting Info

How Large Is the Conjugative Stabilization of Diynes? P. D. Jarowski, M. D. Wodrich, C. S. Wannere, P. v. R. Schleyer, and K. N. Houk pp 15036–15037 DOI: 10.1021/ja046432h Supporting Info

Lewis Acid-Mediated Selective Chlorinations of Silyl Enolate Yanhua Zhang, Kazutaka Shibatomi, and Hisashi Yamamoto pp 15038–15039 DOI: 10.1021/ja0454485 Supporting Info

An Efficient Synthesis of Phthalocyanines Based on an Unprecedented Double-Addition of Oximes to Phthalonitriles Maximilian N. Kopylovich, Vadim Yu. Kukushkin, Matti Haukka, Konstantin V. Luzyanin, and Armando J. L. Pombeiro pp 15040–15041 DOI: 10.1021/ja046759i Supporting Info

Conversion from Arenes Having a Benzene Ring to Those Having a Picolinic Acid by Simple Growing Cell Reactions Using Escherichia coli that Expressed the Six Bacterial Genes Involved in Biphenyl Catabolism Kazutoshi Shindo, Ayako Osawa, Ryoko Nakamura, Yukiko Kagiyama, Shohei Sakuda, Yoshikazu Shizuri, Kensuke Furukawa, and Norihiko Misawa pp 15042–15043 DOI: 10.1021/ja044850g Supporting Info

The Enantioselective Tsuji Allylation Douglas C. Behenna and Brian M. Stoltz pp 15044–15045 DOI: 10.1021/ja044812x Supporting Info

A Strain-Promoted [3 + 2] Azide−Alkyne Cycloaddition for Covalent Modification of Biomolecules in Living Systems Nicholas J. Agard, Jennifer A. Prescher, and Carolyn R. Bertozzi pp 15046–15047 DOI: 10.1021/ja044996f Supporting Info

Attaching Organic Semiconductors to Gate Oxides:  In Situ Assembly of Monolayer Field Effect Transistors George S. Tulevski, Qian Miao, Masafumi Fukuto, Rebecca Abram, Benjamin Ocko, Ronald Pindak, Michael L. Steigerwald, Cherie R. Kagan, and Colin Nuckolls pp 15048–15050 DOI: 10.1021/ja044101z Supporting Info

Directed Evolution of a Glycosynthase via Chemical Complementation Hening Lin, Haiyan Tao, and Virginia W. Cornish pp 15051–15059 DOI: 10.1021/ja046238v Supporting Info

Vanadium Bromoperoxidase-Catalyzed Biosynthesis of Halogenated Marine Natural Products Jayme N. Carter-Franklin and Alison Butler pp 15060–15066 DOI: 10.1021/ja047925p

(S,S)-trans-Cyclopentane-Constrained Peptide Nucleic Acids. A General Backbone Modification that Improves Binding Affinity and Sequence Specificity Jonathan K. Pokorski, Mark A. Witschi, Bethany L. Purnell, and Daniel H. Appella pp 15067–15073 DOI: 10.1021/ja046280q Supporting Info

Ring Closing Enyne Metathesis:  Control over Mode Selectivity and Stereoselectivity Eric C. Hansen and Daesung Lee pp 15074–15080 DOI: 10.1021/ja045422d Supporting Info

Direct Chemical Synthesis of the β-Mannans:  Linear and Block Syntheses of the Alternating β-(1→3)-β-(1→4)-Mannan Common to Rhodotorula glutinis, Rhodotorula mucilaginosa, and Leptospira biflexa David Crich, Wenju Li, and Hongmei Li pp 15081–15086 DOI: 10.1021/ja0471931 Supporting Info

Intermolecular Charge Transfer and Hydrogen Bonding in Solid Furan Manuel Montejo, Amparo Navarro, Gordon J. Kearley, Juana Vázquez, and Juan Jesús López-González pp 15087–15095 DOI: 10.1021/ja040130y Supporting Info

Metal Clips Induce Folding of a Short Unstructured Peptide into an α-Helix via Turn Conformations in Water. Kinetic versus Thermodynamic Products Renée L. Beyer, Huy N. Hoang, Trevor G. Appleton, and David P. Fairlie pp 15096–15105 DOI: 10.1021/ja0453782 Supporting Info

Structure-Based Design of Estrogen Receptor-β Selective Ligands Eric S. Manas, Rayomand J. Unwalla, Zhang B. Xu, Michael S. Malamas, Chris P. Miller, Heather A. Harris, Chulai Hsiao, Tatos Akopian, Wah-Tung Hum, Karl Malakian, Scott Wolfrom, Ashok Bapat, Ramesh A. Bhat, Mark L. Stahl, William S. Somers, and Juan C. Alvarez pp 15106–15119 DOI: 10.1021/ja047633o

Oxygen Isotope Effects on Electron Transfer to O2 Probed Using Chemically Modified Flavins Bound to Glucose Oxidase Justine P. Roth, Roseanne Wincek, Gabrielle Nodet, Dale E. Edmondson, William S. McIntire, and Judith P. Klinman pp 15120–15131 DOI: 10.1021/ja047050e Supporting Info

Duplex Formation and the Onset of Helicity in Poly d(CG)n Oligonucleotides in a Solvent-Free Environment Jennifer Gidden, Alessandra Ferzoco, Erin Shammel Baker, and Michael T. Bowers pp 15132–15140 DOI: 10.1021/ja046433+

Solvent Dependence of PII Conformation in Model Alanine Peptides Zhigang Liu, Kang Chen, Angela Ng, Zhengshuang Shi, Robert W. Woody, and Neville R. Kallenbach pp 15141–15150 DOI: 10.1021/ja047594g

[Fe2(SR)2(μ-CO)(CNMe)6]2+ and Analogues:  A New Class of Diiron Dithiolates as Structural Models for the HoxAir State of the Fe-Only Hydrogenase Christine A. Boyke, Thomas B. Rauchfuss, Scott R. Wilson, Marie-Madeleine Rohmer, and Marc Bénard pp 15151–15160 DOI: 10.1021/ja049050k Supporting Info

Macromolecular Helicity Induction in a Cationic Polyacetylene Assisted by an Anionic Polyisocyanide with Helicity Memory in Water:  Replication of Macromolecular Helicity Katsuhiro Maeda, Masayoshi Ishikawa, and Eiji Yashima pp 15161–15166 DOI: 10.1021/ja0469636 Supporting Info

Solute Solvent Dynamics and Energetics in Enzyme Catalysis:  The SN2 Reaction of Dehalogenase as a General Benchmark Mats H. M. Olsson and Arieh Warshel pp 15167–15179 DOI: 10.1021/ja047151c

Fluorescence and Aggregation Behavior of Poly(amidoamine) Dendrimers Peripherally Modified with Aromatic Chromophores:  the Effect of Dendritic Architectures Bing-Bing Wang, Xin Zhang, Xin-Ru Jia, Zi-Chen Li, Yan Ji, Ling Yang, and Yen Wei pp 15180–15194 DOI: 10.1021/ja048219r Supporting Info

Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis Gereon Altenhoff, Richard Goddard, Christian W. Lehmann, and Frank Glorius pp 15195–15201 DOI: 10.1021/ja045349r Supporting Info

Anion Binding to a Ferric Porphyrin Complexed with Per-O-methylated β-Cyclodextrin in Aqueous Solution Koji Kano, Hiroaki Kitagishi, Shigeto Tamura, and Akihisa Yamada pp 15202–15210 DOI: 10.1021/ja045472i Supporting Info

Helically Annelated and Cross-Conjugated Oligothiophenes:  Asymmetric Synthesis, Resolution, and Characterization of a Carbon−Sulfur [7]Helicene Andrzej Rajca, Makoto Miyasaka, Maren Pink, Hua Wang, and Suchada Rajca pp 15211–15222 DOI: 10.1021/ja0462530 Supporting Info

Lipopeptides Incorporated into Supported Phospholipid Monolayers Have High Specific Activity at Low Incorporation Levels Tor W. Jensen, Bi-Huang Hu, Shara M. Delatore, Ana Sofia Garcia, Phillip B. Messersmith, and William M. Miller pp 15223–15230 DOI: 10.1021/ja048684o Supporting Info

Chelate-Controlled Synthesis of Racemic ansa-Zirconocenes Matthew D. LoCoco, Xingwang Zhang, and Richard F. Jordan pp 15231–15244 DOI: 10.1021/ja046629+ Supporting Info

General, Room-Temperature Method for the Synthesis of Isolated as Well as Arrays of Single-Crystalline ABO4-Type Nanorods Yuanbing Mao and Stanislaus S. Wong pp 15245–15252 DOI: 10.1021/ja046331j Supporting Info

Local Measures of Intermolecular Free Energies in Solution Ching-Ling Teng, Silvia Martini, and Robert G. Bryant pp 15253–15257 DOI: 10.1021/ja0462528

A Generalized Model for the Molecular Arrangement in the Columnar Mesophases of Polycatenar Mesogens. Crystal and Molecular Structure of Two Hexacatenar Mesogens Bertrand Donnio, Benoît Heinrich, Hassan Allouchi, Jens Kain, Siegmar Diele, Daniel Guillon, and Duncan W. Bruce pp 15258–15268 DOI: 10.1021/ja0471673 Supporting Info

Reversible Surface Oxidation and Efficient Luminescence Quenching in Semiconductor Single-Wall Carbon Nanotubes Gordana Dukovic, Brian E. White, Zhiyong Zhou, Feng Wang, Steffen Jockusch, Michael L. Steigerwald, Tony F. Heinz, Richard A. Friesner, Nicholas J. Turro, and Louis E. Brus pp 15269–15276 DOI: 10.1021/ja046526r Supporting Info

Membrane Localization and Flexibility of a Lipidated Ras Peptide Studied by Molecular Dynamics Simulations Alemayehu A. Gorfe, Riccardo Pellarin, and Amedeo Caflisch pp 15277–15286 DOI: 10.1021/ja046607n

Development of a Functionalized Xenon Biosensor Megan M. Spence, E. Janette Ruiz, Seth M. Rubin, Thomas J. Lowery, Nicolas Winssinger, Peter G. Schultz, David E. Wemmer, and Alexander Pines pp 15287–15294 DOI: 10.1021/ja0483037 Supporting Info

Preparation and Characterization of π-Stacking Quinodimethane Oligothiophenes. Predicting Semiconductor Behavior and Bandwidths from Crystal Structures and Molecular Orbital Calculations Daron E. Janzen, Michael W. Burand, Paul C. Ewbank, Ted M. Pappenfus, Hiroyuki Higuchi, Demetrio A. da Silva Filho, Victor G. Young, Jean-Luc Brédas, and Kent R. Mann pp 15295–15308 DOI: 10.1021/ja0484597 Supporting Info

Planar Tetracoordinate Carbon in Extended Systems Pattath D. Pancharatna, Miguel Angel Méndez-Rojas, Gabriel Merino, Alberto Vela, and Roald Hoffmann pp 15309–15315 DOI: 10.1021/ja046405r Supporting Info

Studies toward Diazonamide A:  Development of a Hetero-Pinacol Macrocyclization Cascade for the Construction of the Bis-Macrocyclic Framework of the Originally Proposed Structure [J. Am. Chem. Soc. 2004, 126, 10174−10182]. K. C. Nicolaou, Scott A. Snyder, Nicolas Giuseppone, Xianhai Huang, Marco Bella, Mali V. Reddy, Paraselli Bheema Rao, Alexandros E. Koumbis, Paraskevi Giannakakou, and Aurora O'Brate p 15316 DOI: 10.1021/ja040822m

Chemistry and Biology of Diazonamide A:  First Total Synthesis and Confirmation of the True Structure [J. Am. Chem. Soc. 2004, 126, 12888−12896]. K. C. Nicolaou, David Y.-K. Chen, Xianhai Huang, Taotao Ling, Marco Bella, and Scott A. Snyder p 15316 DOI: 10.1021/ja040823e

Chemistry and Biology of Diazonamide A:  Second Total Synthesis and Biological Investigations [J. Am. Chem. Soc. 2004, 126, 12897−12906]. K. C. Nicolaou, Junliang Hao, Mali V. Reddy, Paraselli Bheema Rao, Gerasimos Rassias, Scott A. Snyder, Xianhai Huang, David Y.-K. Chen, William E. Brenzovich, Nicolas Giuseppone, Paraskevi Giannakakou, and Aurora O'Brate p 15316 DOI: 10.1021/ja0408247

Ligand-Dependent Scope and Divergent Mechanistic Behavior in Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes  [J. Am. Chem. Soc. 2004, 126, 3698−3699].  Gireesh M. Mahandru, Gang Liu, and John Montgomery p 15316 DOI: 10.1021/ja044394w

Reactor ChemAxon Ltd., Maramaros koz 2/a, Budapest, 1037 Hungary. www.chemaxon.com. Contact ChemAxon for pricing information. Jeffrey W. Bode p 15317 DOI: 10.1021/ja040968l

Analysis and Purification Methods in Combinatorial Chemistry Edited by Bing Yan (Discover Partners International, San Francisco, CA). From the series:  Chemical Analysis, Volume 163. Edited by J. D. Winefordner. John Wiley & Sons, Inc.:  Hoboken. 2004. xiv + 466 pp. $99.95. ISBN 0-471-26929-8. Luis E. Martínez p 15318 DOI: 10.1021/ja033674t

Thiophenes By Salo Gronowitz and Anna-Britta Hörnfeldt (Lund University, Sweden). From the Series Best Synthetic Methods. Elsevier/Academic Press:  Oxford. 2004. xxii + 964 pp. $286.00. ISBN 0-12-303953-3. p 15318 DOI: 10.1021/ja040977u

Issue 47

Solid-State 17O NMR as a Probe for Structural Studies of Proteins in Biomembranes Vincent Lemaître, Maurits R. R. de Planque, Andy P. Howes, Mark E. Smith, Ray Dupree, and Anthony Watts pp 15320–15321 DOI: 10.1021/ja0473283 Supporting Info

Synthesis, Crystal Structure, and Transistor Performance of Tetracene Derivatives Hyunsik Moon, Roswitha Zeis, Evert-Jan Borkent, Celine Besnard, Andrew J. Lovinger, Theo Siegrist, Christian Kloc, and Zhenan Bao pp 15322–15323 DOI: 10.1021/ja045208p Supporting Info

Thermal and Photochemistry of a Pyrene Dihydrodioxin (PDHD) and Its Radical Cation:  A Photoactivated Masking Group for ortho-Quinones Eric T. Mack, A. Björn Carle, J. T.-M. Liang, W. Coyle, and R. Marshall Wilson pp 15324–15325 DOI: 10.1021/ja0473788 Supporting Info

Mesostructured Selenides with Cubic MCM-48 Type Symmetry:  Large Framework Elasticity and Uncommon Resiliency to Strong Acids Pantelis N. Trikalitis, Nan Ding, Christos Malliakas, Simon J. L. Billinge, and Mercouri G. Kanatzidis pp 15326–15327 DOI: 10.1021/ja044954r Supporting Info

A Molecular Spring for Vision Ute F. Röhrig, Leonardo Guidoni, Alessandro Laio, Irmgard Frank, and Ursula Rothlisberger pp 15328–15329 DOI: 10.1021/ja048265r Supporting Info

High-Resolution Structure of an Extended A-Tract:  [d(CGCAAATTTGCG)]2 Kristen Kruger Woods, Tatsuya Maehigashi, Shelley B. Howerton, Chad C. Sines, Sarah Tannenbaum, and Loren Dean Williams pp 15330–15331 DOI: 10.1021/ja045207x Supporting Info

Two CO Molecules Can Bind Concomitantly at the Diiron Site of NO Reductase from Bacillus azotoformans Shen Lu, Suharti, Simon de Vries, and Pierre Moënne-Loccoz pp 15332–15333 DOI: 10.1021/ja045233v Supporting Info

Regiospecific Functionalization of Methyl C−H Bonds of Alkyl Groups in Reagents with Heteroatom Functionality Joshua D. Lawrence, Makoto Takahashi, Chulsung Bae, and John F. Hartwig pp 15334–15335 DOI: 10.1021/ja044933x Supporting Info

Direct Aziridination of Alkenes by a Cationic (Salen)ruthenium(VI) Nitrido Complex Wai-Lun Man, William W. Y. Lam, Shek-Man Yiu, Tai-Chu Lau, and Shie-Ming Peng pp 15336–15337 DOI: 10.1021/ja045845f Supporting Info

Catalytic Enantioselective Hydrogenation of Vinyl Bis(boronates) Jeremy B. Morgan and James P. Morken pp 15338–15339 DOI: 10.1021/ja044396g Supporting Info

High-Resolution NMR Spectroscopy of Membrane Proteins in Aligned Bicelles Anna A. De Angelis, Alexander A. Nevzorov, Sang Ho Park, Stanley C. Howell, Anthony A. Mrse, and Stanley J. Opella pp 15340–15341 DOI: 10.1021/ja045631y

Ligand-Switchable Directing Effects of Tethered Alkenes in Nickel-Catalyzed Additions to Alkynes Karen M. Miller and Timothy F. Jamison pp 15342–15343 DOI: 10.1021/ja0446799 Supporting Info

A Quantitative Assessment of the Influence of Permanent Kinks on the Mixing Behavior of Phospholipids in Cholesterol-Rich Bilayers Bingwen Jing, Nobuya Tokutake, Donald H. McCullough III, and Steven L. Regen pp 15344–15345 DOI: 10.1021/ja044517c Supporting Info

Total Synthesis of (−)-Disorazole C1 Peter Wipf and Thomas H. Graham pp 15346–15347 DOI: 10.1021/ja0443068 Supporting Info

Spirodiepoxides in Total Synthesis:  Epoxomicin Sreenivas Katukojvala, Kristin N. Barlett, Stephen D. Lotesta, and Lawrence J. Williams pp 15348–15349 DOI: 10.1021/ja044563c Supporting Info

Phosphoryl Choline Introduces Dual Activity in Biomimetic Ionomers Fredrik Nederberg, Tim Bowden, Bo Nilsson, Jaan Hong, and Jöns Hilborn pp 15350–15351 DOI: 10.1021/ja0457314 Supporting Info

Understanding Strong Two-Photon Absorption in π-Conjugated Porphyrin Dimers via Double-Resonance Enhancement in a Three-Level Model Mikhail Drobizhev, Yuriy Stepanenko, Yuliya Dzenis, Aliaksandr Karotki, Aleksander Rebane, Peter N. Taylor, and Harry L. Anderson pp 15352–15353 DOI: 10.1021/ja0445847 Supporting Info

Palladium-Catalyzed Carbon−Carbon Bond-Forming 1,2-Ligand Migration of Organoalanes Eric Fillion, Rebekah J. Carson, Vincent E. Trépanier, Julie M. Goll, and Anna A. Remorova pp 15354–15355 DOI: 10.1021/ja045783t Supporting Info

Direct Access to Ketones from Aldehydes via Rhodium-Catalyzed Cross-Coupling Reaction with Potassium Trifluoro(organo)borates Mathieu Pucheault, Sylvain Darses, and Jean-Pierre Genet pp 15356–15357 DOI: 10.1021/ja044749b Supporting Info

A Liquid Derivative of 12-Tungstophosphoric Acid with Unusually High Conductivity Athanasios B. Bourlinos, Kannan Raman, Rafael Herrera, Qiang Zhang, Lynden A. Archer, and Emmanuel P. Giannelis pp 15358–15359 DOI: 10.1021/ja046821b Supporting Info

Structures and Reactivity of Zr(IV) Chlorobenzene Complexes Fan Wu, Aswini K. Dash, and Richard F. Jordan pp 15360–15361 DOI: 10.1021/ja044303v Supporting Info

Dynamic in Situ Electrochemical Neutron Reflectivity Measurements Jonathan M. Cooper, Robert Cubitt, Robert M. Dalgliesh, Nikolaj Gadegaard, Andrew Glidle, A. Robert Hillman, Roger J. Mortimer, Karl S. Ryder, and Emma L. Smith pp 15362–15363 DOI: 10.1021/ja044682s

Anion-Templated Assembly of a [2]Catenane Mark R. Sambrook, Paul D. Beer, James A. Wisner, Rowena L. Paul, and Andrew R. Cowley pp 15364–15365 DOI: 10.1021/ja045080b Supporting Info

Heterocyclic Peptide Backbone Modifications in an α-Helical Coiled Coil W. Seth Horne, Maneesh K. Yadav, C. David Stout, and M. Reza Ghadiri pp 15366–15367 DOI: 10.1021/ja0450408 Supporting Info

Protein Patterning Based on Electrochemical Activation of Bioinactive Surfaces with Hydroquinone-Caged Biotin Kyuwon Kim, Haesik Yang, Sangyong Jon, Eunkyung Kim, and Juhyoun Kwak pp 15368–15369 DOI: 10.1021/ja0459330 Supporting Info

Chemistry and Biology of Deoxy-myo-inositol Phosphates:  Stereospecificity of Substrate Interactions within an Archaeal and a Bacterial IMPase Adam J. Morgan, Yangling Karen Wang, Mary F. Roberts, and Scott J. Miller pp 15370–15371 DOI: 10.1021/ja047360x Supporting Info

Cysteine-Reactive Polymers Synthesized by Atom Transfer Radical Polymerization for Conjugation to Proteins Debora Bontempo, Karina L. Heredia, Benjamin A. Fish, and Heather D. Maynard pp 15372–15373 DOI: 10.1021/ja045063m Supporting Info

Sequence-Selective and Hydrolytic Cleavage of DNA by Zinc Finger Mutants Akiko Nomura and Yukio Sugiura pp 15374–15375 DOI: 10.1021/ja045663l Supporting Info

Specific Redistribution of Cell-Penetrating Peptides from Endosomes to the Cytoplasm and Nucleus upon Laser Illumination James R. Maiolo III, Elizabeth A. Ottinger, and Marc Ferrer* pp 15376–15377 DOI: 10.1021/ja044867z Supporting Info

Expanding the Scope of C−H Amination through Catalyst Design Christine G. Espino, Kristin Williams Fiori, Mihyong Kim, and J. Du Bois pp 15378–15379 DOI: 10.1021/ja0446294 Supporting Info

Comparative Study of Electron Transfer Reactions at the Ionic Liquid/Water and Organic/Water Interfaces François O. Laforge, Takashi Kakiuchi, Fumiko Shigematsu, and Michael V. Mirkin pp 15380–15381 DOI: 10.1021/ja045420t

Design of Mesomorphic Diarylethene-Based Photochromes Michel Frigoli, Chris Welch, and Georg H. Mehl pp 15382–15383 DOI: 10.1021/ja0468269 Supporting Info

Vinyl Acetate Formation by the Reaction of Ethylene with Acetate Species on Oxygen-Covered Pd(111) Dario Stacchiola, Florencia Calaza, Luke Burkholder, and Wilfred T. Tysoe pp 15384–15385 DOI: 10.1021/ja044641w

Understanding the Basis of Resistance in the Irksome Lys103Asn HIV-1 Reverse Transcriptase Mutant through Targeted Molecular Dynamics Simulations Fátima Rodríguez-Barrios and Federico Gago pp 15386–15387 DOI: 10.1021/ja045409t Supporting Info

Platinum-Functionalized Random Copolymers for Use in Solution-Processible, Efficient, Near-White Organic Light-Emitting Diodes Paul T. Furuta, Lan Deng, Simona Garon, Mark E. Thompson, and Jean M. J. Fréchet pp 15388–15389 DOI: 10.1021/ja0446247 Supporting Info

Zero Thermal Expansion in a Prussian Blue Analogue Serena Margadonna, Kosmas Prassides, and Andrew N. Fitch pp 15390–15391 DOI: 10.1021/ja044959o Supporting Info

A Selective, Cell-Permeable Optical Probe for Hydrogen Peroxide in Living Cells Michelle C. Y. Chang, Arnd Pralle, Ehud Y. Isacoff, and Christopher J. Chang pp 15392–15393 DOI: 10.1021/ja0441716 Supporting Info

Coordination Polymers Containing 1D Channels as Selective Luminescent Probes Bin Zhao, Xiao-Yan Chen, Peng Cheng, Dai-Zheng Liao, Shi-Ping Yan, and Zong-Hui Jiang pp 15394–15395 DOI: 10.1021/ja047141b Supporting Info

Pyrimidine-Core Extended π-Systems:  General Synthesis and Interesting Fluorescent Properties Kenichiro Itami, Daisuke Yamazaki, and Jun-ichi Yoshida pp 15396–15397 DOI: 10.1021/ja044923w Supporting Info

Induction of Homochirality in Achiral Enantiomorphous Monolayers Manfred Parschau, Sara Romer, and Karl-Heinz Ernst pp 15398–15399 DOI: 10.1021/ja044136z Supporting Info

Chemical Input Multiplicity Facilitates Arithmetical Processing David Margulies, Galina Melman, Clifford E. Felder, Rina Arad-Yellin, and Abraham Shanzer pp 15400–15401 DOI: 10.1021/ja0453329 Supporting Info

Combating Drug-Resistant Bacteria:  Small Molecule Mimics of Plasmid Incompatibility as Antiplasmid Compounds Johna C. B. DeNap, Jason R. Thomas, Dinty J. Musk, and Paul J. Hergenrother pp 15402–15404 DOI: 10.1021/ja044207u Supporting Info

The Complex of a Bivalent Derivative of Galanthamine with Torpedo Acetylcholinesterase Displays Drastic Deformation of the Active-Site Gorge:  Implications for Structure-Based Drug Design Harry M. Greenblatt, Catherine Guillou, Daniel Guénard, Anat Argaman, Simone Botti, Bernard Badet, Claude Thal, Israel Silman, and Joel L. Sussman pp 15405–15411 DOI: 10.1021/ja0466154

A General and High Yielding Fragment Coupling Synthesis of Heteroatom-Bridged Calixarenes and the Unprecedented Examples of Calixarene Cavity Fine-Tuned by Bridging Heteroatoms Mei-Xiang Wang and Hai-Bo Yang pp 15412–15422 DOI: 10.1021/ja0465092 Supporting Info

Catalytic Cyclization of o-Alkynylbenzaldehyde Acetals and Thioacetals. Unprecedented Activation of the Platinum Catalyst by Olefins. Scope and Mechanism of the Reaction Itaru Nakamura, Gan B. Bajracharya, Huanyou Wu, Kengo Oishi, Yuya Mizushima, Ilya D. Gridnev, and Yoshinori Yamamoto pp 15423–15430 DOI: 10.1021/ja044603c Supporting Info

Electron Transfer within 2,7-Dinitronaphthalene Radical Anion Stephen F. Nelsen, Michael N. Weaver, Asgeir E. Konradsson, João P. Telo, and Timothy Clark pp 15431–15438 DOI: 10.1021/ja046566v Supporting Info

Size-Dependent Exciton Chirality in (R)-(+)-1,1‘-Bi-2-naphthol Dimethyl Ether Nanoparticles Debao Xiao, Wensheng Yang, Jiannian Yao, Lu Xi, Xia Yang, and Zhigang Shuai pp 15439–15444 DOI: 10.1021/ja047309t Supporting Info

A Family of Manganese Rods:  Syntheses, Structures, and Magnetic Properties Gopalan Rajaraman, Muralee Murugesu, E. Carolina Sañudo, Monica Soler, Wolfgang Wernsdorfer, Madeleine Helliwell, Chris Muryn, Jim Raftery, Simon J. Teat, George Christou, and Euan K. Brechin pp 15445–15457 DOI: 10.1021/ja0471929

Effects of Methyl Substitution on Radiative and Solvent Quenching Rate Constants of [Ru(phen)2dppz]2+ in Polyol Solvents and Bound to DNA Johan Olofsson, L. Marcus Wilhelmsson, and Per Lincoln pp 15458–15465 DOI: 10.1021/ja047166a Supporting Info

Chemical Surface Passivation of Ge Nanowires Tobias Hanrath and Brian A. Korgel pp 15466–15472 DOI: 10.1021/ja0465808 Supporting Info

Is the A-Ring of Sparteine Essential for High Enantioselectivity in the Asymmetric Lithiation−Substitution of N-Boc-pyrrolidine? Puay-Wah Phuan, James C. Ianni, and Marisa C. Kozlowski pp 15473–15479 DOI: 10.1021/ja046321i Supporting Info

An Experimental and Computational Study of the Enantioselective Lithiation of N-Boc-pyrrolidine Using Sparteine-like Chiral Diamines Peter O'Brien, Kenneth B. Wiberg, William F. Bailey, Jean-Paul R. Hermet, and Matthew J. McGrath pp 15480–15489 DOI: 10.1021/ja046834p Supporting Info

Solution Redox Chemistry of Carbon Nanotubes Ming Zheng and Bruce A. Diner pp 15490–15494 DOI: 10.1021/ja0457967

A General Technique To Rank Protein−Ligand Binding Affinities and Determine Allosteric versus Direct Binding Site Competition in Compound Mixtures D. Allen Annis, Naim Nazef, Cheng-Chi Chuang, Margaret Porter Scott, and Huw M. Nash pp 15495–15503 DOI: 10.1021/ja048365x Supporting Info

NMR-Based Reappraisal of the Coordination of a Metal Ion at the Pro-Rp Oxygen of the A9/G10.1 Site in a Hammerhead Ribozyme Ken-ichi Suzumura, Yasuomi Takagi, Masaya Orita, and Kazunari Taira pp 15504–15511 DOI: 10.1021/ja0472937

Dynamics of Alkoxy−Oligothiophene Ground and Excited States in Nanochannels Marina Brustolon, Antonio Barbon, Marco Bortolus, Anna Lisa Maniero, Piero Sozzani, Angiolina Comotti, and Roberto Simonutti pp 15512–15519 DOI: 10.1021/ja046804m Supporting Info

Electromechanics of a Redox-Active Rotaxane in a Monolayer Assembly on an Electrode Eugenii Katz, Oleg Lioubashevsky, and Itamar Willner pp 15520–15532 DOI: 10.1021/ja045465u Supporting Info

Conformationally Locked Isostere of PhosphoSer−cis-Pro Inhibits Pin1 23-Fold Better than PhosphoSer−trans-Pro Isostere Xiaodong J. Wang, Bailing Xu, Ashley B. Mullins, Freda K. Neiler, and Felicia A. Etzkorn pp 15533–15542 DOI: 10.1021/ja046396m Supporting Info

Michael Addition Reactions with η2-Coordinated Anisoles:  Controlling the Stereochemistry of the Para and Benzylic Carbons Philip L. Smith, Joseph M. Keane, Sarah E. Shankman, Mahendra D. Chordia, and W. Dean Harman pp 15543–15551 DOI: 10.1021/ja047054j Supporting Info

Reductive Electron Injection into Duplex DNA by Aromatic Amines Takeo Ito and Steven E. Rokita pp 15552–15559 DOI: 10.1021/ja045637n Supporting Info

Rutheniun-Catalyzed Cycloisomerization of o-(Ethynyl)phenylalkenes to Diene Derivatives via Skeletal Rearrangement Reniguntala J. Madhushaw, Ching-Yu Lo, Chun-Wei Hwang, Ming-Der Su, Hung-Chin Shen, Sitaram Pal, Isak R. Shaikh, and Rai-Shung Liu pp 15560–15565 DOI: 10.1021/ja045516n Supporting Info

Inner-Sphere Electron-Transfer Reorganization Energies of Zinc Porphyrins Xenia Amashukeli, Nadine E. Gruhn, Dennis L. Lichtenberger, Jay R. Winkler, and Harry B. Gray pp 15566–15571 DOI: 10.1021/ja0351037

Tin−Chalcogen Double-Bond Compounds, Stannanethione and Stannaneselone:  Synthesis, Structure, and Reactivities Masaichi Saito, Norihiro Tokitoh, and Renji Okazaki pp 15572–15582 DOI: 10.1021/ja048453h Supporting Info

Bimetallic Palladium−Gold Dendrimer-Encapsulated Catalysts Robert W. J. Scott, Orla M. Wilson, Sang-Keun Oh, Edward A. Kenik, and Richard M. Crooks pp 15583–15591 DOI: 10.1021/ja0475860 Supporting Info

Ruthenium-Catalyzed Enyne Cycloisomerizations. Effect of Allylic Silyl Ether on Regioselectivity Barry M. Trost, Jean-Philippe Surivet, and F. Dean Toste pp 15592–15602 DOI: 10.1021/ja046824o Supporting Info

Structural and Electron-Transfer Characteristics of O-, S-, and Se-Tethered Porphyrin Monolayers on Si(100) Amir A. Yasseri, Dennis Syomin, Robert S. Loewe, Jonathan S. Lindsey, Francisco Zaera, and David F. Bocian pp 15603–15612 DOI: 10.1021/ja045243w Supporting Info

A Substituent Effects Study Reveals the Kinetic Pathway for an Interfacial Reaction Ellen S. Gawalt and Milan Mrksich pp 15613–15617 DOI: 10.1021/ja048978+

Full Quantitative Multiple-Scattering Analysis of X-ray Absorption Spectra:  Application to Potassium Hexacyanoferrat(II) and -(III) Complexes Kuniko Hayakawa, Keisuke Hatada, Paola D'Angelo, Stefano Della Longa, Calogero R. Natoli, and Maurizio Benfatto pp 15618–15623 DOI: 10.1021/ja045561v

One-Bond Spin−Spin Coupling Constants of X−1H Proton Donors in Complexes with X−H−Y Hydrogen Bonds, for X = 13C, 15N, 17O, and 19F:  Predictions, Comparisons, and Relationships among 1JX-H, 1KX-H, and X−H Distances Janet E. Del Bene and José Elguero pp 15624–15631 DOI: 10.1021/ja0401545

Nanoparticles:  From Theory to Application Edited by Günter Schmid (University of Duisberg-Essen). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2004. x + 434 pp. $210.00. ISBN 3-527-30507-6. Gary A. Baker pp 15632–15633 DOI: 10.1021/ja040954f

Fieser's Reagents for Organic Synthesis, Volume 22 By Tse-Lok Ho (National Chiao Tung University, Republic of China). John Wiley & Sons, Inc.:  Hoboken. 2004. xiv + 608 pp. $99.95. ISBN 0-471-28515-3. p 15633 DOI: 10.1021/ja040979e

Organic Reactions, Volume 64 Edited by Larry E. Overman (University of California, Irvine). John Wiley & Sons, Inc.:  Hoboken. 2004. viii + 640 pp. $125.00. ISBN 0-471-68262-4. p 15633 DOI: 10.1021/ja0409816

Handbook of Infrared Spectroscopy of Ultrathin Films By Valeri P. Tolstoy (St. Petersburg State University, Russia), Irina V. Chernyshova (St. Petersburg State Polytechnical University, Russia), and Valeri A. Skryshevsky (Kyiv National Taras Shevchenko University, Ukraine). John Wiley and Sons, Inc.:  Hoboken. 2003. xxvi + 710 pp. $250.00. ISBN 0-471-35404-X. David L. Allara pp 15633–15634 DOI: 10.1021/ja0335770

Issue 48

Dendrimers with Both Polar and Apolar Nanocontainer Characteristics Dharma Rao Vutukuri, Subhadeep Basu, and S. Thayumanavan pp 15636–15637 DOI: 10.1021/ja0449628 Supporting Info

Near-Infrared Fluorescence Microscopy of Single-Walled Carbon Nanotubes in Phagocytic Cells Paul Cherukuri, Sergei M. Bachilo, Silvio H. Litovsky, and R. Bruce Weisman pp 15638–15639 DOI: 10.1021/ja0466311 Supporting Info

Microarray Platform for Profiling Enzyme Activities in Complex Proteomes Stephan A. Sieber, Tony S. Mondala, Steven R. Head, and Benjamin F. Cravatt pp 15640–15641 DOI: 10.1021/ja044286+ Supporting Info

A Strong Positive Dendritic Effect in a Peptide Dendrimer-Catalyzed Ester Hydrolysis Reaction Estelle Delort, Tamis Darbre, and Jean-Louis Reymond pp 15642–15643 DOI: 10.1021/ja044652p Supporting Info

Fluorinated Imidazoles as Proton Carriers for Water-Free Fuel Cell Membranes Wei-Qiao Deng, Valeria Molinero, and William A. Goddard III pp 15644–15645 DOI: 10.1021/ja046999y Supporting Info

DNA−Nanotube Artificial Ion Channels C. Chad Harrell, Punit Kohli, Zuzanna Siwy, and Charles R. Martin pp 15646–15647 DOI: 10.1021/ja044948v Supporting Info

Initial Observation of Magnetization Hysteresis and Quantum Tunneling in Mixed Manganese−Lanthanide Single-Molecule Magnets Abhudaya Mishra, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 15648–15649 DOI: 10.1021/ja0452727 Supporting Info

Stannylative Cycloaddition of Enynes Catalyzed by Palladium−Iminophosphine Yoshiaki Nakao, Yasuhiro Hirata, Shinjiro Ishihara, Shinichi Oda, Tomoya Yukawa, Eiji Shirakawa, and Tamejiro Hiyama pp 15650–15651 DOI: 10.1021/ja044429s Supporting Info

Asymmetric α-Alkylation of N‘-tert-Butanesulfinyl Amidines. Application to the Total Synthesis of (6R,7S)-7-Amino-7,8-dihydro-α-bisabolene Takuya Kochi and Jonathan A. Ellman pp 15652–15653 DOI: 10.1021/ja044753n Supporting Info

Site-Specific Incorporation of the Mucin-Type N-Acetylgalactosamine-α-O-threonine into Protein in Escherichia coli Ran Xu, Sarah R. Hanson, Zhiwen Zhang, Yu-Ying Yang, Peter G. Schultz, and Chi-Huey Wong pp 15654–15655 DOI: 10.1021/ja044711z Supporting Info

Cell-Specific Delivery of a Chemotherapeutic to Lung Cancer Cells Xin Zhou, Ya-Ching Chang, Tsukasa Oyama, Michael J. McGuire, and Kathlynn C. Brown pp 15656–15657 DOI: 10.1021/ja0446496 Supporting Info

The Hydratase Activity of Malonate Semialdehyde Decarboxylase:  Mechanistic and Evolutionary Implications Gerrit J. Poelarends, Hector Serrano, William H. Johnson, Jr., David W. Hoffman, and Christian P. Whitman pp 15658–15659 DOI: 10.1021/ja044304n

Direct Observation of Enantiomer Discrimination of Epoxides by Chiral Salen Complexes Using ENDOR Ian A. Fallis, Damien M. Murphy, David J. Willock, Richard J. Tucker, Robert D. Farley, Robert Jenkins, and Robert R. Strevens pp 15660–15661 DOI: 10.1021/ja045491s Supporting Info

Oxonia-Cope Prins Cyclizations:  A Facile Method for the Synthesis of Tetrahydropyranones Bearing Quaternary Centers Jackline E. Dalgard and Scott D. Rychnovsky pp 15662–15663 DOI: 10.1021/ja044736y Supporting Info

Total Synthesis of (±)-Pentacycloanammoxic Acid Vincent Mascitti and E. J. Corey pp 15664–15665 DOI: 10.1021/ja044089a Supporting Info

Stille Coupling of Stereochemically Defined α-Sulfonamidoorganostannanes Kevin W. Kells and J. Michael Chong pp 15666–15667 DOI: 10.1021/ja044354s Supporting Info

Correlated C−C and C−O Bond Conformations in Saccharide Hydroxymethyl Groups:  Parametrization and Application of Redundant 1H−1H, 13C−1H, and 13C−13C NMR J-Couplings Christophe Thibaudeau, Roland Stenutz, Brian Hertz, Thomas Klepach, Shikai Zhao, Qingquan Wu, Ian Carmichael, and Anthony S. Serianni pp 15668–15685 DOI: 10.1021/ja0306718 Supporting Info

Isolation of Fast Purine Nucleotide Synthase Ribozymes Matthew W. L. Lau, Kelly E. C. Cadieux, and Peter J. Unrau pp 15686–15693 DOI: 10.1021/ja045387a Supporting Info

Kinetics and Mechanism of •NO2 Reacting with Various Oxidation States of Myoglobin Sara Goldstein, Gabor Merenyi, and Amram Samuni pp 15694–15701 DOI: 10.1021/ja046186+

Dynamics of Hemoglobin in Human Erythrocytes and in Solution:  Influence of Viscosity Studied by Ultrafast Vibrational Echo Experiments Brian L. McClain, Ilya J. Finkelstein, and M. D. Fayer pp 15702–15710 DOI: 10.1021/ja0454790

Loop-Contraction Mutagenesis of Type 1 Copper Sites Sachiko Yanagisawa and Christopher Dennison pp 15711–15719 DOI: 10.1021/ja047295r Supporting Info

Promoting Vibrations in Human Purine Nucleoside Phosphorylase. A Molecular Dynamics and Hybrid Quantum Mechanical/Molecular Mechanical Study Sara Núñez, Dimitri Antoniou, Vern L. Schramm, and Steven D. Schwartz pp 15720–15729 DOI: 10.1021/ja0457563

A Proficient Enzyme:  Insights on the Mechanism of Orotidine Monophosphate Decarboxylase from Computer Simulations Simone Raugei, Michele Cascella, and Paolo Carloni pp 15730–15737 DOI: 10.1021/ja0455143

Probing the Hydrophobic Cavity of Lipid Transfer Protein from Nicotiana tabacum through Xenon-Based NMR Spectroscopy Lionel Dubois, Pedro Da Silva, Céline Landon, J. Gaspard Huber, Michel Ponchet, Françoise Vovelle, Patrick Berthault, and Hervé Desvaux pp 15738–15746 DOI: 10.1021/ja046195i Supporting Info

Synthetic Ion Channel Activity Documented by Electrophysiological Methods in Living Cells W. Matthew Leevy, James E. Huettner, Robert Pajewski, Paul H. Schlesinger, and George W. Gokel pp 15747–15753 DOI: 10.1021/ja046626x

Assembly of Well-Aligned Multiwalled Carbon Nanotubes in Confined Polyacrylonitrile Environments:  Electrospun Composite Nanofiber Sheets Jason J. Ge, Haoqing Hou, Qing Li, Matthew J. Graham, Andreas Greiner, Darrell H. Reneker, Frank W. Harris, and Stephen Z. D. Cheng pp 15754–15761 DOI: 10.1021/ja048648p Supporting Info

Control of Peptide Structure and Recognition by Fe(III)-Induced Helix Destabilization Shiroh Futaki, Tatsuto Kiwada, and Yukio Sugiura pp 15762–15769 DOI: 10.1021/ja046870o Supporting Info

N-Halosuccinimide/BF3−H2O, Efficient Electrophilic Halogenating Systems for Aromatics G. K. Surya Prakash, Thomas Mathew, Dushyanthi Hoole, Pierre M. Esteves, Qi Wang, Golam Rasul, and George A. Olah pp 15770–15776 DOI: 10.1021/ja0465247 Supporting Info

Hydration of Pyridylketenes:  Formation of Acid Enol and Dihydropyridine (Eneaminone) Transients Annette D. Allen, Andrei V. Fedorov, Thomas T. Tidwell, and Sinisa Vukovic pp 15777–15783 DOI: 10.1021/ja047623n Supporting Info

Hybridization of Oligonucleotide-Modified Silver and Gold Nanoparticles in Aqueous Dispersions and on Gold Films Iryna Tokareva and Eliza Hutter pp 15784–15789 DOI: 10.1021/ja046779k

Direct Measurement of the Hydrogen-Bonding Effect on the Intrinsic Redox Potentials of [4Fe−4S] Cubane Complexes Xin Yang, Shuqiang Niu, Toshiko Ichiye, and Lai-Sheng Wang pp 15790–15794 DOI: 10.1021/ja045709a

A New Type of Intermediate, C+(BCH3)11- ↔ C(BCH3)11, in a Grob Fragmentation Coupled with Intramolecular Hydride Transfer. A Nonclassical Carbocation Ylide or a Carbenoid? Kamesh Vyakaranam, Stefanie Körbe, Hana Divišová, and Josef Michl pp 15795–15801 DOI: 10.1021/ja0466558 Supporting Info

Linear Rheology of Water-Soluble Reversible Neodymium(III) Coordination Polymers Tina Vermonden, Mies J. van Steenbergen, Nicolaas A. M. Besseling, Antonius T. M. Marcelis, Wim E. Hennink, Ernst J. R. Sudhölter, and Martien A. Cohen Stuart pp 15802–15808 DOI: 10.1021/ja0458928

Difference RuleA New Thermodynamic Principle:  Prediction of Standard Thermodynamic Data for Inorganic Solvates H. Donald Brooke Jenkins and Leslie Glasser pp 15809–15817 DOI: 10.1021/ja040137f Supporting Info

Synthetic, Structural, and Mechanistic Aspects of an Amine Activation Process Mediated at a Zwitterionic Pd(II) Center Connie C. Lu and Jonas C. Peters pp 15818–15832 DOI: 10.1021/ja046415s Supporting Info

Insignificance of P−H···P Hydrogen Bonding:  Structural Chemistry of Neutral and Protonated 1,8-Di(phosphinyl)naphthalene Stephan A. Reiter, Stefan D. Nogai, Konstantin Karaghiosoff, and Hubert Schmidbaur pp 15833–15843 DOI: 10.1021/ja045460x Supporting Info

Dynamic and Redox Active Pillared Bilayer Open Framework:  Single-Crystal-to-Single-Crystal Transformations upon Guest Removal, Guest Exchange, and Framework Oxidation Hye Jin Choi and Myunghyun Paik Suh pp 15844–15851 DOI: 10.1021/ja0466715 Supporting Info

Self-Assembly and Molecular Recognition of a Luminescent Gold Rectangle Ronger Lin, John H. K. Yip, Ke Zhang, Lip Lin Koh, Kwok-Yin Wong, and Kam Piu Ho pp 15852–15869 DOI: 10.1021/ja0456508 Supporting Info

Tuning the Hemolytic and Antibacterial Activities of Amphiphilic Polynorbornene Derivatives M. Firat Ilker, Klaus Nüsslein, Gregory N. Tew, and E. Bryan Coughlin pp 15870–15875 DOI: 10.1021/ja045664d Supporting Info

Nitrile-Functionalized Pyridinium Ionic Liquids:  Synthesis, Characterization, and Their Application in Carbon−Carbon Coupling Reactions Dongbin Zhao, Zhaofu Fei, Tilmann J. Geldbach, Rosario Scopelliti, and Paul J. Dyson pp 15876–15882 DOI: 10.1021/ja0463482 Supporting Info

Contiguous versus Segmented Hydrophobicity in Micellar Systems Fredric M. Menger and Ashley L. Galloway pp 15883–15889 DOI: 10.1021/ja040105s

Surface Reaction of Alkynes and Alkenes with H-Si(111):  A Density Functional Theory Study Noboru Takeuchi, Yosuke Kanai, and Annabella Selloni pp 15890–15896 DOI: 10.1021/ja046702w Supporting Info

Molecular Conductance:  Chemical Trends of Anchoring Groups San-Huang Ke, Harold U. Baranger, and Weitao Yang pp 15897–15904 DOI: 10.1021/ja047367e

Structure and Dynamics of a Molecular Hydrogel Derived from a Tripodal Cholamide Samrat Mukhopadhyay, Uday Maitra, Ira, Guruswamy Krishnamoorthy, Judith Schmidt, and Yeshayahu Talmon pp 15905–15914 DOI: 10.1021/ja046788t

Consistent Experimental and Theoretical Evidence for Long-Lived Intermediate Radicals in Living Free Radical Polymerization Achim Feldermann, Michelle L. Coote, Martina H. Stenzel, Thomas P. Davis, and Christopher Barner-Kowollik pp 15915–15923 DOI: 10.1021/ja046292b Supporting Info

Identification of Inhibitors for UDP-Galactopyranose Mutase [J. Am. Chem. Soc. 2004, 126, 10532−10533]. Michelle Soltero-Higgin, Erin E. Carlson, John H. Phillips, and Laura L. Kiessling p 15924 DOI: 10.1021/ja040825z

Issue 49

Molecule-Based Photonically Switched Half-Adder Joakim Andréasson, Gerdenis Kodis, Yuichi Terazono, Paul A. Liddell, Subhajit Bandyopadhyay, Reginald H. Mitchell, Thomas A. Moore, Ana L. Moore, and Devens Gust pp 15926–15927 DOI: 10.1021/ja045577l Supporting Info

Methyl Group Dynamics as a Probe of the Protein Dynamical Transition Joseph E. Curtis, Mounir Tarek, and Douglas J. Tobias pp 15928–15929 DOI: 10.1021/ja0480623 Supporting Info

Persulfated Molecular Umbrellas as Anti-HIV and Anti-HSV Agents Bingwen Jing, Vaclav Janout, Betsy C. Herold, Mary E. Klotman, Taylor Heald, and Steven L. Regen pp 15930–15931 DOI: 10.1021/ja044400o Supporting Info

TiCp2Cl-Catalyzed Living Radical Polymerization of Styrene Initiated by Oxirane Radical Ring Opening Alexandru D. Asandei and Isaac W. Moran pp 15932–15933 DOI: 10.1021/ja046936f Supporting Info

Two-Pump−One-Probe Femtosecond Studies of Ni(II) Porphyrins Excited States Andrey V. Zamyatin, Alex V. Gusev, and Michael A. J. Rodgers pp 15934–15935 DOI: 10.1021/ja0448059 Supporting Info

Sizable Concentration-Dependent Frequency Shifts in Solution NMR Using Sensitive Probes Susie Y. Huang, Clemens Anklin, Jamie D. Walls, and Yung-Ya Lin pp 15936–15937 DOI: 10.1021/ja046208s Supporting Info

Hybrid Microgels Photoresponsive in the Near-Infrared Spectral Range Ivan Gorelikov, Lora M. Field, and Eugenia Kumacheva pp 15938–15939 DOI: 10.1021/ja0448869 Supporting Info

Small Molecule Transcription Factor Mimic Youngjoo Kwon, Hans-Dieter Arndt, Qian Mao, Yongmun Choi, Yoshinori Kawazoe, Peter B. Dervan, and Motonari Uesugi pp 15940–15941 DOI: 10.1021/ja0445140 Supporting Info

A Three-Component Mannich-Type Reaction for Selective Tyrosine Bioconjugation Neel S. Joshi, Leanna R. Whitaker, and Matthew B. Francis pp 15942–15943 DOI: 10.1021/ja0439017 Supporting Info

Artificial Ion Channel Formed by Cucurbit[n]uril Derivatives with a Carbonyl Group Fringed Portal Reminiscent of the Selectivity Filter of K+ Channels Young Jin Jeon, Hyejung Kim, Sangyong Jon, Narayanan Selvapalam, Dong Hyun Oh, Inra Seo, Chul-Seung Park, Seung Ryoung Jung, Duk-Su Koh, and Kimoon Kim pp 15944–15945 DOI: 10.1021/ja044748j Supporting Info

Axially Polar Columnar Phase Made of Polycatenar Bent-Shaped Molecules Ewa Gorecka, Damian Pociecha, Jozef Mieczkowski, Joanna Matraszek, Daniel Guillon, and Bertrand Donnio pp 15946–15947 DOI: 10.1021/ja044597k Supporting Info

MD Simulations of Spontaneous Membrane Protein/Detergent Micelle Formation Peter J. Bond, Jonathan M. Cuthbertson, Sundeep S. Deol, and Mark S. P. Sansom pp 15948–15949 DOI: 10.1021/ja044819e Supporting Info

Nanosensors Based on Responsive Polymer Brushes and Gold Nanoparticle Enhanced Transmission Surface Plasmon Resonance Spectroscopy Iryna Tokareva, Sergiy Minko, Janos H. Fendler, and Eliza Hutter pp 15950–15951 DOI: 10.1021/ja044575y Supporting Info

Photoinduced Desorption of Sulfur from Gold Nanoparticles Loaded on Metal Oxide Surfaces Hiroaki Tada, Tetsuro Soejima, Seishiro Ito, and Hisayoshi Kobayashi pp 15952–15953 DOI: 10.1021/ja0449980 Supporting Info

Porphyrin Nanotubes by Ionic Self-Assembly Zhongchun Wang, Craig J. Medforth, and John A. Shelnutt pp 15954–15955 DOI: 10.1021/ja045068j Supporting Info

Photoinduced Electron Transfer Reactivity of Aza[60]fullerene:  Three Discrete Functionalization Pathways with a Single Substrate Georgios C. Vougioukalakis and Michael Orfanopoulos pp 15956–15957 DOI: 10.1021/ja045495x Supporting Info

Shape-Tunable Polymer Nodules Grown from Liposomes via Ring-Opening Metathesis Polymerization Nathalie Jarroux, Patrick Keller, Anne-Françoise Mingotaud, Christophe Mingotaud, and Cécile Sykes pp 15958–15959 DOI: 10.1021/ja045482j Supporting Info

Proton Transfer at Helium Temperatures during Dioxygen Activation by Heme Monooxygenases Roman Davydov, Sergey Chemerisov, David E. Werst, Tijana Rajh, Toshitaka Matsui, Masao Ikeda-Saito, and Brian M. Hoffman pp 15960–15961 DOI: 10.1021/ja044646t

A Phage Display System with Unnatural Amino Acids Feng Tian, Meng-Lin Tsao, and Peter G. Schultz pp 15962–15963 DOI: 10.1021/ja045673m Supporting Info

A Unique Catalyst Effects the Rapid Room-Temperature Cross-Coupling of Organozinc Reagents with Carboxylic Acid Fluorides, Chlorides, Anhydrides, and Thioesters Yongda Zhang and Tomislav Rovis pp 15964–15965 DOI: 10.1021/ja044113k Supporting Info

Observation of a Rectangular Columnar Phase in a DNA−Calcium−Zwitterionic Lipid Complex Jennifer J. McManus, Joachim O. Rädler, and Kenneth A. Dawson pp 15966–15967 DOI: 10.1021/ja046105+

The Total Synthesis of (−)-SNF4435 C and (+)-SNF4435 D Kathlyn A. Parker and Yeon-Hee Lim pp 15968–15969 DOI: 10.1021/ja044733l Supporting Info

Total Synthesis of Amphidinolide X Olivier Lepage, Egmont Kattnig, and Alois Fürstner pp 15970–15971 DOI: 10.1021/ja044130+ Supporting Info

Right-Handed Helical Structure of Expanded Oligo(l-leucine) Containing [Ru(terpyridine)2]2+ Moieties Taka-aki Okamura, Taku Iwamura, Shuichiro Seno, Hitoshi Yamamoto, and Norikazu Ueyama pp 15972–15973 DOI: 10.1021/ja044310j Supporting Info

Self-Assembled Electrooptic Thin Films with Remarkably Blue-Shifted Optical Absorption Based on an X-Shaped Chromophore Hu Kang, Peiwang Zhu, Yu Yang, Antonio Facchetti, and Tobin J. Marks pp 15974–15975 DOI: 10.1021/ja045043k Supporting Info

Redox Buffering of Hypochlorous Acid by Thiocyanate in Physiologic Fluids Michael T. Ashby, Amy C. Carlson, and M. Jared Scott pp 15976–15977 DOI: 10.1021/ja0438361 Supporting Info

Gold(I)-Catalyzed Propargyl Claisen Rearrangement Benjamin D. Sherry and F. Dean Toste pp 15978–15979 DOI: 10.1021/ja044602k Supporting Info

γ4-Aminoxy Peptides as New Peptidomimetic Foldamers Fei Chen, Nian-Yong Zhu, and Dan Yang pp 15980–15981 DOI: 10.1021/ja044493+ Supporting Info

A Sonochemical Route to Single-Walled Carbon Nanotubes under Ambient Conditions Soo-Hwan Jeong, Ju-Hye Ko, Jong-Bong Park, and Wanjun Park pp 15982–15983 DOI: 10.1021/ja0451867 Supporting Info

In Situ Chemical Aminoacylation with Amino Acid Thioesters Linked to a Peptide Nucleic Acid Keiko Ninomiya, Toshikazu Minohata, Masaki Nishimura, and Masahiko Sisido pp 15984–15989 DOI: 10.1021/ja048200o Supporting Info

Facile, Efficient, and Enantiospecific Syntheses of 1,1‘-N-Linked Pseudodisaccharides as a New Class of Glycosidase Inhibitors Tony K. M. Shing, Connie S. K. Kwong, Aries W. C. Cheung, Stanton H.-L. Kok, Zhifeng Yu, Jianmei Li, and Christopher H. K. Cheng pp 15990–15992 DOI: 10.1021/ja0470158 Supporting Info

Unusually Broad Substrate Tolerance of a Heat-Stable Archaeal Sugar Nucleotidyltransferase for the Synthesis of Sugar Nucleotides Rahman M. Mizanur, Corbin J. Zea, and Nicola L. Pohl pp 15993–15998 DOI: 10.1021/ja046070d Supporting Info

Photocatalytic Oxygenation of Anthracenes and Olefins with Dioxygen via Selective Radical Coupling Using 9-Mesityl-10-methylacridinium Ion as an Effective Electron-Transfer Photocatalyst Hiroaki Kotani, Kei Ohkubo, and Shunichi Fukuzumi pp 15999–16006 DOI: 10.1021/ja048353b Supporting Info

Ligand Binding Properties of Myoglobin Reconstituted with Iron Porphycene:  Unusual O2 Binding Selectivity against CO Binding1 Takashi Matsuo, Hirohisa Dejima, Shun Hirota, Dai Murata, Hideaki Sato, Takahiro Ikegami, Hiroshi Hori, Yoshio Hisaeda, and Takashi Hayashi pp 16007–16017 DOI: 10.1021/ja045880m

Counterion Controlled Photoisomerization of Retinal Chromophore Models:  a Computational Investigation Alessandro Cembran, Fernando Bernardi, Massimo Olivucci, and Marco Garavelli pp 16018–16037 DOI: 10.1021/ja048782+ Supporting Info

Refinement of NMR Structures Using Implicit Solvent and Advanced Sampling Techniques Jianhan Chen, Wonpil Im, and Charles L. Brooks, III pp 16038–16047 DOI: 10.1021/ja047624f

Dispersion Interactions Enable the Self-Directed Growth of Linear Alkane Nanostructures Covalently Bound to Silicon Gino A. DiLabio, Paul G. Piva, Peter Kruse, and Robert A. Wolkow pp 16048–16050 DOI: 10.1021/ja0460007 Supporting Info

Fragmentation of Aryl Halide π Anion Radicals. Bending of the Cleaving Bond and Activation vs Driving Force Relationships Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 16051–16057 DOI: 10.1021/ja045989u Supporting Info

Deoxygenation and Other Photochemical Reactions of Aromatic Selenoxides1 Ryan D. McCulla and William S. Jenks pp 16058–16065 DOI: 10.1021/ja045935k Supporting Info

Ruthenium- and Platinum-Catalyzed Sequential Reactions:  Selective Synthesis of Fused Polycyclic Compounds from Propargylic Alcohols and Alkenes Yoshiaki Nishibayashi, Masato Yoshikawa, Youichi Inada, Masanobu Hidai, and Sakae Uemura pp 16066–16072 DOI: 10.1021/ja045532k Supporting Info

Calix[4]pyrrole[2]carbazole:  A New Kind of Expanded Calixpyrrole Piotr Pitek, Vincent M. Lynch, and Jonathan L. Sessler pp 16073–16076 DOI: 10.1021/ja045218q Supporting Info

A Library of Spirooxindoles Based on a Stereoselective Three-Component Coupling Reaction Michael M.-C. Lo, Christopher S. Neumann, Satoshi Nagayama, Ethan O. Perlstein, and Stuart L. Schreiber pp 16077–16086 DOI: 10.1021/ja045089d Supporting Info

Allylic Ionization versus Oxidative Addition into Vinyl C−X Bonds by Pd with Polyfunctional Olefin Templates Eamon Comer, Michael G. Organ, and Stephen J. Hynes pp 16087–16092 DOI: 10.1021/ja045416h Supporting Info

Hemiortho Esters and Hydrotrioxides as the Primary Products in the Low-Temperature Ozonation of Cyclic Acetals:  An Experimental and Theoretical Investigation Tell Tuttle, Janez Cerkovnik, Božo Plesniar, and Dieter Cremer pp 16093–16104 DOI: 10.1021/ja0450511 Supporting Info

Organogermanium Reactive Intermediates. The Direct Detection and Characterization of Transient Germylenes and Digermenes in Solution William J. Leigh, Cameron R. Harrington, and Ignacio Vargas-Baca pp 16105–16116 DOI: 10.1021/ja046308y Supporting Info

Cu[Au(CN)2]2(DMSO)2:  Golden Polymorphs That Exhibit Vapochromic Behavior Julie Lefebvre, Raymond J. Batchelor, and Daniel B. Leznoff pp 16117–16125 DOI: 10.1021/ja049069n Supporting Info

Studying and Switching Electron Transfer:  From the Ensemble to the Single Molecule Michael W. Holman, Ruchuan Liu, Ling Zang, Ping Yan, Sara A. DiBenedetto, Robert D. Bowers, and David M. Adams pp 16126–16133 DOI: 10.1021/ja047386o Supporting Info

Electronic Structure and Chemical Bonding in MOn- and MOn Clusters (M = Mo, W; n = 3−5):  A Photoelectron Spectroscopy and ab Initio Study Hua-Jin Zhai, Boggavarapu Kiran, Li-Feng Cui, Xi Li, David A. Dixon, and Lai-Sheng Wang pp 16134–16141 DOI: 10.1021/ja046536s

Enantioselective Hydrogenation of Imines in Ionic Liquid/Carbon Dioxide Media Maurizio Solinas, Andreas Pfaltz, Pier Giorgio Cozzi, and Walter Leitner pp 16142–16147 DOI: 10.1021/ja046129g

Differential Transition-State Stabilization in Enzyme Catalysis:  Quantum Chemical Analysis of Interactions in the Chorismate Mutase Reaction and Prediction of the Optimal Catalytic Field Borys Szefczyk, Adrian J. Mulholland, Kara E. Ranaghan, and W. Andrzej Sokalski pp 16148–16159 DOI: 10.1021/ja049376t Supporting Info

Theoretical Analysis of the Smallest Carbon Cluster Containing a Planar Tetracoordinate Carbon Gabriel Merino, Miguel A. Méndez-Rojas, Hiram I. Beltrán, Clemence Corminboeuf, Thomas Heine, and Alberto Vela pp 16160–16169 DOI: 10.1021/ja047848y

Extraction of Au Nanoparticles Having Narrow Size Distributions from within Dendrimer Templates Joaquin C. Garcia-Martinez and Richard M. Crooks pp 16170–16178 DOI: 10.1021/ja046567n Supporting Info

An Enantioselective Fluorescent Sensor for Sugar Acids Jianzhang Zhao, Matthew G. Davidson, Mary F. Mahon, Gabriele Kociok-Köhn, and Tony D. James pp 16179–16186 DOI: 10.1021/ja046289s Supporting Info

Porphyrin Boxes Constructed by Homochiral Self-Sorting Assembly:  Optical Separation, Exciton Coupling, and Efficient Excitation Energy Migration In-Wook Hwang, Taisuke Kamada, Tae Kyu Ahn, Dah Mee Ko, Takeshi Nakamura, Akihiko Tsuda, Atsuhiro Osuka, and Dongho Kim pp 16187–16198 DOI: 10.1021/ja046241e Supporting Info

Oriented Attachment and Membrane Reconstitution of His-Tagged Cytochrome c Oxidase to a Gold Electrode:  In Situ Monitoring by Surface-Enhanced Infrared Absorption Spectroscopy Kenichi Ataka, Frank Giess, Wolfgang Knoll, Renate Naumann, Sabina Haber-Pohlmeier, Björn Richter, and Joachim Heberle pp 16199–16206 DOI: 10.1021/ja045951h

Catalytic Roles of Active-Site Amino Acid Residues of Coenzyme B12-Dependent Diol Dehydratase:  Protonation State of Histidine and Pull Effect of Glutamate Takashi Kamachi, Tetsuo Toraya, and Kazunari Yoshizawa pp 16207–16216 DOI: 10.1021/ja045572o Supporting Info

Influence of Halogenation on the Properties of Uracil and Its Noncovalent Interactions with Alkali Metal Ions. Threshold Collision-Induced Dissociation and Theoretical Studies Zhibo Yang and M. T. Rodgers pp 16217–16226 DOI: 10.1021/ja045375p Supporting Info

Planar Tetra-, Penta-, Hexa-, Hepta-, and Octacoordinate Silicons:  A Universal Structural Pattern Si-Dian Li, Chang-Qing Miao, Jin-Chang Guo, and Guang-Ming Ren pp 16227–16231 DOI: 10.1021/ja045303y Supporting Info

A DFT Study of the Ground State Multiplicities of Linear vs Angular Polyheteroacenes Christos P. Constantinides, Panayiotis A. Koutentis, and Jürgen Schatz pp 16232–16241 DOI: 10.1021/ja045006t Supporting Info

Autocatalytic Formation of Green Heme:  Evidence for H2O2-Dependent Formation of a Covalent Methionine−Heme Linkage in Ascorbate Peroxidase Clive L. Metcalfe, Michael Ott, Neesha Patel, Kuldip Singh, Sharad C. Mistry, Harold M. Goff, and Emma Lloyd Raven pp 16242–16248 DOI: 10.1021/ja048242c

Diastereoselective Self-Assembly of Chiral Diamine-Chelated Aryllithiums to Dimeric Aggregates Anne M. Arink, Claudia M. P. Kronenburg, Johann T. B. H. Jastrzebski, Martin Lutz, Anthony L. Spek, Robert A. Gossage, and Gerard van Koten pp 16249–16258 DOI: 10.1021/ja045914q Supporting Info

Charged Gels as Orienting Media for Measurement of Residual Dipolar Couplings in Soluble and Integral Membrane Proteins Tomasz Cierpicki and John H. Bushweller pp 16259–16266 DOI: 10.1021/ja046054g

Channel Activity of a Viral Transmembrane Peptide in Micro-BLMs:  Vpu1-32 from HIV-1 Winfried Römer, Yuen H. Lam, Dahlia Fischer, Anthony Watts, Wolfgang B. Fischer, Petra Göring, Ralf B. Wehrspohn, Ulrich Gösele, and Claudia Steinem pp 16267–16274 DOI: 10.1021/ja0451970 Supporting Info

Issue 50

Heterostructured Bi2Se3 Nanowires with Periodic Phase Boundaries Xiaofeng Qiu, Clemens Burda, Ruiling Fu, Lin Pu, Hongyuan Chen, and Junjie Zhu pp 16276–16277 DOI: 10.1021/ja045556r

Polymetallic Lanthanide Complexes with PAMAM-Naphthalimide Dendritic Ligands:  Luminescent Lanthanide Complexes Formed in Solution Jason P. Cross, Miriam Lauz, Paul D. Badger, and Stéphane Petoud pp 16278–16279 DOI: 10.1021/ja045706y Supporting Info

Catalysis by a Synthetic Receptor Sealed at One End and Functionalized at the Other Sébastien Richeter and Julius Rebek, Jr. pp 16280–16281 DOI: 10.1021/ja045167x Supporting Info

Identification of a Cluster of Genes that Directs Desferrioxamine Biosynthesis in Streptomyces coelicolor M145 Francisco Barona-Gómez, Ursula Wong, Anastassios E. Giannakopulos, Peter J. Derrick, and Gregory L. Challis pp 16282–16283 DOI: 10.1021/ja045774k Supporting Info

Nonracemic Dopant-Mediated Hierarchical Amplification of Macromolecular Helicity in a Charged Polyacetylene Leading to a Cholesteric Liquid Crystal in Water Katsuhiro Maeda, Yoshihisa Takeyama, Koichi Sakajiri, and Eiji Yashima pp 16284–16285 DOI: 10.1021/ja044264n Supporting Info

Controlling Primary Hepatocyte Adhesion and Spreading on Protein-Free Polyelectrolyte Multilayer Films Srivatsan Kidambi, Ilsoon Lee, and Christina Chan pp 16286–16287 DOI: 10.1021/ja046188u Supporting Info

Use of a Retroinverso p53 Peptide as an Inhibitor of MDM2 Kaori Sakurai, Hak Suk Chung, and Daniel Kahne pp 16288–16289 DOI: 10.1021/ja044883w Supporting Info

Particle−Rod Hybrids:  Growth of Arachidic Acid Molecular Rods from Capped Cadmium Selenide Nanoparticles Dongzhong Chen, Ruomiao Wang, Indika Arachchige, Guangzhao Mao, and Stephanie L. Brock pp 16290–16291 DOI: 10.1021/ja045011x Supporting Info

Crystal-to-Crystal Guest Exchange of Large Organic Molecules within a 3D Coordination Network Osamu Ohmori, Masaki Kawano, and Makoto Fujita pp 16292–16293 DOI: 10.1021/ja046478a Supporting Info

Strong Modulation of Two-Photon Excited Fluorescence of Quadripolar Dyes by (De)Protonation Martinus H. V. Werts, Said Gmouh, Olivier Mongin, Thomas Pons, and Mireille Blanchard-Desce pp 16294–16295 DOI: 10.1021/ja0446606 Supporting Info

Tetra-TTF Calix[4]pyrrole:  A Rationally Designed Receptor for Electron-Deficient Neutral Guests Kent A. Nielsen, Won-Seob Cho, Jan O. Jeppesen, Vincent M. Lynch, Jan Becher, and Jonathan L. Sessler pp 16296–16297 DOI: 10.1021/ja044664a Supporting Info

Long-Range Flow-Induced Alignment of Self-Assembled Rosette Nanotubes on Si/SiOx and Poly(Methyl Methacrylate)-Coated Si/SiOx Jose Raez, Jesus G. Moralez, and Hicham Fenniri pp 16298–16299 DOI: 10.1021/ja044487d Supporting Info

Total Synthesis of Ingenol Andrew Nickel, Toru Maruyama, Haifeng Tang, Prescott D. Murphy, Blake Greene, Naeem Yusuff, and John L. Wood pp 16300–16301 DOI: 10.1021/ja044123l Supporting Info

Insights into the Spin-Forbidden Reaction between L2Pd0 and Molecular Oxygen Clark R. Landis, Christine M. Morales, and Shannon S. Stahl pp 16302–16303 DOI: 10.1021/ja044674b Supporting Info

A Trimetallic Mixed Ru(II)/Fe(II) Terpyridyl Complex with A Long-Lived Excited State in Solution at Room Temperature Sujoy Baitalik, Xian-yong Wang, and Russell H. Schmehl pp 16304–16305 DOI: 10.1021/ja044561s Supporting Info

The Structure of α-Zn4Sb3:  Ordering of the Phonon-Glass Thermoelectric Material β-Zn4Sb3 Johanna Nylén, Magnus Andersson, Sven Lidin, and Ulrich Häussermann pp 16306–16307 DOI: 10.1021/ja044980p Supporting Info

Hydroxyl Radical at the Air−Water Interface Martina Roeselová, John Vieceli, Liem X. Dang, Bruce C. Garrett, and Douglas J. Tobias pp 16308–16309 DOI: 10.1021/ja045552m Supporting Info

Direct Assessment of Interresidue Forces in Watson−Crick Base Pairs Using Theoretical Compliance Constants Jörg Grunenberg pp 16310–16311 DOI: 10.1021/ja046282a

Probing the Active Catalyst in Product-Accelerated Proline-Mediated Reactions Hiroshi Iwamura, David H. Wells, Jr., Suju P. Mathew, Martin Klussmann, Alan Armstrong, and Donna G. Blackmond pp 16312–16313 DOI: 10.1021/ja0444177 Supporting Info

Photoactivation of a Substrate for Cell Adhesion under Standard Fluorescence Microscopes Jun Nakanishi, Yukiko Kikuchi, Tohru Takarada, Hidekazu Nakayama, Kazuo Yamaguchi, and Mizuo Maeda pp 16314–16315 DOI: 10.1021/ja044684c Supporting Info

Recombinant HDL-Like Nanoparticles:  A Specific Contrast Agent for MRI of Atherosclerotic Plaques Juan C. Frias, Kevin Jon Williams, Edward A. Fisher, and Zahi A. Fayad pp 16316–16317 DOI: 10.1021/ja044911a Supporting Info

Water-Coordinated Neutral Silane Complex:  A Frozen Intermediate of Hydrolysis of Alkoxysilanes Junji Kobayashi, Keiko Kawaguchi, and Takayuki Kawashima pp 16318–16319 DOI: 10.1021/ja047249r Supporting Info

Protein Damage in Drop-on-Demand Printers Gary M. Nishioka, Andrea A. Markey, and Charles K. Holloway pp 16320–16321 DOI: 10.1021/ja044539z

Terminal Cobalt(III) Imido Complexes Supported by Tris(Carbene) Ligands:  Imido Insertion into the Cobalt−Carbene Bond Xile Hu and Karsten Meyer pp 16322–16323 DOI: 10.1021/ja044271b Supporting Info

Nucleic Acid-Triggered Fluorescent Probe Activation by the Staudinger Reaction Jianfeng Cai, Xiaoxu Li, Xuan Yue, and John Stephen Taylor pp 16324–16325 DOI: 10.1021/ja0452626 Supporting Info

New Phenoxyketimine Titanium Complexes:  Combining Isotacticity and Living Behavior in Propylene Polymerization Andrew F. Mason and Geoffrey W. Coates pp 16326–16327 DOI: 10.1021/ja044268s Supporting Info

Palladium-Catalyzed Enantioselective Diboration of Prochiral Allenes Nicholas F. Pelz, Angela R. Woodward, Heather E. Burks, Joshua D. Sieber, and James P. Morken pp 16328–16329 DOI: 10.1021/ja044167u Supporting Info

Bifunctional, Conjugated Oligomers for Orthogonal Self-Assembly:  Selectivity Varies from Planar Substrates to Nanoparticles Brandon R. Walker, Ronald A. Wassel, Diana M. Ştefanescu, and Christopher B. Gorman pp 16330–16331 DOI: 10.1021/ja046491v Supporting Info

Existence of Specific “Folds” in Polyproline II Ensembles of an “Unfolded” Alanine Peptide Detected by Molecular Dynamics Vibin Ramakrishnan, Ranjit Ranbhor, and Susheel Durani pp 16332–16333 DOI: 10.1021/ja045787y Supporting Info

Synthesis of Uniform Cu2S Nanowires from Copper−Thiolate Polymer Precursors by a Solventless Thermolytic Method Ling Chen, Yu-Biao Chen, and Li-Ming Wu pp 16334–16335 DOI: 10.1021/ja045074f Supporting Info

Simultaneous Measurement of Diffusion along Multiple Directions Xiao-Ping Tang, Eric E. Sigmund, and Yi-Qiao Song pp 16336–16337 DOI: 10.1021/ja0447457

Preparation of Free-Standing Nanowire Arrays on Conductive Substrates Yongqi Liang, Changgua Zhen, Dechun Zou, and Dongsheng Xu pp 16338–16339 DOI: 10.1021/ja044545v Supporting Info

Directly Probing the Hybrid Bonding of Styrene on Cu(111) Wei Wei, Wei Zhao, andWei Zhao, and J. M. White pp 16340–16341 DOI: 10.1021/ja044381i

Self-Assembly of Chiral DNA Nanotubes James C. Mitchell, J. Robin Harris, Jonathan Malo, Jonathan Bath, and Andrew J. Turberfield pp 16342–16343 DOI: 10.1021/ja043890h Supporting Info

Design and Characterization of Programmable DNA Nanotubes Paul W. K. Rothemund, Axel Ekani-Nkodo, Nick Papadakis, Ashish Kumar, Deborah Kuchnir Fygenson, and Erik Winfree pp 16344–16352 DOI: 10.1021/ja044319l Supporting Info

Design and Synthesis of Highly Sensitive and Selective Fluorescein-Derived Magnesium Fluorescent Probes and Application to Intracellular 3D Mg2+ Imaging Hirokazu Komatsu, Naoko Iwasawa, Daniel Citterio, Yoshio Suzuki, Takeshi Kubota, Kentaro Tokuno, Yoshiichiro Kitamura, Kotaro Oka, and Koji Suzuki pp 16353–16360 DOI: 10.1021/ja049624l Supporting Info

Porphyrin Distortion during Affinity Maturation of a Ferrochelatase Antibody, Monitored by Resonance Raman Spectroscopy Swarnalatha Venkateshrao, Jun Yin, Andrzej A. Jarzcki, Peter G. Schultz, and Thomas G. Spiro pp 16361–16367 DOI: 10.1021/ja0465395

Synthesis of Fluorescently Labeled Mono- and Diprenylated Rab7 GTPase Thomas Durek, Kirill Alexandrov, Roger S. Goody, Alexandra Hildebrand, Ines Heinemann, and Herbert Waldmann pp 16368–16378 DOI: 10.1021/ja046164n Supporting Info

Synthetic Mimics of Small Mammalian Cell Surface Receptors Siwarutt Boonyarattanakalin, Scott E. Martin, Sheryl A. Dykstra, and Blake R. Peterson pp 16379–16386 DOI: 10.1021/ja046663o Supporting Info

Energetics of Nucleic Acid Stability:  The Effect of ΔCP Anna Tikhomirova, Nicolas Taulier, and Tigran V. Chalikian pp 16387–16394 DOI: 10.1021/ja046387d

Aryl Thiol Substrate 3-Carboxy-4-Nitrobenzenethiol Strongly Stimulating Thiol Peroxidase Activity of Glutathione Peroxidase Mimic 2, 2'-Ditellurobis(2-Deoxy-β-Cyclodextrin) Zeyuan Dong, Junqiu Liu, Shizhong Mao, Xin Huang, Bing Yang, Xiaojun Ren, Guimin Luo, and Jiacong Shen pp 16395–16404 DOI: 10.1021/ja045964v Supporting Info

Loop-Length-Dependent Folding of G-Quadruplexes Pascale Hazel, Julian Huppert, Shankar Balasubramanian, and Stephen Neidle pp 16405–16415 DOI: 10.1021/ja045154j Supporting Info

Temperature Effects on the Catalytic Activity of the D38E Mutant of 3-Oxo-Δ5-Steroid Isomerase:  Favorable Enthalpies and Entropies of Activation Relative to the Nonenzymatic Reaction Catalyzed by Acetate Ion Wendy J. Houck and Ralph M. Pollack pp 16416–16425 DOI: 10.1021/ja046819k Supporting Info

Rational Modification of a Selection Strategy Leads to Deoxyribozymes that Create Native 3‘-5‘ RNA Linkages Rebecca L. Coppins and Scott K. Silverman pp 16426–16432 DOI: 10.1021/ja045817x Supporting Info

Highly Active Palladium Catalysts Supported by Bulky Proazaphosphatrane Ligands for Stille Cross-Coupling:  Coupling of Aryl and Vinyl Chlorides, Room Temperature Coupling of Aryl Bromides, Coupling of Aryl Triflates, and Synthesis of Sterically Hindered Biaryls Weiping Su, Sameer Urgaonkar, Patrick A. McLaughlin, and John G. Verkade pp 16433–16439 DOI: 10.1021/ja0450096 Supporting Info

Donor-Mediated Band Gap Reduction in a Homologous Series of Conjugated Polymers Christopher A. Thomas, Kyukwan Zong, Khalil A. Abboud, Peter J. Steel, and John R. Reynolds pp 16440–16450 DOI: 10.1021/ja048637w Supporting Info

Time Gating Improves Sensitivity in Energy Transfer Assays with Terbium Chelate/Dark Quencher Oligonucleotide Probes Mary Katherine Johansson, Ronald M. Cook, Jide Xu, and Kenneth N. Raymond pp 16451–16455 DOI: 10.1021/ja0452368

A New Tripodal Receptor for Molecular Recognition of Monosaccharides. A Paradigm for Assessing Glycoside Binding Affinities and Selectivities by 1H NMR Spectroscopy Alberto Vacca, Cristina Nativi, Martina Cacciarini, Roberto Pergoli, and Stefano Roelens pp 16456–16465 DOI: 10.1021/ja045813s Supporting Info

Proton-Driven Self-Assembled Systems Based on Cyclam-Cored Dendrimers and [Ru(bpy)(CN)4]2- Giacomo Bergamini, Christophe Saudan, Paola Ceroni, Mauro Maestri, Vincenzo Balzani, Marius Gorka, Sang-Kyu Lee, Jeroen van Heyst, and Fritz Vögtle pp 16466–16471 DOI: 10.1021/ja0450814

Crystalline, Mixed-Valence Manganese Analogue of Prussian Blue:  Magnetic, Spectroscopic, X-ray and Neutron Diffraction Studies Patrick Franz, Christina Ambrus, Andreas Hauser, Dmitry Chernyshov, Marc Hostettler, Jürg Hauser, Lukas Keller, Karl Krämer, Helen Stoeckli-Evans, Philip Pattison, Hans-Beat Bürgi, and Silvio Decurtins pp 16472–16477 DOI: 10.1021/ja0465451 Supporting Info

Grafted Metallocalixarenes as Single-Site Surface Organometallic Catalysts Justin M. Notestein, Enrique Iglesia, and Alexander Katz pp 16478–16486 DOI: 10.1021/ja0470259 Supporting Info

Computational Assignment of the EC Numbers for Genomic-Scale Analysis of Enzymatic Reactions Masaaki Kotera, Yasushi Okuno, Masahiro Hattori, Susumu Goto, and Minoru Kanehisa pp 16487–16498 DOI: 10.1021/ja0466457 Supporting Info

An Excimer-Based, Binuclear, On−Off Switchable Calix[4]crown Chemosensor Sung Kuk Kim, Seoung Ho Lee, Ji Yeon Lee, Jin Yong Lee, Richard A. Bartsch, and Jong Seung Kim pp 16499–16506 DOI: 10.1021/ja045689c Supporting Info

Nature of Urea−Fluoride Interaction:  Incipient and Definitive Proton Transfer Massimo Boiocchi, Laura Del Boca, David Esteban Gómez, Luigi Fabbrizzi, Maurizio Licchelli, and Enrico Monzani pp 16507–16514 DOI: 10.1021/ja045936c Supporting Info

Tuning the Specificity of a Synthetic Receptor Using a Selected Nucleic Acid Receptor Joseph C. Manimala, Sheryl L. Wiskur, Andrew D. Ellington, and Eric V. Anslyn pp 16515–16519 DOI: 10.1021/ja0478476

pH-Selective Synthesis and Structures of Alkynyl, Acyl, and Ketonyl Intermediates in Anti-Markovnikov and Markovnikov Hydrations of a Terminal Alkyne with a Water-Soluble Iridium Aqua Complex in Water Seiji Ogo, Keiji Uehara, Tsutomu Abura, Yoshihito Watanabe, and Shunichi Fukuzumi pp 16520–16527 DOI: 10.1021/ja0473541 Supporting Info

Helical Aromatic Oligoamides:  Reliable, Readily Predictable Folding from the Combination of Rigidified Structural Motifs Lihua Yuan, Huaqiang Zeng, Kazuhiro Yamato, Adam R. Sanford, Wen Feng, Hanudatta S. Atreya, Dinesh K. Sukumaran, Thomas Szyperski, and Bing Gong pp 16528–16537 DOI: 10.1021/ja046858w

Selection Rules for Helicate Ligand Component Self-Assembly:  Steric, pH, Charge, and Solvent Effects Jonathan R. Nitschke, David Schultz, Gérald Bernardinelli, and David Gérard pp 16538–16543 DOI: 10.1021/ja046001z Supporting Info

Structural, Volumetric, and Thermodynamic Characterization of a Micellar Sphere-to-Rod Transition Heiko Heerklotz, Alekos Tsamaloukas, Katarzyna Kita-Tokarczyk, Pavel Strunz, and Thomas Gutberlet pp 16544–16552 DOI: 10.1021/ja045525w Supporting Info

Total Synthesis of (−)-Incarvilline, (+)-Incarvine C, and (−)-Incarvillateine Masaya Ichikawa, Masaki Takahashi, Sakae Aoyagi, and Chihiro Kibayashi pp 16553–16558 DOI: 10.1021/ja0401702 Supporting Info

Diastereoselective Alkylation of β-Amino Esters:  Structural and Rate Studies Reveal Alkylations of Hexameric Lithium Enolates Anne J. McNeil, Gilman E. S. Toombes, Sol M. Gruner, Emil Lobkovsky, David B. Collum, Sithamalli V. Chandramouli, Benoit J. Vanasse, and Timothy A. Ayers pp 16559–16568 DOI: 10.1021/ja045144i Supporting Info

Ambidentate Pyridyl-carboxylate Ligands in the Coordination-Driven Self-Assembly of 2D Pt Macrocycles:  Self-Selection for a Single Isomer Ki-Whan Chi, Chris Addicott, Atta M. Arif, and Peter J. Stang pp 16569–16574 DOI: 10.1021/ja045542l Supporting Info

Selective 226Ra2+ Ionophores Provided by Self-Assembly of Guanosine and Isoguanosine Derivatives Fijs W. B. van Leeuwen, Willem Verboom, Xiaodong Shi, Jeffery T. Davis, and David N. Reinhoudt pp 16575–16581 DOI: 10.1021/ja0455650 Supporting Info

A Precipitator for the Detection of Thiophilic Metals in Aqua Tobin J. Dickerson, Neal N. Reed, James J. LaClair, and Kim D. Janda pp 16582–16586 DOI: 10.1021/ja045798r

Crystalline Inclusion Compounds Constructed through Self-Assembly of Isonicotinic Acid and Thiocyanato Coordination Bridges Ryo Sekiya, Shin-ichi Nishikiori, and Katsuyuki Ogura pp 16587–16600 DOI: 10.1021/ja0463280 Supporting Info

Oxidation of Methionine Residues in Aqueous Solutions:  Free Methionine and Methionine in Granulocyte Colony-Stimulating Factor Jhih-Wei Chu, Bernard R. Brooks, and Bernhardt L. Trout pp 16601–16607 DOI: 10.1021/ja0467059 Supporting Info

Magic Angle Spinning Solid-State NMR Spectroscopy for Structural Studies of Protein Interfaces. Resonance Assignments of Differentially Enriched Escherichia coli Thioredoxin Reassembled by Fragment Complementation Dabeiba Marulanda, Maria Luisa Tasayco, Ann McDermott, Marcela Cataldi, Vilma Arriaran, and Tatyana Polenova pp 16608–16620 DOI: 10.1021/ja0464589 Supporting Info

In Situ Raman Spectroscopy of Bias-Induced Structural Changes in Nitroazobenzene Molecular Electronic Junctions Aletha M. Nowak and Richard L. McCreery pp 16621–16631 DOI: 10.1021/ja045763r

Conformational Change of H+-ATPase β Monomer Revealed on Segmental Isotope Labeling NMR Spectroscopy Hiromasa Yagi, Takuya Tsujimoto, Toshio Yamazaki, Masasuke Yoshida, and Hideo Akutsu pp 16632–16638 DOI: 10.1021/ja045279o

Electronic and Molecular Structure of High-Spin d4 Complexes:  Experimental and Theoretical Study of the [Cr(D2O)6]2+ Cation in Tutton's Salts Christopher Dobe, Christopher Noble, Graham Carver, Philip L. W. Tregenna-Piggott, Garry J. McIntyre, Anne-Laure Barra, Antonia Neels, Stefan Janssen, and Fanni Juranyi pp 16639–16652 DOI: 10.1021/ja046095c Supporting Info

Surface-Bound Porphyrazines:  Controlling Reduction Potentials of Self-Assembled Monolayers through Molecular Proximity/Orientation to a Metal Surface Benjamin J. Vesper, Khalid Salaita, Hong Zong, Chad A. Mirkin, Anthony G. M. Barrett, and Brian M. Hoffman pp 16653–16658 DOI: 10.1021/ja045270m Supporting Info

Label-Free Molecular Interaction Determinations with Nanoscale Interferometry Dmitry A. Markov, Kelly Swinney, and Darryl J. Bornhop pp 16659–16664 DOI: 10.1021/ja047820m

Primary and Secondary Structure Dependence of Peptide Flexibility Assessed by Fluorescence-Based Measurement of End-to-End Collision Rates Fang Huang, Robert R. Hudgins, and Werner M. Nau pp 16665–16675 DOI: 10.1021/ja0466053

Investigations of Polypeptide Rotational Diffusion in Aligned Membranes by 2H and 15N Solid-State NMR Spectroscopy Christopher Aisenbrey and Burkhard Bechinger pp 16676–16683 DOI: 10.1021/ja0468675

Hydrolysis in Drug and Prodrug Metabolism:  Chemistry, Biochemistry, and Enzymology By Bernard Testa (University of Lausanne, Switzerland) and Joachim M. Mayer (deceased). Verlag Helvetica Chimica Acta:  Zurich and Wiley-VCH GmbH & Co. KGaA:  Weinheim, Germany. 2003. xx + 780 pp. $215.00. ISBN 3-906390-25-X. Patrick J. Davis p 16684 DOI: 10.1021/ja033676d

Issue 51

Structure-Based Design of Potent, Conformationally Constrained Smac Mimetics Haiying Sun, Zaneta Nikolovska-Coleska, Chao-Yie Yang, Liang Xu, Meilan Liu, York Tomita, Hongguang Pan, Yoshiko Yoshioka, Krzysztof Krajewski, Peter P. Roller, and Shaomeng Wang pp 16686–16687 DOI: 10.1021/ja047438+ Supporting Info

Electronic Effects Steer the Mechanism of Asymmetric Hydrogenations of Unfunctionalized Aryl-Substituted Alkenes Yubo Fan, Xiuhua Cui, Kevin Burgess, and Michael B. Hall pp 16688–16689 DOI: 10.1021/ja044240g Supporting Info

Automatic and Subsequent Dissolution and Precipitation Process in Inorganic Macroionic Solutions Guang Liu, Yuguang Cai, and Tianbo Liu pp 16690–16691 DOI: 10.1021/ja045688k

Water-Dependent Reactions of Diiron(II) Carboxylate Complexes Sungho Yoon and Stephen J. Lippard pp 16692–16693 DOI: 10.1021/ja044489y Supporting Info

Cavity-Induced Spin−Spin Interaction between Organic Radicals within a Self-Assembled Coordination Cage Koji Nakabayashi, Masaki Kawano, Michito Yoshizawa, Shin-ichi Ohkoshi, and Makoto Fujita pp 16694–16695 DOI: 10.1021/ja044445p Supporting Info

Acyclic Telluroiminium Salts:  Isolation and Characterization Yuichiro Mutoh, Toshiaki Murai, and Shigeru Yamago pp 16696–16697 DOI: 10.1021/ja044022n Supporting Info

Large-Scale Fabrication of Aligned Single-Walled Carbon Nanotube Array and Hierarchical Single-Walled Carbon Nanotube Assembly Junbo Gao, Aiping Yu, Mikhail E. Itkis, Elena Bekyarova, Bin Zhao, Sandip Niyogi, and Robert C. Haddon pp 16698–16699 DOI: 10.1021/ja044499z Supporting Info

c-di-GMP Displays A Monovalent Metal Ion-Dependent Polymorphism Zhaoying Zhang, Barbara L. Gaffney, and Roger A. Jones pp 16700–16701 DOI: 10.1021/ja0449832 Supporting Info

Site-Specific Replacement of a Conserved Tyrosine in Ribonucleotide Reductase with an Aniline Amino Acid:  A Mechanistic Probe for a Redox-Active Tyrosine Michelle C. Y. Chang, Cyril S. Yee, Daniel G. Nocera, and JoAnne Stubbe pp 16702–16703 DOI: 10.1021/ja044124d Supporting Info

Light-Directed Radial Combinatorial Chemistry:  Orthogonal Safety-Catch Protecting Groups for the Synthesis of Small Molecule Microarrays Alex Shaginian, Madhusudan Patel, Mo-Huang Li, Shane T. Flickinger, Changhan Kim, Franco Cerrina, and Peter J. Belshaw pp 16704–16705 DOI: 10.1021/ja044702q Supporting Info

Direct Imaging of Zero-Field Dipolar Structures in Colloidal Dispersions of Synthetic Magnetite Mark Klokkenburg, Chantal Vonk, Eva M. Claesson, Johannes D. Meeldijk, Ben H. Erné, and Albert P. Philipse pp 16706–16707 DOI: 10.1021/ja0456252

Detection and Reactivity of Pd((C8H14)PCH2CH2P(C8H14))(CHPhCH2Ph)(H) as Determined by Parahydrogen-Enhanced NMR Spectroscopy J. P. Dunne, S. Aiken, S. B. Duckett, D. Konya, K. Q. Almeida Leñero, and E. Drent pp 16708–16709 DOI: 10.1021/ja044875f Supporting Info

Laser Tweezers Raman Study of Optically Trapped Aerosol Droplets of Seawater and Oleic Acid Reacting with Ozone:  Implications for Cloud-Droplet Properties Martin D. King, Katherine C. Thompson, and Andrew D. Ward pp 16710–16711 DOI: 10.1021/ja044717o

Efficient Photodissociation of O2 from Synthetic Heme and Heme/M (M = Fe, Cu) Complexes H. Christopher Fry, Paul G. Hoertz, Ian M. Wasser, Kenneth D. Karlin, and Gerald J. Meyer pp 16712–16713 DOI: 10.1021/ja045195f Supporting Info

Isoxazolyl-Serine-Based Agonists of Peroxisome Proliferator-Activated Receptor:  Design, Synthesis, and Effects on Cardiomyocyte Differentiation Zhi-Liang Wei, Pavel A. Petukhov, Fero Bizik, Joaquim Cabral Teixeira, Mark Mercola, Eugene A. Volpe, Robert I. Glazer, Timothy M. Willson, and Alan P. Kozikowski pp 16714–16715 DOI: 10.1021/ja046386l Supporting Info

A Sterically Expanded “Constrained Geometry Catalyst” for Highly Active Olefin Polymerization and Copolymerization:  An Unyielding Comonomer Effect Levi J. Irwin, Joseph H. Reibenspies, and Stephen A. Miller pp 16716–16717 DOI: 10.1021/ja044678g Supporting Info

Hydrogen Bonds of RNA Are Stronger than Those of DNA, but NMR Monitors Only Presence of Methyl Substituent in Uracil/Thymine Marcel Swart, Célia Fonseca Guerra, and F. Matthias Bickelhaupt pp 16718–16719 DOI: 10.1021/ja045276b Supporting Info

Self-Metallization of Photocatalytic Porphyrin Nanotubes Zhongchun Wang, Craig J. Medforth, and John A. Shelnutt pp 16720–16721 DOI: 10.1021/ja044148k Supporting Info

Dispersion and Current−Voltage Characteristics of Helical Polyacetylene Single Fibers Hyun J. Lee, Zhao X. Jin, Andrey N. Aleshin, Ju Y. Lee, Mun J. Goh, Kazuo Akagi, Young S. Kim, Dong W. Kim, and Yung W. Park pp 16722–16723 DOI: 10.1021/ja044615y Supporting Info

Electrochemical and Conductivity Measurements of Single-Wall Carbon Nanotube Network Electrodes Thomas M. Day, Neil R. Wilson, and Julie V. Macpherson pp 16724–16725 DOI: 10.1021/ja044540y Supporting Info

Characterization of tylM3/tylM2 and mydC/mycB Pairs Required for Efficient Glycosyltransfer in Macrolide Antibiotic Biosynthesis Charles E. Melançon III, Haruko Takahashi, and Hung-wen Liu pp 16726–16727 DOI: 10.1021/ja043900e Supporting Info

Specific Radiation Damage Illustrates Light-Induced Structural Changes in the Photosynthetic Reaction Center Richard H. G. Baxter, Brandon-Luke Seagle, Nina Ponomarenko, and James R. Norris pp 16728–16729 DOI: 10.1021/ja0448115 Supporting Info

Effect of a Weak Magnetic Field on the Reaction between Neutral Free Radicals in Isotropic Solution Claire B. Vink and Jonathan R. Woodward pp 16730–16731 DOI: 10.1021/ja043945f

Engineering the Reactivity of Metal Catalysts:  A Model Study of Methane Dehydrogenation on Rh(111) Anton Kokalj, Nicola Bonini, Carlo Sbraccia, Stefano de Gironcoli, and Stefano Baroni pp 16732–16733 DOI: 10.1021/ja045169h Supporting Info

Determination of the Chromophore Structures in the Photoinduced Reaction Cycle of Phytochrome Maria Andrea Mroginski, Daniel H. Murgida, David von Stetten, Christa Kneip, Franz Mark, and Peter Hildebrandt pp 16734–16735 DOI: 10.1021/ja043959l Supporting Info

Predictive in Silico All-Atom Folding of a Four-Helix Protein with a Free-Energy Model Alexander Schug and Wolfgang Wenzel pp 16736–16737 DOI: 10.1021/ja0453681 Supporting Info

A DFT Computational Study on Electrophilic Substitutions upon α-Oxy-Substituted Benzylorganolithium Compounds:  Lithium Catalysis Is the Hidden Piece of the Puzzle Magdalena Capó and José M. Saá pp 16738–16739 DOI: 10.1021/ja045203s Supporting Info

Threading-Followed-by-Shrinking Protocol for the Synthesis of a [2]Rotaxane Incorporating a Pd(II)−Salophen Moiety Il Yoon, Mamiko Narita, Toshimi Shimizu, and Masumi Asakawa pp 16740–16741 DOI: 10.1021/ja0464490 Supporting Info

Formation of the Aureothin Tetrahydrofuran Ring by a Bifunctional Cytochrome P450 Monooxygenase Jing He, Markus Müller, and Christian Hertweck pp 16742–16743 DOI: 10.1021/ja046104h Supporting Info

Fabrication of ZnO “Dandelions” via a Modified Kirkendall Process Bin Liu and Hua Chun Zeng pp 16744–16746 DOI: 10.1021/ja044825a Supporting Info

Superbowl Container Molecules Elizabeth S. Barrett, Jacob L. Irwin, Alison J. Edwards, and Michael S. Sherburn pp 16747–16749 DOI: 10.1021/ja044405l Supporting Info

Structural Insights into Nonheme Alkylperoxoiron(III) and Oxoiron(IV) Intermediates by X-ray Absorption Spectroscopy Jan-Uwe Rohde, Stéphane Torelli, Xiaopeng Shan, Mi Hee Lim, Eric J. Klinker, József Kaizer, Kui Chen, Wonwoo Nam, and Lawrence Que, Jr. pp 16750–16761 DOI: 10.1021/ja047667w Supporting Info

Toward Assessing the Position-Dependent Contributions of Backbone Hydrogen Bonding to β-Sheet Folding Thermodynamics Employing Amide-to-Ester Perturbations Songpon Deechongkit, Philip E. Dawson, and Jeffery W. Kelly pp 16762–16771 DOI: 10.1021/ja045934s

Formation and Manipulation of Protopolymer Chains Gregory S. McCarty and Paul S. Weiss pp 16772–16776 DOI: 10.1021/ja038930g

Characterization of 5-Hydroxy-8-oxo-7,8-dihydroguanosine in the Photosensitized Oxidation of 8-Oxo-7,8-dihydroguanosine and Its Rearrangement to Spiroiminodihydantoin Jeremy E. B. McCallum, Corrie Y. Kuniyoshi, and Christopher S. Foote pp 16777–16782 DOI: 10.1021/ja030678p Supporting Info

Stereoselectivity Control by Oxaspiro Rings during Diels−Alder Cycloadditions to Cross-Conjugated Cyclohexadienones:  The Syn Oxygen Phenomenon Katsuo Ohkata, Yukiko Tamura, Brandon B. Shetuni, Ryukichi Takagi, Wataru Miyanaga, Satoshi Kojima, and Leo A. Paquette pp 16783–16792 DOI: 10.1021/ja047027t Supporting Info

Synthesis and Properties of Highly Fluorescent Indolizino[3,4,5-ab]isoindoles Teruyuki Mitsumori, Michael Bendikov, Olivier Dautel, Fred Wudl, Takeshi Shioya, Hideki Sato, and Yoshiharu Sato pp 16793–16803 DOI: 10.1021/ja049214x Supporting Info

Temperature-Dependent Behavior of a Symmetric Long-Chain Bolaamphiphile with Phosphocholine Headgroups in Water:  From Hydrogel to Nanoparticles Karen Köhler, Günter Förster, Anton Hauser, Bodo Dobner, Ulrich F. Heiser, Friederike Ziethe, Walter Richter, Frank Steiniger, Markus Drechsler, Heiko Stettin, and Alfred Blume pp 16804–16813 DOI: 10.1021/ja046537k Supporting Info

Tetra-Rhenium Molecular Rectangles as Organizational Motifs for the Investigation of Ligand-Centered Mixed Valency:  Three Examples of Full Delocalization Peter H. Dinolfo and Joseph T. Hupp pp 16814–16819 DOI: 10.1021/ja045457d Supporting Info

Enantioselective Synthesis of Six-Membered Palladacycles Having Metal-Bound Stereogenic Carbons:  Isolation and Reactivity of Palladacycles Containing Readily Accessible β-Hydrogens Brenda J. Burke and Larry E. Overman pp 16820–16833 DOI: 10.1021/ja045047p Supporting Info

Stepwise and Concerted Electron-Transfer/Bond Breaking Reactions. Solvent Control of the Existence of Unstable π Ion Radicals and of the Activation Barriers of Their Heterolytic Cleavage Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 16834–16840 DOI: 10.1021/ja045294t

Vapochromism and Its Structural Basis in a Luminescent Pt(II) Terpyridine−Nicotinamide Complex Thaddeus J. Wadas, Quan-Ming Wang, Yong-joo Kim, Christine Flaschenreim, Thomas N. Blanton, and Richard Eisenberg pp 16841–16849 DOI: 10.1021/ja047955s Supporting Info

Perturbation of Fluorescence by Nonspecific Interactions between Anionic Poly(phenylenevinylene)s and Proteins:  Implications for Biosensors Stephen J. Dwight, Brent S. Gaylord, Janice W. Hong, and Guillermo C. Bazan pp 16850–16859 DOI: 10.1021/ja0469737 Supporting Info

Role of the Orbitally Degenerate Mn(III) Ions in the Single-Molecule Magnet Behavior of the Cyanide Cluster {[MnII(tmphen)2]3[MnIII(CN)6]2} (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) Andrei V. Palii, Sergei M. Ostrovsky, Sophia I. Klokishner, Boris S. Tsukerblat, Curtis P. Berlinguette, Kim R. Dunbar, and José Ramón Galán-Mascarós pp 16860–16867 DOI: 10.1021/ja046771a Supporting Info

Ligand K-edge X-ray Absorption Spectroscopy and DFT Calculations on [Fe3S4]0,+ Clusters:  Delocalization, Redox, and Effect of the Protein Environment Abhishek Dey, Thorsten Glaser, Jose J.-G. Moura, Richard H. Holm, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 16868–16878 DOI: 10.1021/ja0466208 Supporting Info

Nanocrystalline Iron Oxide Aerogels as Mesoporous Magnetic Architectures Jeffrey W. Long, Michael S. Logan, Christopher P. Rhodes, Everett E. Carpenter, Rhonda M. Stroud, and Debra R. Rolison pp 16879–16889 DOI: 10.1021/ja046044f Supporting Info

A Family of Decamethylmetallocene Charge-Transfer Salt Magnets Using Methyl Tricyanoethylenecarboxylate (MTCE) as the Electron Acceptor Guangbin Wang, Carla Slebodnick, Ray J. Butcher, Mary C. Tam, T. Daniel Crawford, and Gordon T. Yee pp 16890–16895 DOI: 10.1021/ja0457213 Supporting Info

Dioxygen Activation at a Single Copper Site:  Structure, Bonding, and Mechanism of Formation of 1:1 Cu−O2 Adducts Nermeen W. Aboelella, Sergey V. Kryatov, Benjamin F. Gherman, William W. Brennessel, Victor G. Young, Jr., Ritimukta Sarangi, Elena V. Rybak-Akimova, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, Christopher J. Cramer, and William B. Tolman pp 16896–16911 DOI: 10.1021/ja045678j Supporting Info

Dissociation of Carbanions from Acyl Iridium Compounds:  An Experimental and Computational Investigation Joseph G. Cordaro and Robert G. Bergman pp 16912–16929 DOI: 10.1021/ja045859l Supporting Info

Preparation and Characterization of the Native Iron(II)-Containing DNA Repair AlkB Protein Directly from Escherichia coli Yukiko Mishina, Lin X. Chen, and Chuan He pp 16930–16936 DOI: 10.1021/ja045066z Supporting Info

Zirconium Sandwich Complexes with η9 Indenyl Ligands:  Well-Defined Precursors for Zirconocene-Mediated Coupling Reactions Christopher A. Bradley, Ivan Keresztes, Emil Lobkovsky, Victor G. Young, and Paul J. Chirik pp 16937–16950 DOI: 10.1021/ja045072v Supporting Info

Self-Assembled Monolayers of Cobalt(II)− (4-tert-Butylphenyl)-Porphyrins:  The Influence of the Electronic Dipole on Scanning Tunneling Microscopy Images Valentina Arima, Eduardo Fabiano, Robert I. R. Blyth, Fabio Della Sala, Francesca Matino, Julie Thompson, Roberto Cingolani, and Ross Rinaldi pp 16951–16958 DOI: 10.1021/ja0470970

pH-Triggered Assembly of Organometallic Receptors for Lithium Ions Zacharias Grote, Rosario Scopelliti, and Kay Severin pp 16959–16972 DOI: 10.1021/ja044874n Supporting Info

Brownian Force Profile Reconstruction of Interfacial 1-Nonanol Solvent Structure Paul D. Ashby and Charles M. Lieber pp 16973–16980 DOI: 10.1021/ja045970r

The Mobile Proton in Polyalanine Peptides Motoya Kohtani, Jean E. Schneider, Thaddeus C. Jones, and Martin F. Jarrold pp 16981–16987 DOI: 10.1021/ja045336d

Electron Transfer at a Dithiolate-Bridged Diiron Assembly:  Electrocatalytic Hydrogen Evolution Stacey J. Borg, Thomas Behrsing, Stephen P. Best, Mathieu Razavet, Xiaoming Liu, and Christopher J. Pickett pp 16988–16999 DOI: 10.1021/ja045281f Supporting Info

XeAuF Stephen A. Cooke and Michael C. L. Gerry pp 17000–17008 DOI: 10.1021/ja044955j

Stability of Polypeptide Multilayers As Studied by in Situ Ellipsometry:  Effects of Drying and Post-Buildup Changes in Temperature and pH Tobias J. Halthur, Per M. Claesson, and Ulla M. Elofsson pp 17009–17015 DOI: 10.1021/ja0464645

Sequence and Structural Duality:  Designing Peptides to Adopt Two Stable Conformations Maya J. Pandya, Eleonora Cerasoli, Abbey Joseph, Rhys G. Stoneman, Eleanor Waite, and Derek N. Woolfson pp 17016–17024 DOI: 10.1021/ja045568c Supporting Info

Synthesis and Derivatization of Daptomycin:  A Chemoenzymatic Route to Acidic Lipopeptide Antibiotics Jan Grünewald, Stephan A. Sieber, Christoph Mahlert, Uwe Linne, and Mohamed A. Marahiel pp 17025–17031 DOI: 10.1021/ja045455t Supporting Info

Density Functional Theory Studies on the Mechanisms of Regioselective Allylic and cis-Vinylic Deprotonation of Allyl Amides and Allylamines Fredrik Haeffner, Madeleine A. Jacobson, Ivan Keresztes, and Paul G. Williard pp 17032–17039 DOI: 10.1021/ja0487731 Supporting Info

Structure−Property Correlations in Polypropylene from Metallocene Catalysts:  Stereodefective, Regioregular Isotactic Polypropylene Claudio De Rosa, Finizia Auriemma, Annunziata Di Capua, Luigi Resconi, Simona Guidotti, Isabella Camurati, Ilya E. Nifant'ev, and Ilya P. Laishevtsev pp 17040–17049 DOI: 10.1021/ja045684f Supporting Info

Assembly of a Supramolecular Capsule on a Molecular Printboard Francesca Corbellini, Alart Mulder, Andrea Sartori, Manon J. W. Ludden, Alessandro Casnati, Rocco Ungaro, Jurriaan Huskens, Mercedes Crego-Calama, and David N. Reinhoudt pp 17050–17058 DOI: 10.1021/ja046780j

Dehydrogenation versus Oxygenation in Two-Electron and Four-Electron Reduction of Dioxygen by 9-Alkyl-10-methyl-9,10-dihydroacridines Catalyzed by Monomeric Cobalt Porphyrins and Cofacial Dicobalt Porphyrins in the Presence of Perchloric Acid Shunichi Fukuzumi, Ken Okamoto, Yoshihiro Tokuda, Claude P. Gros, and Roger Guilard pp 17059–17066 DOI: 10.1021/ja046422g

Diphosphine−Phosphenium Coordination Complexes Representing Monocations with Pendant Donors and Ligand Tethered Dications Neil Burford, David E. Herbert, Paul J. Ragogna, Robert McDonald, and Michael J. Ferguson pp 17067–17073 DOI: 10.1021/ja0452121 Supporting Info

Photochemistry of Artificial Photosynthetic Reaction Centers in Liquid Crystals Probed by Multifrequency EPR (9.5 and 95 GHz) Marilena Di Valentin, Arianna Bisol, Giancarlo Agostini, Michael Fuhs, Paul A. Liddell, Ana L. Moore, Thomas A. Moore, Devens Gust, and Donatella Carbonera pp 17074–17086 DOI: 10.1021/ja046067u